CN107652419A - 聚酯以及由其制成的制品 - Google Patents
聚酯以及由其制成的制品 Download PDFInfo
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- CN107652419A CN107652419A CN201710933585.6A CN201710933585A CN107652419A CN 107652419 A CN107652419 A CN 107652419A CN 201710933585 A CN201710933585 A CN 201710933585A CN 107652419 A CN107652419 A CN 107652419A
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Abstract
Description
Claims (21)
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Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2890544B2 (en) * | 2012-08-31 | 2023-11-15 | Société Anonyme des Eaux Minérales d'Evian et en Abrégé "S.A.E.M.E" | Bottle, method of making the same and use of fdca and diol monomers in such bottle |
JP6507156B2 (ja) | 2013-06-20 | 2019-04-24 | フラニックス・テクノロジーズ・ベーフェー | 繊維の製造方法、ならびにその繊維から製造される繊維およびヤーン |
DE102013223496A1 (de) * | 2013-11-18 | 2015-05-21 | Tesa Se | Neuartiges Polyester geeignet zur Herstellung von Trägermaterialien für Klebebändern |
WO2015093525A1 (ja) * | 2013-12-19 | 2015-06-25 | 東洋紡株式会社 | ポリエステルエラストマー |
KR20160102227A (ko) * | 2013-12-20 | 2016-08-29 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 푸란계 중합체성 탄화수소 연료 배리어 구조체 |
CN110229478B (zh) | 2013-12-20 | 2022-01-25 | 纳幕尔杜邦公司 | 聚(2,5-呋喃二甲酸1,3-丙二醇酯)(ptf)的成核结晶及其制品 |
MX2016014278A (es) * | 2014-05-01 | 2017-02-06 | Du Pont | Poliesteres furanicos transesterificados y articulos elaborados con estos. |
AU2015307312B2 (en) | 2014-08-25 | 2020-07-23 | Furanix Technologies B.V. | Process for producing an oriented film comprising poly(ethylene-2,5-furandicarboxylate) |
US9771487B2 (en) | 2014-11-10 | 2017-09-26 | Xerox Corporation | Method of three-dimensional printing |
CA2975490C (en) * | 2015-02-13 | 2023-08-08 | The Coca-Cola Company | Barrier enhanced pet multilayer container |
WO2016168233A1 (en) | 2015-04-14 | 2016-10-20 | E I Du Pont De Nemours | Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom |
CN115926396A (zh) | 2015-06-11 | 2023-04-07 | 纳幕尔杜邦公司 | 通过聚(呋喃二甲酸乙二醇酯)和聚(对苯二甲酸乙二醇酯)的共混物增强的阻隔性能 |
NL2015265B1 (en) * | 2015-08-04 | 2017-02-21 | Furanix Technologies Bv | Polyester composition. |
CN107922781A (zh) * | 2015-09-04 | 2018-04-17 | 奥里格聚合物股份有限公司 | 具有基于呋喃的聚酯的聚合物共混物 |
SG11201805514VA (en) | 2016-01-13 | 2018-07-30 | Stora Enso Oyj | Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof |
US11111057B2 (en) * | 2016-03-04 | 2021-09-07 | Amisha Patel | Bioplastic collapsible dispensing tube |
ITUA20162764A1 (it) * | 2016-04-20 | 2017-10-20 | Novamont Spa | Nuovo poliestere e composizioni che lo contengono |
CA3022096A1 (en) * | 2016-04-25 | 2017-11-02 | E I Du Pont De Nemours And Company | Process for producing polyester article |
EP3486275A4 (en) * | 2016-07-15 | 2020-03-04 | Kuraray Co., Ltd. | WATERPROOFING FILM AND MANUFACTURING METHOD THEREOF |
EP3523349B1 (en) | 2016-10-05 | 2020-12-02 | Furanix Technologies B.V | Process for the production of a solid-state polymerized poly (tetramethylene-2, 5-furan dicarboxylate) polymer and polymer thus produce |
CN110072908A (zh) * | 2016-10-14 | 2019-07-30 | 纳幕尔杜邦公司 | 用于制备聚(呋喃二甲酸三亚甲酯)的方法 |
CA3042685A1 (en) * | 2016-11-03 | 2018-05-11 | The Coca-Cola Company | Acrolein scavenging in ptf and other 1,3-propanediol derived polymers |
US10155907B2 (en) | 2016-12-12 | 2018-12-18 | International Business Machines Corporation | Cross-linkable flame retardant materials |
US10106564B2 (en) | 2016-12-12 | 2018-10-23 | International Business Machines Corporation | Furan-containing flame retardant molecules |
US9822208B1 (en) | 2017-01-03 | 2017-11-21 | International Business Machines Corporation | Flame retardant materials derived from furan dicarboxylic methyl ester |
WO2018156859A1 (en) * | 2017-02-24 | 2018-08-30 | E. I. Du Pont De Nemours And Company | Process for preparing poly(trimethylene furandicarboxylate) using zinc catalyst |
CH713888A1 (de) | 2017-06-08 | 2018-12-14 | Alpla Werke Alwin Lehner Gmbh & Co Kg | PET-Barriere-Flasche. |
BR112020000611B1 (pt) | 2017-07-12 | 2024-03-05 | Stora Enso Oyj | Produtos purificados de via de ácido 2,5-furanoodicarboxílico |
CN111164017B (zh) * | 2017-10-06 | 2022-02-08 | 龟甲万株式会社 | 合成树脂制多重瓶 |
CN111655474A (zh) * | 2018-01-24 | 2020-09-11 | 利乐拉瓦尔集团及财务有限公司 | 阻隔膜、包括该膜的层压包装材料和由其制成的包装容器 |
US20230303825A1 (en) * | 2018-10-22 | 2023-09-28 | Covation Inc. | Process for producing polyester article |
CN109575257B (zh) * | 2018-11-16 | 2021-09-07 | 中国科学院宁波材料技术与工程研究所 | 聚2,5-呋喃二甲酸-1,4-丁二酸新戊二醇酯及其制备方法、制品 |
JP7293630B2 (ja) * | 2018-12-13 | 2023-06-20 | Dic株式会社 | コーティング材組成物、および積層体 |
US11305910B2 (en) * | 2019-03-05 | 2022-04-19 | Furanix Technologies B.V. | Multilayer container comprising a polyethylene furanoate layer |
SE544880C2 (en) * | 2020-05-11 | 2022-12-20 | Stora Enso Oyj | Multilayer preform and container |
RU2760519C1 (ru) * | 2020-12-02 | 2021-11-26 | Нина Владимировна Смирнова | Способ получения ненасыщенных полиэфирных смол |
EP4352161A1 (en) * | 2021-05-28 | 2024-04-17 | Parkdale Incorporated | Blended textile composition with improved dyeing properties |
CN113336925A (zh) * | 2021-06-03 | 2021-09-03 | 东胜化学(上海)有限公司 | 一种饱和聚酯树脂及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008291244A (ja) * | 2007-04-24 | 2008-12-04 | Mitsubishi Chemicals Corp | フラン構造を含むポリエステル樹脂の製造方法 |
CN101343404A (zh) * | 2007-07-12 | 2009-01-14 | 佳能株式会社 | 树脂组合物 |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
US20110282020A1 (en) * | 2008-12-30 | 2011-11-17 | Furanix Technologies B.V. | Process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers |
CN102432847A (zh) * | 2011-08-25 | 2012-05-02 | 中国科学院长春应用化学研究所 | 2,5-呋喃二甲酸-对苯二甲酸-脂肪族二元醇共聚酯及其制备方法 |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB621971A (en) * | 1946-11-12 | 1949-04-25 | James Gordon Napier Drewitt | Improvements in polymers |
US3671379A (en) | 1971-03-09 | 1972-06-20 | Du Pont | Composite polyester textile fibers |
JPS59158232A (ja) * | 1983-02-28 | 1984-09-07 | Toyo Seikan Kaisha Ltd | 多層延伸ポリエステルボトルの製法 |
US4900612A (en) * | 1985-05-24 | 1990-02-13 | Mitsui Petrochemical Industries, Ltd. | Laminated structure |
GB8724243D0 (en) * | 1987-10-15 | 1987-11-18 | Metal Box Plc | Laminates of polyolefin-based film |
US5061532A (en) * | 1988-04-20 | 1991-10-29 | Idemitsu Petrochemical, Co., Ltd. | Multilayer structure and easily openable container and lid |
JPH0757387B2 (ja) * | 1990-05-16 | 1995-06-21 | 東洋製罐株式会社 | 薄肉化絞り缶 |
US5366791A (en) * | 1990-07-06 | 1994-11-22 | Paramount Packaging Corporation | Thermoformable laminate material with registered print and method of making the same |
US5340909A (en) | 1991-12-18 | 1994-08-23 | Hoechst Celanese Corporation | Poly(1,3-propylene terephthalate) |
ZA946726B (en) * | 1993-09-10 | 1995-04-21 | Plastipak Packaging Inc | Polyethylene terephthalate multi-layer preform used for plastic blow molding and method for making the preform. |
DE4430634A1 (de) | 1994-08-29 | 1996-03-07 | Hoechst Ag | Verfahren zur Herstellung thermostabiler, farbneutraler, antimonfreier Polyester und die danach herstellbaren Produkte |
DE19519579C2 (de) | 1995-05-29 | 1997-03-20 | Hoechst Ag | Amorphe, transparente Platte aus einem kristallisierbaren Thermoplast |
DE19522118C1 (de) | 1995-06-19 | 1997-03-13 | Hoechst Ag | Amorphe, transparente, UV-stabilisierte Platte aus einem kristallisierbaren Thermoplast, Verfahren zu deren Herstellung sowie deren Verwendung |
TW462977B (en) | 1996-06-28 | 2001-11-11 | Toray Industries | Resin compositions, processes for producing thereby, and process for producing titanium oxide |
DE19705249A1 (de) | 1997-02-12 | 1998-08-13 | Zimmer Ag | Verfahren zur Herstellung von Polypropylenterphthalat |
AR018672A1 (es) * | 1998-06-15 | 2001-11-28 | Eastman Chem Co | Una composicion de combinaciones de poliester /fenilendi(oxiacetico), acido copoliester, que tienen mejoradas propiedades de barrera de gases |
KR100445849B1 (ko) | 1998-10-30 | 2004-08-25 | 아사히 가세이 가부시키가이샤 | 폴리에스테르 수지조성물 및 섬유 |
JP4432168B2 (ja) | 1998-11-30 | 2010-03-17 | ソニー株式会社 | 移動体搭載用バッテリ装置 |
EP1139419A1 (en) | 2000-03-29 | 2001-10-04 | STMicroelectronics S.r.l. | Method of manufacturing an electrically programmable, non-volatile memory with logic circuitry |
US7101624B2 (en) * | 2000-06-22 | 2006-09-05 | Cello-Foil Products, Inc. | Laminate antioxidant film |
JP4470491B2 (ja) * | 2002-03-07 | 2010-06-02 | 東レ株式会社 | ポリエステルフィルムおよびガスバリア性ポリエステルフィルム |
RU2238284C2 (ru) * | 2002-11-04 | 2004-10-20 | Саехан Индастриз Инкорпорейшн | Насыщенный сложный полиэфир для пластмассовых контейнеров с высокой термостойкостью и газонепроницаемостью и способ его получения |
US7396896B2 (en) * | 2004-12-21 | 2008-07-08 | E.I. Dupont De Nemours And Company | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom |
JP4881127B2 (ja) * | 2005-11-07 | 2012-02-22 | キヤノン株式会社 | 高分子化合物およびその合成方法 |
US8413829B2 (en) * | 2006-01-27 | 2013-04-09 | Amcor Limited | Blow-molded container having finish with thread groove and tamper evident features |
JP5055279B2 (ja) * | 2006-07-21 | 2012-10-24 | 帝人株式会社 | 芳香族ポリエステルおよびその製造法 |
IT1387503B (it) * | 2008-05-08 | 2011-04-13 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
JP5351612B2 (ja) * | 2009-06-02 | 2013-11-27 | キヤノン株式会社 | ポリエステル、その製造方法、及び成形品 |
JP5517494B2 (ja) * | 2009-06-03 | 2014-06-11 | キヤノン株式会社 | ポリエステル、その製造方法、及び成形品 |
IT1399032B1 (it) * | 2009-11-06 | 2013-04-05 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
US20110124839A1 (en) * | 2009-11-25 | 2011-05-26 | Canon Kabushiki Kaisha | Flame-retardant polyester copolymer, and production process and molded article thereof |
CN102190782B (zh) * | 2010-03-17 | 2015-08-19 | 东丽纤维研究所(中国)有限公司 | 一种共聚酯化合物以及制备方法 |
JP2012229395A (ja) * | 2011-04-11 | 2012-11-22 | Canon Inc | プラスチックフィルム |
CN102276812B (zh) * | 2011-06-29 | 2012-11-21 | 中国科学院长春应用化学研究所 | 一种聚2,5-呋喃二甲酸二醇酯的制备方法 |
BRPI1106661A2 (pt) * | 2011-09-30 | 2013-08-27 | Univ Rio De Janeiro | processo para produÇço de resinas À base de poli(2,5-furanodicarboxilato de etileno), resinas À base de poli (2,5-furanodicarboxilato de etileno) e uso das referidas resinas |
US20130095269A1 (en) * | 2011-10-14 | 2013-04-18 | Eastman Chemical Company | Polyester compositions containing furandicarboxylic acid or an ester thereof and ethylene glycol |
-
2013
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008291244A (ja) * | 2007-04-24 | 2008-12-04 | Mitsubishi Chemicals Corp | フラン構造を含むポリエステル樹脂の製造方法 |
CN101343404A (zh) * | 2007-07-12 | 2009-01-14 | 佳能株式会社 | 树脂组合物 |
US20110282020A1 (en) * | 2008-12-30 | 2011-11-17 | Furanix Technologies B.V. | Process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
CN102432847A (zh) * | 2011-08-25 | 2012-05-02 | 中国科学院长春应用化学研究所 | 2,5-呋喃二甲酸-对苯二甲酸-脂肪族二元醇共聚酯及其制备方法 |
Non-Patent Citations (2)
Title |
---|
MÓNICA GOMES ET AL: "Synthesis and Characterization of Poly(2,5-furan dicarboxylate)s Based on a Variety of Diols", 《JOURNAL OF POLYMER SCIENCE PART A: POLYMER CHEMISTRY》 * |
段予忠等: "《塑料配方设计及应用900例》", 30 September 1995, 中国石化出版社 * |
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