RU2014143803A - Сложные полиэфиры и изделия, изготовленные из них - Google Patents

Сложные полиэфиры и изделия, изготовленные из них Download PDF

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RU2014143803A
RU2014143803A RU2014143803A RU2014143803A RU2014143803A RU 2014143803 A RU2014143803 A RU 2014143803A RU 2014143803 A RU2014143803 A RU 2014143803A RU 2014143803 A RU2014143803 A RU 2014143803A RU 2014143803 A RU2014143803 A RU 2014143803A
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polymer
substrate
ptf
poly
product according
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RU2014143803A
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RU2652802C2 (ru
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Фредрик НЕДЕРБЕРГ
Бхума РАДЖАГОПАЛАН
Джулиус УРАДНИШЕК
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Е.И.Дюпон Де Немур Энд Компани
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  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

1. Изделие, включающее:подложку, содержащую первую поверхность и вторую поверхность, где вторая поверхность контактирует с внешней средой,где подложка содержит полимер, включающий поли(триметиленфурандикарбоксилат) (PTF), игде полимер обеспечивает улучшение газобарьерных свойств подложки по сравнению с подложкой, выполненной из свежеполученного поли(этилентерефталата) (ПЭТ),где улучшение в отношении кислорода составляет 2-99%, улучшение в отношении диоксида углерода составляет 11-99%, и улучшение в отношении влаги составляет 3-99%.2. Изделие по п. 1, где кристалличность полимера составляет менее чем 100 Дж/г согласно измерениям, выполненным с помощью дифференциальной сканирующей калориметрии со скоростью нагрева 10°С/мин.3. Изделие по п. 1, где полимер представляет собой полимерную смесь, содержащую поли(триметиленфурандикарбоксилат) (PTF) и поли(алкиленфурандикарбоксилат), игде массовая доля PTF в полимере составляет 0,1-99,9% от общей массы полимерной смеси.4. Изделие по п. 1, где полимер представляет собой полимерную смесь, содержащую поли(триметиленфурандикарбоксилат) (PTF) и поли(алкилентерефталат), игде массовая доля PTF в полимере составляет 0,1-99,9% от общей массы полимерной смеси.5. Изделие по п. 1, где подложка содержит полимер, расположенный между первым слоем и вторым слоем, и с которыми он контактирует, где первый слой контактирует с первой поверхностью подложки, а второй слой контактирует со второй поверхностью подложки,где полимер содержит поли(триметиленфурандикарбоксилат) (PTF), ии где содержание полимера, выраженное в массовых долях, находится в пределах 0,1-99,9% от общей массы первого слоя, полимера и второго слоя.6. Изделие по п. 1, где по меньшей мере один из первого или второго слоев со

Claims (15)

1. Изделие, включающее:
подложку, содержащую первую поверхность и вторую поверхность, где вторая поверхность контактирует с внешней средой,
где подложка содержит полимер, включающий поли(триметиленфурандикарбоксилат) (PTF), и
где полимер обеспечивает улучшение газобарьерных свойств подложки по сравнению с подложкой, выполненной из свежеполученного поли(этилентерефталата) (ПЭТ),
где улучшение в отношении кислорода составляет 2-99%, улучшение в отношении диоксида углерода составляет 11-99%, и улучшение в отношении влаги составляет 3-99%.
2. Изделие по п. 1, где кристалличность полимера составляет менее чем 100 Дж/г согласно измерениям, выполненным с помощью дифференциальной сканирующей калориметрии со скоростью нагрева 10°С/мин.
3. Изделие по п. 1, где полимер представляет собой полимерную смесь, содержащую поли(триметиленфурандикарбоксилат) (PTF) и поли(алкиленфурандикарбоксилат), и
где массовая доля PTF в полимере составляет 0,1-99,9% от общей массы полимерной смеси.
4. Изделие по п. 1, где полимер представляет собой полимерную смесь, содержащую поли(триметиленфурандикарбоксилат) (PTF) и поли(алкилентерефталат), и
где массовая доля PTF в полимере составляет 0,1-99,9% от общей массы полимерной смеси.
5. Изделие по п. 1, где подложка содержит полимер, расположенный между первым слоем и вторым слоем, и с которыми он контактирует, где первый слой контактирует с первой поверхностью подложки, а второй слой контактирует со второй поверхностью подложки,
где полимер содержит поли(триметиленфурандикарбоксилат) (PTF), и
и где содержание полимера, выраженное в массовых долях, находится в пределах 0,1-99,9% от общей массы первого слоя, полимера и второго слоя.
6. Изделие по п. 1, где по меньшей мере один из первого или второго слоев содержит PTF, ПЭТ, ПЭНД, ПЭВД, ПЭ, ПП или EvOH.
7. Изделие по п. 1, где подложка представляет собой корпус, снабженный входом для введения материала таким образом, что материал контактирует с первой поверхностью подложки.
8. Изделие по п. 7, дополнительно содержащее средство для закрытия входа, таким образом, что при закрывании отверстия материал изолируется от внешней среды.
9. Изделие по п. 7, где изделие представляет собой одно или несколько из следующих изделий: контейнер, контейнер и крышка или контейнер и герметичное уплотнение.
10. Изделие согласно п. 7, где изделие представляет собой контейнер для напитка.
11. Изделие по п. 1, где подложка представляет собой пленку или лист.
12. Изделие по п. 1, где полимер в качестве покрытия расположен по меньшей мере на одной из первой поверхности или второй поверхности подложки.
13. Изделие по п. 12, где полимерное покрытие придает подложке устойчивость к истиранию.
14. Изделие по п. 12, где по меньшей мере одна из первой или второй поверхностей подложки содержит металл или пластмассу.
15. Полимерная композиция, включающая полимер, имеющий повторяющееся звено формулы:
Figure 00000001
где n меньше чем 185.
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