JP5980214B2 - 低密度ポリエチレンを製造するための重合プロセス - Google Patents

低密度ポリエチレンを製造するための重合プロセス Download PDF

Info

Publication number
JP5980214B2
JP5980214B2 JP2013531659A JP2013531659A JP5980214B2 JP 5980214 B2 JP5980214 B2 JP 5980214B2 JP 2013531659 A JP2013531659 A JP 2013531659A JP 2013531659 A JP2013531659 A JP 2013531659A JP 5980214 B2 JP5980214 B2 JP 5980214B2
Authority
JP
Japan
Prior art keywords
reactor
polymer
region
ethylene
autoclave
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2013531659A
Other languages
English (en)
Japanese (ja)
Other versions
JP2013543025A5 (enExample
JP2013543025A (ja
Inventor
バービー,オット,ジェー.
ドエルダー,コーネリス,エフ.,ジェー. デン
ドエルダー,コーネリス,エフ.,ジェー. デン
ホスマン,コーネリス,ジェー.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of JP2013543025A publication Critical patent/JP2013543025A/ja
Publication of JP2013543025A5 publication Critical patent/JP2013543025A5/ja
Application granted granted Critical
Publication of JP5980214B2 publication Critical patent/JP5980214B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2013531659A 2010-09-30 2011-09-21 低密度ポリエチレンを製造するための重合プロセス Active JP5980214B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38815210P 2010-09-30 2010-09-30
US61/388,152 2010-09-30
PCT/US2011/052525 WO2012044504A1 (en) 2010-09-30 2011-09-21 Polymerization process to make low density polyethylene

Publications (3)

Publication Number Publication Date
JP2013543025A JP2013543025A (ja) 2013-11-28
JP2013543025A5 JP2013543025A5 (enExample) 2014-11-06
JP5980214B2 true JP5980214B2 (ja) 2016-08-31

Family

ID=44720187

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2013531659A Active JP5980214B2 (ja) 2010-09-30 2011-09-21 低密度ポリエチレンを製造するための重合プロセス

Country Status (9)

Country Link
US (2) US9234055B2 (enExample)
EP (1) EP2621963B1 (enExample)
JP (1) JP5980214B2 (enExample)
KR (2) KR20140009164A (enExample)
CN (1) CN103237819B (enExample)
AR (1) AR083077A1 (enExample)
BR (1) BR112013007510B1 (enExample)
ES (1) ES2592184T3 (enExample)
WO (1) WO2012044504A1 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150681B2 (en) 2010-10-29 2015-10-06 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
CN104011095B (zh) 2011-10-19 2016-10-05 陶氏环球技术有限责任公司 用于制备低密度基于乙烯的聚合物的采用新鲜乙烯分配的聚合方法
IN2014CN03760A (enExample) 2011-11-23 2015-09-04 Dow Global Technologies Llc
ES2742509T3 (es) 2011-11-23 2020-02-14 Dow Global Technologies Llc Polímeros a base de etileno de baja densidad con distribuciones amplias de pesos moleculares y contenido de extraíbles bajo
WO2013095969A1 (en) 2011-12-22 2013-06-27 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and processes for the same
WO2014003783A1 (en) * 2012-06-29 2014-01-03 Exxonmobil Chemical Patents Inc. Dual modifiers in high pressure polyethylene processes to prevent reactor fouling
KR102037561B1 (ko) * 2012-09-28 2019-10-28 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-기재 중합체 및 그의 제조 방법
US9394389B2 (en) 2012-11-20 2016-07-19 Dow Global Technologies Llc Low density ethylene-based polymers with high melt strength
ES2637970T3 (es) 2013-05-22 2017-10-18 Dow Global Technologies Llc Composiciones poliméricas basadas en etileno de baja densidad con alta resistencia en estado fundido y control de densidad medio-alto
KR102171521B1 (ko) 2013-05-22 2020-10-30 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도, 출력 및 기계적 특성을 갖는 저밀도 에틸렌계 조성물
WO2015100318A1 (en) * 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to form ethylene-based polymers using asymmetrical polyenes
JP6331390B2 (ja) * 2013-12-27 2018-05-30 キョーラク株式会社 発泡成形体
US9206293B2 (en) * 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
CN105585765A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种用于制造高透明薄膜的低密度聚乙烯树脂及其制备方法
CN105585766A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种药用薄膜用低密度聚乙烯树脂及其制备方法
KR101692123B1 (ko) * 2014-12-24 2017-01-02 한화토탈 주식회사 보호필름용 폴리에틸렌 수지의 제조방법
ES2772183T3 (es) 2014-12-30 2020-07-07 Dow Global Technologies Llc Proceso para controlar la producción y calidad del polímero a base de etileno formado mediante polimerización por radicales libres a alta presión
ES2786677T3 (es) * 2015-06-25 2020-10-13 Dow Global Technologies Llc Proceso para formar polímeros basados en etileno
EP3313894B1 (en) * 2015-06-25 2019-12-18 Dow Global Technologies LLC Improved process to make tubular ethylene based polymers with high g' and broad mwd
CN107810208B (zh) * 2015-06-25 2020-07-24 陶氏环球技术有限责任公司 具有低己烷可萃取率的乙烯基聚合物
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
EP3313902B1 (en) 2015-06-25 2023-07-19 Dow Global Technologies LLC A process for producing an ethylene-based polymer
JP6865181B2 (ja) 2015-06-30 2021-04-28 ダウ グローバル テクノロジーズ エルエルシー 高圧力フリーラジカル重合
EP3168239A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure free radical polymerizations
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3238938A1 (en) 2016-04-29 2017-11-01 Borealis AG Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers
EP3260473A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
WO2018218470A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
CN110770259B (zh) * 2017-06-28 2022-05-27 陶氏环球技术有限责任公司 用于生产基于乙烯的聚合物的高压自由基聚合
EP3658592B1 (en) 2017-07-28 2021-08-25 Dow Global Technologies Llc Low density ethylene-based polymers for low speed extrusion coating operations
KR102410623B1 (ko) * 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
WO2019078561A1 (ko) * 2017-10-19 2019-04-25 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
EP3938167A1 (en) * 2019-03-14 2022-01-19 Braskem S.A. Extrusion coating resin from tubular reactor
AR119432A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta
KR102446740B1 (ko) * 2019-11-22 2022-09-23 롯데케미칼 주식회사 가공성이 우수한 압출코팅용 에틸렌 비닐 아세테이트 공중합체 및 그 제조방법
CN112250780B (zh) * 2020-10-19 2021-09-07 浙江大学 一种用于高压烯烃聚合的方法
JP2022156612A (ja) * 2021-03-31 2022-10-14 住友化学株式会社 ポリエチレンの製造方法
CN115197348B (zh) * 2021-04-14 2024-06-14 浙江大学 乙烯聚合物以及用于制备乙烯聚合物的高压自由基聚合方法与装置
CN114989340A (zh) * 2022-06-28 2022-09-02 杭州双安科技有限公司 一种烯烃聚合方法
EP4467575A1 (en) 2023-05-26 2024-11-27 Basell Polyolefine GmbH High pressure polymerization of ethylene
CN118085148B (zh) * 2024-02-20 2025-04-29 浙江大学 一种用于制备乙烯-极性单体共聚物的方法和装置
KR102755274B1 (ko) 2024-07-05 2025-01-22 최병렬 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964515A (en) 1957-07-01 1960-12-13 Nat Distillers Chem Corp Ethylene polymerization process
US3756996A (en) 1964-10-02 1973-09-04 Nat Distillers Chem Corp Process for the production of ethylene polymers
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3536693A (en) 1968-01-31 1970-10-27 Eastman Kodak Co Process for preparing polyethylene having improved properties
DE2107945A1 (en) 1971-02-19 1972-08-24 F J Gattys Ing Buero F Chem Ma High pressure polyethylene prodn - using stirred autoclave and tubular after-reactor for high yield and quality
US3913698A (en) 1974-02-01 1975-10-21 Power Matic Corp Variable speed transmission
JPS5322582A (en) * 1976-08-13 1978-03-02 Sumitomo Chem Co Ltd Production of polyethylene
DE2814650C2 (de) 1978-04-05 1984-02-02 EC Erdölchemie GmbH, 5000 Köln Herstellung von Homo-oder Copolymeren des Äthylens nach dem Hochdruckverfahren in Rührautoklaven mit praktisch vollständiger Rückvermischung
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4599392A (en) 1983-06-13 1986-07-08 The Dow Chemical Company Interpolymers of ethylene and unsaturated carboxylic acids
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4988781A (en) 1989-02-27 1991-01-29 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
DE3912975A1 (de) * 1989-04-20 1990-11-08 Basf Ag Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen
DE4132012A1 (de) * 1991-09-26 1993-04-01 Basf Ag Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung
KR100438247B1 (ko) 1995-09-29 2004-08-16 다우 글로벌 테크놀로지스 인크. 가교결합된폴리올레핀계발포체및이들의제조방법
US6407191B1 (en) * 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
ATE275590T1 (de) * 1998-01-12 2004-09-15 Dow Global Technologies Inc Äthylenpolymere mittlerer dichte, verfahren zur herstellung dieser polymere und verwendung von carbonyl-haltigen kettenübertragungsmitteln in diesem verfahren
US7406537B2 (en) 2002-11-26 2008-07-29 Progress Software Corporation Dynamic subscription and message routing on a topic between publishing nodes and subscribing nodes
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
BRPI0516921B1 (pt) 2004-11-02 2016-04-12 Dow Global Technologies Inc homopolímero ou copolímero de etileno e processo de polimerização com iniciação via radical livre
BRPI0914059A2 (pt) 2008-10-07 2015-11-03 Dow Global Technologies Llc polímero a base de etileno e processo para preparar um polímero a base de etileno
JP5873803B2 (ja) 2009-12-18 2016-03-01 ダウ グローバル テクノロジーズ エルエルシー 低密度ポリエチレンを製造するための重合法
CN104011095B (zh) 2011-10-19 2016-10-05 陶氏环球技术有限责任公司 用于制备低密度基于乙烯的聚合物的采用新鲜乙烯分配的聚合方法

Also Published As

Publication number Publication date
AR083077A1 (es) 2013-01-30
US20130197168A1 (en) 2013-08-01
EP2621963B1 (en) 2016-07-06
US9234055B2 (en) 2016-01-12
CN103237819B (zh) 2016-10-26
EP2621963A1 (en) 2013-08-07
BR112013007510A2 (pt) 2016-11-08
ES2592184T3 (es) 2016-11-28
KR20140009164A (ko) 2014-01-22
KR20180049190A (ko) 2018-05-10
US9534064B2 (en) 2017-01-03
KR101911673B1 (ko) 2018-10-24
US20160115256A1 (en) 2016-04-28
JP2013543025A (ja) 2013-11-28
CN103237819A (zh) 2013-08-07
BR112013007510B1 (pt) 2020-10-20
WO2012044504A1 (en) 2012-04-05

Similar Documents

Publication Publication Date Title
JP5980214B2 (ja) 低密度ポリエチレンを製造するための重合プロセス
JP5873803B2 (ja) 低密度ポリエチレンを製造するための重合法
US9403928B2 (en) Polymerization process to make low density polyethylene
JP6759263B2 (ja) 高い溶融強度を有する低密度エチレン系ポリマー
US8871876B2 (en) Ethylene-based interpolymers and processes to make the same
US9228036B2 (en) Low density ethylene-based polymers with broad molecular weight distributions and low extractables
KR102166723B1 (ko) 고용융 강도를 갖는 저밀도 에틸렌-기반 폴리머를 함유하는 조성물 및 이로부터 형성된 필름

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140917

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20140917

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20150513

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20150623

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150717

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20151215

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20160405

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20160414

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20160705

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20160726

R150 Certificate of patent or registration of utility model

Ref document number: 5980214

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250