KR101911673B1 - 저밀도 폴리에틸렌을 제조하는 중합 방법 - Google Patents

저밀도 폴리에틸렌을 제조하는 중합 방법 Download PDF

Info

Publication number
KR101911673B1
KR101911673B1 KR1020187012061A KR20187012061A KR101911673B1 KR 101911673 B1 KR101911673 B1 KR 101911673B1 KR 1020187012061 A KR1020187012061 A KR 1020187012061A KR 20187012061 A KR20187012061 A KR 20187012061A KR 101911673 B1 KR101911673 B1 KR 101911673B1
Authority
KR
South Korea
Prior art keywords
zone
reactor
polymer
ethylene
cta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020187012061A
Other languages
English (en)
Korean (ko)
Other versions
KR20180049190A (ko
Inventor
오토 제이 베르베
도엘더 코르넬리스 에프 제이 덴
코르넬리스 제이 호스만
Original Assignee
다우 글로벌 테크놀로지스 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 엘엘씨 filed Critical 다우 글로벌 테크놀로지스 엘엘씨
Publication of KR20180049190A publication Critical patent/KR20180049190A/ko
Application granted granted Critical
Publication of KR101911673B1 publication Critical patent/KR101911673B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
KR1020187012061A 2010-09-30 2011-09-21 저밀도 폴리에틸렌을 제조하는 중합 방법 Active KR101911673B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38815210P 2010-09-30 2010-09-30
US61/388,152 2010-09-30
PCT/US2011/052525 WO2012044504A1 (en) 2010-09-30 2011-09-21 Polymerization process to make low density polyethylene

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020137010956A Division KR20140009164A (ko) 2010-09-30 2011-09-21 저밀도 폴리에틸렌을 제조하는 중합 방법

Publications (2)

Publication Number Publication Date
KR20180049190A KR20180049190A (ko) 2018-05-10
KR101911673B1 true KR101911673B1 (ko) 2018-10-24

Family

ID=44720187

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020187012061A Active KR101911673B1 (ko) 2010-09-30 2011-09-21 저밀도 폴리에틸렌을 제조하는 중합 방법
KR1020137010956A Ceased KR20140009164A (ko) 2010-09-30 2011-09-21 저밀도 폴리에틸렌을 제조하는 중합 방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020137010956A Ceased KR20140009164A (ko) 2010-09-30 2011-09-21 저밀도 폴리에틸렌을 제조하는 중합 방법

Country Status (9)

