CN103237819B - 制备低密度聚乙烯的聚合方法 - Google Patents
制备低密度聚乙烯的聚合方法 Download PDFInfo
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- CN103237819B CN103237819B CN201180057577.0A CN201180057577A CN103237819B CN 103237819 B CN103237819 B CN 103237819B CN 201180057577 A CN201180057577 A CN 201180057577A CN 103237819 B CN103237819 B CN 103237819B
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- polymer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38815210P | 2010-09-30 | 2010-09-30 | |
| US61/388,152 | 2010-09-30 | ||
| PCT/US2011/052525 WO2012044504A1 (en) | 2010-09-30 | 2011-09-21 | Polymerization process to make low density polyethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103237819A CN103237819A (zh) | 2013-08-07 |
| CN103237819B true CN103237819B (zh) | 2016-10-26 |
Family
ID=44720187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180057577.0A Active CN103237819B (zh) | 2010-09-30 | 2011-09-21 | 制备低密度聚乙烯的聚合方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9234055B2 (enExample) |
| EP (1) | EP2621963B1 (enExample) |
| JP (1) | JP5980214B2 (enExample) |
| KR (2) | KR101911673B1 (enExample) |
| CN (1) | CN103237819B (enExample) |
| AR (1) | AR083077A1 (enExample) |
| BR (1) | BR112013007510B1 (enExample) |
| ES (1) | ES2592184T3 (enExample) |
| WO (1) | WO2012044504A1 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9150681B2 (en) | 2010-10-29 | 2015-10-06 | Dow Global Technologies Llc | Ethylene-based polymers and processes for the same |
| ES2850252T3 (es) | 2011-10-19 | 2021-08-26 | Dow Global Technologies Llc | Procedimientos de polimerización con distribuciones de etileno de nueva aportación para preparar polímeros basados en etileno de baja densidad |
| IN2014CN03760A (enExample) | 2011-11-23 | 2015-09-04 | Dow Global Technologies Llc | |
| CN104080851B (zh) | 2011-11-23 | 2016-10-26 | 陶氏环球技术有限责任公司 | 具有宽分子量分布和低可提取物的低密度的基于乙烯的聚合物 |
| MX360854B (es) | 2011-12-22 | 2018-11-20 | Dow Global Technologies Llc | Polímeros basados en etileno con una resistencia a la fusión mejorada, y procesos para lo mismo. |
| WO2014003783A1 (en) * | 2012-06-29 | 2014-01-03 | Exxonmobil Chemical Patents Inc. | Dual modifiers in high pressure polyethylene processes to prevent reactor fouling |
| IN2015DN02921A (enExample) * | 2012-09-28 | 2015-09-18 | Dow Global Technologies Llc | |
| MX363922B (es) | 2012-11-20 | 2019-04-05 | Dow Global Technologies Llc | Polimeros de baja densidad a base de etileno con alta resistencia a la fusion. |
| US9828496B2 (en) | 2013-05-22 | 2017-11-28 | Dow Global Technologies Llc | Low density ethylene-based polymer compositions with high melt strength and mid-high density control |
| BR112015027849B1 (pt) | 2013-05-22 | 2020-08-18 | Dow Global Technologies Llc | Composição, artigo e filme |
| WO2015100318A1 (en) * | 2013-12-26 | 2015-07-02 | Dow Global Technologies Llc | Processes to form ethylene-based polymers using asymmetrical polyenes |
| JP6331390B2 (ja) * | 2013-12-27 | 2018-05-30 | キョーラク株式会社 | 発泡成形体 |
| US9206293B2 (en) * | 2014-01-31 | 2015-12-08 | Fina Technology, Inc. | Polyethyene and articles produced therefrom |
| CN105585765A (zh) * | 2014-10-20 | 2016-05-18 | 中国石油化工股份有限公司 | 一种用于制造高透明薄膜的低密度聚乙烯树脂及其制备方法 |
| CN105585766A (zh) * | 2014-10-20 | 2016-05-18 | 中国石油化工股份有限公司 | 一种药用薄膜用低密度聚乙烯树脂及其制备方法 |
| KR101692123B1 (ko) * | 2014-12-24 | 2017-01-02 | 한화토탈 주식회사 | 보호필름용 폴리에틸렌 수지의 제조방법 |
| ES2772183T3 (es) | 2014-12-30 | 2020-07-07 | Dow Global Technologies Llc | Proceso para controlar la producción y calidad del polímero a base de etileno formado mediante polimerización por radicales libres a alta presión |
| US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
| CN107743496B (zh) | 2015-06-25 | 2020-06-16 | 陶氏环球技术有限责任公司 | 制备具有高熔融强度的管状乙烯类聚合物的改进方法 |
| EP3313902B1 (en) | 2015-06-25 | 2023-07-19 | Dow Global Technologies LLC | A process for producing an ethylene-based polymer |
| BR112017026984B1 (pt) * | 2015-06-25 | 2022-01-18 | Dow Global Technologies Llc | Processo para formar um polímero baseado em etileno |
| KR102612773B1 (ko) * | 2015-06-25 | 2023-12-12 | 다우 글로벌 테크놀로지스 엘엘씨 | 낮은 헥산 추출물을 갖는 에틸렌계 폴리머 |
| CN107873035B (zh) | 2015-06-30 | 2021-04-09 | 陶氏环球技术有限责任公司 | 高压自由基聚合 |
| EP3168237A1 (en) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| EP3168239A1 (en) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure free radical polymerizations |
| EP3238938A1 (en) | 2016-04-29 | 2017-11-01 | Borealis AG | Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers |
| EP3260473A1 (en) * | 2016-06-24 | 2017-12-27 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| WO2018218470A1 (en) | 2017-05-29 | 2018-12-06 | Dow Global Technologies Llc | Thermoplastic polyolefin compositions useful for aldehyde abatement |
| JP7171628B2 (ja) * | 2017-06-28 | 2022-11-15 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを生成するための高圧フリーラジカル重合 |
| ES2890954T3 (es) | 2017-07-28 | 2022-01-25 | Dow Global Technologies Llc | Polímeros basados en etileno de baja densidad para operaciones de revestimiento por extrusión de baja velocidad |
| WO2019078561A1 (ko) * | 2017-10-19 | 2019-04-25 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조 방법 |
| KR102410623B1 (ko) * | 2017-10-19 | 2022-06-17 | 주식회사 엘지화학 | 폴리에틸렌 수지의 제조 방법 |
| EP3938167A1 (en) * | 2019-03-14 | 2022-01-19 | Braskem S.A. | Extrusion coating resin from tubular reactor |
| AR119432A1 (es) | 2019-07-31 | 2021-12-15 | Dow Global Technologies Llc | Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta |
| KR102446740B1 (ko) * | 2019-11-22 | 2022-09-23 | 롯데케미칼 주식회사 | 가공성이 우수한 압출코팅용 에틸렌 비닐 아세테이트 공중합체 및 그 제조방법 |
| CN112250780B (zh) * | 2020-10-19 | 2021-09-07 | 浙江大学 | 一种用于高压烯烃聚合的方法 |
| JP2022156612A (ja) * | 2021-03-31 | 2022-10-14 | 住友化学株式会社 | ポリエチレンの製造方法 |
| CN115197348B (zh) * | 2021-04-14 | 2024-06-14 | 浙江大学 | 乙烯聚合物以及用于制备乙烯聚合物的高压自由基聚合方法与装置 |
| CN114989340A (zh) * | 2022-06-28 | 2022-09-02 | 杭州双安科技有限公司 | 一种烯烃聚合方法 |
| EP4467575A1 (en) | 2023-05-26 | 2024-11-27 | Basell Polyolefine GmbH | High pressure polymerization of ethylene |
| CN118085148B (zh) * | 2024-02-20 | 2025-04-29 | 浙江大学 | 一种用于制备乙烯-极性单体共聚物的方法和装置 |
| KR102755274B1 (ko) | 2024-07-05 | 2025-01-22 | 최병렬 | 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100978A (en) * | 1989-04-20 | 1992-03-31 | Basf Aktiengesellschaft | Preparation of polyethylene and copolymers of predominant amounts of ethylene |
| US6407191B1 (en) * | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| WO2006049783A1 (en) * | 2004-11-02 | 2006-05-11 | Dow Global Technologies Inc. | Process for producing low density polyethylene compositions and polymers produced therefrom |
| WO2010042390A1 (en) * | 2008-10-07 | 2010-04-15 | Dow Global Technologies Inc. | High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2964515A (en) | 1957-07-01 | 1960-12-13 | Nat Distillers Chem Corp | Ethylene polymerization process |
| US3756996A (en) | 1964-10-02 | 1973-09-04 | Nat Distillers Chem Corp | Process for the production of ethylene polymers |
| US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
| US3536693A (en) | 1968-01-31 | 1970-10-27 | Eastman Kodak Co | Process for preparing polyethylene having improved properties |
| DE2107945A1 (en) | 1971-02-19 | 1972-08-24 | F J Gattys Ing Buero F Chem Ma | High pressure polyethylene prodn - using stirred autoclave and tubular after-reactor for high yield and quality |
| US3913698A (en) | 1974-02-01 | 1975-10-21 | Power Matic Corp | Variable speed transmission |
| JPS5322582A (en) * | 1976-08-13 | 1978-03-02 | Sumitomo Chem Co Ltd | Production of polyethylene |
| DE2814650C2 (de) | 1978-04-05 | 1984-02-02 | EC Erdölchemie GmbH, 5000 Köln | Herstellung von Homo-oder Copolymeren des Äthylens nach dem Hochdruckverfahren in Rührautoklaven mit praktisch vollständiger Rückvermischung |
| US4340563A (en) | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
| US4322027A (en) | 1980-10-02 | 1982-03-30 | Crown Zellerbach Corporation | Filament draw nozzle |
| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| US4599392A (en) | 1983-06-13 | 1986-07-08 | The Dow Chemical Company | Interpolymers of ethylene and unsaturated carboxylic acids |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
| US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
| US4988781A (en) | 1989-02-27 | 1991-01-29 | The Dow Chemical Company | Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters |
| DE4132012A1 (de) | 1991-09-26 | 1993-04-01 | Basf Ag | Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung |
| EP0852596B1 (en) | 1995-09-29 | 2000-06-07 | The Dow Chemical Company | Cross-linked polyolefinic foams and process for their production |
| EP0928797B3 (en) * | 1998-01-12 | 2012-01-11 | Dow Global Technologies LLC | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| US7406537B2 (en) | 2002-11-26 | 2008-07-29 | Progress Software Corporation | Dynamic subscription and message routing on a topic between publishing nodes and subscribing nodes |
| TW200517426A (en) | 2003-08-25 | 2005-06-01 | Dow Global Technologies Inc | Aqueous dispersion, its production method, and its use |
| BR112012015026B1 (pt) * | 2009-12-18 | 2019-11-05 | Dow Global Technologies Llc | processo de polimerização em alta pressão para formar um polímero a base de etileno, polímero a base de etileno, composição, artigo e película |
| ES2850252T3 (es) | 2011-10-19 | 2021-08-26 | Dow Global Technologies Llc | Procedimientos de polimerización con distribuciones de etileno de nueva aportación para preparar polímeros basados en etileno de baja densidad |
-
2011
- 2011-09-21 KR KR1020187012061A patent/KR101911673B1/ko active Active
- 2011-09-21 JP JP2013531659A patent/JP5980214B2/ja active Active
- 2011-09-21 ES ES11763825.4T patent/ES2592184T3/es active Active
- 2011-09-21 WO PCT/US2011/052525 patent/WO2012044504A1/en not_active Ceased
- 2011-09-21 EP EP11763825.4A patent/EP2621963B1/en active Active
- 2011-09-21 KR KR1020137010956A patent/KR20140009164A/ko not_active Ceased
- 2011-09-21 CN CN201180057577.0A patent/CN103237819B/zh active Active
- 2011-09-21 US US13/876,292 patent/US9234055B2/en active Active
- 2011-09-21 AR ARP110103452A patent/AR083077A1/es not_active Application Discontinuation
- 2011-09-21 BR BR112013007510-4A patent/BR112013007510B1/pt active IP Right Grant
-
2015
- 2015-12-28 US US14/980,701 patent/US9534064B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100978A (en) * | 1989-04-20 | 1992-03-31 | Basf Aktiengesellschaft | Preparation of polyethylene and copolymers of predominant amounts of ethylene |
| US6407191B1 (en) * | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| WO2006049783A1 (en) * | 2004-11-02 | 2006-05-11 | Dow Global Technologies Inc. | Process for producing low density polyethylene compositions and polymers produced therefrom |
| WO2010042390A1 (en) * | 2008-10-07 | 2010-04-15 | Dow Global Technologies Inc. | High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents |
Also Published As
| Publication number | Publication date |
|---|---|
| US9534064B2 (en) | 2017-01-03 |
| US20130197168A1 (en) | 2013-08-01 |
| KR20140009164A (ko) | 2014-01-22 |
| CN103237819A (zh) | 2013-08-07 |
| JP5980214B2 (ja) | 2016-08-31 |
| KR20180049190A (ko) | 2018-05-10 |
| US9234055B2 (en) | 2016-01-12 |
| EP2621963B1 (en) | 2016-07-06 |
| EP2621963A1 (en) | 2013-08-07 |
| WO2012044504A1 (en) | 2012-04-05 |
| KR101911673B1 (ko) | 2018-10-24 |
| AR083077A1 (es) | 2013-01-30 |
| JP2013543025A (ja) | 2013-11-28 |
| ES2592184T3 (es) | 2016-11-28 |
| BR112013007510B1 (pt) | 2020-10-20 |
| US20160115256A1 (en) | 2016-04-28 |
| BR112013007510A2 (pt) | 2016-11-08 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |