CN103748158B - 橡胶组合物及轮胎 - Google Patents
橡胶组合物及轮胎 Download PDFInfo
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- CN103748158B CN103748158B CN201280039788.6A CN201280039788A CN103748158B CN 103748158 B CN103748158 B CN 103748158B CN 201280039788 A CN201280039788 A CN 201280039788A CN 103748158 B CN103748158 B CN 103748158B
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- rubber
- polymkeric substance
- rubber combination
- farnesene
- carbon black
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 153
- 239000005060 rubber Substances 0.000 title claims abstract description 153
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 claims abstract description 128
- 239000000126 substance Substances 0.000 claims abstract description 85
- 239000006229 carbon black Substances 0.000 claims abstract description 67
- 239000000470 constituent Substances 0.000 claims abstract description 37
- CXENHBSYCFFKJS-UHFFFAOYSA-N (3E,6E)-3,7,11-Trimethyl-1,3,6,10-dodecatetraene Natural products CC(C)=CCCC(C)=CCC=C(C)C=C CXENHBSYCFFKJS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 25
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- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 21
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 21
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- 239000005061 synthetic rubber Substances 0.000 claims abstract description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 47
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 40
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- JSNRRGGBADWTMC-QINSGFPZSA-N (E)-beta-Farnesene Natural products CC(C)=CCC\C(C)=C/CCC(=C)C=C JSNRRGGBADWTMC-QINSGFPZSA-N 0.000 claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
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- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 9
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- 235000019241 carbon black Nutrition 0.000 description 63
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- 239000003795 chemical substances by application Substances 0.000 description 22
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
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- 229920000459 Nitrile rubber Polymers 0.000 description 5
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- 239000000047 product Substances 0.000 description 5
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 4
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- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/22—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having three or more carbon-to-carbon double bonds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L47/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
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- Chemical Kinetics & Catalysis (AREA)
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CN201610342576.5A CN106009069A (zh) | 2011-09-30 | 2012-09-21 | 橡胶组合物及轮胎 |
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PCT/JP2012/074168 WO2013047347A1 (ja) | 2011-09-30 | 2012-09-21 | ゴム組成物及びタイヤ |
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Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013115010A1 (ja) | 2012-02-01 | 2013-08-08 | 住友ゴム工業株式会社 | 分枝共役ジエン共重合体、ゴム組成物および空気入りタイヤ |
EP2810963B1 (en) | 2012-02-02 | 2017-05-03 | Sumitomo Rubber Industries, Ltd. | Branched conjugated diene copolymer, rubber composition and pneumatic tire |
ES2614822T3 (es) * | 2012-02-24 | 2017-06-02 | Kuraray Co., Ltd. | Composición de caucho y neumático |
US10040877B2 (en) | 2012-03-06 | 2018-08-07 | Sumitomo Rubber Industries, Ltd. | Hydrogenated branched conjugated diene copolymer, rubber composition and pneumatic tire |
EP2835386B1 (en) * | 2012-04-04 | 2017-01-11 | Kuraray Co., Ltd. | Copolymer, rubber composition using same, and tire |
KR101969311B1 (ko) * | 2012-04-04 | 2019-04-16 | 주식회사 쿠라레 | 공중합체, 그것을 사용한 고무 조성물 및 타이어 |
RU2631318C2 (ru) * | 2012-04-04 | 2017-09-21 | Курарей Ко., Лтд. | Сополимер, резиновая композиция с его использованием и шина |
JP6190806B2 (ja) * | 2012-06-08 | 2017-08-30 | 株式会社クラレ | 水添ブロック共重合体、及びその製造方法 |
US9822245B2 (en) | 2013-03-27 | 2017-11-21 | Sumitomo Rubber Industries, Ltd. | Studless winter tire |
JP6021734B2 (ja) * | 2013-05-10 | 2016-11-09 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
WO2014157624A1 (ja) * | 2013-03-29 | 2014-10-02 | 株式会社クラレ | 重合体及びその製造方法、並びに該重合体を含有する樹脂組成物 |
JP6504459B2 (ja) * | 2013-08-23 | 2019-04-24 | 株式会社クラレ | ゴム組成物、及びタイヤ |
JP6084911B2 (ja) * | 2013-09-10 | 2017-02-22 | 住友ゴム工業株式会社 | 空気入りタイヤ |
CN103467789B (zh) * | 2013-09-17 | 2015-08-12 | 山东永泰集团有限公司 | 一种充气轮胎 |
TWI617589B (zh) * | 2013-09-30 | 2018-03-11 | 可樂麗股份有限公司 | 樹脂組成物、使其硬化而成之硬化物及含有該樹脂組成物之光學用黏著劑 |
JP6352691B2 (ja) * | 2014-06-16 | 2018-07-04 | 住友ゴム工業株式会社 | トラック・バスタイヤ |
JP6348347B2 (ja) * | 2014-06-16 | 2018-06-27 | 住友ゴム工業株式会社 | 空気入りタイヤ |
KR101623027B1 (ko) * | 2014-06-30 | 2016-05-31 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어 |
JP2016030799A (ja) * | 2014-07-29 | 2016-03-07 | 株式会社クラレ | 加硫ゴム、加硫ゴムの製造方法及びタイヤ |
JP6375174B2 (ja) * | 2014-08-11 | 2018-08-15 | 株式会社クラレ | 変性ファルネセン重合体、及びその製造方法、ゴム組成物、並びにタイヤ |
JP6562603B2 (ja) * | 2014-08-11 | 2019-08-21 | 株式会社クラレ | 変性ファルネセン重合体を含むゴム組成物及びタイヤ、並びに変性ファルネセン重合体の製造方法 |
JP6440249B2 (ja) * | 2014-10-08 | 2018-12-19 | 株式会社クラレ | 免震構造体用ゴム組成物、及びこれを用いた免震構造体 |
JP2016089051A (ja) * | 2014-11-05 | 2016-05-23 | 株式会社クラレ | ゴム組成物及びタイヤ |
JP6520319B2 (ja) * | 2015-04-03 | 2019-05-29 | 横浜ゴム株式会社 | タイヤ用ゴム組成物 |
US9334394B1 (en) | 2015-06-03 | 2016-05-10 | Fina Technology, Inc. | Farnesene resins, rubber compositions, and tire compositions |
WO2017002651A1 (ja) * | 2015-06-30 | 2017-01-05 | 株式会社クラレ | ファルネセン重合体及びその製造方法 |
JP6423322B2 (ja) * | 2015-06-30 | 2018-11-14 | 株式会社クラレ | ゴム組成物、及びタイヤ |
JP6430901B2 (ja) * | 2015-06-30 | 2018-11-28 | 株式会社クラレ | ゴム組成物、及びタイヤ |
JP6360107B2 (ja) * | 2016-07-05 | 2018-07-18 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
US10544241B2 (en) | 2016-09-15 | 2020-01-28 | Fina Technology, Inc. | Farnesene-based macromonomers and methods of making and using the same |
CN108276808B (zh) * | 2017-01-05 | 2021-09-14 | 国家能源投资集团有限责任公司 | 一种补强填料及其制备方法 |
RU2742878C1 (ru) * | 2017-03-01 | 2021-02-11 | Сумитомо Раббер Индастриз, Лтд. | Нешипованная шина |
JP2018048349A (ja) * | 2017-12-14 | 2018-03-29 | 株式会社クラレ | ゴム組成物及びタイヤ |
KR102501596B1 (ko) * | 2018-07-17 | 2023-02-20 | 주식회사 엘지화학 | 변성 중합 개시제 및 이의 제조방법 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101885862A (zh) * | 2010-05-28 | 2010-11-17 | 北京化工大学 | 一种汽车轮胎用橡胶纳米短纤维复合材料及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2179555C (en) * | 1995-06-26 | 2007-02-20 | Takeshi Moritani | Process for producing vinyl acetate polymer and saponified product of vinyl acetate polymer and resin composition |
JP3516808B2 (ja) * | 1995-06-26 | 2004-04-05 | 株式会社クラレ | 酢酸ビニル系重合体の製法、酢酸ビニル系重合体ケン化物の製法および樹脂組成物 |
JP3217973B2 (ja) | 1996-08-12 | 2001-10-15 | 奇美実業股▲分▼有限公司 | スチレン系樹脂組成物 |
CN1051565C (zh) * | 1996-08-23 | 2000-04-19 | 奇美实业股份有限公司 | 苯乙烯系树脂组合物 |
US6220323B1 (en) * | 1998-01-29 | 2001-04-24 | The Goodyear Tire & Rubber Company | Composition and tire with tread containing calcium carbonate |
CN101550255B (zh) * | 2001-12-10 | 2011-05-04 | 埃克森美孚化学专利公司 | 弹性体组合物 |
WO2004000931A1 (ja) * | 2002-06-19 | 2003-12-31 | Bridgestone Corporation | タイヤ用ゴム組成物及びこれを用いたタイヤ |
JP2004091742A (ja) | 2002-09-03 | 2004-03-25 | Sanei Gen Ffi Inc | キーライム香料およびキーライム香料含有食品 |
JP4447877B2 (ja) * | 2003-10-03 | 2010-04-07 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物 |
WO2006052035A1 (ja) | 2004-12-21 | 2006-05-18 | Ube Industries, Ltd. | ゴム組成物 |
TW200813147A (en) | 2006-05-11 | 2008-03-16 | Ciba Sc Holding Ag | A non-agricultural article |
KR101472597B1 (ko) * | 2008-08-07 | 2014-12-15 | 스미도모 고무 고교 가부시기가이샤 | 타이어 |
TWI393742B (zh) | 2008-09-04 | 2013-04-21 | Amyris Inc | 聚法呢烯及含聚法呢烯的組合物 |
US7655739B1 (en) * | 2009-06-26 | 2010-02-02 | Amyris Biotechnologies, Inc. | Adhesive compositions comprising a polyfarnesene |
ES2381651T3 (es) * | 2008-09-04 | 2012-05-30 | Amyris, Inc. | Composiciones adhesivas que compreden un polifarneseno |
US8217128B2 (en) * | 2008-09-04 | 2012-07-10 | Amyris, Inc. | Farnesene interpolymers |
JP5402112B2 (ja) | 2009-03-11 | 2014-01-29 | Jsr株式会社 | ゴム組成物及び空気入りタイヤ |
JP2011132298A (ja) | 2009-12-22 | 2011-07-07 | Sumitomo Rubber Ind Ltd | 変性共重合体、それを用いたゴム組成物および空気入りタイヤ |
JP2011195804A (ja) | 2010-02-26 | 2011-10-06 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
US8785542B2 (en) | 2011-09-30 | 2014-07-22 | Kuraray Co., Ltd. | Rubber composition and tire |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101885862A (zh) * | 2010-05-28 | 2010-11-17 | 北京化工大学 | 一种汽车轮胎用橡胶纳米短纤维复合材料及其制备方法 |
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KR101388404B1 (ko) | 2014-04-22 |
CA2837545A1 (en) | 2013-04-04 |
EP2762525B1 (en) | 2016-09-14 |
PT2762525T (pt) | 2016-12-14 |
RU2613969C2 (ru) | 2017-03-22 |
JP2013234330A (ja) | 2013-11-21 |
IN2014CN02317A (ja) | 2015-06-19 |
JP6050727B2 (ja) | 2016-12-21 |
ES2605168T3 (es) | 2017-03-13 |
US8912269B2 (en) | 2014-12-16 |
US20150065636A1 (en) | 2015-03-05 |
KR20140007948A (ko) | 2014-01-20 |
TWI471375B (zh) | 2015-02-01 |
JP5314811B1 (ja) | 2013-10-16 |
TW201323505A (zh) | 2013-06-16 |
US20140213715A1 (en) | 2014-07-31 |
JPWO2013047347A1 (ja) | 2015-03-26 |
WO2013047347A1 (ja) | 2013-04-04 |
CN106009069A (zh) | 2016-10-12 |
CN103748158A (zh) | 2014-04-23 |
US9534111B2 (en) | 2017-01-03 |
RU2014112227A (ru) | 2015-11-10 |
EP2762525A1 (en) | 2014-08-06 |
EP2762525A4 (en) | 2015-08-12 |
BR112014007431B1 (pt) | 2020-10-13 |
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