CN103237819B - 制备低密度聚乙烯的聚合方法 - Google Patents

制备低密度聚乙烯的聚合方法 Download PDF

Info

Publication number
CN103237819B
CN103237819B CN201180057577.0A CN201180057577A CN103237819B CN 103237819 B CN103237819 B CN 103237819B CN 201180057577 A CN201180057577 A CN 201180057577A CN 103237819 B CN103237819 B CN 103237819B
Authority
CN
China
Prior art keywords
zone
ethylene
reactor
polymer
cta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180057577.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN103237819A (zh
Inventor
O.J.贝比
C.F.J.邓多尔德
C.J.霍斯曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CN103237819A publication Critical patent/CN103237819A/zh
Application granted granted Critical
Publication of CN103237819B publication Critical patent/CN103237819B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201180057577.0A 2010-09-30 2011-09-21 制备低密度聚乙烯的聚合方法 Active CN103237819B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38815210P 2010-09-30 2010-09-30
US61/388,152 2010-09-30
PCT/US2011/052525 WO2012044504A1 (en) 2010-09-30 2011-09-21 Polymerization process to make low density polyethylene

Publications (2)

Publication Number Publication Date
CN103237819A CN103237819A (zh) 2013-08-07
CN103237819B true CN103237819B (zh) 2016-10-26

Family

ID=44720187

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180057577.0A Active CN103237819B (zh) 2010-09-30 2011-09-21 制备低密度聚乙烯的聚合方法

Country Status (9)

Country Link
US (2) US9234055B2 (enExample)
EP (1) EP2621963B1 (enExample)
JP (1) JP5980214B2 (enExample)
KR (2) KR101911673B1 (enExample)
CN (1) CN103237819B (enExample)
AR (1) AR083077A1 (enExample)
BR (1) BR112013007510B1 (enExample)
ES (1) ES2592184T3 (enExample)
WO (1) WO2012044504A1 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5980219B2 (ja) 2010-10-29 2016-08-31 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびその方法
JP6141288B2 (ja) * 2011-10-19 2017-06-07 ダウ グローバル テクノロジーズ エルエルシー 低密度エチレン系ポリマー調製のための新しいエチレンの分配を有する重合プロセス
BR112014012268B1 (pt) 2011-11-23 2020-09-29 Dow Global Technologies Llc Polímero a base de etileno, composição e artigo
ES2767367T3 (es) 2011-11-23 2020-06-17 Dow Global Technologies Llc Polímeros a base de etileno de baja densidad con distribuciones amplias de pesos moleculares y contenido de extraíbles bajo
KR101989335B1 (ko) 2011-12-22 2019-06-17 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도를 가진 에틸렌-기재 중합체 및 그의 제조 방법
WO2014003783A1 (en) * 2012-06-29 2014-01-03 Exxonmobil Chemical Patents Inc. Dual modifiers in high pressure polyethylene processes to prevent reactor fouling
BR112015006812B1 (pt) * 2012-09-28 2021-03-23 Dow Global Technologies Llc Composição
ES2640018T3 (es) 2012-11-20 2017-10-31 Dow Global Technologies Llc Polímeros a base de etileno de baja densidad con alta resistencia en estado fundido
JP6688217B2 (ja) 2013-05-22 2020-04-28 ダウ グローバル テクノロジーズ エルエルシー 高溶融強度及び中高密度制御を有する低密度エチレン系ポリマー組成物
KR20200124326A (ko) 2013-05-22 2020-11-02 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도, 출력 및 기계적 특성을 갖는 저밀도 에틸렌계 조성물
ES2717973T3 (es) * 2013-12-26 2019-06-26 Dow Global Technologies Llc Procedimientos para formar polímeros basados en etileno utilizando polienos asimétricos
JP6331390B2 (ja) * 2013-12-27 2018-05-30 キョーラク株式会社 発泡成形体
US9206293B2 (en) * 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
CN105585766A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种药用薄膜用低密度聚乙烯树脂及其制备方法
CN105585765A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种用于制造高透明薄膜的低密度聚乙烯树脂及其制备方法
KR101692123B1 (ko) * 2014-12-24 2017-01-02 한화토탈 주식회사 보호필름용 폴리에틸렌 수지의 제조방법
KR20170125804A (ko) 2014-12-30 2017-11-15 다우 글로벌 테크놀로지스 엘엘씨 고압 자유 라디칼 중합에 의해 형성된 에틸렌계 중합체의 생산량과 품질을 제어하는 방법
BR112017027564B1 (pt) * 2015-06-25 2022-02-01 Dow Global Technologies Llc Processo para produzir polímero à base de etileno
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
EP3317306B1 (en) 2015-06-25 2020-03-18 Dow Global Technologies LLC Process for forming ethylene based polymers
BR112017027794A2 (pt) * 2015-06-25 2018-08-28 Dow Global Technologies Llc polímeros à base de etileno com baixos extraíveis de hexano e baixas densidades
CN107750257B (zh) 2015-06-25 2021-03-30 陶氏环球技术有限责任公司 制备具有较高g′和较宽mwd的管状乙烯基聚合物的改进方法
KR102571535B1 (ko) 2015-06-30 2023-08-29 다우 글로벌 테크놀로지스 엘엘씨 고압 자유 라디칼 중합
EP3168239A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure free radical polymerizations
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3238938A1 (en) 2016-04-29 2017-11-01 Borealis AG Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers
EP3260473A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
WO2018218470A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
WO2019005812A1 (en) * 2017-06-28 2019-01-03 Dow Global Technologies Llc HIGH PRESSURE FREE RADICAL POLYMERIZATIONS FOR PRODUCING ETHYLENE POLYMERS
KR102617111B1 (ko) 2017-07-28 2023-12-27 다우 글로벌 테크놀로지스 엘엘씨 저속 압출 코팅 작업용 저밀도 에틸렌계 폴리머
KR102410623B1 (ko) * 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
WO2019078561A1 (ko) * 2017-10-19 2019-04-25 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
EP3938167A1 (en) * 2019-03-14 2022-01-19 Braskem S.A. Extrusion coating resin from tubular reactor
AR119432A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta
KR102446740B1 (ko) * 2019-11-22 2022-09-23 롯데케미칼 주식회사 가공성이 우수한 압출코팅용 에틸렌 비닐 아세테이트 공중합체 및 그 제조방법
CN112250780B (zh) * 2020-10-19 2021-09-07 浙江大学 一种用于高压烯烃聚合的方法
JP2022156612A (ja) * 2021-03-31 2022-10-14 住友化学株式会社 ポリエチレンの製造方法
CN115197348B (zh) * 2021-04-14 2024-06-14 浙江大学 乙烯聚合物以及用于制备乙烯聚合物的高压自由基聚合方法与装置
CN114989340A (zh) * 2022-06-28 2022-09-02 杭州双安科技有限公司 一种烯烃聚合方法
EP4467575A1 (en) 2023-05-26 2024-11-27 Basell Polyolefine GmbH High pressure polymerization of ethylene
CN118085148B (zh) * 2024-02-20 2025-04-29 浙江大学 一种用于制备乙烯-极性单体共聚物的方法和装置
KR102755274B1 (ko) 2024-07-05 2025-01-22 최병렬 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5100978A (en) * 1989-04-20 1992-03-31 Basf Aktiengesellschaft Preparation of polyethylene and copolymers of predominant amounts of ethylene
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
WO2006049783A1 (en) * 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) * 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964515A (en) 1957-07-01 1960-12-13 Nat Distillers Chem Corp Ethylene polymerization process
US3756996A (en) 1964-10-02 1973-09-04 Nat Distillers Chem Corp Process for the production of ethylene polymers
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3536693A (en) 1968-01-31 1970-10-27 Eastman Kodak Co Process for preparing polyethylene having improved properties
DE2107945A1 (en) 1971-02-19 1972-08-24 F J Gattys Ing Buero F Chem Ma High pressure polyethylene prodn - using stirred autoclave and tubular after-reactor for high yield and quality
US3913698A (en) 1974-02-01 1975-10-21 Power Matic Corp Variable speed transmission
JPS5322582A (en) * 1976-08-13 1978-03-02 Sumitomo Chem Co Ltd Production of polyethylene
DE2814650C2 (de) 1978-04-05 1984-02-02 EC Erdölchemie GmbH, 5000 Köln Herstellung von Homo-oder Copolymeren des Äthylens nach dem Hochdruckverfahren in Rührautoklaven mit praktisch vollständiger Rückvermischung
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4599392A (en) 1983-06-13 1986-07-08 The Dow Chemical Company Interpolymers of ethylene and unsaturated carboxylic acids
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4988781A (en) 1989-02-27 1991-01-29 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
DE4132012A1 (de) 1991-09-26 1993-04-01 Basf Ag Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung
AU704073B2 (en) 1995-09-29 1999-04-15 Dow Chemical Company, The Cross-linked polyolefinic foams and process for their production
ATE275590T1 (de) * 1998-01-12 2004-09-15 Dow Global Technologies Inc Äthylenpolymere mittlerer dichte, verfahren zur herstellung dieser polymere und verwendung von carbonyl-haltigen kettenübertragungsmitteln in diesem verfahren
US7406537B2 (en) 2002-11-26 2008-07-29 Progress Software Corporation Dynamic subscription and message routing on a topic between publishing nodes and subscribing nodes
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
EP2513162B1 (en) 2009-12-18 2015-11-04 Dow Global Technologies LLC Polymerization process to make low density polyethylene
JP6141288B2 (ja) 2011-10-19 2017-06-07 ダウ グローバル テクノロジーズ エルエルシー 低密度エチレン系ポリマー調製のための新しいエチレンの分配を有する重合プロセス

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5100978A (en) * 1989-04-20 1992-03-31 Basf Aktiengesellschaft Preparation of polyethylene and copolymers of predominant amounts of ethylene
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
WO2006049783A1 (en) * 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) * 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents

Also Published As

Publication number Publication date
KR20180049190A (ko) 2018-05-10
US9534064B2 (en) 2017-01-03
EP2621963A1 (en) 2013-08-07
CN103237819A (zh) 2013-08-07
BR112013007510B1 (pt) 2020-10-20
KR20140009164A (ko) 2014-01-22
US20160115256A1 (en) 2016-04-28
ES2592184T3 (es) 2016-11-28
JP2013543025A (ja) 2013-11-28
WO2012044504A1 (en) 2012-04-05
KR101911673B1 (ko) 2018-10-24
US9234055B2 (en) 2016-01-12
EP2621963B1 (en) 2016-07-06
US20130197168A1 (en) 2013-08-01
AR083077A1 (es) 2013-01-30
BR112013007510A2 (pt) 2016-11-08
JP5980214B2 (ja) 2016-08-31

Similar Documents

Publication Publication Date Title
CN103237819B (zh) 制备低密度聚乙烯的聚合方法
JP6759263B2 (ja) 高い溶融強度を有する低密度エチレン系ポリマー
JP5873803B2 (ja) 低密度ポリエチレンを製造するための重合法
US9403928B2 (en) Polymerization process to make low density polyethylene
US9228036B2 (en) Low density ethylene-based polymers with broad molecular weight distributions and low extractables
KR102166723B1 (ko) 고용융 강도를 갖는 저밀도 에틸렌-기반 폴리머를 함유하는 조성물 및 이로부터 형성된 필름
US8871876B2 (en) Ethylene-based interpolymers and processes to make the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant