CN103237819B - 制备低密度聚乙烯的聚合方法 - Google Patents

制备低密度聚乙烯的聚合方法 Download PDF

Info

Publication number
CN103237819B
CN103237819B CN201180057577.0A CN201180057577A CN103237819B CN 103237819 B CN103237819 B CN 103237819B CN 201180057577 A CN201180057577 A CN 201180057577A CN 103237819 B CN103237819 B CN 103237819B
Authority
CN
China
Prior art keywords
zone
ethylene
reactor
polymer
cta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180057577.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN103237819A (zh
Inventor
O.J.贝比
C.F.J.邓多尔德
C.J.霍斯曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CN103237819A publication Critical patent/CN103237819A/zh
Application granted granted Critical
Publication of CN103237819B publication Critical patent/CN103237819B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201180057577.0A 2010-09-30 2011-09-21 制备低密度聚乙烯的聚合方法 Active CN103237819B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38815210P 2010-09-30 2010-09-30
US61/388,152 2010-09-30
PCT/US2011/052525 WO2012044504A1 (en) 2010-09-30 2011-09-21 Polymerization process to make low density polyethylene

Publications (2)

Publication Number Publication Date
CN103237819A CN103237819A (zh) 2013-08-07
CN103237819B true CN103237819B (zh) 2016-10-26

Family

ID=44720187

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180057577.0A Active CN103237819B (zh) 2010-09-30 2011-09-21 制备低密度聚乙烯的聚合方法

Country Status (9)

Country Link
US (2) US9234055B2 (enExample)
EP (1) EP2621963B1 (enExample)
JP (1) JP5980214B2 (enExample)
KR (2) KR101911673B1 (enExample)
CN (1) CN103237819B (enExample)
AR (1) AR083077A1 (enExample)
BR (1) BR112013007510B1 (enExample)
ES (1) ES2592184T3 (enExample)
WO (1) WO2012044504A1 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150681B2 (en) 2010-10-29 2015-10-06 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
ES2850252T3 (es) 2011-10-19 2021-08-26 Dow Global Technologies Llc Procedimientos de polimerización con distribuciones de etileno de nueva aportación para preparar polímeros basados en etileno de baja densidad
IN2014CN03760A (enExample) 2011-11-23 2015-09-04 Dow Global Technologies Llc
CN104080851B (zh) 2011-11-23 2016-10-26 陶氏环球技术有限责任公司 具有宽分子量分布和低可提取物的低密度的基于乙烯的聚合物
MX360854B (es) 2011-12-22 2018-11-20 Dow Global Technologies Llc Polímeros basados en etileno con una resistencia a la fusión mejorada, y procesos para lo mismo.
WO2014003783A1 (en) * 2012-06-29 2014-01-03 Exxonmobil Chemical Patents Inc. Dual modifiers in high pressure polyethylene processes to prevent reactor fouling
IN2015DN02921A (enExample) * 2012-09-28 2015-09-18 Dow Global Technologies Llc
MX363922B (es) 2012-11-20 2019-04-05 Dow Global Technologies Llc Polimeros de baja densidad a base de etileno con alta resistencia a la fusion.
US9828496B2 (en) 2013-05-22 2017-11-28 Dow Global Technologies Llc Low density ethylene-based polymer compositions with high melt strength and mid-high density control
BR112015027849B1 (pt) 2013-05-22 2020-08-18 Dow Global Technologies Llc Composição, artigo e filme
WO2015100318A1 (en) * 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to form ethylene-based polymers using asymmetrical polyenes
JP6331390B2 (ja) * 2013-12-27 2018-05-30 キョーラク株式会社 発泡成形体
US9206293B2 (en) * 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
CN105585765A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种用于制造高透明薄膜的低密度聚乙烯树脂及其制备方法
CN105585766A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种药用薄膜用低密度聚乙烯树脂及其制备方法
KR101692123B1 (ko) * 2014-12-24 2017-01-02 한화토탈 주식회사 보호필름용 폴리에틸렌 수지의 제조방법
ES2772183T3 (es) 2014-12-30 2020-07-07 Dow Global Technologies Llc Proceso para controlar la producción y calidad del polímero a base de etileno formado mediante polimerización por radicales libres a alta presión
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
CN107743496B (zh) 2015-06-25 2020-06-16 陶氏环球技术有限责任公司 制备具有高熔融强度的管状乙烯类聚合物的改进方法
EP3313902B1 (en) 2015-06-25 2023-07-19 Dow Global Technologies LLC A process for producing an ethylene-based polymer
BR112017026984B1 (pt) * 2015-06-25 2022-01-18 Dow Global Technologies Llc Processo para formar um polímero baseado em etileno
KR102612773B1 (ko) * 2015-06-25 2023-12-12 다우 글로벌 테크놀로지스 엘엘씨 낮은 헥산 추출물을 갖는 에틸렌계 폴리머
CN107873035B (zh) 2015-06-30 2021-04-09 陶氏环球技术有限责任公司 高压自由基聚合
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3168239A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure free radical polymerizations
EP3238938A1 (en) 2016-04-29 2017-11-01 Borealis AG Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers
EP3260473A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
WO2018218470A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
JP7171628B2 (ja) * 2017-06-28 2022-11-15 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーを生成するための高圧フリーラジカル重合
ES2890954T3 (es) 2017-07-28 2022-01-25 Dow Global Technologies Llc Polímeros basados en etileno de baja densidad para operaciones de revestimiento por extrusión de baja velocidad
WO2019078561A1 (ko) * 2017-10-19 2019-04-25 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
KR102410623B1 (ko) * 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
EP3938167A1 (en) * 2019-03-14 2022-01-19 Braskem S.A. Extrusion coating resin from tubular reactor
AR119432A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta
KR102446740B1 (ko) * 2019-11-22 2022-09-23 롯데케미칼 주식회사 가공성이 우수한 압출코팅용 에틸렌 비닐 아세테이트 공중합체 및 그 제조방법
CN112250780B (zh) * 2020-10-19 2021-09-07 浙江大学 一种用于高压烯烃聚合的方法
JP2022156612A (ja) * 2021-03-31 2022-10-14 住友化学株式会社 ポリエチレンの製造方法
CN115197348B (zh) * 2021-04-14 2024-06-14 浙江大学 乙烯聚合物以及用于制备乙烯聚合物的高压自由基聚合方法与装置
CN114989340A (zh) * 2022-06-28 2022-09-02 杭州双安科技有限公司 一种烯烃聚合方法
EP4467575A1 (en) 2023-05-26 2024-11-27 Basell Polyolefine GmbH High pressure polymerization of ethylene
CN118085148B (zh) * 2024-02-20 2025-04-29 浙江大学 一种用于制备乙烯-极性单体共聚物的方法和装置
KR102755274B1 (ko) 2024-07-05 2025-01-22 최병렬 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5100978A (en) * 1989-04-20 1992-03-31 Basf Aktiengesellschaft Preparation of polyethylene and copolymers of predominant amounts of ethylene
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
WO2006049783A1 (en) * 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) * 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964515A (en) 1957-07-01 1960-12-13 Nat Distillers Chem Corp Ethylene polymerization process
US3756996A (en) 1964-10-02 1973-09-04 Nat Distillers Chem Corp Process for the production of ethylene polymers
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3536693A (en) 1968-01-31 1970-10-27 Eastman Kodak Co Process for preparing polyethylene having improved properties
DE2107945A1 (en) 1971-02-19 1972-08-24 F J Gattys Ing Buero F Chem Ma High pressure polyethylene prodn - using stirred autoclave and tubular after-reactor for high yield and quality
US3913698A (en) 1974-02-01 1975-10-21 Power Matic Corp Variable speed transmission
JPS5322582A (en) * 1976-08-13 1978-03-02 Sumitomo Chem Co Ltd Production of polyethylene
DE2814650C2 (de) 1978-04-05 1984-02-02 EC Erdölchemie GmbH, 5000 Köln Herstellung von Homo-oder Copolymeren des Äthylens nach dem Hochdruckverfahren in Rührautoklaven mit praktisch vollständiger Rückvermischung
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4599392A (en) 1983-06-13 1986-07-08 The Dow Chemical Company Interpolymers of ethylene and unsaturated carboxylic acids
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4988781A (en) 1989-02-27 1991-01-29 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
DE4132012A1 (de) 1991-09-26 1993-04-01 Basf Ag Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung
EP0852596B1 (en) 1995-09-29 2000-06-07 The Dow Chemical Company Cross-linked polyolefinic foams and process for their production
EP0928797B3 (en) * 1998-01-12 2012-01-11 Dow Global Technologies LLC Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
US7406537B2 (en) 2002-11-26 2008-07-29 Progress Software Corporation Dynamic subscription and message routing on a topic between publishing nodes and subscribing nodes
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
BR112012015026B1 (pt) * 2009-12-18 2019-11-05 Dow Global Technologies Llc processo de polimerização em alta pressão para formar um polímero a base de etileno, polímero a base de etileno, composição, artigo e película
ES2850252T3 (es) 2011-10-19 2021-08-26 Dow Global Technologies Llc Procedimientos de polimerización con distribuciones de etileno de nueva aportación para preparar polímeros basados en etileno de baja densidad

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5100978A (en) * 1989-04-20 1992-03-31 Basf Aktiengesellschaft Preparation of polyethylene and copolymers of predominant amounts of ethylene
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
WO2006049783A1 (en) * 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) * 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents

Also Published As

Publication number Publication date
US9534064B2 (en) 2017-01-03
US20130197168A1 (en) 2013-08-01
KR20140009164A (ko) 2014-01-22
CN103237819A (zh) 2013-08-07
JP5980214B2 (ja) 2016-08-31
KR20180049190A (ko) 2018-05-10
US9234055B2 (en) 2016-01-12
EP2621963B1 (en) 2016-07-06
EP2621963A1 (en) 2013-08-07
WO2012044504A1 (en) 2012-04-05
KR101911673B1 (ko) 2018-10-24
AR083077A1 (es) 2013-01-30
JP2013543025A (ja) 2013-11-28
ES2592184T3 (es) 2016-11-28
BR112013007510B1 (pt) 2020-10-20
US20160115256A1 (en) 2016-04-28
BR112013007510A2 (pt) 2016-11-08

Similar Documents

Publication Publication Date Title
CN103237819B (zh) 制备低密度聚乙烯的聚合方法
JP6759263B2 (ja) 高い溶融強度を有する低密度エチレン系ポリマー
JP5873803B2 (ja) 低密度ポリエチレンを製造するための重合法
US9403928B2 (en) Polymerization process to make low density polyethylene
US9228036B2 (en) Low density ethylene-based polymers with broad molecular weight distributions and low extractables
US10358543B2 (en) Compositions containing low density ethylene-based polymers with high melt strength and films formed from the same
US8871876B2 (en) Ethylene-based interpolymers and processes to make the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant