CN107848249A - 片状成型体及层叠体 - Google Patents
片状成型体及层叠体 Download PDFInfo
- Publication number
- CN107848249A CN107848249A CN201680042552.6A CN201680042552A CN107848249A CN 107848249 A CN107848249 A CN 107848249A CN 201680042552 A CN201680042552 A CN 201680042552A CN 107848249 A CN107848249 A CN 107848249A
- Authority
- CN
- China
- Prior art keywords
- sheet
- formed body
- resin
- line
- vinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 116
- 239000011347 resin Substances 0.000 claims abstract description 116
- 238000009958 sewing Methods 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000012545 processing Methods 0.000 claims abstract description 20
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 83
- 239000000843 powder Substances 0.000 claims description 52
- 239000011342 resin composition Substances 0.000 claims description 45
- 238000007493 shaping process Methods 0.000 claims description 28
- 239000004014 plasticizer Substances 0.000 claims description 20
- 239000004677 Nylon Substances 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 19
- 229920001778 nylon Polymers 0.000 claims description 19
- 229920000728 polyester Polymers 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 210000003195 fascia Anatomy 0.000 claims description 6
- 229920005749 polyurethane resin Polymers 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229920005672 polyolefin resin Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 abstract description 26
- 239000004814 polyurethane Substances 0.000 abstract description 26
- 239000002994 raw material Substances 0.000 abstract description 15
- 238000013461 design Methods 0.000 abstract description 13
- 238000004519 manufacturing process Methods 0.000 abstract description 13
- 150000002148 esters Chemical class 0.000 description 44
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 42
- -1 alkenes hydro carbons Chemical class 0.000 description 41
- 239000000463 material Substances 0.000 description 28
- 239000002585 base Substances 0.000 description 22
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 239000000049 pigment Substances 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 19
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 19
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 229910001701 hydrotalcite Inorganic materials 0.000 description 13
- 229960001545 hydrotalcite Drugs 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 8
- 210000002615 epidermis Anatomy 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical group N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000007767 bonding agent Substances 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004088 foaming agent Substances 0.000 description 5
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229920002397 thermoplastic olefin Polymers 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 125000005591 trimellitate group Chemical group 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920000305 Nylon 6,10 Polymers 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical class [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical class OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- IMYZYCNQZDBZBQ-SJORKVTESA-N (9S,10R)-epoxyoctadecanoic acid Chemical compound CCCCCCCC[C@H]1O[C@H]1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-SJORKVTESA-N 0.000 description 2
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 2
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- UYXTWWCETRIEDR-UHFFFAOYSA-N Tributyrin Chemical compound CCCC(=O)OCC(OC(=O)CCC)COC(=O)CCC UYXTWWCETRIEDR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- GCAIEATUVJFSMC-UHFFFAOYSA-N benzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- FTJPDYTXORWVLU-UHFFFAOYSA-N dotetracontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC FTJPDYTXORWVLU-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000012945 sealing adhesive Substances 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NEOGGGHDLGYATP-UHFFFAOYSA-N 1,6-dimethylimidazo[4,5-b]pyridin-2-amine Chemical compound CC1=CN=C2N=C(N)N(C)C2=C1 NEOGGGHDLGYATP-UHFFFAOYSA-N 0.000 description 1
- LRQGFQDEQPZDQC-UHFFFAOYSA-N 1-Phenyl-1,3-eicosanedione Chemical compound CCCCCCCCCCCCCCCCCC(=O)CC(=O)C1=CC=CC=C1 LRQGFQDEQPZDQC-UHFFFAOYSA-N 0.000 description 1
- UKDKWYQGLUUPBF-UHFFFAOYSA-N 1-ethenoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOC=C UKDKWYQGLUUPBF-UHFFFAOYSA-N 0.000 description 1
- DBLXXVQTWJFJFI-UHFFFAOYSA-N 1-phenyloctadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 DBLXXVQTWJFJFI-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Natural products CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 1
- ZRXHQNQYIKVKNQ-UHFFFAOYSA-N 2-ethylhexanoic acid;zinc Chemical compound [Zn].CCCCC(CC)C(O)=O ZRXHQNQYIKVKNQ-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- AUZRCMMVHXRSGT-UHFFFAOYSA-N 2-methylpropane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CC(C)CS(O)(=O)=O AUZRCMMVHXRSGT-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- NUCFNMOPTGEHQA-UHFFFAOYSA-N 3-bromo-2h-pyrazolo[4,3-c]pyridine Chemical compound C1=NC=C2C(Br)=NNC2=C1 NUCFNMOPTGEHQA-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical class C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- ULVDMKRXBIKOMK-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2,3-dihydroisoindol-1-one Chemical class ClC1=C(Cl)C(Cl)=C2CNC(=O)C2=C1Cl ULVDMKRXBIKOMK-UHFFFAOYSA-N 0.000 description 1
- LEUWBMAQQQENOO-UHFFFAOYSA-N 4-(4-chlorophenyl)-6-methyl-2-oxo-3,4-dihydro-1h-pyridine-5-carboxylic acid Chemical compound C1C(=O)NC(C)=C(C(O)=O)C1C1=CC=C(Cl)C=C1 LEUWBMAQQQENOO-UHFFFAOYSA-N 0.000 description 1
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 description 1
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 description 1
- UKWUOTZGXIZAJC-UHFFFAOYSA-N 4-nitrosalicylic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1O UKWUOTZGXIZAJC-UHFFFAOYSA-N 0.000 description 1
- MEJAPGGFIJZHEJ-UHFFFAOYSA-N 5-acetamido-1,3,4-thiadiazole-2-sulfonyl chloride Chemical compound CC(=O)NC1=NN=C(S(Cl)(=O)=O)S1 MEJAPGGFIJZHEJ-UHFFFAOYSA-N 0.000 description 1
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229910020038 Mg6Al2 Inorganic materials 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- MKUXAQIIEYXACX-UHFFFAOYSA-N aciclovir Chemical class N1C(N)=NC(=O)C2=C1N(COCCO)C=N2 MKUXAQIIEYXACX-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001278 adipic acid derivatives Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- BHDOPTZJCSDVJE-CVBJKYQLSA-L barium(2+);(z)-octadec-9-enoate Chemical compound [Ba+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O BHDOPTZJCSDVJE-CVBJKYQLSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- XRFYGUOAWVKOCQ-UHFFFAOYSA-N bis(8-methylnonyl) cyclohex-4-ene-1,2-dicarboxylate Chemical compound CC(C)CCCCCCCOC(=O)C1CC=CCC1C(=O)OCCCCCCCC(C)C XRFYGUOAWVKOCQ-UHFFFAOYSA-N 0.000 description 1
- 125000006226 butoxyethyl group Chemical group 0.000 description 1
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical class CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- CBPRYBYRYMOWDF-UHFFFAOYSA-N ethyl-dimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC[N+](C)(C)CCCNC(=O)C=C CBPRYBYRYMOWDF-UHFFFAOYSA-N 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 150000002237 fumaric acid derivatives Chemical class 0.000 description 1
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 229910001853 inorganic hydroxide Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RWZYAGGXGHYGMB-UHFFFAOYSA-N o-aminobenzenecarboxylic acid Natural products NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- RIBCJYJORLBDDA-UHFFFAOYSA-N octadecanoic acid;strontium Chemical compound [Sr].CCCCCCCCCCCCCCCCCC(O)=O RIBCJYJORLBDDA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- ODFKDYBAQKFTOU-KTKRTIGZSA-N phenyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC1=CC=CC=C1 ODFKDYBAQKFTOU-KTKRTIGZSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006350 polyacrylonitrile resin Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229910001753 sapphirine Inorganic materials 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000003329 sebacic acid derivatives Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- FJFYFBRNDHRTHL-UHFFFAOYSA-N tris(8-methylnonyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)=C1 FJFYFBRNDHRTHL-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/14—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/18—Slush casting, i.e. pouring moulding material into a hollow mould with excess material being poured off
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/14—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements the preformed part being a lining
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/35—Component parts; Details or accessories
- B29C44/351—Means for preventing foam to leak out from the foaming device during foaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
- B32B7/09—Interconnection of layers by mechanical means by stitching, needling or sewing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K37/00—Dashboards
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K37/00—Dashboards
- B60K37/20—Dashboard panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
- B60R13/0256—Dashboard liners
-
- D—TEXTILES; PAPER
- D05—SEWING; EMBROIDERING; TUFTING
- D05B—SEWING
- D05B23/00—Sewing apparatus or machines not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/56—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
- B29C65/62—Stitching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/72—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by combined operations or combined techniques, e.g. welding and stitching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3008—Instrument panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/102—Oxide or hydroxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0278—Polyurethane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Transportation (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Instrument Panels (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供片状成型体以及具有该片状成型体和发泡聚氨酯层的层叠体，该片状成型体是对片状物实施缝制加工而成的，在缝制加工的至少一部分使用由包含线用树脂的线用树脂组合物形成的、熔点为200℃以下的线，该层叠体具有该片状成型体和发泡聚氨酯成型体，该片状成型体能够使用廉价且简易的方法制造，设计性不会随时间受损，并且在将发泡聚氨酯层内衬时能够防止原料等从缝制处流出。
Description
技术领域
本发明涉及用于汽车仪表板等的片状成型体及层叠体。
背景技术
汽车仪表板具有如下结构：发泡聚氨酯层设置在由氯乙烯树脂、热塑性聚氨酯树脂、热塑性烯烃树脂等合成树脂或皮革形成的表皮与基材之间。
在汽车仪表板中，为了提高设计性、商品性，有时会对表皮实施缝线图案等的缝制加工。在这样的情况下，存在这样的问题：在表皮的里侧形成发泡聚氨酯层时，发泡聚氨酯层的原料等从缝制局部的孔向表侧流出。由于发泡聚氨酯层的原料等流出的部位会变色，因此导致汽车仪表板的外观受损。
作为防止在表皮的里侧形成发泡聚氨酯层时的原料等的流出的方法，例如专利文献1公开了如下内容：为了防止发泡剂等从由氯乙烯等塑料片形成的表皮材料的针脚泄漏，通过从表皮材料的里侧贴上密封用胶带的方法、进行使粘接剂涂敷并干燥的交联固化处理的方法、在缝线为树脂线的情况下从里侧加热树脂线而将其熔化的方法等，从而进行针脚的密封处理。此外，专利文献2公开了如下内容：在熔融状态的热塑性树脂材料的缝制处缝纫上线和下线，使该缝制处固化而使热塑性树脂材料与上线及下线成为一体，从而将缝纫于树脂材料的缝制线的外周面与树脂材料的缝隙密封。
现有技术文献
专利文献
专利文献1：日本特开平3-1938号公报；
专利文献2：日本特开2014-19060号公报。
发明内容
发明要解决的问题
在如专利文献1、2那样表皮材料为树脂制的情况下，为了使表皮材料的柔软性等提高，通常可添加增塑剂等各种添加剂。该各种成分因热等会随时间向发泡聚氨酯层移动，因此有时表皮材料会随时间而变色。
在如专利文献1那样使用密封用胶带、粘接剂的情况下，存在这样的问题：由于在使用这些材料处各种成分的移动速度变化，因此该处的色调的变化与该处周围不同，会暴露在里侧配置有胶带、粘接剂的情况。此外，如专利文献1那样想要熔化树脂线而进行密封的情况下，存在表皮材料同时熔融、分解等而导致设计性受损的问题。
另一方面，根据专利文献2所记载的方法，虽然不需要密封表皮材料的里侧，因此不会产生上述专利文献1那样的问题，但由于需要通过加热装置或保温的缝制针而使缝制处熔融，因此需要高度的温度管理，存在制造装置和制造工序复杂化，成本高的问题。
因此本发明的课题在于提供能够使用廉价且简易的方法制造、设计性不会随时间受损、并且在将发泡聚氨酯层内衬时能够防止原料等从缝制处流出的片状成型体，以及具有该片状成型体和发泡聚氨酯层的层叠体。
用于解决问题的方案
即，本发明的第1方式为对片状物实施缝制加工而成的片状成型体，在上述缝制加工的至少一部分使用由包含线用树脂的线用树脂组合物形成的、熔点为200℃以下的线。
在本发明中，优选构成上述线用树脂组合物的线用树脂以聚酯和尼龙作为主成分。在本发明中，线用树脂“以尼龙和聚酯作为主成分”意味着线用树脂所包含的尼龙成分和聚酯成分的合计相对于100质量％的线用树脂为80质量％以上。
在本发明中，优选上述线用树脂含有50质量％以上的熔点为200℃以下的尼龙。
在本发明中，可以在上述片状物的至少一面熔融粘合有上述线。
在本发明中，上述片状物可以将片用树脂组合物作为主成分。在本发明中，片状物“以片用树脂组合物作为主成分”意味着片状物相对于100质量％的该片状物含有80质量％以上的片用树脂组合物。
在本发明中，上述片用树脂组合物是粉体成型用树脂组合物，上述片状物可以是对上述粉体成型用树脂组合物进行粉末搪塑成型而成的。
优选上述粉体成型用树脂组合物包含选自含有氯乙烯树脂的氯乙烯树脂组合物、含有聚氨酯树脂的聚氨酯树脂组合物以及含有烯烃树脂的烯烃树脂组合物中的至少1种。
在本发明中，优选上述粉体成型用树脂组合物为上述氯乙烯树脂组合物。
在本发明中，优选上述氯乙烯树脂的平均聚合度为800～5000。
在本发明中，优选上述粉体成型用树脂组合物中，相对于100质量份的上述氯乙烯树脂包含30～200质量份的增塑剂。
在本发明中，优选上述缝制加工使用上线和下线实施，在上述上线和上述下线中，至少上述下线是由包含上述线用树脂的上述线用树脂组合物形成的、熔点为200℃以下的上述线。另外，此处所谓的“上线”是指在设置本发明的第1方式的片状成型体或后述的本发明的第2方式的层叠体时配置在设计面(可从外部看到的面，下同)侧的线，“下线”是指在设置本发明的第1方式的片状成型体或后述的本发明的第2方式的层叠体时配置在与设计面相对侧的线。
本发明的第2方式是具有上述本发明的第1方式的片状成型体和发泡聚氨酯成型体的层叠体。
本发明的第2方式的层叠体能够优选用作汽车仪表板用层叠体。
发明效果
根据本发明，能够提供能够使用廉价且简易的方法制造、设计性不会随时间受损、并且在将发泡聚氨酯层内衬时能够防止原料等从缝制处流出的片状成型体，以及具有该片状成型体和发泡聚氨酯层的层叠体。
附图说明
图1为本发明的一个实施方式的层叠体10的立体图。
图2为本发明的一个实施方式的层叠体10的缝制处的剖面图，为沿图1中II-II所示的线的剖面图。
具体实施方式
以下，对于本发明的实施方式进行说明。另外，以下所示方式为本发明的例示，本发明不限定于以下所示的方式。此外，在以下所示的图中，存在将一部分的构件省略、夸张而示出的情况。
<片状成型体及层叠体>
本发明的片状成型体是对片状物实施缝制加工而成的，在缝制加工的至少一部分使用由包含线用树脂的线用树脂组合物形成的、熔点为200℃以下的线。此外，本发明的层叠体具有由该片状成型体形成的表皮层和由发泡聚氨酯成型体形成的发泡聚氨酯层。
以下，参照图1、2说明本发明的一个实施方式的片状成型体和层叠体。
图1为本发明的一个实施方式的层叠体10的立体图。图2为沿图1中II-II所示的线的层叠体10的剖面图。在图2的剖面图中，着重于包含重复结构的一部分，而省略其两端部。
如图1所示，层叠体10具有依次层叠有片状成型体1、发泡聚氨酯成型体4以及基材5的结构，上述片状成型体1是使用线3对片状物2实施缝制加工(缝线S)而成的。此外，为了对层叠体10赋予由片状物1形成的表皮材料彼此被缝合那样的美感，沿着缝线S形成凹槽6。如图2的剖面图所示，线3包含上线3a和下线3b，缝线S通过使用该上线3a和下线3b的双线锁缝方式而实施于片状物2。如图2所示，在层叠体10中，上线3a构成层叠体10的设计面(指在设置层叠体时可从外部看到的面。下同)的一部分，发挥提高层叠体10的设计性的作用。另一方面，下线3b通常不会从外部看到，配置在发泡聚氨酯成型体4所层叠的一侧，主要发挥在层叠发泡聚氨酯成型体4时防止原料等从缝制处7流出的作用。
<片状物>
本发明的片状物可用作汽车用的仪表板、座间储物箱(Console Box)或车门内饰、或者家具等住宅用内装品等的表皮材料，是提高设计性、商品性的构件。
本发明所使用的片状物的材质没有特别限定，可举出氯乙烯树脂、热塑性聚氨酯树脂、热塑性烯烃树脂等树脂或皮革等。在片状物为树脂制的方式中，片状物所包含的片用树脂组合物的量相对于100质量％的该片状物优选为80质量％以上，更优选为85质量％以上，进一步优选为90质量％以上，特别优选为100质量％。
片用树脂组合物只要是能够成型为片状的树脂组合物则没有特别限定，从成型加工性优异、石油依赖低而环境负荷小的观点出发，优选为粉体成型用树脂组合物，片状物优选为对该粉体成型用树脂组合物进行粉末搪塑成型而得到的。作为粉体成型用树脂组合物，可举出含有氯乙烯树脂(PVC)的氯乙烯树脂组合物、含有聚氨酯树脂(优选为热塑性聚氨酯树脂(TPU))的聚氨酯树脂组合物、含有烯烃树脂(优选为热塑性烯烃树脂(TPO))的烯烃树脂组合物等，其中优选使用氯乙烯树脂组合物。以下，将用作粉体成型用树脂组合物的氯乙烯树脂组合物称为“粉体成型用氯乙烯树脂组合物”。
粉体成型用氯乙烯树脂组合物所含有的氯乙烯树脂(a)优选包含平均聚合度为800～5000的氯乙烯树脂粒子(a1)。构成该氯乙烯树脂粒子(a1)的氯乙烯树脂除了包含氯乙烯的均聚物之外，还包含优选含有50质量％以上的氯乙烯单元、更优选含有70质量％以上的氯乙烯单元的共聚物。氯乙烯共聚物的共聚单体的具体例子为：乙烯、丙烯等烯烃类；烯丙基氯、偏氯乙烯、乙烯基氟、三氟氯乙烯等卤化烯烃类；醋酸乙烯酯、丙酸乙烯酯等羧酸乙烯酯类；异丁基乙烯基醚、十六烷基乙烯基醚等乙烯基醚类；烯丙基-3-氯-2-氧基丙基醚、烯丙基缩水甘油醚等烯丙基醚类；丙烯酸、马来酸、衣康酸、丙烯酸-2-羟基乙酯、甲基丙烯酸甲酯、马来酸单甲酯、马来酸二乙酯、马来酸酐等不饱和羧酸、其酯或其酸酐类；丙烯腈、甲基丙烯腈等不饱和腈类；丙烯酰胺、N-羟甲基丙烯酰胺、丙烯酰胺基-2-甲基丙磺酸、(甲基)丙烯酰胺基丙基三甲基氯化铵等丙烯酰胺类；烯丙基胺安息香酸盐、二烯丙基二甲基氯化铵等烯丙基胺及其衍生物类等。以上所例示的单体只不过是能够与氯乙烯共聚的单体的一部分，可使用近畿化学协会乙烯基部汇编《聚氯乙烯》日刊工业新闻社(1988年)第75～104页所例示的各种单体。可使用这些单体的1种或2种以上。上述构成氯乙烯树脂粒子(a1)的氯乙烯树脂还包含将(1)氯乙烯或(2)氯乙烯和上述的能够共聚的单体接枝聚合于乙烯-醋酸乙烯酯共聚物、乙烯-甲基丙烯酸甲酯共聚物、乙烯-丙烯酸乙酯共聚物、氯化聚乙烯等树脂的树脂。
上述构成氯乙烯树脂粒子(a1)的氯乙烯树脂可通过悬浮聚合法、乳液聚合法、溶液聚合法、本体聚合法等现有已知的任一种制造法而制造。特别优选通过悬浮聚合法而制造的氯乙烯树脂。
上述氯乙烯树脂粒子(a1)的平均聚合度优选为800～5000，更优选为800～3000，进一步优选为800～2000。另外，平均聚合度按照JIS K 6720-2而测定。
上述氯乙烯树脂粒子(a1)的平均粒径没有特别限定。该平均粒径优选为50μm以上且500μm以下，更优选为50μm以上且250μm以下，进一步优选为100μm以上且200μm以下。当氯乙烯树脂粒子(a1)的平均粒径为上述范围时，粉体成型用氯乙烯树脂组合物的粉体流动性提高，并且，对上述粉体成型用氯乙烯树脂组合物进行粉体成型而成的氯乙烯树脂成型体的平滑性提高。另外，平均粒径按照JIS Z8801所规定的使用JIS标准筛的筛分法而测定。
氯乙烯树脂(a)根据需要可含有氯乙烯树脂微粒(a2)。氯乙烯树脂微粒(a2)作为使粉体成型用氯乙烯树脂组合物的粉体流动性提高的隔离剂而发挥功能。
构成上述氯乙烯树脂微粒(a2)的氯乙烯树脂可通过悬浮聚合法、乳液聚合法、溶液聚合法、本体聚合法等现有已知的任一种制造法而制造。特别优选通过乳液聚合法而制造的氯乙烯树脂。
构成上述氯乙烯树脂微粒(a2)的氯乙烯树脂的优选的平均聚合度为500～5000，更优选的该平均聚合度为600～3000，进一步优选的平均聚合度为700～2500。另外，平均聚合度按照JIS K 6720-2而测定。
优选上述氯乙烯树脂微粒(a2)的平均粒径为0.1μm以上且10μm以下。这是因为，粉体成型用氯乙烯树脂组合物的粉体流动性会提高。另外，平均粒径按照JIS Z8825，使用例如(株)岛津制作所制造“SALD-2300”，采用激光衍射法而测定。
100质量％的上述氯乙烯树脂(a)中的氯乙烯树脂微粒(a2)的含量优选为0～30质量％，更优选为1～30质量％，进一步优选为5～25质量％，特别优选为8～20质量％。当上述氯乙烯树脂微粒(a2)的含量为上述范围时，粉体成型用氯乙烯树脂组合物的粉体流动性良好。
上述粉体成型用氯乙烯树脂组合物优选含有增塑剂。增塑剂的具体例子为：偏苯三酸三正己酯、偏苯三酸三正庚酯、偏苯三酸三正辛酯、偏苯三酸三-(2-乙基己基)酯、偏苯三酸三正壬酯、偏苯三酸三正癸酯、偏苯三酸三异癸酯、偏苯三酸三正十一烷基酯、偏苯三酸三正十二烷基酯、偏苯三酸三正烷基(烷基的碳原子数为6～12的混合)酯、偏苯三酸三烷基(烷基的碳原子数为8～10的混合)酯、偏苯三酸三正烷基(烷基的碳原子数为8～10的混合)酯等偏苯三酸酯；均苯四甲酸四正己酯、均苯四甲酸四正庚酯、均苯四甲酸四正辛酯、均苯四甲酸四-(2-乙基己基)酯、均苯四甲酸四正壬酯、均苯四甲酸四正癸酯、均苯四甲酸四异癸酯、均苯四甲酸四正十一烷基酯、均苯四甲酸四十二烷基酯、均苯四甲酸四正烷基(烷基的碳原子数为6～12的混合)酯等均苯四甲酸酯增塑剂；环氧化大豆油、环氧化亚麻仁油等环氧化植物油；邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二-(2-乙基己基)酯、邻苯二甲酸二正辛酯、邻苯二甲酸二异丁酯、邻苯二甲酸二庚酯、邻苯二甲酸二苯酯、邻苯二甲酸二异癸酯、邻苯二甲酸双十三烷基酯、邻苯二甲酸双十一烷基酯、邻苯二甲酸二苄基酯、邻苯二甲酸丁基苄基酯、邻苯二甲酸二壬酯、邻苯二甲酸二环己酯等邻苯二甲酸衍生物；间苯二甲酸二甲酯、间苯二甲酸二-(2-乙基己基)酯、间苯二甲酸二异辛酯等间苯二甲酸衍生物；四氢邻苯二甲酸二-(2-乙基己基)酯、四氢邻苯二甲酸二正辛酯、四氢邻苯二甲酸二异癸酯等四氢邻苯二甲酸衍生物；己二酸二正丁酯、己二酸二-(2-乙基己基)酯、己二酸二异癸酯、己二酸二异壬酯等己二酸衍生物；壬二酸二-(2-乙基己基)酯、壬二酸二异辛酯、壬二酸二正己酯等壬二酸衍生物；癸二酸二正丁酯、癸二酸二-(2-乙基己基)酯、癸二酸二异癸酯、癸二酸二-(2-丁基辛基)酯等癸二酸衍生物；马来酸二正丁酯、马来酸二甲酯、马来酸二乙酯、马来酸二-(2-乙基己基)酯等马来酸衍生物；富马酸二正丁酯、富马酸二(2-乙基己基)酯等富马酸衍生物；柠檬酸三乙酯、柠檬酸三正丁酯、乙酰柠檬酸三乙酯、乙酰柠檬酸三-(2-乙基己基)酯等柠檬酸衍生物；衣康酸单甲酯、衣康酸单丁酯、衣康酸二甲酯、衣康酸二乙酯、衣康酸二丁酯、衣康酸二-(2-乙基己基)酯等衣康酸衍生物；油酸丁酯、单油酸甘油酯、单油酸二乙二醇酯等油酸衍生物；乙酰蓖麻油酸甲酯、乙酰蓖麻油酸丁酯、单蓖麻油酸甘油酯、单蓖麻油酸二乙二醇酯等蓖麻油酸衍生物；硬脂酸正丁酯、二硬脂酸二乙二醇酯等硬脂酸衍生物；单月桂酸二乙二醇酯、二壬酸二乙二醇酯、脂肪酸季戊四醇酯等其它脂肪酸衍生物；磷酸三乙酯、磷酸三丁酯、磷酸三-(2-乙基己基)酯、磷酸三丁氧基乙酯、磷酸三苯酯、磷酸甲苯基二苯酯、磷酸三甲苯酯、磷酸三(二甲苯)酯、磷酸三(氯乙基)酯等磷酸衍生物；二苯甲酸二乙二醇酯、二苯甲酸二丙二醇酯、二苯甲酸三乙二醇酯、二-(2-乙基丁酸)三乙二醇酯、二-(2-乙基己酸)三乙二醇酯、亚甲基双硫乙醇酸二丁酯等二醇衍生物；单乙酸甘油酯、三乙酸甘油酯、三丁酸甘油酯等甘油衍生物；环氧六氢邻苯二甲酸二异癸酯、环氧甘油三酯、环氧化油酸辛酯、环氧化油酸癸酯等环氧衍生物；己二酸系聚酯、癸二酸系聚酯、邻苯二甲酸系聚酯等聚酯系增塑剂等所谓的主增塑剂；以及氯化石蜡、二辛酸三乙二醇酯等二醇的脂肪酸酯；硬脂酸丁基环氧基酯、油酸苯酯、二氢松香酸甲酯等所谓的辅助增塑剂等。可以使用1种或2种以上增塑剂。在使用辅助增塑剂的情况下，优选并用与其等质量以上的主增塑剂。
上述增塑剂的相对于100质量份的氯乙烯树脂(a)的优选的含量为30～200质量份，更优选的含量为60～170质量份，进一步优选的含量为90～160质量份。当上述增塑剂的含量为上述范围时，上述增塑剂可被氯乙烯树脂(a)良好地吸收，粉体成型用氯乙烯树脂组合物的粉体成型性变得良好。
上述粉体成型用氯乙烯树脂组合物可以含有高氯酸处理水滑石作为稳定剂。高氯酸处理水滑石能够通过例如以下的方式容易地制造，即，将水滑石加入到高氯酸的稀水溶液中并进行搅拌，之后根据需要过滤、脱水或干燥，由此水滑石中的碳酸根阴离子(CO3 2-)的至少一部分被高氯酸根阴离子(ClO4 -)置换(每1摩尔碳酸根阴离子用2摩尔的高氯酸根阴离子置换)。上述水滑石与上述高氯酸的摩尔比能够任意地设定，一般相对于1摩尔的水滑石，设定高氯酸为0.1～2摩尔。
未处理(未置换)的水滑石中的碳酸根阴离子向高氯酸根阴离子的置换率优选为50摩尔％以上，更优选为70摩尔％以上，进一步优选为85摩尔％以上。此外，未处理(未置换)的水滑石中的碳酸根阴离子向高氯酸根阴离子的置换率优选为95摩尔％以下。
水滑石是通式[Mg1-xAlx(OH)2]x+[(CO3)x/2·mH2O]x-所表示的非化学计量化合物，是由带正电的基本层[Mg1-xAlx(OH)2]x+和带负电的中间层[(CO3)x/2·mH2O]x-形成的具有层状的晶体结构的无机物质。在此，x为比0大且为0.33以下的范围的数。天然的水滑石为Mg6Al2(OH)16CO3·4H2O。作为合成的水滑石，市售有Mg4.5Al2(OH)13CO3·3.5H2O。合成水滑石的合成方法记载于日本特开昭61-174270号公报中。
高氯酸处理水滑石的相对于100质量份的氯乙烯树脂(a)的优选的含量为0.5～7质量份，更优选的含量为1～6质量份，进一步优选的含量为1.5～5.5质量份。
上述粉体成型用氯乙烯树脂组合物可含有沸石作为稳定剂。沸石为通式Mx/n·[(AlO2)x·(SiO2)y]·zH2O(式中，M为原子价n的金属离子、x+y为每单位晶格的四面体个数、z为水的摩尔数)所表示的化合物，作为该式中的M的种类，可举出Na、Li、Ca、Mg、Zn等一价或二价的金属及它们的混合型。
沸石的含量没有限定于特定的范围。优选的该含量相对于100质量份的氯乙烯树脂(a)为0.1～5质量份。
上述粉体成型用氯乙烯树脂组合物可以含有脂肪酸金属盐作为稳定剂。优选的脂肪酸金属盐为一元脂肪酸金属盐，更优选的脂肪酸金属盐为碳原子数为12以上且24以下的一元脂肪酸金属盐，进一步优选的脂肪酸金属盐为碳原子数为15以上且21以下的一元脂肪酸金属盐。脂肪酸金属盐的具体例子为硬脂酸锂、硬脂酸镁、硬脂酸铝、硬脂酸钙、硬脂酸锶、硬脂酸钡、硬脂酸锌、月桂酸钙、月桂酸钡、月桂酸锌、2-乙基己酸钡、2-乙基己酸锌、蓖麻油酸钡、蓖麻油酸锌等。作为构成脂肪酸金属盐的金属，优选可生成多价阳离子的金属，更优选可生成2价阳离子的金属，进一步优选周期表第3周期～第6周期的可生成2价阳离子的金属，特别优选周期表第4周期的可生成2价阳离子的金属。最优选的脂肪酸金属盐为硬脂酸锌。
脂肪酸金属盐的相对于100质量份的氯乙烯树脂(a)的优选的含量为0.05～5质量份，更优选为0.1～1质量份，进一步优选为0.1～0.5质量份。当脂肪酸金属盐的含量为上述范围时，能够减小对粉体成型用氯乙烯树脂组合物进行粉体成型而成的片状物的色差的值。
上述粉体成型用氯乙烯树脂组合物可含有除氯乙烯树脂微粒(a2)以外的隔离剂(以下，有时称为“其它隔离剂”。)。其它隔离剂的具体例子为：碳酸钙、滑石、氧化铝等无机微粒；聚丙烯腈树脂微粒、聚(甲基)丙烯酸酯树脂微粒、聚苯乙烯树脂微粒、聚乙烯树脂微粒、聚丙烯树脂微粒、聚酯树脂微粒、聚酰胺树脂微粒等有机微粒。其中，优选平均粒径为10nm以上且100nm以下的无机微粒。
其它隔离剂的含量没有限定于特定的范围。该含量相对于100质量份的氯乙烯树脂(a)优选为20质量份以下，进一步优选为10质量份以下。
上述粉体成型用氯乙烯树脂组合物可含有着色剂、耐冲击性改良剂、除高氯酸处理水滑石以外的高氯酸化合物(高氯酸钠、高氯酸钾等)、抗氧化剂、防霉剂、阻燃剂、防静电剂、填充剂、紫外线吸收剂等光稳定剂、发泡剂、β-二酮类等其它添加剂。
着色剂的具体例子为喹吖啶酮系颜料、苝系颜料、多偶氮缩合颜料、异吲哚啉酮系颜料、铜酞菁系颜料、钛白、炭黑。可以使用1种或2种以上的颜料。喹吖啶酮系颜料是用浓硫酸处理对亚苯基邻氨基苯甲酸类而得到的，显示从黄红到红紫的色调。喹吖啶酮系颜料的具体例子为喹吖啶酮红、喹吖啶酮品红、喹吖啶酮紫。苝系颜料是通过苝-3,4,9,10-四羧酸酐与芳香族伯胺的缩合反应而得到的，显示从红色到红紫、茶色的色调。苝系颜料的具体例子为苝红、苝橙、苝栗、苝朱红、苝枣红。多偶氮缩合颜料是偶氮色素在溶剂中被缩合而被高分子量化从而得到的，显示黄、红系颜料的色调。多偶氮缩合颜料的具体例子为多偶氮红、多偶氮黄、固美透橙(Cromophtal Orange)、固美透红、固美透猩红。异吲哚啉酮系颜料是通过4,5,6,7-四氯异吲哚啉酮与芳香族伯二胺的缩合反应而得到的，显示从绿黄色到红、褐色的色调。异吲哚啉酮系颜料的具体例子为异吲哚啉酮黄。铜酞菁系颜料是将铜配位于酞菁类的颜料，显示从黄绿色到亮蓝色的色调。铜酞菁系颜料的具体例子为酞菁绿、酞菁蓝。钛白是由二氧化钛形成的白色颜料，遮盖力大，有锐钛矿型与金红石型。炭黑是以碳为主要成分的包含氧、氢、氮的黑色颜料。炭黑的具体例子为热炭黑、乙炔炭黑、槽法炭黑、炉法炭黑、灯黑、骨炭黑。
耐冲击性改良剂的具体例子为丙烯腈-丁二烯-苯乙烯共聚物、甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物、氯化聚乙烯、乙烯-醋酸乙烯酯共聚物、氯磺化聚乙烯等。能够使用1种或2种以上耐冲击性改良剂。耐冲击性改良剂在粉体成型用氯乙烯树脂组合物中呈微细的弹性粒子的不均匀相而分散。在上述粉体成型用氯乙烯树脂组合物含有氯乙烯树脂粒子(a1)的情况下，接枝聚合于该弹性粒子的链和极性基团与氯乙烯树脂粒子(a1)相溶，提高片状物的耐冲击性。
抗氧化剂的具体例子为酚系抗氧化剂、硫系抗氧化剂、磷系抗氧化剂等。
防霉剂的具体例子为脂肪族酯系防霉剂、烃系防霉剂、有机氮系防霉剂、有机氮硫系防霉剂等。
阻燃剂的具体例子为氯化石蜡等卤素系阻燃剂；磷酸酯等磷系阻燃剂；氢氧化镁、氢氧化铝等无机氢氧化物等。
防静电剂的具体例子为脂肪酸盐类、高级醇硫酸酯类、磺酸盐类等阴离子系防静电剂；脂肪族胺盐类、季铵盐类的阳离子系防静电剂；聚氧乙烯烷基醚类、聚氧乙烯烷基酚醚类等非离子系防静电剂等。
填充剂的具体例子为二氧化硅、滑石、云母、碳酸钙、黏土等。
光稳定剂的具体例子为苯并三唑系、二苯甲酮系、镍螯合物系等紫外线吸收剂、受阻胺系光稳定剂等。
发泡剂的具体例子为偶氮二甲酰胺、偶氮双异丁基腈等偶氮化合物、N,N’-二亚硝基五亚甲基四胺等亚硝基化合物、对甲苯磺酰肼、对,对-氧基双(苯磺酰肼)等磺酰肼化合物等有机发泡剂；氟利昂气体、二氧化碳、水、戊烷等挥发性烃化合物、内包了这些的微囊等气体系发泡剂等。
β-二酮类能够作为稳定剂而用于更有效地抑制片状物的初始色调的变动，该片状物是对上述粉体成型用氯乙烯树脂组合物进行粉体成型而得到的。β-二酮类的具体例子为二苯甲酰甲烷、硬脂酰苯甲酰甲烷、棕榈酰苯甲酰甲烷等。这些β-二酮类可以使用1种，也可以组合使用2种以上。
β-二酮类的含量没有限定于特定的范围。优选的该含量相对于100质量份的氯乙烯树脂(a)为0.1～5质量份。
氯乙烯树脂(a)和根据需要而添加的添加剂的混合方法没有限定。优选的混合方法为：通过干混将除增塑剂和隔离剂(氯乙烯树脂微粒(a2))以外的成分进行混合，然后依次混合增塑剂、隔离剂的方法。干混优选使用亨舍尔(Henschel)混合机。此外，干混时的温度优选为50～100℃，更优选为70～80℃。
本发明的片状成型体和层叠体所具有的片状物优选是对上述粉体成型用氯乙烯树脂组合物进行粉体成型而得到的，更优选是对上述粉体成型用氯乙烯树脂组合物进行粉末搪塑成型而得到的。粉末搪塑成型时的模具温度优选为200℃以上且300℃以下，更优选为220℃以上且280℃以下。上述片状物能够通过如下方式而合适地得到：将上述粉体成型用氯乙烯树脂组合物撒入到上述温度范围的模具中，放置5秒以上且30秒以下，然后，抖落剩余的该组合物，进一步放置30秒以上且3分钟以下后，将模具冷却至10℃以上且60℃以下，从模具脱模，由此得到片状物。另外，上述片状物适于用作汽车用的仪表板或除仪表板以外的汽车内装材料例如车门内饰等的表皮。
上述片状物的厚度没有限定于特定的范围。优选的该厚度为100μm～3mm，进一步优选的该厚度为500μm～2mm，特别优选的该厚度为800μm～1.5mm。
<线>
在本发明中，在缝制加工的至少一部分使用由包含线用树脂的线用树脂组合物形成的、熔点为200℃以下的线。另外，关于线的熔点，使用差示扫描量热仪(DSC)，在升温速度10℃/分钟、测定温度范围为30～300℃、试样量为2mg、氮环境下进行测定，以面积最大的吸热峰的显现温度作为熔点。
从对线加热的情况下的加热熔融加工性的观点出发，本发明所使用的线的熔点优选为200℃以下，更优选为180℃以下，进一步优选为170℃以下。另一方面，从缝制加工性和耐热老化性的观点出发，线的熔点优选为30℃以上，更优选为60℃以上，进一步优选为90℃以上。
构成本发明所使用的线的线用树脂组合物优选以线用树脂作为主成分。即，构成线用树脂组合物的线用树脂的含量相对于100质量％的线用树脂组合物为80质量％以上，优选为85质量％以上，更优选为90质量％以上，进一步优选为100质量％。作为线用树脂组合物的其它构成要素，可以在不损害本发明的效果的范围添加作为消光剂的二氧化钛、作为滑剂的二氧化硅、氧化铝的微粒、作为抗氧化剂的受阻酚衍生物、着色颜料等其它添加剂。作为其它添加剂的含量，相对于100质量％的线用树脂组合物，优选为20质量％以下。
本发明所使用的线用树脂只要是能够成型为线状的树脂则没有特别限定，优选以尼龙和聚酯作为主成分。即，构成线用树脂的尼龙成分和聚酯成分的合计相对于100质量％的线用树脂优选为80质量％以上，更优选为85质量％以上，进一步优选为90质量％以上，特别优选为100质量％。通过使线用树脂以尼龙和聚酯作为主成分，从而易于满足上述线的熔点的范围，易于在将发泡聚氨酯成型体内衬于片状成型体时防止原料等从缝制处流出。
另外，本发明所使用的线用树脂可以是尼龙和聚酯的混合物，也可以是尼龙和聚酯的聚合物合金。
在线用树脂包含尼龙的情况下，线用树脂优选含有熔点为200℃以下的尼龙。线用树脂所包含的熔点为200℃以下的尼龙的含量相对于100质量％的线用树脂优选为50质量％以上，更优选为65质量％以上，进一步优选为80质量％以上，特别优选为85质量％以上。通过使线用树脂所包含的熔点为200℃以下的尼龙的含量为上述下限值以上，从而易于满足上述线的熔点的范围，易于在将发泡聚氨酯成型体内衬于片状成型体时防止原料等从缝制处流出。
此外，满足上述含量且包含于线用树脂的尼龙的熔点优选为200℃以下，更优选为180℃以下，进一步优选为170℃以下。另一方面，从缝制加工性和耐热老化性的观点出发，包含于线用树脂的尼龙的熔点优选为30℃以上，更优选为60℃以上，进一步优选为90℃以上。
在线用树脂包含聚酯的情况下，包含于线用树脂的聚酯的含量相对于100质量％的线用树脂优选为50质量％以下，更优选为35质量％以下，进一步优选为20质量％以下，特别优选为15质量％以下。
本发明所使用的线的纤度优选为500dtex以上，更优选为800dtex以上，进一步优选为900dtex以上，特别优选为1000dtex以上。另外，在此所谓的纤度，不论是单线或由2根以上的单线形成的束线、绞线，均意味着作为线的总纤度。通过使线的纤度为上述下限值以上，从而在将发泡聚氨酯成型体内衬于片状成型体时易于防止原料等从缝制处流出。
如图2所示，在使用上线和下线实施缝制加工的情况下，只要至少在下线使用满足上述的条件的线即可。在仅下线使用满足上述的条件的线的情况下，上线的材料没有特别限定，能够使用现有公知的线。
另外，从缝制加工后的成型品设计性的观点出发，优选上线和下线均使用满足上述的条件的线。
根据本发明，通过使用以尼龙和聚酯作为主成分的线进行缝制加工，从而在将发泡聚氨酯成型体内衬于片状成型体时能够防止原料等从缝制处流出。因此，不必一定要通过加热等使线熔融粘合于片状物，但也可以在片状物的至少一面(至少层叠发泡聚氨酯成型体的面)将线熔融粘合。通过使线熔融粘合于片状物的至少一面，将发泡聚氨酯成型体内衬于该熔融粘合有线的面的一侧，从而即使在将发泡聚氨酯成型体内衬时熔融粘合有该线的面的一侧成为高压的情况下，也易于防止原料等从缝制处流出。
另外，在图2中例示了通过使用上线和下线的双线锁缝而实施缝制加工的方式，但缝制加工的方法不限定于本方式，也可以实施例如使用1根线的单线环缝。
<发泡聚氨酯成型体>
对于上述片状成型体，内衬有发泡聚氨酯成型体。将发泡聚氨酯成型体层叠于片状成型体的方法可举出：在分别制作片状成型体和发泡聚氨酯成型体后，通过热熔接或热粘接或使用公知的粘接剂等从而使它们贴合的方法；在片状成型体上使作为发泡聚氨酯成型体的原料的异氰酸酯类与多元醇类等反应而进行聚合，并通过公知的方法进行聚氨酯的发泡，由此层叠的方法等。后者的方法工序简单，并且在得到各种形状的层叠体的情况下都能够可靠地进行片状成型体与发泡聚氨酯成型体的粘接，因此更加优选。另外，在使用后者的方法将发泡聚氨酯成型体层叠于片状成型体的情况下，优选在设计面中至少在缝制处(例如图2的符号7)配置覆盖缝制处的构件。通过配置至少覆盖缝制处的构件，从而能够进一步提高防止聚氨酯的原料等从缝制处流出的效果。覆盖缝制处的构件只要沿着缝制处的形状则没有特别限定，可以为金属制、树脂制、木材制等。
根据本发明，通过使用上述片状成型体，从而在使用上述例示的任一方法层叠发泡聚氨酯成型体的情况下都能够防止粘接剂、发泡聚氨酯的原料等从缝制处流出。
<基材>
在本发明中，还可以在发泡聚氨酯成型体中进一步内衬基材。通过具有基材，从而能够提高层叠体的刚性。本发明所使用的基材没有特别限定，能够使用金属制、合成树脂制等公知的材料。层叠基材的方法没有特别限定，可举出：分别制作片状成型体与发泡聚氨酯成型体的层叠体以及基材后，通过热熔接或热粘接或使用公知的粘接剂等从而使它们贴合的方法；在片状成型体与基材之间使用上述公知的方法进行聚氨酯的发泡的方法等。后者的方法工序简单，并且在得到各种形状的层叠体的情况下都能够可靠地进行发泡聚氨酯成型体与基材的粘接，因此更加优选。
实施例
以下，通过实施例进一步详细说明本发明，但是本发明并不限定于这些实施例。另外，在此使用的“份”、“％”只要没有特别限定，则为质量基准。
<聚氨酯泄漏确认评价>
如在后说明的那样，制作使用规定的线对片状物实施了缝制加工而成的片状成型体以及将发泡聚氨酯成型体层叠于片状成型体而成的层叠体。计数各条件的缝线数，目视确认其中几处有聚氨酯泄漏。在此“聚氨酯泄漏”是指从设计面的缝线部能看到聚氨酯的情况。用该聚氨酯泄漏发生的缝线数除以总缝线数，求出聚氨酯泄漏发生比例。结果如表2所示。
<片状成型体及层叠体的制作>
(实施例1)
将表1所示的配合成分中除增塑剂和隔离剂以外的成分加入亨舍尔混合机进行混合，在混合物的温度上升至80℃的时刻添加增塑剂，然后进行干混(指增塑剂被氯乙烯树脂粒子吸收，上述混合物变得干爽的状态。)，然后，在混合物冷却至70℃以下的时刻添加作为隔离剂的乳液聚合氯乙烯树脂，制备粉体成型用氯乙烯树脂组合物。
将粉体成型用氯乙烯树脂组合物撒入到加热至250℃的带有纹理的模具中，放置按照以氯乙烯树脂成型片的厚度达到1mm的方式而调整的时间(具体为8～18秒)使其熔融后，抖落剩余的粉体成型用氯乙烯树脂组合物，在设定成200℃的烘箱中静置，然后在经过60秒的时刻用水将模具冷却，在模具温度冷却至40℃的时刻将150mm×200mm×1mm厚的氯乙烯树脂成型片(以下，称为“片状物”。)从模具脱模。
对片状物实施缝制加工。使用的缝纫机为JUKI公司制造LU-2860-7。缝制线使用如下，上线：大贯纤维(株)制造ACE CROWN车辆用#5(聚酯100％；熔点249℃)，下线：FUJIXLtd.制造melter No.3(尼龙85％、聚酯15％；熔点114℃、纤度1160dtex)。以缝线间隔为3针/cm、速度为3.3针/秒缝制9～10cm左右的长度。将其在同一片状物上缝制加工2根，制作实施例1的片状成型体。
接着，在200mm×300mm×10mm的模具下，放置250mm×340mm×2mm的铝板，将2张得到的片状成型体以带有纹理的面成为盖侧的方式排列于348mm×255mm×10mm的模具的盖，并分别暂时固定，将包含50质量份的丙二醇的PO·EO嵌段加成物(羟值28、末端EO单元的含量10％、内部EO单元的含量4％)、50质量份的甘油的PO·EO嵌段加成物(羟值21、末端EO单元的含量14％)、2.5质量份的水、0.2质量份的三乙二胺的乙二醇溶液(Tosoh(株)制造、商品名：“TEDA-L33”)、1.2质量份的三乙醇胺、0.5质量份的三乙胺及0.5质量份的整泡剂(信越化学工业(株)制造、商品名：“F-122”)的多元醇混合物与多亚甲基多亚苯基多异氰酸酯(polymeric MDI)以指数为98的比例进行混合而制作混合液，将其注入到模具中，用暂时固定了上述片状成型体的盖将模具密闭。5分钟后，从模具取出实施例1的层叠体，该层叠体是在由1mm厚的片状成型体形成的表皮依次内衬了9mm厚、密度0.18g/cm3的发泡聚氨酯和上述铝板的试样。
(实施例2)
对片状物实施3根缝制加工，将加热至100℃的家用熨斗对实施了该缝制加工的片状物的里面抵压30秒，使下线熔融粘合，除此以外，与实施例1同样地进行，制作实施例2的片状成型体和层叠体。
(比较例1)
作为缝制加工所使用的下线，使用大贯纤维(株)制造ACE CROWN车辆用#8(聚酯100％；熔点249℃)，对片状物实施3根缝制加工，除此以外，与实施例1同样地进行，制作比较例1的片状成型体和层叠体。
[表1]
[表2]
(表2)
如表2所示，在实施例1、2的层叠体中，在缝线局部没有发生聚氨酯泄漏。另一方面，在使用熔点超过200℃的线作为下线的比较例1的层叠体中，总缝线的半数以上的缝线发生了聚氨酯泄漏。
附图标记说明
1 片状成型体
2 片状物
3 线
3a 上线
3b 下线
4 发泡聚氨酯成型体(发泡聚氨酯层)
5 基材
6 凹槽
7 缝制处
10 层叠体
Claims (13)
1.一种片状成型体，其是对片状物实施缝制加工而成的，在所述缝制加工的至少一部分使用由包含线用树脂的线用树脂组合物形成的、熔点为200℃以下的线。
2.根据权利要求1所述的片状成型体，其中，所述线用树脂以聚酯和尼龙作为主成分。
3.根据权利要求1或2所述的片状成型体，其中，所述线用树脂含有50质量％以上的熔点为200℃以下的尼龙。
4.根据权利要求1～3中任一项所述的片状成型体，其中，在所述片状物的至少一面熔融粘合有所述线。
5.根据权利要求1～4中任一项所述的片状成型体，其中，所述片状物以片用树脂组合物作为主成分。
6.根据权利要求5所述的片状成型体，其中，所述片用树脂组合物为粉体成型用树脂组合物，
所述片状物是对所述粉体成型用树脂组合物进行粉末搪塑成型而成的。
7.根据权利要求6所述的片状成型体，其中，所述粉体成型用树脂组合物包含选自含有氯乙烯树脂的氯乙烯树脂组合物、含有聚氨酯树脂的聚氨酯树脂组合物以及含有烯烃树脂的烯烃树脂组合物中的至少1种。
8.根据权利要求7所述的片状成型体，其中，所述粉体成型用树脂组合物为所述氯乙烯树脂组合物。
9.根据权利要求7或8所述的片状成型体，其中，所述氯乙烯树脂的平均聚合度为800～5000。
10.根据权利要求7～9中任一项所述的片状成型体，其中，所述粉体成型用树脂组合物中，相对于100质量份的所述氯乙烯树脂包含30～200质量份的增塑剂。
11.根据权利要求1～10中任一项所述的片状成型体，其中，所述缝制加工使用上线和下线实施，在所述上线和所述下线中，至少所述下线是由包含所述线用树脂的所述线用树脂组合物形成的、熔点为200℃以下的所述线。
12.一种层叠体，具有权利要求1～11中任一项所述的片状成型体和发泡聚氨酯成型体。
13.根据权利要求12所述的层叠体，其为汽车仪表板用层叠体。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015149260 | 2015-07-29 | ||
| JP2015-149260 | 2015-07-29 | ||
| PCT/JP2016/071776 WO2017018390A1 (ja) | 2015-07-29 | 2016-07-25 | シート状成形体、及び、積層体 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107848249A true CN107848249A (zh) | 2018-03-27 |
Family
ID=57884434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680042552.6A Pending CN107848249A (zh) | 2015-07-29 | 2016-07-25 | 片状成型体及层叠体 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11052635B2 (zh) |
| EP (1) | EP3330074A4 (zh) |
| JP (1) | JP6760289B2 (zh) |
| KR (1) | KR20180035820A (zh) |
| CN (1) | CN107848249A (zh) |
| CA (1) | CA2993641A1 (zh) |
| MX (1) | MX2018000909A (zh) |
| TW (1) | TW201710071A (zh) |
| WO (1) | WO2017018390A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112867592A (zh) * | 2018-10-31 | 2021-05-28 | 日本瑞翁株式会社 | 粉体成型用氯乙烯树脂组合物、氯乙烯树脂成型体以及层叠体 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112292289B (zh) * | 2018-06-28 | 2023-04-14 | 上海延锋金桥汽车饰件系统有限公司 | 车辆装饰部件 |
| US11840188B2 (en) * | 2018-06-28 | 2023-12-12 | Shanghai Yanfeng Jinqiao Automotive Trim Systems Co. Ltd. | Vehicle interior component |
| JP2021079822A (ja) * | 2019-11-19 | 2021-05-27 | 豊田合成株式会社 | 表皮付き製品 |
| JP7268639B2 (ja) * | 2020-05-19 | 2023-05-08 | トヨタ自動車株式会社 | 発泡成形体 |
| JP7423116B1 (ja) | 2023-10-30 | 2024-01-29 | 株式会社K&I | 皮革製品の製造方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6222682A (ja) * | 1985-07-23 | 1987-01-30 | 高島屋日発工業株式会社 | 座席用クツシヨン体の製造方法 |
| JPS63242606A (ja) * | 1987-03-31 | 1988-10-07 | Tokai Chem Ind Ltd | 表皮材をもつ発泡樹脂成形体の製造方法 |
| JPH06136173A (ja) * | 1992-02-10 | 1994-05-17 | Toagosei Chem Ind Co Ltd | 粉末成形用樹脂組成物 |
| CN1977073A (zh) * | 2004-06-29 | 2007-06-06 | 井上株式会社 | 发泡成形体用缝纫线、发泡成形体以及发泡成形体的制造方法 |
| JP2013119688A (ja) * | 2011-12-08 | 2013-06-17 | Kanagawa Kk | 熱膨張性縫製糸及びその縫製方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4247345A (en) * | 1978-11-30 | 1981-01-27 | Olin Corporation | Method for joining synthetic materials |
| EP0228203B1 (en) * | 1985-12-05 | 1990-07-25 | Sakae Lace Co. Ltd. | Warp knitted lace fabrics |
| JPS63291748A (ja) | 1987-05-25 | 1988-11-29 | Kasai Kogyo Co Ltd | 自動車用内装部品 |
| JPH031938A (ja) | 1989-05-30 | 1991-01-08 | Honda Motor Co Ltd | ステッチ模様を有する内装材及びその製法 |
| GB9104895D0 (en) * | 1991-03-08 | 1991-04-24 | Gen Motors Corp | Upholstery fabric |
| US5203939A (en) * | 1991-08-05 | 1993-04-20 | Coats Viyella, Plc | Process for production of internally bonded sewing threads |
| US5225214A (en) * | 1992-05-18 | 1993-07-06 | Davidson Textron Inc. | Laterally adjustable divider wall for molding two color shells |
| JPH07314465A (ja) | 1994-05-23 | 1995-12-05 | Nishikawa Kasei Co Ltd | スラッシュ表皮を有する発泡成形品 |
| JPH08243271A (ja) * | 1995-03-13 | 1996-09-24 | Achilles Corp | 縫製表皮材及びこれを用いた表皮一体発泡成形方法 |
| JP2963642B2 (ja) | 1995-05-17 | 1999-10-18 | 株式会社イノアックコーポレーション | ヘッドレストの製造方法 |
| US5682771A (en) * | 1996-03-12 | 1997-11-04 | General Motors Corporation | Knitted cover |
| US5887452A (en) * | 1996-08-29 | 1999-03-30 | Lear Corporation | Knitted cover |
| JPH10306187A (ja) * | 1997-05-06 | 1998-11-17 | Zeon Kasei Co Ltd | 粉末成形用塩化ビニル系樹脂組成物 |
| JP3893514B2 (ja) * | 2001-11-29 | 2007-03-14 | 平岡織染株式会社 | 接合部分の耐熱クリープ性に優れたテント膜構造体用ポリオレフィン系樹脂シート接合体及びその製造方法 |
| EP1334818B1 (en) * | 2002-02-08 | 2004-11-17 | Visteon Global Technologies, Inc. | Method of manufacturing a decorative panel cover and corresponding panel |
| DE10244311B4 (de) * | 2002-09-23 | 2019-01-03 | Volkswagen Ag | Innenausstattungsteil für Fahrzeuge und Verfahren zur Herstellung desselben |
| EP1714566A3 (en) * | 2003-06-27 | 2007-09-05 | W.L.Gore & Associates Gmbh | Microseam |
| US20050188907A1 (en) * | 2004-02-27 | 2005-09-01 | American & Efird, Inc. | Sewing method to increase seam strength |
| US20060014016A1 (en) * | 2004-03-01 | 2006-01-19 | Gilberto Lardizabal | Method of producing yarns and fabrics |
| CA2674316A1 (en) * | 2007-01-05 | 2008-07-17 | Johnson Controls Technology Company | Localized deep soft area of a trim panel |
| DE102007057637A1 (de) * | 2007-11-30 | 2009-06-04 | Trw Automotive Safety Systems Gmbh | Verfahren zum Beledern eines Fahrzeuginnenraumteiles, insbesondere eines Fahrzeuglenkrades |
| US9682512B2 (en) * | 2009-02-06 | 2017-06-20 | Nike, Inc. | Methods of joining textiles and other elements incorporating a thermoplastic polymer material |
| JP5926947B2 (ja) * | 2011-12-16 | 2016-05-25 | 倉敷紡績株式会社 | 繊維強化樹脂成形体及びそれを用いた車両用内装材 |
| US8597760B2 (en) * | 2012-03-30 | 2013-12-03 | Swnr Development, Llc | Stitched multi-layer fabric |
| US9272486B2 (en) * | 2012-03-30 | 2016-03-01 | Swnr Development, Llc | Stitched multi-layer fabric |
| US20130255103A1 (en) * | 2012-04-03 | 2013-10-03 | Nike, Inc. | Apparel And Other Products Incorporating A Thermoplastic Polymer Material |
| DK2662480T3 (en) * | 2012-05-11 | 2014-11-17 | Groz Beckert Kg | Textile part, composite material element with textile part and method for making the same |
| JP2014019060A (ja) | 2012-07-18 | 2014-02-03 | Toyota Motor Corp | 成形方法と成形品 |
| US8678458B2 (en) * | 2012-08-09 | 2014-03-25 | Faurecia Interior Systems, Inc. | Vehicle interior components with decorative stitching |
| US20140079901A1 (en) * | 2012-09-14 | 2014-03-20 | Anji Mountain | Decorative laminate pad for supporting an item of furniture |
| JP6824157B2 (ja) * | 2014-08-22 | 2021-02-03 | インテヴァ プロダクツ, エルエルシーInteva Products, Llc | 形成部材にブラインドステッチを施すための方法および装置ならびにその方法から形成される部材 |
| JP6597529B2 (ja) * | 2016-09-08 | 2019-10-30 | トヨタ車体株式会社 | 内装部品及びその製造方法 |
| JP6766548B2 (ja) * | 2016-09-20 | 2020-10-14 | トヨタ紡織株式会社 | 内装部品及びその製造方法 |
-
2016
- 2016-07-25 MX MX2018000909A patent/MX2018000909A/es unknown
- 2016-07-25 US US15/746,130 patent/US11052635B2/en active Active
- 2016-07-25 EP EP16830495.4A patent/EP3330074A4/en active Pending
- 2016-07-25 JP JP2017530865A patent/JP6760289B2/ja active Active
- 2016-07-25 CN CN201680042552.6A patent/CN107848249A/zh active Pending
- 2016-07-25 KR KR1020187002865A patent/KR20180035820A/ko unknown
- 2016-07-25 WO PCT/JP2016/071776 patent/WO2017018390A1/ja active Application Filing
- 2016-07-25 CA CA2993641A patent/CA2993641A1/en not_active Abandoned
- 2016-07-27 TW TW105123661A patent/TW201710071A/zh unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6222682A (ja) * | 1985-07-23 | 1987-01-30 | 高島屋日発工業株式会社 | 座席用クツシヨン体の製造方法 |
| JPS63242606A (ja) * | 1987-03-31 | 1988-10-07 | Tokai Chem Ind Ltd | 表皮材をもつ発泡樹脂成形体の製造方法 |
| JPH06136173A (ja) * | 1992-02-10 | 1994-05-17 | Toagosei Chem Ind Co Ltd | 粉末成形用樹脂組成物 |
| CN1977073A (zh) * | 2004-06-29 | 2007-06-06 | 井上株式会社 | 发泡成形体用缝纫线、发泡成形体以及发泡成形体的制造方法 |
| JP2013119688A (ja) * | 2011-12-08 | 2013-06-17 | Kanagawa Kk | 熱膨張性縫製糸及びその縫製方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112867592A (zh) * | 2018-10-31 | 2021-05-28 | 日本瑞翁株式会社 | 粉体成型用氯乙烯树脂组合物、氯乙烯树脂成型体以及层叠体 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017018390A1 (ja) | 2017-02-02 |
| US11052635B2 (en) | 2021-07-06 |
| EP3330074A1 (en) | 2018-06-06 |
| MX2018000909A (es) | 2018-05-15 |
| JPWO2017018390A1 (ja) | 2018-05-17 |
| EP3330074A4 (en) | 2019-04-10 |
| TW201710071A (zh) | 2017-03-16 |
| KR20180035820A (ko) | 2018-04-06 |
| JP6760289B2 (ja) | 2020-09-23 |
| US20180207908A1 (en) | 2018-07-26 |
| CA2993641A1 (en) | 2017-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107848249A (zh) | 片状成型体及层叠体 | |
| CN102918102B (zh) | 粉体成形用氯乙烯树脂组合物、氯乙烯树脂成形体及层合体 | |
| CN104812833B (zh) | 粉体成形用氯乙烯树脂组合物、氯乙烯树脂成形体和层合体 | |
| CN107001750A (zh) | 氯乙烯树脂组合物及其制造方法、氯乙烯树脂成型体及其制造方法以及层叠体 | |
| JP5729552B2 (ja) | 粉体成形用塩化ビニル樹脂組成物、塩化ビニル樹脂成形体及び積層体 | |
| CN105992799A (zh) | 氯乙烯树脂组合物、氯乙烯树脂成型体及层合体 | |
| CN105916933A (zh) | 粉体成型用氯乙烯树脂组合物、氯乙烯树脂成型体及层叠体 | |
| CN107428136A (zh) | 汽车内装饰材料用层叠体 | |
| CN107109010A (zh) | 粉体成型用氯乙烯树脂组合物及其制造方法、氯乙烯树脂成型体及其制造方法、以及层叠体 | |
| CN107075217A (zh) | 真缝线表皮用粉体成型性氯乙烯树脂组合物及其制造方法、真缝线表皮用氯乙烯树脂成型体及其制造方法以及层叠体 | |
| CN107406001A (zh) | 汽车内装饰材料用层叠体 | |
| CN107848250A (zh) | 层叠体的制造方法 | |
| JP6760078B2 (ja) | 熱可塑性樹脂組成物、熱可塑性樹脂成形体及びその製造方法、並びに、積層体 | |
| CN106029775A (zh) | 氯乙烯树脂组合物、氯乙烯树脂成型体和层叠体 | |
| WO2011086813A1 (ja) | 自動車インスツルメントパネル用積層体 | |
| JP6589881B2 (ja) | 粉体成形用塩化ビニル樹脂組成物及びその製造方法、塩化ビニル樹脂成形体及びその製造方法、並びに、積層体 | |
| JPWO2016143343A1 (ja) | 粉体成形用塩化ビニル樹脂組成物、塩化ビニル樹脂成形体及び積層体 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180327 |