CN109563211B - 新型聚丙烯酸酯-聚硅烷嵌段共聚物 - Google Patents

新型聚丙烯酸酯-聚硅烷嵌段共聚物 Download PDF

Info

Publication number
CN109563211B
CN109563211B CN201780046182.8A CN201780046182A CN109563211B CN 109563211 B CN109563211 B CN 109563211B CN 201780046182 A CN201780046182 A CN 201780046182A CN 109563211 B CN109563211 B CN 109563211B
Authority
CN
China
Prior art keywords
polyacrylate
block copolymer
range
polysilane
integer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780046182.8A
Other languages
English (en)
Chinese (zh)
Other versions
CN109563211A (zh
Inventor
S·D·潘迪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Publication of CN109563211A publication Critical patent/CN109563211A/zh
Application granted granted Critical
Publication of CN109563211B publication Critical patent/CN109563211B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10—Esters
    • C08F120/12—Esters of monohydric alcohols or phenols
    • C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F130/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F130/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F130/08—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/08—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
    • C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8093—Compounds containing active methylene groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/837—Chemically modified polymers by silicon containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Silicon Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
CN201780046182.8A 2016-07-27 2017-07-17 新型聚丙烯酸酯-聚硅烷嵌段共聚物 Active CN109563211B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16181390.2A EP3275909A1 (en) 2016-07-27 2016-07-27 Novel polyacrylate-polysilane block copolymers
EP16181390.2 2016-07-27
PCT/EP2017/068048 WO2018019642A1 (en) 2016-07-27 2017-07-17 Novel polyacrylate-polysilane block copolymers

Publications (2)

Publication Number Publication Date
CN109563211A CN109563211A (zh) 2019-04-02
CN109563211B true CN109563211B (zh) 2022-03-22

Family

ID=56555224

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780046182.8A Active CN109563211B (zh) 2016-07-27 2017-07-17 新型聚丙烯酸酯-聚硅烷嵌段共聚物

Country Status (14)

Country Link
US (1) US10968321B2 (enExample)
EP (2) EP3275909A1 (enExample)
JP (1) JP7068269B2 (enExample)
KR (1) KR102385976B1 (enExample)
CN (1) CN109563211B (enExample)
BR (1) BR112019000358B1 (enExample)
CA (1) CA3030061C (enExample)
ES (1) ES2910984T3 (enExample)
MX (1) MX2019001091A (enExample)
PL (1) PL3491035T3 (enExample)
RU (1) RU2019105172A (enExample)
SG (1) SG11201811317UA (enExample)
TW (1) TWI803464B (enExample)
WO (1) WO2018019642A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7480168B2 (ja) * 2019-03-14 2024-05-09 ダウ シリコーンズ コーポレーション ポリオルガノシロキサンハイブリッド感圧接着剤並びにその調製方法及び使用方法
EP4061863B1 (en) * 2019-11-21 2025-07-16 Dow Global Technologies LLC Multistage polymer
CN114591452B (zh) * 2022-03-14 2023-10-17 内蒙古扬帆新材料有限公司 一种含有α-氨基酮多官能化大分子光引发剂及其制造方法和应用
WO2025070541A1 (ja) * 2023-09-25 2025-04-03 国立大学法人京都大学 コーティング組成物

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0412770A1 (en) * 1989-08-07 1991-02-13 Minnesota Mining And Manufacturing Company Polysiloxane-grafted copolymer topical binder composition with novel hydrophilic monomers and method of coating therewith
US5290548A (en) * 1987-04-10 1994-03-01 University Of Florida Surface modified ocular implants, surgical instruments, devices, prostheses, contact lenses and the like
US20060210929A1 (en) * 2005-03-15 2006-09-21 Canon Kabushiki Kaisha Photosensitive composition and forming process of structured material using the composition
JP2009521489A (ja) * 2005-12-21 2009-06-04 アボット ラボラトリーズ 室温硬化性ポリマー
CN102803420A (zh) * 2009-04-24 2012-11-28 汉高公司 基于硅氧烷丙烯酸杂化聚合物的粘合剂
CN102875745A (zh) * 2011-07-14 2013-01-16 京东方科技集团股份有限公司 一种碱可溶性树脂和含有其的感光性树脂组合物及其应用
CN102947370A (zh) * 2010-04-23 2013-02-27 汉高公司 硅酮-丙烯酸共聚物
US20130209693A1 (en) * 2012-02-10 2013-08-15 Rohm And Haas Electronic Materials Llc Block copolymer and methods relating thereto
CN103261236A (zh) * 2010-08-25 2013-08-21 汉高公司 在链末端附近具有湿气可固化官能团簇的可固化组合物
CN103590248A (zh) * 2013-11-14 2014-02-19 淮安凯悦科技开发有限公司 水性肤感耐刮无手痕合成革表面处理剂
CN103626933A (zh) * 2013-10-14 2014-03-12 杭州师范大学 一种聚倍半硅氧烷-聚丙烯酸酯-纳米SiO2复合乳液及其制备方法与应用
CN104045761A (zh) * 2014-06-16 2014-09-17 张家港康得新光电材料有限公司 哑光耐划伤水性树脂及其制备方法
CN104395364A (zh) * 2012-08-03 2015-03-04 日油株式会社 由聚烯烃树脂组成的成型体的表面物性改良剂组合物、含有该组合物的树脂组合物及其树脂成型体
WO2015100194A1 (en) * 2013-12-27 2015-07-02 3M Innovative Properties Company Moisture-curable, semi-crystalline (meth)acrylic oligomers and methods of making and using same in adhesive articles

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS644640A (en) * 1987-06-27 1989-01-09 Mitsubishi Rayon Co Block copolymer resin composition
JP2766300B2 (ja) * 1989-03-31 1998-06-18 東芝シリコーン株式会社 （メタ）アクリレート共重合体
JP4573929B2 (ja) * 1999-09-06 2010-11-04 中国塗料株式会社 ポリシロキサン−アクリル樹脂ブロック共重合体組成物、防汚剤組成物、防汚塗膜、防汚処理基材、並びに基材の防汚処理方法
JP2006293326A (ja) * 2005-03-15 2006-10-26 Canon Inc 感光性組成物及び該組成物を用いた構造体の製造方法
JP5825640B2 (ja) * 2010-03-02 2015-12-02 大日精化工業株式会社 アルコキシシリル基含有ブロックコポリマー、該ブロックコポリマーの製造方法、樹脂処理顔料、および顔料分散体
JP6379979B2 (ja) 2013-10-31 2018-08-29 日信化学工業株式会社 アクリル変性シリコーン樹脂含有熱可塑性樹脂組成物
JP2017102270A (ja) * 2015-12-02 2017-06-08 セイコーエプソン株式会社 電気泳動粒子の製造方法、電気泳動粒子、電気泳動分散液、電気泳動シート、電気泳動装置および電子機器

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290548A (en) * 1987-04-10 1994-03-01 University Of Florida Surface modified ocular implants, surgical instruments, devices, prostheses, contact lenses and the like
EP0412770A1 (en) * 1989-08-07 1991-02-13 Minnesota Mining And Manufacturing Company Polysiloxane-grafted copolymer topical binder composition with novel hydrophilic monomers and method of coating therewith
US20060210929A1 (en) * 2005-03-15 2006-09-21 Canon Kabushiki Kaisha Photosensitive composition and forming process of structured material using the composition
JP2009521489A (ja) * 2005-12-21 2009-06-04 アボット ラボラトリーズ 室温硬化性ポリマー
CN102803420A (zh) * 2009-04-24 2012-11-28 汉高公司 基于硅氧烷丙烯酸杂化聚合物的粘合剂
CN102947370A (zh) * 2010-04-23 2013-02-27 汉高公司 硅酮-丙烯酸共聚物
CN103261236A (zh) * 2010-08-25 2013-08-21 汉高公司 在链末端附近具有湿气可固化官能团簇的可固化组合物
CN102875745A (zh) * 2011-07-14 2013-01-16 京东方科技集团股份有限公司 一种碱可溶性树脂和含有其的感光性树脂组合物及其应用
US20130209693A1 (en) * 2012-02-10 2013-08-15 Rohm And Haas Electronic Materials Llc Block copolymer and methods relating thereto
CN104395364A (zh) * 2012-08-03 2015-03-04 日油株式会社 由聚烯烃树脂组成的成型体的表面物性改良剂组合物、含有该组合物的树脂组合物及其树脂成型体
CN103626933A (zh) * 2013-10-14 2014-03-12 杭州师范大学 一种聚倍半硅氧烷-聚丙烯酸酯-纳米SiO2复合乳液及其制备方法与应用
CN103590248A (zh) * 2013-11-14 2014-02-19 淮安凯悦科技开发有限公司 水性肤感耐刮无手痕合成革表面处理剂
WO2015100194A1 (en) * 2013-12-27 2015-07-02 3M Innovative Properties Company Moisture-curable, semi-crystalline (meth)acrylic oligomers and methods of making and using same in adhesive articles
CN104045761A (zh) * 2014-06-16 2014-09-17 张家港康得新光电材料有限公司 哑光耐划伤水性树脂及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Ve＇ronique Mellon et al.Block Copolymers of ç-Methacryloxypropyltrimethoxysilane and Methyl Methacrylate by RAFT Polymerization. A New Class of Polymeric Precursors for the Sol-Gel Process.《Macromolecules》.2005, *
有机硅改性丙烯酸酯涂料的性能研究;严微;《化学与生物工程》;20111231;第28卷(第9期);第32-35页 *
聚硅氧烷-g-聚丙烯酸酯乳液接枝共聚的研究;吴福迪 等;《高分子材料科学与工程》;19990531;第15卷(第3期);第61-63,67页 *

Also Published As

Publication number Publication date
JP2019525985A (ja) 2019-09-12
CA3030061C (en) 2023-12-19
MX2019001091A (es) 2019-07-04
RU2019105172A (ru) 2020-08-27
SG11201811317UA (en) 2019-01-30
BR112019000358A2 (pt) 2019-04-16
BR112019000358B1 (pt) 2022-10-25
KR20190035793A (ko) 2019-04-03
CN109563211A (zh) 2019-04-02
US20190161584A1 (en) 2019-05-30
ES2910984T3 (es) 2022-05-17
TWI803464B (zh) 2023-06-01
CA3030061A1 (en) 2018-02-01
EP3491035B1 (en) 2022-02-16
EP3275909A1 (en) 2018-01-31
EP3491035A1 (en) 2019-06-05
PL3491035T3 (pl) 2022-06-27
JP7068269B2 (ja) 2022-05-16
RU2019105172A3 (enExample) 2020-11-23
TW201811874A (zh) 2018-04-01
KR102385976B1 (ko) 2022-04-14
WO2018019642A1 (en) 2018-02-01
US10968321B2 (en) 2021-04-06

Similar Documents

Publication Publication Date Title
CN102046725B (zh) 可用水交联的密封物质
JP5637687B2 (ja) 高い引掻耐性及び耐候性を有する被覆剤
TWI803464B (zh) 新穎聚丙烯酸酯-聚矽烷嵌段共聚物
JP7239901B2 (ja) 硬化性樹脂組成物、並びに、ブロック共重合体及びその製造方法
US20100222504A1 (en) Silane-substituted raft-reagents and silane-cross-linkable polymers
WO2013055572A1 (en) Preparation of novel fluorocompounds, methods of preparation and compositions made therefrom
JPWO2018181251A1 (ja) 硬化性樹脂組成物及びその製造方法
JPH04103668A (ja) 硬化性樹脂組成物
CA1303620C (en) Reaction products of mercapto-functional monohydric alcohols and vinyl silanes, and nco-functional compounds therefrom
JPH05194880A (ja) 塗料用硬化性組成物
JP2024000050A (ja) ビニル系重合体及びその製造方法並びに硬化性樹脂組成物
JP6900663B2 (ja) 共重合体
JP2673227B2 (ja) 被覆用樹脂組成物
IL39270A (en) Polymers of alkyl methacrylates their preparation and use
JPH1180169A (ja) 新規なポリシロキサン及びこれを用いた樹脂組成物
JPH01254719A (ja) ポリシロキサン基含有重合体
JP2001181551A (ja) フッ素系塗料用組成物および該組成物の塗装方法
JP3124360B2 (ja) 塗料用硬化性組成物
JPH0120662B2 (enExample)
JPH0533247B2 (enExample)
JP5328067B2 (ja) 樹脂組成物および該樹脂組成物を塗布してなる塗装物
JP2003155469A (ja) シーリング材組成物
JPH0249079A (ja) 被覆組成物
JP3212718B2 (ja) 硬化性組成物
JP2005015512A (ja) 特定の分子構造を有するグラフト共重合体の製造方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant