CN103380156B - 作为用于熔融沉积成型（fdm）印刷机的可溶性支撑材料的马来酸酐共聚物 - Google Patents

作为用于熔融沉积成型（fdm）印刷机的可溶性支撑材料的马来酸酐共聚物 Download PDF

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Publication number
CN103380156B
CN103380156B CN201280009711.4A CN201280009711A CN103380156B CN 103380156 B CN103380156 B CN 103380156B CN 201280009711 A CN201280009711 A CN 201280009711A CN 103380156 B CN103380156 B CN 103380156B
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China
Prior art keywords
weight
support material
maleic anhydride
copolymer
styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201280009711.4A
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English (en)
Chinese (zh)
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CN103380156A (zh
Inventor
F·赫米斯
S·伯恩哈特
D·珀普
G·施米特
M·普里德尔
G·罗赫丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roma Chemical Co ltd
Evonik Operations GmbH
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Evonik Roehm GmbH
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Publication of CN103380156A publication Critical patent/CN103380156A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride
    • C08F222/08—Maleic anhydride with vinyl aromatic monomers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/40—Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201280009711.4A 2011-04-20 2012-03-13 作为用于熔融沉积成型（fdm）印刷机的可溶性支撑材料的马来酸酐共聚物 Expired - Fee Related CN103380156B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP111631990 2011-04-20
EP11163199A EP2514775A1 (en) 2011-04-20 2011-04-20 Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer
EP11163199.0 2011-04-20
PCT/EP2012/054306 WO2012143182A1 (en) 2011-04-20 2012-03-13 Maleic anhydride copolymers as soluble support material for fused deposition modelling (fdm) printer

Publications (2)

Publication Number Publication Date
CN103380156A CN103380156A (zh) 2013-10-30
CN103380156B true CN103380156B (zh) 2016-01-20

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CN201280009711.4A Expired - Fee Related CN103380156B (zh) 2011-04-20 2012-03-13 作为用于熔融沉积成型（fdm）印刷机的可溶性支撑材料的马来酸酐共聚物

Country Status (11)

Country Link
US (1) US8822590B2 (enExample)
EP (2) EP2514775A1 (enExample)
JP (1) JP5893128B2 (enExample)
KR (1) KR20140009442A (enExample)
CN (1) CN103380156B (enExample)
AU (1) AU2012244499B2 (enExample)
BR (1) BR112013023429B8 (enExample)
CA (1) CA2833752C (enExample)
IL (1) IL227363A (enExample)
RU (1) RU2013151313A (enExample)
WO (1) WO2012143182A1 (enExample)

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EP2699611B1 (en) 2015-05-06
BR112013023429A2 (pt) 2016-12-13
KR20140009442A (ko) 2014-01-22
US8822590B2 (en) 2014-09-02
IL227363A0 (en) 2013-09-30
JP2014511933A (ja) 2014-05-19
IL227363A (en) 2016-09-29
WO2012143182A1 (en) 2012-10-26
BR112013023429B8 (pt) 2022-07-05
EP2514775A1 (en) 2012-10-24
AU2012244499A1 (en) 2013-07-25
JP5893128B2 (ja) 2016-03-23
BR112013023429B1 (pt) 2020-11-17
EP2699611A1 (en) 2014-02-26
CA2833752A1 (en) 2012-10-26
CA2833752C (en) 2019-05-14
AU2012244499B2 (en) 2015-05-21
US20130317164A1 (en) 2013-11-28
RU2013151313A (ru) 2015-05-27
CN103380156A (zh) 2013-10-30

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