CN1051525C - 羟铵盐的制备方法 - Google Patents
羟铵盐的制备方法 Download PDFInfo
- Publication number
- CN1051525C CN1051525C CN96114556A CN96114556A CN1051525C CN 1051525 C CN1051525 C CN 1051525C CN 96114556 A CN96114556 A CN 96114556A CN 96114556 A CN96114556 A CN 96114556A CN 1051525 C CN1051525 C CN 1051525C
- Authority
- CN
- China
- Prior art keywords
- platinum
- catalyzer
- metallic particles
- palladium
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 230000008569 process Effects 0.000 title abstract description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 50
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 15
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 10
- 238000010531 catalytic reduction reaction Methods 0.000 claims abstract description 3
- 239000013528 metallic particle Substances 0.000 claims description 18
- 239000008187 granular material Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 239000012190 activator Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 18
- 239000002245 particle Substances 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 3
- -1 nitrate ions Chemical class 0.000 abstract description 3
- 229910002651 NO3 Inorganic materials 0.000 abstract description 2
- 239000002923 metal particle Substances 0.000 abstract 3
- 230000000694 effects Effects 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 230000004913 activation Effects 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical class O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 4
- 239000002912 waste gas Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 150000002923 oximes Chemical class 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-L L-tartrate(2-) Chemical compound [O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-L 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 235000019846 buffering salt Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRTYPQGPARWINR-UHFFFAOYSA-N palladium platinum Chemical compound [Pd].[Pt] JRTYPQGPARWINR-UHFFFAOYSA-N 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/16—Halides of ammonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE9500936 | 1995-11-10 | ||
| BE9500936A BE1009767A3 (nl) | 1995-11-10 | 1995-11-10 | Werkwijze voor de bereiding van hydroxylammoniumzouten. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1157257A CN1157257A (zh) | 1997-08-20 |
| CN1051525C true CN1051525C (zh) | 2000-04-19 |
Family
ID=3889291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96114556A Expired - Fee Related CN1051525C (zh) | 1995-11-10 | 1996-11-08 | 羟铵盐的制备方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5792439A (enExample) |
| EP (1) | EP0773189B1 (enExample) |
| JP (1) | JP4058123B2 (enExample) |
| KR (1) | KR100416467B1 (enExample) |
| CN (1) | CN1051525C (enExample) |
| BE (1) | BE1009767A3 (enExample) |
| BR (1) | BR9605490A (enExample) |
| CO (1) | CO4560567A1 (enExample) |
| CZ (1) | CZ331296A3 (enExample) |
| DE (1) | DE69607289T2 (enExample) |
| ES (1) | ES2146354T3 (enExample) |
| MX (1) | MX9605488A (enExample) |
| PL (1) | PL316897A1 (enExample) |
| RU (1) | RU2159211C2 (enExample) |
| SK (1) | SK282192B6 (enExample) |
| TW (1) | TW449572B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103492313A (zh) * | 2011-04-22 | 2014-01-01 | 帝斯曼知识产权资产管理有限公司 | 催化的羟胺制备 |
| CN103492314A (zh) * | 2011-04-22 | 2014-01-01 | 帝斯曼知识产权资产管理有限公司 | 催化的羟胺制备 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085559C (zh) * | 1998-12-16 | 2002-05-29 | 中国科学院兰州化学物理研究所 | 合成磷酸羟胺用催化剂 |
| DE19935034A1 (de) * | 1999-07-26 | 2001-02-01 | Basf Ag | Verfahren zur Filtration eines wässrigen bei der Herstellung von Hydroxylamin anfallenden Reaktionsgemisches |
| NL1013899C2 (nl) † | 1999-12-21 | 2001-06-25 | Dsm Nv | Werkwijze voor het bereiden en zuiveren van een hydroxylammoniumzoutoplossing. |
| DE10062325A1 (de) * | 2000-12-14 | 2002-06-20 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Hydroxylammoniumsalzen |
| EP1275616A1 (en) * | 2001-07-11 | 2003-01-15 | Dsm N.V. | Process for the preparation of hydroxylammonium |
| JP4630010B2 (ja) * | 2004-06-24 | 2011-02-09 | 株式会社神戸製鋼所 | 硝酸溶液の処理方法 |
| JP4707382B2 (ja) * | 2004-12-15 | 2011-06-22 | 日揮触媒化成株式会社 | 硝酸性窒素含有水処理用触媒およびその製造方法 |
| PL1901994T3 (pl) * | 2005-07-08 | 2010-06-30 | Dsm Ip Assets Bv | Sposób ciągłego wytwarzania hydroksyloaminy |
| DE102006054156A1 (de) | 2006-11-16 | 2008-05-21 | Wacker Chemie Ag | Pyrogene Kieselsäure hergestellt in einer Produktions-Anlage mit großer Kapazität |
| TWI370750B (en) * | 2008-11-20 | 2012-08-21 | China Petrochemical Dev Corp Taipei Taiwan | Catalyst composition for producing hydroxylamine |
| CN101745392B (zh) * | 2008-12-01 | 2012-12-26 | 中国石油化学工业开发股份有限公司 | 用于制备羟铵盐的催化剂组合物 |
| WO2012143330A1 (en) * | 2011-04-22 | 2012-10-26 | Dsm Ip Assets B.V. | Method for preparing hydroxylamine |
| CN107519868B (zh) * | 2016-06-20 | 2020-08-11 | 中国科学院金属研究所 | 一种催化还原水中硝酸根的纳米钯银合金催化材料及其制备方法和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1387725A (en) * | 1971-07-01 | 1975-03-19 | Stamicarbon | Preparation of a hydroxylammonium salt solution |
| GB1515190A (en) * | 1974-09-23 | 1978-06-21 | Stamicarbon | Process for preparing a hydroxylammonium salt solution |
| US4832938A (en) * | 1988-05-13 | 1989-05-23 | E. I. Du Pont De Nemours And Company | Hydrogen peroxide production method using platinum/palladium catalysts |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL148570B (nl) * | 1967-12-14 | 1976-02-16 | Stamicarbon | Werkwijze voor het bereiden van zouten van hydroxylamine. |
| CH585580A5 (enExample) * | 1974-01-14 | 1977-03-15 | Inventa Ag | |
| US4111842A (en) * | 1977-06-01 | 1978-09-05 | Stamicarbon, B.V. | Process for the preparation of supported catalysts |
| NL7902291A (nl) * | 1979-03-23 | 1980-09-25 | Stamicarbon | Werkwijze voor de bereiding van een hydroxylaminezout en daarbij te gebruiken katalysator. |
-
1995
- 1995-11-10 BE BE9500936A patent/BE1009767A3/nl not_active IP Right Cessation
-
1996
- 1996-10-29 EP EP96203007A patent/EP0773189B1/en not_active Expired - Lifetime
- 1996-10-29 DE DE69607289T patent/DE69607289T2/de not_active Expired - Fee Related
- 1996-10-29 ES ES96203007T patent/ES2146354T3/es not_active Expired - Lifetime
- 1996-11-05 KR KR1019960052714A patent/KR100416467B1/ko not_active Expired - Fee Related
- 1996-11-06 CO CO96058441A patent/CO4560567A1/es unknown
- 1996-11-06 RU RU96121521/12A patent/RU2159211C2/ru active
- 1996-11-07 SK SK1446-96A patent/SK282192B6/sk unknown
- 1996-11-08 CN CN96114556A patent/CN1051525C/zh not_active Expired - Fee Related
- 1996-11-08 BR BR9605490A patent/BR9605490A/pt not_active IP Right Cessation
- 1996-11-08 PL PL96316897A patent/PL316897A1/xx unknown
- 1996-11-08 MX MX9605488A patent/MX9605488A/es unknown
- 1996-11-08 JP JP33134496A patent/JP4058123B2/ja not_active Expired - Fee Related
- 1996-11-08 US US08/746,365 patent/US5792439A/en not_active Expired - Fee Related
- 1996-11-09 TW TW085113702A patent/TW449572B/zh not_active IP Right Cessation
- 1996-11-11 CZ CZ963312A patent/CZ331296A3/cs unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1387725A (en) * | 1971-07-01 | 1975-03-19 | Stamicarbon | Preparation of a hydroxylammonium salt solution |
| GB1515190A (en) * | 1974-09-23 | 1978-06-21 | Stamicarbon | Process for preparing a hydroxylammonium salt solution |
| US4832938A (en) * | 1988-05-13 | 1989-05-23 | E. I. Du Pont De Nemours And Company | Hydrogen peroxide production method using platinum/palladium catalysts |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103492313A (zh) * | 2011-04-22 | 2014-01-01 | 帝斯曼知识产权资产管理有限公司 | 催化的羟胺制备 |
| CN103492314A (zh) * | 2011-04-22 | 2014-01-01 | 帝斯曼知识产权资产管理有限公司 | 催化的羟胺制备 |
| CN103492313B (zh) * | 2011-04-22 | 2016-03-09 | Capiii有限公司 | 催化的羟胺制备 |
| CN103492314B (zh) * | 2011-04-22 | 2016-09-21 | Capiii有限公司 | 催化的羟胺制备 |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ331296A3 (cs) | 1998-05-13 |
| BE1009767A3 (nl) | 1997-08-05 |
| JPH09183614A (ja) | 1997-07-15 |
| DE69607289D1 (de) | 2000-04-27 |
| MX9605488A (es) | 1997-08-30 |
| DE69607289T2 (de) | 2000-11-30 |
| CO4560567A1 (es) | 1998-02-10 |
| BR9605490A (pt) | 1998-08-11 |
| SK144696A3 (en) | 1998-03-04 |
| RU2159211C2 (ru) | 2000-11-20 |
| US5792439A (en) | 1998-08-11 |
| SK282192B6 (sk) | 2001-12-03 |
| KR100416467B1 (ko) | 2004-04-17 |
| EP0773189B1 (en) | 2000-03-22 |
| CN1157257A (zh) | 1997-08-20 |
| JP4058123B2 (ja) | 2008-03-05 |
| EP0773189A1 (en) | 1997-05-14 |
| PL316897A1 (en) | 1997-05-12 |
| KR970026910A (ko) | 1997-06-24 |
| ES2146354T3 (es) | 2000-08-01 |
| TW449572B (en) | 2001-08-11 |
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