JP5402112B2 - ゴム組成物及び空気入りタイヤ - Google Patents
ゴム組成物及び空気入りタイヤ Download PDFInfo
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- JP5402112B2 JP5402112B2 JP2009058407A JP2009058407A JP5402112B2 JP 5402112 B2 JP5402112 B2 JP 5402112B2 JP 2009058407 A JP2009058407 A JP 2009058407A JP 2009058407 A JP2009058407 A JP 2009058407A JP 5402112 B2 JP5402112 B2 JP 5402112B2
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- 229920001971 elastomer Polymers 0.000 title claims description 106
- 239000005060 rubber Substances 0.000 title claims description 106
- 239000000203 mixture Substances 0.000 title claims description 66
- 150000001875 compounds Chemical class 0.000 claims description 96
- -1 tin carboxylate Chemical class 0.000 claims description 85
- 125000004432 carbon atom Chemical group C* 0.000 claims description 72
- 229920000642 polymer Polymers 0.000 claims description 70
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 56
- 150000001993 dienes Chemical class 0.000 claims description 45
- 239000004636 vulcanized rubber Substances 0.000 claims description 41
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
- 239000000377 silicon dioxide Substances 0.000 claims description 28
- 150000003839 salts Chemical class 0.000 claims description 27
- 150000002430 hydrocarbons Chemical group 0.000 claims description 26
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 26
- 239000000945 filler Substances 0.000 claims description 25
- 229920003244 diene elastomer Polymers 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 19
- 125000004122 cyclic group Chemical group 0.000 claims description 18
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 16
- 125000000524 functional group Chemical group 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 125000001931 aliphatic group Chemical group 0.000 claims description 15
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 15
- 239000006229 carbon black Substances 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 125000001302 tertiary amino group Chemical group 0.000 claims description 11
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- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 238000009833 condensation Methods 0.000 claims description 10
- 230000005494 condensation Effects 0.000 claims description 10
- 125000003700 epoxy group Chemical group 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 125000002015 acyclic group Chemical group 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- AWIJRPNMLHPLNC-UHFFFAOYSA-N methanethioic s-acid Chemical compound SC=O AWIJRPNMLHPLNC-UHFFFAOYSA-N 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 7
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- 239000003607 modifier Substances 0.000 claims description 7
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 7
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- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
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- 125000005370 alkoxysilyl group Chemical group 0.000 claims description 5
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 5
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
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- 238000010539 anionic addition polymerization reaction Methods 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 4
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 claims description 4
- 125000003172 aldehyde group Chemical group 0.000 claims description 3
- 150000007933 aliphatic carboxylic acids Chemical group 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical group O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 3
- NONOKGVFTBWRLD-UHFFFAOYSA-N isocyanatosulfanylimino(oxo)methane Chemical group O=C=NSN=C=O NONOKGVFTBWRLD-UHFFFAOYSA-N 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 125000004076 pyridyl group Chemical group 0.000 claims description 3
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 3
- 125000000101 thioether group Chemical group 0.000 claims description 3
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 3
- 150000003606 tin compounds Chemical class 0.000 claims description 3
- 150000003609 titanium compounds Chemical class 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 241000872198 Serjania polyphylla Species 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 29
- 238000005096 rolling process Methods 0.000 description 26
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- 150000002602 lanthanoids Chemical class 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 239000002685 polymerization catalyst Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- 239000000178 monomer Substances 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 239000002879 Lewis base Substances 0.000 description 12
- 239000000446 fuel Substances 0.000 description 12
- 150000007527 lewis bases Chemical class 0.000 description 12
- 229920002554 vinyl polymer Polymers 0.000 description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 125000002947 alkylene group Chemical group 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 229910052718 tin Inorganic materials 0.000 description 9
- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 description 8
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 8
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000007942 carboxylates Chemical class 0.000 description 7
- 230000009477 glass transition Effects 0.000 description 7
- 239000011572 manganese Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- 239000004606 Fillers/Extenders Substances 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000004898 kneading Methods 0.000 description 6
- 229910001507 metal halide Inorganic materials 0.000 description 6
- 150000005309 metal halides Chemical class 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910052779 Neodymium Inorganic materials 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 125000003277 amino group Chemical group 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
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- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
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- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 4
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- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 3
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
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- 238000013329 compounding Methods 0.000 description 3
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
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- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
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- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
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- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
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- DZMKDJZCKIJKFW-UHFFFAOYSA-N di(octan-2-yl)phosphinic acid Chemical compound CCCCCCC(C)P(O)(=O)C(C)CCCCCC DZMKDJZCKIJKFW-UHFFFAOYSA-N 0.000 description 1
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- GSYVJAOBRKCNOT-UHFFFAOYSA-N diethoxymethyl-[3-[3-(diethoxymethylsilyl)propyltetrasulfanyl]propyl]silane Chemical compound CCOC(OCC)[SiH2]CCCSSSSCCC[SiH2]C(OCC)OCC GSYVJAOBRKCNOT-UHFFFAOYSA-N 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
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- PWPGWRIGYKWLEV-UHFFFAOYSA-N dimethoxy-methyl-[2-(oxiran-2-ylmethoxy)ethyl]silane Chemical compound CO[Si](C)(OC)CCOCC1CO1 PWPGWRIGYKWLEV-UHFFFAOYSA-N 0.000 description 1
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
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- LQQFSMCMZMSDQQ-UHFFFAOYSA-M dimethyl-octadecyl-(3-trimethylsilylpropyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCC[Si](C)(C)C LQQFSMCMZMSDQQ-UHFFFAOYSA-M 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
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- DXQYKFGICLVQFD-UHFFFAOYSA-N dioctan-2-yl hydrogen phosphate Chemical compound CCCCCCC(C)OP(O)(=O)OC(C)CCCCCC DXQYKFGICLVQFD-UHFFFAOYSA-N 0.000 description 1
- GNPSMYTXIPVJDU-UHFFFAOYSA-N dioctylalumane Chemical compound C(CCCCCCC)[AlH]CCCCCCCC GNPSMYTXIPVJDU-UHFFFAOYSA-N 0.000 description 1
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 1
- HCWOVPZEAFLXPL-UHFFFAOYSA-N diphenyl propanedioate Chemical compound C=1C=CC=CC=1OC(=O)CC(=O)OC1=CC=CC=C1 HCWOVPZEAFLXPL-UHFFFAOYSA-N 0.000 description 1
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- 239000012847 fine chemical Substances 0.000 description 1
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- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
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- RIWRFSMVIUAEBX-UHFFFAOYSA-N n-methyl-1-phenylmethanamine Chemical compound CNCC1=CC=CC=C1 RIWRFSMVIUAEBX-UHFFFAOYSA-N 0.000 description 1
- DTPZJXALAREFEY-UHFFFAOYSA-N n-methyl-3-triethoxysilylpropan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNC DTPZJXALAREFEY-UHFFFAOYSA-N 0.000 description 1
- DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- IJJSYKQZFFGIEE-UHFFFAOYSA-N naphthalene;potassium Chemical compound [K].C1=CC=CC2=CC=CC=C21 IJJSYKQZFFGIEE-UHFFFAOYSA-N 0.000 description 1
- URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- DZNFWGVDYGAMJB-UHFFFAOYSA-K neodymium(3+);phosphate Chemical compound [Nd+3].[O-]P([O-])([O-])=O DZNFWGVDYGAMJB-UHFFFAOYSA-K 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- PFENPVAFZTUOOM-UHFFFAOYSA-N phenyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OC1=CC=CC=C1 PFENPVAFZTUOOM-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- IGALFTFNPPBUDN-UHFFFAOYSA-N phenyl-[2,3,4,5-tetrakis(oxiran-2-ylmethyl)phenyl]methanediamine Chemical compound C=1C(CC2OC2)=C(CC2OC2)C(CC2OC2)=C(CC2OC2)C=1C(N)(N)C1=CC=CC=C1 IGALFTFNPPBUDN-UHFFFAOYSA-N 0.000 description 1
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- ZILUASOLDUBEBG-UHFFFAOYSA-N propanenitrile;propan-2-one Chemical compound CCC#N.CC(C)=O ZILUASOLDUBEBG-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 125000005374 siloxide group Chemical group 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- KXLQKNLVPVYVKX-UHFFFAOYSA-J tetrabromorhenium Chemical compound Br[Re](Br)(Br)Br KXLQKNLVPVYVKX-UHFFFAOYSA-J 0.000 description 1
- UXMRNSHDSCDMLG-UHFFFAOYSA-J tetrachlororhenium Chemical compound Cl[Re](Cl)(Cl)Cl UXMRNSHDSCDMLG-UHFFFAOYSA-J 0.000 description 1
- KGKLLWHEYDUTBF-UHFFFAOYSA-J tetraiodorhenium Chemical compound I[Re](I)(I)I KGKLLWHEYDUTBF-UHFFFAOYSA-J 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- YSCVYRUCAPMZFG-UHFFFAOYSA-K trichlorotin Chemical compound Cl[Sn](Cl)Cl YSCVYRUCAPMZFG-UHFFFAOYSA-K 0.000 description 1
- ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 description 1
- KMLVDTJUQJXRRH-UHFFFAOYSA-N triethoxy(2-pyridin-2-ylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC=N1 KMLVDTJUQJXRRH-UHFFFAOYSA-N 0.000 description 1
- MMZPUXVBQAQQDQ-UHFFFAOYSA-N triethoxy(2-pyridin-4-ylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=NC=C1 MMZPUXVBQAQQDQ-UHFFFAOYSA-N 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- LENYMJLFWIMHEP-UHFFFAOYSA-N triethoxy(3-pyrrolidin-1-ylpropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN1CCCC1 LENYMJLFWIMHEP-UHFFFAOYSA-N 0.000 description 1
- FPDNTFVPPHWDGF-UHFFFAOYSA-N triethoxy(sulfonylmethyl)silane Chemical compound CCO[Si](OCC)(OCC)C=S(=O)=O FPDNTFVPPHWDGF-UHFFFAOYSA-N 0.000 description 1
- UDUKMRHNZZLJRB-UHFFFAOYSA-N triethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OCC)(OCC)OCC)CCC2OC21 UDUKMRHNZZLJRB-UHFFFAOYSA-N 0.000 description 1
- RWJUTPORTOUFDY-UHFFFAOYSA-N triethoxy-[2-(oxiran-2-ylmethoxy)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCOCC1CO1 RWJUTPORTOUFDY-UHFFFAOYSA-N 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- KLFNHRIZTXWZHT-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSCCC[Si](OCC)(OCC)OCC KLFNHRIZTXWZHT-UHFFFAOYSA-N 0.000 description 1
- XSIGLRIVXRKQRA-UHFFFAOYSA-N triethoxysilylmethanethiol Chemical compound CCO[Si](CS)(OCC)OCC XSIGLRIVXRKQRA-UHFFFAOYSA-N 0.000 description 1
- HPEPIADELDNCED-UHFFFAOYSA-N triethoxysilylmethanol Chemical compound CCO[Si](CO)(OCC)OCC HPEPIADELDNCED-UHFFFAOYSA-N 0.000 description 1
- PPLMQFARLJLZAO-UHFFFAOYSA-N triethyl(iodo)silane Chemical compound CC[Si](I)(CC)CC PPLMQFARLJLZAO-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- GCZKMPJFYKFENV-UHFFFAOYSA-K triiodogold Chemical compound I[Au](I)I GCZKMPJFYKFENV-UHFFFAOYSA-K 0.000 description 1
- XVZMLSWFBPLMEA-UHFFFAOYSA-N trimethoxy(2-pyridin-2-ylethyl)silane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC=N1 XVZMLSWFBPLMEA-UHFFFAOYSA-N 0.000 description 1
- JEWZDPPVTXQKCA-UHFFFAOYSA-N trimethoxy(2-pyridin-4-ylethyl)silane Chemical compound CO[Si](OC)(OC)CCC1=CC=NC=C1 JEWZDPPVTXQKCA-UHFFFAOYSA-N 0.000 description 1
- NGLLPRYTJGRGEU-UHFFFAOYSA-N trimethoxy(3-pyrrolidin-1-ylpropyl)silane Chemical compound CO[Si](OC)(OC)CCCN1CCCC1 NGLLPRYTJGRGEU-UHFFFAOYSA-N 0.000 description 1
- SQSDQKFNZWSCJT-UHFFFAOYSA-N trimethoxy(sulfonylmethyl)silane Chemical compound CO[Si](OC)(OC)C=S(=O)=O SQSDQKFNZWSCJT-UHFFFAOYSA-N 0.000 description 1
- JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- ZNXDCSVNCSSUNB-UHFFFAOYSA-N trimethoxy-[2-(oxiran-2-ylmethoxy)ethyl]silane Chemical compound CO[Si](OC)(OC)CCOCC1CO1 ZNXDCSVNCSSUNB-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- QJOOZNCPHALTKK-UHFFFAOYSA-N trimethoxysilylmethanethiol Chemical compound CO[Si](CS)(OC)OC QJOOZNCPHALTKK-UHFFFAOYSA-N 0.000 description 1
- SPHALHRGAQVBKI-UHFFFAOYSA-N trimethoxysilylmethanol Chemical compound CO[Si](CO)(OC)OC SPHALHRGAQVBKI-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- JOJQVUCWSDRWJE-UHFFFAOYSA-N tripentylalumane Chemical compound CCCCC[Al](CCCCC)CCCCC JOJQVUCWSDRWJE-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 229960001939 zinc chloride Drugs 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Description
Sn(OCOR 10 ) 2 ・・・(4)
(前記一般式(4)中、R 10 は、相互に独立に、炭素数2〜19の有機基を示す)
R 11 r SnA 4 t B 1 (4−t−r) ・・・(5)
(前記一般式(5)中、A 4 は、炭素数2〜30の脂肪族カルボン酸残基、炭素数5〜30の1,3−ジカルボニル含有基、炭素数1〜30のヒドロカルビルオキシ基、及び炭素数1〜20のヒドロカルビル基からなる群より選択される基で合計三置換(同一であっても、異なっていてもよい)されたシロキシ基を示し、B 1 は、ヒドロキシル基又はハロゲン原子を示し、R 11 は、炭素数1〜30の脂肪族炭化水素基を示し、rは、1〜3の整数を示し、tは、1又は2の整数を示し、t+r=3又は4である。A 4 が複数ある場合には、複数のA 4 は同一であっても、異なっていてもよい。R 11 が複数ある場合には、複数のR 11 は同一であっても、異なっていてもよい)
A 5 x TiB 2 (4−x) ・・・(6)
(前記一般式(6)中、A 5 は、炭素数1〜30のヒドロカルビルオキシ基、及び炭素数1〜30のアルキル基からなる群より選択される基で合計三置換されたシロキシ基を示し、B 2 は、炭素数5〜30の1,3−ジカルボニル含有基を示し、xは、2又は4の整数を示す。A 5 が複数ある場合には、複数のA 5 は同一であっても、異なっていてもよい。B 2 が複数ある場合には、複数のB 2 は同一であっても、異なっていてもよい)
本発明のゴム組成物は、(A)ゴム成分と、(B)充填剤と、を含有するものである。以下、その詳細について説明する。
(A)ゴム成分は、ジエン系ゴムを含有するものである。このジエン系ゴムには、(a1)変性スチレン−ブタジエン共重合体(以下、「(a1)共重合体」ともいう)、及び(a2)変性共役ジエン系重合体(以下、「(a2)重合体」ともいう)が含有されている。なお、ジエン系ゴムは、本質的に(a1)共重合体と(a2)重合体からなるものであることが好ましい。
ジエン系ゴムに含有される(a1)共重合体の割合は、(a1)共重合体と(a2)重合体の合計を100質量%とした場合に、20質量%以上、好ましくは20〜95質量%、更に好ましくは25〜90質量%である。(a1)共重合体の含有割合が20質量%未満であると、加硫ゴムの破壊強度、耐摩耗性、転がり抵抗性が劣る場合がある。
(a1)共重合体は、スチレン−ブタジエン共重合体の末端が変性されたもの(変性SBR)である。(a1)共重合体に含まれる1,3−ブタジエンに由来する構造単位の割合は、全構造単位中、通常、55〜99質量%、好ましくは55〜95質量%、更に好ましくは58〜90質量%である。また、1,3−ブタジエンに由来する構造単位中のビニル結合含有量は、通常、70%以下、好ましくは15〜70%、更に好ましくは18〜67%である。ビニル結合含有量が70%超であると、加硫ゴムの破壊強度、耐摩耗性、転がり抵抗性が劣る場合がある。なお、1,3−ブタジエンに由来する構造単位中のビニル結合含有量は、重合反応中にエーテル化合物と3級アミン化合物の少なくともいずれかを添加することで調整することができる。
(a2)重合体は、シス−1,4−結合の含有割合が80%以上である共役ジエン系重合体の活性末端がアルコキシシラン化合物で第一次変性されたものである。
(a2)重合体を調製するために用いられる共役ジエン系重合体は、共役ジエン化合物に由来する構造単位中、シス−1,4−結合の含有割合が80%以上、好ましくは、82%以上、更に好ましくは84%以上のものである。この共役ジエン系重合体を調製する際の重合反応方法については、特に制限されるものではなく、溶液重合方法、気相重合方法、バルク重合方法等の従来公知の方法を用いることができる。なかでも、溶液重合方法が好ましい。溶液重合方法により重合を行う場合、反応に不活性な有機溶媒を重合溶媒として使用することが好ましい。重合溶媒として用いられる有機溶媒の具体例としては、脂肪族、脂環族、芳香族等の炭化水素溶媒等を挙げることができる。より具体的には、プロパン、n−ブタン、イソブタン、n−ペンタン、イソペンタン、n−ヘキサン、シクロヘキサン、プロペン、1−ブテン、イソブテン、トランス−2−ブテン、シス−2−ブテン、1−ペンテン、2−ペンテン、1−ヘキセン、2−ヘキセン、ベンゼン、トルエン、キシレン、エチルベンゼン等を挙げることができる。なお、これらの有機溶媒は、一種単独で又は二種以上を組み合わせて用いることができる。
(f)成分:アルモキサン、及び/又は、一般式(4):AlR10R11R12で表される有機アルミニウム化合物(但し、一般式(4)中、R10及びR11は、相互に独立に、水素原子又は炭素数1〜10の炭化水素基を示し、R12は、炭素数1〜10の炭化水素基を示す)
(g)成分:その分子構造中に少なくとも一つのハロゲン元素を含有するハロゲン含有化合物
共役ジエン系重合体の活性末端を第一次変性するために用いるアルコキシシラン化合物は、下記一般式(1)で表される化合物、下記一般式(2)で表される化合物、下記一般式(3)で表される化合物、及びこれらの化合物の部分縮合物からなる群より選択される少なくとも一種である。なお、ここでいう「部分縮合物」とは、下記一般式(1)〜(3)で表される化合物のSi−OR結合の一部(全部ではない)が、縮合によりSi−O−Si結合に変化したものをいう。
縮合促進剤は、下記一般式(4)で表される酸化数2のスズの炭素数3〜20のカルボン酸塩、下記一般式(5)で表される酸化数4のスズ化合物、及び下記一般式(6)で表される酸化数4のチタン化合物からなる群より選択される少なくとも一種の化合物と、水と、からなるものである。
Sn(OCOR10)2 ・・・(4)
R11 rSnA4 tB1 (4−t−r) ・・・(5)
A5 xTiB2 (4−x) ・・・(6)
第二次変性は、縮合促進剤の存在下、例えばアルコキシシラン化合物を用いて行われる。この際に用いられるアルコキシシラン化合物の具体例としては、前述の「アルコキシシラン化合物」において例示したものと同様のものを挙げることができる。なお、第一次変性の際に用いられるアルコキシシラン化合物と、第二次変性の際に用いられるアルコキシシラン化合物は、異なるものであってもよいが、同一のものであることが好ましい。
(A)ゴム成分に含有されるジエン系ゴムには、(a1)共重合体及び(a2)重合体以外の「他のジエン系ゴム」が含有されていてもよい。「他のジエン系ゴム」の具体例としては、天然ゴム、ポリイソプレンゴム、高シス1,4結合−ポリブタジエンゴム等を挙げることができる。なお、「他のジエン系ゴム」をジエン系ゴムに含有させる場合における、「他のジエン系ゴム」の割合は、ジエン系ゴムの全体に対して75質量%以下であることが好ましく、50質量%以下であることが更に好ましく、40質量%以下であることが特に好ましい。
(B)充填剤には、(b1)カーボンブラックと(b2)シリカの少なくともいずれかが含有されている。この(B)充填剤は、加硫ゴムの引張強度等の破壊特性、耐摩耗性、転がり抵抗性等を向上させるとともに、ゴム組成物の加工性を良好にする効果がある。
(b1)カーボンブラックは、加硫ゴムの引張強度等の破壊特性の改良効果に優れる。特に制限されるものではないが、(b1)カーボンブラックの具体例としては、SRF、GPF、FEF、ISAF、SAF等を挙げることができる。なかでも、ヨウ素吸着量が60mg以上であるとともに、ジブチルフタレート吸油量が80mL/100gであるものが好ましく、得られる加硫ゴムの耐摩耗性を向上させる観点からは、HAF、ISAF、SAFが更に好ましい。
特に制限されるものではないが、(b2)シリカの具体例としては、湿式シリカ、乾式シリカ、ケイ酸カルシウム、ケイ酸アルミニウム等を挙げることができる。なかでも、得られる加硫ゴムの引張強度等の破壊強度、ウェッドスキッド抵抗性、転がり抵抗性を向上させる観点からは、湿式シリカが好ましい。
(B)充填剤には、(b1)カーボンブラック及び(b2)シリカ以外の(b3)無機充填剤を含有させることもできる。(b3)無機充填剤の具体例としては、水酸化アルミニウム、水酸化マグネシウム、酸化マグネシウム、タルク、アタパルジャイト、チタン白、チタン黒、酸化カルシウム、水酸化カルシウム、酸化アルミニウムマグネシウム、クレー、カオリン、パイロフィライト、ベントナイト、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムカルシウム、ケイ酸マグネシウムカルシウム、マイカ等を挙げることができる。なお、これらの(b3)無機充填剤は、一種単独で又は二種以上を組み合わせて用いることができる。
本発明のゴム組成物には、その性質を損なわない範囲で、(A)ゴム成分以外の「他のゴム」を含有させることができる。「他のゴム」の具体例としては、エチレン−プロピレンゴム、シリコーンゴム、フッ化ビニリデンゴム等を挙げることができる。なお、「他のゴム」を本発明のゴム組成物に含有させる場合における、「他のゴム」の割合は、(A)ゴム成分の全体に対して0〜30質量%であることが好ましく、0〜25質量%であることが更に好ましく、0〜20質量%であることが特に好ましい。
本発明のゴム組成物には、その性質を損なわない範囲で、(A)ゴム成分及び(B)充填剤以外のその他の成分を含有させることもできる。その他の成分の具体例としては、加硫剤、加硫促進剤、プロセス油、老化防止剤、スコーチ防止剤、亜鉛華、ステアリン酸、ワックス等の加工助剤、粘着付与剤等を挙げることができる。
本発明のゴム組成物は、耐摩耗性、破壊強度、転がり抵抗性、ウェッドスキッド抵抗性等に優れた空気入りタイヤ等を製造するのに好適な加硫ゴムを調製可能なものである。このため本発明のゴム組成物は、タイヤトレッド用の加硫ゴムを製造するための材料として好適である。なお、タイヤトレッド用以外にも、アンダートレッド用、カーカス用、サイドウォール用、及びビート部用の加硫ゴムを製造するための材料としても好適である。
本発明のゴム組成物は、(A)ゴム成分、及び(B)充填剤、並びに必要に応じて添加させるその他の成分を混練することで製造することができる。混練に際しては、ロール等の開放式混練機、バンバリーミキサーをはじめとする密閉式混練機等の混練機を用いることができる。なお、混練に際しては、ゴム組成物に伸展油を配合することも好ましい。伸展油を配合すると、ゴム組成物の加工性を良好にすることができる。伸展油の配合量は、(A)ゴム成分100質量部に対して、6〜55質量部であることが好ましく、10〜50質量部であることが更に好ましい。伸展油の配合量が6質量部未満であると、加工性と低燃費性を両立させることが困難な場合がある。一方、55質量部超であると、低燃費性に劣る場合がある。
本発明の空気入りタイヤは、前述のゴム組成物を用いてなるものである。より具体的には、本発明の空気入りタイヤは、前述のゴム組成物を加硫して得られる加硫ゴムを用いて製造されるものである。このため、本発明の空気入りタイヤは、耐摩耗性、破壊強度、転がり抵抗性、ウェッドスキッド抵抗性等に優れたものである。
カラム:商品名「カラムGMHHXL」(東ソー社製)
流速:1.0m/s
温度:50℃
窒素置換された内容積5Lのオートクレーブ反応器に、シクロヘキサン2500g、テトラヒドロフラン25g、スチレン100g、及び1,3−ブタジエン390gを仕込んだ。反応器の内容物の温度を20℃に調整した後、n−ブチルリチウム375mgを添加して重合を開始した。断熱条件で重合し、最高温度は85℃に達した。重合転化率が99%に達した時点でブタジエン10gを追加し、更に5分重合させた後、メチルトリエトキシシラン1043mgを変性剤として加えて15分間反応を行った。重合反応終了後、2,6−ジ−tert−ブチル−p−クレゾールを添加した。次いで、スチームストリッピングにより脱溶媒を行い、110℃に調温された熱ロールにより乾燥して変性スチレン−ブタジエン共重合体(SBR−A)を得た。得られたSBR−Aのビニル結合含有量は55%、結合スチレン含有量は20%、ガラス転移温度は−36℃、ムーニー粘度(ML1+4,100℃)は28、及び重量平均分子量(Mw)は2300000であった。
表1に示す配合処方としたこと以外は、前述の合成例1の場合と同様の操作により変性スチレン−ブタジエン共重合体(SBR−B、SBR−C、SBR−D、SBR−E)を得た。得られたSBR−B〜SBR−Eのビニル結合含有量、結合スチレン含有量、ガラス転移温度、ムーニー粘度(ML1+4,100℃)、及び重量平均分子量(Mw)を表1に示す。
窒素置換された内容積5Lのオートクレーブ反応器に、シクロヘキサン2500g、テトラヒドロフラン25g、スチレン100g、及び1,3−ブタジエン390gを仕込んだ。反応器の内容物の温度を20℃に調整した後、n−ブチルリチウム375mg及びピペリジン473mgをシクロヘキサン溶剤中で予め反応させて調製した開始剤を添加して重合を開始した。断熱条件で重合し、最高温度は85℃に達した。重合転化率が99%に達した時点でブタジエン10gを追加し、更に5分重合させた後、N−メチルピロリドン579mgを変性剤として加えて10分間反応を行った。その後、四塩化スズ85mgを更に加えて10分間反応を行った。重合反応終了後、2,6−ジ−tert−ブチル−p−クレゾールを添加した。次いで、スチームストリッピングにより脱溶媒を行い、110℃に調温された熱ロールにより乾燥して変性スチレン−ブタジエン共重合体(SBR−F)を得た。得られたSBR−Fのビニル結合含有量、結合スチレン含有量、ガラス転移温度、ムーニー粘度(ML1+4,100℃)、及び重量平均分子量(Mw)を表1に示す。
窒素置換された5Lオートクレーブに、窒素雰囲気下、シクロヘキサン2400g、及び1,3−ブタジエン300gを仕込んだ。バーサチック酸ネオジム(0.09mmol)のシクロヘキサン溶液、メチルアルモキサン(1.8mmol)のトルエン溶液、水素化ジイソブチルアルミニウム(5.0mmol)、四塩化ケイ素(0.045mmol)のトルエン溶液、及び1,3−ブタジエン(4.5mmol)を、50℃で30分間反応熟成させて予め調製した触媒を添加し、80℃で60分間重合反応を行った。1,3−ブタジエンの重合転化率は、ほぼ100%であった。重合体溶液200gを抜き取り、2,4−ジ−tert−ブチル−p−クレゾール1.5gを含むメタノール溶液を添加し、重合反応を停止させた。次いで、スチームストリッピングにより脱溶媒を行い、110℃に調温されたロールにより乾燥して共役ジエン系重合体を得た。得られた共役ジエン系重合体(変性反応前)のシス−1,4−結合含有量は97%、1,2−ビニル結合含有量は1.1%、分子量分布(Mw/Mn)は2.2、及びムーニー粘度(ML1+4,100℃)は18であった。
表2に示す配合処方としたこと以外は、前述の合成例7の場合と同様の操作により変性共役ジエン系重合体(BR−Z)を得た。得られたBR−Zの分子量分布(Mw/Mn)、及びムーニー粘度(ML1+4,100℃)を表2に示す。
変性スチレン−ブタジエン共重合体(SBR−A)70部、変性共役ジエン系重合体(BR−Y)30部、伸展油(商品名「アロマックス#3」(富士興産社製))37.5部、シリカ(商品名「ニプシルAQ」(日本シリカ社製))70部、カーボンブラック(商品名「ダイアブラックN339」(三菱化学社製))5.6部、シランカップリング剤(商品名「Si69」(デグサ社製))5.6部、ステアリン酸2部、老化防止剤(商品名「ノクラック810NA」(大内新興化学工業社製))1部、酸化亜鉛3部、加硫促進剤NS(商品名「ノクセラーNS・F」(大内新興化学工業社製))1.5部、加硫促進剤CZ(商品名「ノクセラーCZ」(大内新興化学工業社製))1.8部、及び硫黄1.5部を配合して配合物を得た。なお、配合処方を表3に示す。250ccラボプラストミルを用いて得られた配合物を混練し、ゴム組成物(実施例1)を得た。得られたゴム組成物を145℃加硫して加硫ゴムを調製した。調製した加硫ゴムの引張強度(指数)は118、tanδ(0℃)(指数)は116、tanδ(50℃)(指数)は129、及び耐摩耗性(指数)は122であった。
表4に示す種類の(変性)スチレン−ブタジエン共重合体、及び(変性)共役ジエン系重合体を使用したこと以外は、前述の実施例1の場合と同様の操作により、ゴム組成物(実施例2〜12、比較例1〜9)を得た。また、得られたゴム組成物(実施例2〜12、比較例1〜9)を用いて、前述の実施例1の場合と同様の操作により、加硫ゴムを調製した。調製した加硫ゴムの引張強度(指数)、tanδ(0℃)(指数)、tanδ(50℃)(指数)、及び耐摩耗性(指数)を表4に示す。
BR01:商品名「ポリブタジエンゴムBR01」、JSR社製(シス−1,4−結合含有量=95%、1,2−ビニル結合含有量=2.5%、ムーニー粘度(ML1+4,100℃)=45)
Claims (8)
- スチレン−ブタジエン共重合体の末端が変性された(a1)変性スチレン−ブタジエン共重合体を20質量%以上、及び(a2)変性共役ジエン系重合体を5質量%以上含有するジエン系ゴムを含む(A)ゴム成分と、
(B)充填剤と、を含有し、
前記(a1)変性スチレン−ブタジエン共重合体が、前記スチレン−ブタジエン共重合体の末端に、エポキシ基、水酸基、3級アミノ基、ヘテロ環、及びアルコキシシリル基からなる群より選択される少なくとも一種の官能基が導入されたものであり、
前記(a2)変性共役ジエン系重合体が、シス−1,4−結合の含有割合が80%以上である共役ジエン系重合体の活性末端が、下記一般式(1)で表される化合物、下記一般式(2)で表される化合物、下記一般式(3)で表される化合物、及びこれらの化合物の部分縮合物からなる群より選択される少なくとも一種のアルコキシシラン化合物で第一次変性された後、下記一般式(4)で表される酸化数2のスズの炭素数3〜20のカルボン酸塩、下記一般式(5)で表される酸化数4のスズ化合物、及び下記一般式(6)で表される酸化数4のチタン化合物からなる群より選択される少なくとも一種の化合物と、水と、を含んでなる縮合促進剤の存在下で第二次変性されて得られたものであり、
前記(B)充填剤が、前記(A)ゴム成分100質量部に対して2〜100質量部の(b1)カーボンブラックと、前記(A)ゴム成分100質量部に対して30〜100質量部の(b2)シリカの少なくともいずれかを含有するものであるゴム組成物。
Sn(OCOR 10 ) 2 ・・・(4)
(前記一般式(4)中、R 10 は、相互に独立に、炭素数2〜19の有機基を示す)
R 11 r SnA 4 t B 1 (4−t−r) ・・・(5)
(前記一般式(5)中、A 4 は、炭素数2〜30の脂肪族カルボン酸残基、炭素数5〜30の1,3−ジカルボニル含有基、炭素数1〜30のヒドロカルビルオキシ基、及び炭素数1〜20のヒドロカルビル基からなる群より選択される基で合計三置換(同一であっても、異なっていてもよい)されたシロキシ基を示し、B 1 は、ヒドロキシル基又はハロゲン原子を示し、R 11 は、炭素数1〜30の脂肪族炭化水素基を示し、rは、1〜3の整数を示し、tは、1又は2の整数を示し、t+r=3又は4である。A 4 が複数ある場合には、複数のA 4 は同一であっても、異なっていてもよい。R 11 が複数ある場合には、複数のR 11 は同一であっても、異なっていてもよい)
A 5 x TiB 2 (4−x) ・・・(6)
(前記一般式(6)中、A 5 は、炭素数1〜30のヒドロカルビルオキシ基、及び炭素数1〜30のアルキル基からなる群より選択される基で合計三置換されたシロキシ基を示し、B 2 は、炭素数5〜30の1,3−ジカルボニル含有基を示し、xは、2又は4の整数を示す。A 5 が複数ある場合には、複数のA 5 は同一であっても、異なっていてもよい。B 2 が複数ある場合には、複数のB 2 は同一であっても、異なっていてもよい) - 前記(B)充填剤が、前記(b2)シリカを含有するものである場合に、
前記(b2)シリカ100質量部に対して、5〜20質量部のシランカップリング剤を更に含有する請求項1に記載のゴム組成物。 - 前記(a1)変性スチレン−ブタジエン共重合体が、有機アルカリ金属、有機アルカリ土類金属、アルカリ金属アミド化合物、及びアルカリ土類金属アミド化合物からなる群より選択される少なくとも一種の化合物を開始剤として使用して、ブタジエンとスチレンを炭化水素溶媒中でアニオン重合させた後、その活性重合体末端と変性剤を反応させて得られたものである請求項1又は2に記載のゴム組成物。
- 前記アルコキシシラン化合物が、前記一般式(1)で表される化合物と前記一般式(1)で表される化合物の部分縮合物の少なくともいずれかである請求項1〜3のいずれか一項に記載のゴム組成物。
- 前記アルコキシシラン化合物が、3−グリシドキシプロピルトリメトキシシラン、3−グリシドキシプロピルトリエトキシシラン、及びこれらの化合物の部分縮合物からなる群より選択される少なくとも一種である請求項4に記載のゴム組成物。
- 前記(a2)変性共役ジエン系重合体が、変性ポリブタジエンである請求項1〜5のいずれか一項に記載のゴム組成物。
- タイヤトレッド用の加硫ゴムに用いられる請求項1〜6のいずれか一項に記載のゴム組成物。
- 請求項1〜7のいずれか一項に記載のゴム組成物を用いてなる空気入りタイヤ。
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RU2617481C2 (ru) | 2012-02-24 | 2017-04-25 | Курарей Ко., Лтд. | Резиновая композиция и шина |
CN104364280B (zh) | 2012-04-04 | 2017-03-01 | 株式会社可乐丽 | 共聚物、使用了其的橡胶组合物和轮胎 |
KR102047639B1 (ko) | 2012-04-04 | 2019-11-21 | 주식회사 쿠라레 | 공중합체, 그것을 사용한 고무 조성물 및 타이어 |
JP2014025030A (ja) * | 2012-07-30 | 2014-02-06 | Jsr Corp | 変性重合体の製造方法及び分散剤 |
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US10053526B2 (en) | 2014-07-09 | 2018-08-21 | Ube Industries, Ltd. | Catalyst for conjugated diene polymerization, conjugated diene polymer, modified conjugated diene polymer, polybutadiene, and compositions comprising foregoing |
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JP2019182908A (ja) * | 2018-04-02 | 2019-10-24 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物および空気入りタイヤ |
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