CN105263895B - 用于纯化乙酸和丙烯酸的方法 - Google Patents

用于纯化乙酸和丙烯酸的方法 Download PDF

Info

Publication number
CN105263895B
CN105263895B CN201480029153.7A CN201480029153A CN105263895B CN 105263895 B CN105263895 B CN 105263895B CN 201480029153 A CN201480029153 A CN 201480029153A CN 105263895 B CN105263895 B CN 105263895B
Authority
CN
China
Prior art keywords
boiling point
point solvent
high boiling
acetic acid
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201480029153.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN105263895A (zh
Inventor
穆斯塔法·N·卡里梅
费塞尔·巴克什
穆巴里克·贝希尔
泽山·纳瓦兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of CN105263895A publication Critical patent/CN105263895A/zh
Application granted granted Critical
Publication of CN105263895B publication Critical patent/CN105263895B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C07C51/46—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by azeotropic distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201480029153.7A 2013-05-20 2014-05-19 用于纯化乙酸和丙烯酸的方法 Expired - Fee Related CN105263895B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361825205P 2013-05-20 2013-05-20
US61/825,205 2013-05-20
PCT/US2014/038573 WO2014189829A1 (en) 2013-05-20 2014-05-19 Method for the purification of acetic acid and acrylic acid

Publications (2)

Publication Number Publication Date
CN105263895A CN105263895A (zh) 2016-01-20
CN105263895B true CN105263895B (zh) 2018-04-10

Family

ID=50942932

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480029153.7A Expired - Fee Related CN105263895B (zh) 2013-05-20 2014-05-19 用于纯化乙酸和丙烯酸的方法

Country Status (8)

Country Link
US (1) US9944582B2 (enExample)
EP (1) EP2999686A1 (enExample)
JP (1) JP2016520096A (enExample)
KR (1) KR20160009598A (enExample)
CN (1) CN105263895B (enExample)
AU (1) AU2014268860B2 (enExample)
CA (1) CA2908710A1 (enExample)
WO (1) WO2014189829A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6290460B2 (ja) * 2015-02-05 2018-03-07 株式会社日本触媒 アクリル酸の製造方法
WO2017114831A1 (en) * 2015-12-29 2017-07-06 Shell Internationale Research Maatschappij B.V. Process for converting alkanes and/or alkenes to alkenes and carboxylic acids
KR102079775B1 (ko) 2016-11-25 2020-02-20 주식회사 엘지화학 (메트)아크릴산의 연속 회수 방법 및 장치
FR3060000B1 (fr) * 2016-12-08 2020-05-01 Arkema France Procede pour eviter le depot de polymeres dans un procede de purification d'acide (meth)acrylique.

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3433831A (en) * 1965-06-30 1969-03-18 Asahi Chemical Ind Separation and purification of acrylic acid from acetic acid by solvent extraction and azeotropic distillation with a two component solvent-entrainer system
US3666632A (en) * 1968-10-08 1972-05-30 Asahi Chemical Ind Method for the separation of acrylic acid from aqueous solution containing acrylic acid and acetic acid
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
EP0861820A2 (en) * 1997-02-28 1998-09-02 Nippon Shokubai Co., Ltd. Method for recovering acrylic acid
CN1270952A (zh) * 1999-03-31 2000-10-25 株式会社日本触媒 (甲基)丙烯酸的精制方法
CN1145527C (zh) * 1998-11-16 2004-04-14 沙地基本工业公司 丙烷催化氧化成丙烯酸的催化剂及其制造和使用方法
CN1625544A (zh) * 2002-01-29 2005-06-08 三菱化学株式会社 (甲基)丙烯酸的制造方法
CN1697818A (zh) * 2003-11-28 2005-11-16 三菱化学株式会社 (甲基)丙烯酸的提纯方法

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2748159A (en) 1952-09-08 1956-05-29 Goodyear Tire & Rubber Purification and decolorization of esters
GB783463A (en) 1955-05-10 1957-09-25 Distillers Co Yeast Ltd Esters purification process
US2862958A (en) 1955-10-13 1958-12-02 Hercules Powder Co Ltd Method of improving electrical properties of plasticizers by treatment with magnesium silicate
GB813867A (en) 1956-12-27 1959-05-27 Distillers Co Yeast Ltd Purification of esters of dicarboxylic acids
DE1173473B (de) 1962-06-29 1964-07-09 Reichhold Chemie Ag Verfahren zum Herstellen von aliphatischen oder aromatischen Carbonsaeureestern
DE1264762B (de) 1963-09-03 1968-03-28 Reichhold Chemie Ag Weichmacher fuer organische Polymere
JPS5011364B1 (enExample) * 1965-06-30 1975-04-30
BE706512A (enExample) * 1966-11-14 1968-05-14
US3422831A (en) * 1967-02-20 1969-01-21 Gen Electric Turbine control system
JPS4946942B1 (enExample) 1971-04-05 1974-12-12
JPS5522462B2 (enExample) * 1972-05-24 1980-06-17
JPS4995918A (enExample) * 1973-01-24 1974-09-11
JPS5011364A (enExample) 1973-05-30 1975-02-05
US5243069A (en) * 1981-12-11 1993-09-07 Rohm And Haas Company Ester of Michael addition homopolymers of acrylic acid
JPS62267341A (ja) 1986-05-16 1987-11-20 Mitsubishi Kasei Vinyl Co 可塑剤の製造法
JPH0341051A (ja) * 1989-07-07 1991-02-21 Idemitsu Petrochem Co Ltd アクリル酸エステル又はメタクリル酸エステルの製造方法
JPH089567B2 (ja) * 1992-01-09 1996-01-31 株式会社日本触媒 アクリル酸製造においてアクリル酸を高純度に精製する方法
TW295580B (enExample) * 1992-01-09 1997-01-11 Nippon Catalytic Chem Ind
JP3832868B2 (ja) 1994-07-27 2006-10-11 三菱化学株式会社 アクリル酸の精製法
JP3937462B2 (ja) 1994-08-04 2007-06-27 三菱化学株式会社 アクリル酸精製法
JP3202150B2 (ja) * 1995-08-04 2001-08-27 昭和電工株式会社 酢酸の精製方法
JP3219682B2 (ja) * 1995-09-29 2001-10-15 昭和電工株式会社 酢酸の精製方法、及び酢酸の製造方法
JP3028925B2 (ja) 1995-12-05 2000-04-04 株式会社日本触媒 アクリル酸の製造方法
JPH09263566A (ja) 1996-03-29 1997-10-07 Cosmo Sogo Kenkyusho:Kk 粗ベンゼンジカルボン酸の精製方法、精製に使用する触媒およびその製造方法
FR2753445B1 (fr) * 1996-09-16 1998-10-30 Atochem Elf Sa Procede perfectionne de purification de l'acide acrylique
JP3880128B2 (ja) * 1997-05-08 2007-02-14 株式会社日本触媒 アクリル酸の回収方法
JP3937495B2 (ja) 1997-02-28 2007-06-27 株式会社日本触媒 アクリル酸の回収方法
US5880310A (en) 1997-05-21 1999-03-09 Mitsubishi Gas Chemical Company, Inc. Process for producing plasticizer esters
EP1035103B1 (en) 1999-03-05 2003-10-15 Rohm And Haas Company Process for preparing acrylic acid
JP4809532B2 (ja) * 1999-11-15 2011-11-09 サウディ ベーシック インダストリーズ コーポレイション プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法
JP5021140B2 (ja) * 2000-06-14 2012-09-05 ビーエーエスエフ ソシエタス・ヨーロピア アクロレイン及び／又はアクリル酸の製造方法
JP2005232008A (ja) * 2001-12-27 2005-09-02 Mitsubishi Chemicals Corp （メタ）アクリル酸の蒸留方法
GB0320206D0 (en) 2003-08-29 2003-10-01 Exxonmobil Chem Patents Inc Improvements in or relating to plasticiser
FR2861724B1 (fr) 2003-11-04 2005-12-30 Arkema Procede de purification de l'acide (meth)acrylique obtenu par oxydation d'un substrat gazeux
JP2005179352A (ja) * 2003-11-28 2005-07-07 Mitsubishi Chemicals Corp （メタ）アクリル酸の精製方法
JP4333471B2 (ja) 2004-05-11 2009-09-16 新日本理化株式会社 ジカルボン酸ジエステルの製造方法
JP4621174B2 (ja) * 2006-06-19 2011-01-26 株式会社日本触媒 （メタ）アクリル酸および／またはそのエステルの蒸留方法
CN1884249A (zh) 2006-07-11 2006-12-27 天津天溶化工有限公司 邻苯二甲酸二辛酯清洁生产方法
CN101269899B (zh) 2008-05-13 2011-05-11 吉林大学 一种丙烯酸废水的综合处理方法
CN101367720A (zh) 2008-09-18 2009-02-18 中国石油大学(华东) 一种隔壁共沸精馏塔提纯丙烯酸的工艺方法及装置
CN101530780B (zh) 2009-04-21 2011-08-24 浙江工商大学 一种两步分离提纯柱及其应用
WO2014195887A1 (en) 2013-06-07 2014-12-11 Saudi Basic Industries Corporation Method for purifying dioctyl phthalate

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3433831A (en) * 1965-06-30 1969-03-18 Asahi Chemical Ind Separation and purification of acrylic acid from acetic acid by solvent extraction and azeotropic distillation with a two component solvent-entrainer system
US3666632A (en) * 1968-10-08 1972-05-30 Asahi Chemical Ind Method for the separation of acrylic acid from aqueous solution containing acrylic acid and acetic acid
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
EP0861820A2 (en) * 1997-02-28 1998-09-02 Nippon Shokubai Co., Ltd. Method for recovering acrylic acid
CN1145527C (zh) * 1998-11-16 2004-04-14 沙地基本工业公司 丙烷催化氧化成丙烯酸的催化剂及其制造和使用方法
CN1270952A (zh) * 1999-03-31 2000-10-25 株式会社日本触媒 (甲基)丙烯酸的精制方法
CN1625544A (zh) * 2002-01-29 2005-06-08 三菱化学株式会社 (甲基)丙烯酸的制造方法
CN1697818A (zh) * 2003-11-28 2005-11-16 三菱化学株式会社 (甲基)丙烯酸的提纯方法

Also Published As

Publication number Publication date
CA2908710A1 (en) 2014-11-27
CN105263895A (zh) 2016-01-20
WO2014189829A1 (en) 2014-11-27
AU2014268860A1 (en) 2015-10-22
JP2016520096A (ja) 2016-07-11
US9944582B2 (en) 2018-04-17
EP2999686A1 (en) 2016-03-30
KR20160009598A (ko) 2016-01-26
AU2014268860B2 (en) 2017-02-02
US20160075630A1 (en) 2016-03-17

Similar Documents

Publication Publication Date Title
CN105263895B (zh) 用于纯化乙酸和丙烯酸的方法
CN1550480A (zh) 易聚合的物质的制造方法
EP3027595B1 (en) Alkylene oxide separation systems, methods, and apparatuses
CN1282727A (zh) 由丙烯制备和纯化丙烯酸的改进方法
KR20160005696A (ko) 에탄 산화를 통한 아세트산의 제조 방법
JPS6035328B2 (ja) アクリル酸及びアクロレインの製出法
JP6135565B2 (ja) （メタ）アクリル酸の製造方法
WO2006022294A1 (ja) 高純度ジフェニルカーボネートの工業的製造方法
KR20120099797A (ko) 비닐 아세테이트의 제조 방법
KR20190135018A (ko) 분리벽을 갖는 증류 컬럼을 포함하는 (메트)아크릴산의 정제 방법
US3524892A (en) Hexanediol from cyclohexane
CN107915642B (zh) 碳酸二甲酯和甲醇的分离方法
US7622607B2 (en) Method for purifying (meth)acrylic acid obtained by oxidizing a gaseous substrate
CN101389590A (zh) 链烷二醇和碳酸二烷酯的制备方法
CN103910627B (zh) 草酸二烷基酯的制备方法
JP2007505052A (ja) 有機カーボネートの製造方法
CN110114330B (zh) 从粗丙烯酸中分离甲醛的方法
CN101119959A (zh) 通过质子溶剂萃取从含有（甲基）丙烯酸的混合物中回收有机化合物的方法
US10995050B2 (en) Process for the purification of an unsaturated carboxylic acid
US3522279A (en) Oxidation process
CN101268030A (zh) 碳酸二烷基酯和二醇的制备方法
JP7237239B2 (ja) Ｖａｍ生成時における酢酸エチルの除去
CN106068155B (zh) 用于清洁来自乙酸乙烯酯的制备的含二氧化碳的工艺气体的方法
KR101441771B1 (ko) 산소를 이용한 탄화수소의 산화 방법
CN1771222A (zh) 丙烷和/或异丁烷的非均相催化的部分直接氧化

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180410

Termination date: 20210519