CN102276812B - 一种聚2,5-呋喃二甲酸二醇酯的制备方法 - Google Patents
一种聚2,5-呋喃二甲酸二醇酯的制备方法 Download PDFInfo
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- CN102276812B CN102276812B CN2011101794692A CN201110179469A CN102276812B CN 102276812 B CN102276812 B CN 102276812B CN 2011101794692 A CN2011101794692 A CN 2011101794692A CN 201110179469 A CN201110179469 A CN 201110179469A CN 102276812 B CN102276812 B CN 102276812B
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- dioctyl phthalate
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title abstract 4
- 238000005886 esterification reaction Methods 0.000 claims abstract description 49
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 42
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 230000000694 effects Effects 0.000 claims abstract description 5
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- 238000006068 polycondensation reaction Methods 0.000 claims description 26
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- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 11
- 229960005082 etohexadiol Drugs 0.000 claims description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
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- 125000002270 phosphoric acid ester group Chemical group 0.000 claims description 4
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical group [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
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- 230000007704 transition Effects 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical group [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 description 2
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- 241000335053 Beta vulgaris Species 0.000 description 1
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- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Families Citing this family (9)
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JP2015507684A (ja) * | 2012-01-04 | 2015-03-12 | ペプシコ, インコーポレイテッドPepsiCo Inc. | バイオマスから調製された2,5−フランジカルボン酸系ポリエステル |
WO2013149157A1 (en) * | 2012-03-30 | 2013-10-03 | E. I. Du Pont De Nemours And Company | Polyesters and fibers made therefrom |
CN102827361A (zh) * | 2012-07-24 | 2012-12-19 | 北京金骄生物质化工有限公司 | 一种生物基聚酯及其制备方法 |
CN103333325B (zh) * | 2013-07-23 | 2016-03-30 | 中国科学院长春应用化学研究所 | 聚2,5-呋喃二甲酸-2,3-丁二醇酯及其制备方法 |
JP2017501906A (ja) * | 2013-12-20 | 2017-01-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | フランベースのポリマー炭化水素燃料バリア構造 |
WO2015108026A1 (ja) * | 2014-01-15 | 2015-07-23 | 東洋紡株式会社 | 共重合ポリエステル樹脂及びこれを用いた接着剤 |
CN108484892B (zh) * | 2018-04-14 | 2020-07-14 | 浙江理工大学 | 利用生物质制备聚2,5-呋喃二甲酸-1,6-己二醇酯的方法 |
CN108484959B (zh) * | 2018-04-20 | 2020-09-22 | 中国科学院宁波材料技术与工程研究所 | 2,5-呋喃二甲酸基共聚酯发泡材料及其制备方法 |
CN109161007B (zh) * | 2018-07-17 | 2020-01-31 | 中国科学院长春应用化学研究所 | 一种聚2,5-呋喃二甲酸丁二醇共聚酯及其制备方法 |
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CN101343404A (zh) * | 2007-07-12 | 2009-01-14 | 佳能株式会社 | 树脂组合物 |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
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JP2009215467A (ja) * | 2008-03-11 | 2009-09-24 | Canon Inc | ポリエチレン−2,5−フランジカルボキシレートの製造方法 |
NL2002382C2 (en) * | 2008-12-30 | 2010-07-01 | Furanix Technologies Bv | A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers. |
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CN101343404A (zh) * | 2007-07-12 | 2009-01-14 | 佳能株式会社 | 树脂组合物 |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
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