FR3074181B1 - Composition copolymerique hydrosoluble a ph neutre - Google Patents

Composition copolymerique hydrosoluble a ph neutre Download PDF

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Publication number
FR3074181B1
FR3074181B1 FR1761283A FR1761283A FR3074181B1 FR 3074181 B1 FR3074181 B1 FR 3074181B1 FR 1761283 A FR1761283 A FR 1761283A FR 1761283 A FR1761283 A FR 1761283A FR 3074181 B1 FR3074181 B1 FR 3074181B1
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France
Prior art keywords
neutral
salts
hydrosoluble
acid
water
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Active
Application number
FR1761283A
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English (en)
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FR3074181A1 (fr
Inventor
Anne-Laure Brocas
Sylvie Cazaumayou
Sylvain Bourrigaud
Guillaume Decrevoisier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
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Publication date
Priority to FR1761283A priority Critical patent/FR3074181B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP18821721.0A priority patent/EP3717529A1/fr
Priority to JP2020545891A priority patent/JP7177164B2/ja
Priority to KR1020207017804A priority patent/KR102496407B1/ko
Priority to CN201880077092.XA priority patent/CN111417661A/zh
Priority to US16/766,926 priority patent/US11453735B2/en
Priority to PCT/FR2018/052966 priority patent/WO2019106265A1/fr
Publication of FR3074181A1 publication Critical patent/FR3074181A1/fr
Application granted granted Critical
Publication of FR3074181B1 publication Critical patent/FR3074181B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
    • C08F220/606—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen and containing other heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/22—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/30—Sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention se rapporte au domaine des copolymères hydrosolubles ou hydrodispersibles à pH neutre ou proche du neutre, c'est-à-dire entre 5,5 et 9,5 comprenant au moins un copolymère statistique comprenant de l'acide méthacrylique, de l'acrylate de butyle, du styrène et un monomère choisi parmi l'acide styrène sulfonique ou ses sels, l'acide vinyle benzoique ou ses sels, l'acide 2-acrylamido-2- methane sulfonique ou ses sels, la N-vinyle pyrolidone, seuls ou en combinaison.
FR1761283A 2017-11-28 2017-11-28 Composition copolymerique hydrosoluble a ph neutre Active FR3074181B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1761283A FR3074181B1 (fr) 2017-11-28 2017-11-28 Composition copolymerique hydrosoluble a ph neutre
JP2020545891A JP7177164B2 (ja) 2017-11-28 2018-11-23 中性ｐｈで水溶性の共重合体組成物
KR1020207017804A KR102496407B1 (ko) 2017-11-28 2018-11-23 중성 ph 를 갖는 수용성 공중합체 조성물
CN201880077092.XA CN111417661A (zh) 2017-11-28 2018-11-23 具有中性ph的水溶性共聚物组合物
EP18821721.0A EP3717529A1 (fr) 2017-11-28 2018-11-23 Composition copolymerique hydrosoluble a ph neutre
US16/766,926 US11453735B2 (en) 2017-11-28 2018-11-23 Water-soluble copolymer composition with neutral pH
PCT/FR2018/052966 WO2019106265A1 (fr) 2017-11-28 2018-11-23 Composition copolymerique hydrosoluble a ph neutre

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1761283 2017-11-28
FR1761283A FR3074181B1 (fr) 2017-11-28 2017-11-28 Composition copolymerique hydrosoluble a ph neutre

Publications (2)

Publication Number Publication Date
FR3074181A1 FR3074181A1 (fr) 2019-05-31
FR3074181B1 true FR3074181B1 (fr) 2020-11-06

Family

ID=61873400

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1761283A Active FR3074181B1 (fr) 2017-11-28 2017-11-28 Composition copolymerique hydrosoluble a ph neutre

Country Status (7)

Country Link
US (1) US11453735B2 (fr)
EP (1) EP3717529A1 (fr)
JP (1) JP7177164B2 (fr)
KR (1) KR102496407B1 (fr)
CN (1) CN111417661A (fr)
FR (1) FR3074181B1 (fr)
WO (1) WO2019106265A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3088327B1 (fr) * 2018-11-08 2021-11-05 Arkema France Composition copolymerique hydrosoluble

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928273A (en) * 1974-06-03 1975-12-23 Ford Motor Co Method of making organic solvent free aqueous coating compositions of acrylic polymer latex, water soluble emulsion-polymerized acrylic polymer, and aminoplast
JPS5950056A (ja) * 1982-09-17 1984-03-22 Daicel Chem Ind Ltd ガラス繊維用集束剤
JP3315523B2 (ja) * 1994-04-19 2002-08-19 日本化薬株式会社 無機水硬性組成物用分散剤、水硬性組成物及びその硬化物
DE19640208A1 (de) * 1996-09-30 1998-04-02 Agfa Gevaert Ag Fotografisches Aufzeichnungsmaterial
JP3944890B2 (ja) * 1997-12-30 2007-07-18 荒川化学工業株式会社 剥離紙用アンダーコート剤
DE102006032225A1 (de) 2006-07-07 2008-01-10 Belland Ag Anhydritisiertes Copolymer
JP5474555B2 (ja) * 2006-09-28 2014-04-16 錦湖石油化學 株式會▲社▼ 低溶融粘度のマレイミド−α−アルキルスチレン系四元共重合体およびこれを製造する連続塊状重合工程
EP2447292B1 (fr) 2010-10-29 2017-03-29 BellandTechnology AG Copolymère soluble dans l'eau ou pouvant être désintégré dans l'eau
EP2514775A1 (fr) 2011-04-20 2012-10-24 Evonik Röhm GmbH Copolymères d'anhydride maléique en tant que matériau de support pour imprimante à technique de dépôt de fil fondu
FR2983773B1 (fr) 2011-12-09 2014-10-24 Arkema France Procede de preparation de surfaces
US10675853B2 (en) * 2014-05-16 2020-06-09 Stratasys, Inc. High-temperature soluble support material for additive manufacturing
US20210206960A1 (en) * 2017-10-27 2021-07-08 Basf Se Aqueous binder formulation

Also Published As

Publication number Publication date
EP3717529A1 (fr) 2020-10-07
KR20200079342A (ko) 2020-07-02
CN111417661A (zh) 2020-07-14
FR3074181A1 (fr) 2019-05-31
WO2019106265A1 (fr) 2019-06-06
JP7177164B2 (ja) 2022-11-22
JP2021504558A (ja) 2021-02-15
US11453735B2 (en) 2022-09-27
KR102496407B1 (ko) 2023-02-06
US20200369808A1 (en) 2020-11-26

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