Country Link
US (2) US9234055B2 (enExample)
EP (1) EP2621963B1 (enExample)
JP (1) JP5980214B2 (enExample)
KR (2) KR101911673B1 (enExample)
CN (1) CN103237819B (enExample)
AR (1) AR083077A1 (enExample)
BR (1) BR112013007510B1 (enExample)
ES (1) ES2592184T3 (enExample)
WO (1) WO2012044504A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102755274B1 (ko) 2024-07-05 2025-01-22 최병렬 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103282391B (zh) 2010-10-29 2016-12-07 陶氏环球技术有限责任公司 基于乙烯的聚合物及其制备方法
EP2751146B1 (en) * 2011-10-19 2016-01-20 Dow Global Technologies LLC Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers
IN2014CN03782A (enExample) 2011-11-23 2015-09-25 Dow Global Technologies Llc
KR101945575B1 (ko) 2011-11-23 2019-02-07 다우 글로벌 테크놀로지스 엘엘씨 더 낮은 분자량의 추출물을 갖는 저밀도 에틸렌-계 중합체
KR101989335B1 (ko) 2011-12-22 2019-06-17 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도를 가진 에틸렌-기재 중합체 및 그의 제조 방법
WO2014003783A1 (en) * 2012-06-29 2014-01-03 Exxonmobil Chemical Patents Inc. Dual modifiers in high pressure polyethylene processes to prevent reactor fouling
JP6279584B2 (ja) * 2012-09-28 2018-02-14 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびその製造方法
BR112015010787B1 (pt) 2012-11-20 2022-01-18 Dow Global Technologies Llc Composição a base de etileno de baixa densidade, artigo e método de polimerização para formar uma composição a base de etileno de baixa densidade
CN105189638B (zh) 2013-05-22 2018-02-06 陶氏环球技术有限责任公司 在高熔体强度和中‑高密度控制下的基于低密度乙烯的聚合物组合物
KR20200124326A (ko) 2013-05-22 2020-11-02 다우 글로벌 테크놀로지스 엘엘씨 개선된 용융 강도, 출력 및 기계적 특성을 갖는 저밀도 에틸렌계 조성물
WO2015100318A1 (en) * 2013-12-26 2015-07-02 Dow Global Technologies Llc Processes to form ethylene-based polymers using asymmetrical polyenes
JP6331390B2 (ja) * 2013-12-27 2018-05-30 キョーラク株式会社 発泡成形体
US9206293B2 (en) * 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
CN105585766A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种药用薄膜用低密度聚乙烯树脂及其制备方法
CN105585765A (zh) * 2014-10-20 2016-05-18 中国石油化工股份有限公司 一种用于制造高透明薄膜的低密度聚乙烯树脂及其制备方法
KR101692123B1 (ko) * 2014-12-24 2017-01-02 한화토탈 주식회사 보호필름용 폴리에틸렌 수지의 제조방법
WO2016109266A1 (en) 2014-12-30 2016-07-07 Dow Global Technologies Llc Process to control output and quality of ethylene-based polymer formed by high pressure free radical polymerization
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
US10730973B2 (en) 2015-06-25 2020-08-04 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables and low densities
CN107750257B (zh) * 2015-06-25 2021-03-30 陶氏环球技术有限责任公司 制备具有较高g′和较宽mwd的管状乙烯基聚合物的改进方法
WO2016210055A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables
EP3317306B1 (en) 2015-06-25 2020-03-18 Dow Global Technologies LLC Process for forming ethylene based polymers
WO2017004320A1 (en) 2015-06-30 2017-01-05 Dow Global Technologies Llc High pressure free-radical polymerizations
EP3168239A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure free radical polymerizations
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3238938A1 (en) 2016-04-29 2017-11-01 Borealis AG Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers
EP3260473A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
WO2018218470A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
US11072669B2 (en) * 2017-06-28 2021-07-27 Dow Global Technologies Llc High pressure, free radical polymerizations to produce ethylene-based polymers
BR112020001030B1 (pt) 2017-07-28 2023-10-17 Dow Global Technologies Llc Homopolímero de polietileno, composição e artigo
WO2019078561A1 (ko) * 2017-10-19 2019-04-25 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
KR102410623B1 (ko) * 2017-10-19 2022-06-17 주식회사 엘지화학 폴리에틸렌 수지의 제조 방법
WO2020183248A1 (en) * 2019-03-14 2020-09-17 Braskem S.A. Extrusion coating resin from tubular reactor
AR119432A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta
KR102446740B1 (ko) * 2019-11-22 2022-09-23 롯데케미칼 주식회사 가공성이 우수한 압출코팅용 에틸렌 비닐 아세테이트 공중합체 및 그 제조방법
CN112250780B (zh) * 2020-10-19 2021-09-07 浙江大学 一种用于高压烯烃聚合的方法
JP2022156612A (ja) * 2021-03-31 2022-10-14 住友化学株式会社 ポリエチレンの製造方法
CN115197348B (zh) * 2021-04-14 2024-06-14 浙江大学 乙烯聚合物以及用于制备乙烯聚合物的高压自由基聚合方法与装置
CN114989340A (zh) * 2022-06-28 2022-09-02 杭州双安科技有限公司 一种烯烃聚合方法
EP4467575A1 (en) 2023-05-26 2024-11-27 Basell Polyolefine GmbH High pressure polymerization of ethylene
CN118085148B (zh) * 2024-02-20 2025-04-29 浙江大学 一种用于制备乙烯-极性单体共聚物的方法和装置

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006049783A1 (en) 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents
WO2011075465A1 (en) 2009-12-18 2011-06-23 Dow Global Technology Llc Polymerization process to make low density polyethylene

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964515A (en) 1957-07-01 1960-12-13 Nat Distillers Chem Corp Ethylene polymerization process
US3756996A (en) 1964-10-02 1973-09-04 Nat Distillers Chem Corp Process for the production of ethylene polymers
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3536693A (en) 1968-01-31 1970-10-27 Eastman Kodak Co Process for preparing polyethylene having improved properties
DE2107945A1 (en) 1971-02-19 1972-08-24 F J Gattys Ing Buero F Chem Ma High pressure polyethylene prodn - using stirred autoclave and tubular after-reactor for high yield and quality
US3913698A (en) 1974-02-01 1975-10-21 Power Matic Corp Variable speed transmission
JPS5322582A (en) * 1976-08-13 1978-03-02 Sumitomo Chem Co Ltd Production of polyethylene
DE2814650C2 (de) 1978-04-05 1984-02-02 EC Erdölchemie GmbH, 5000 Köln Herstellung von Homo-oder Copolymeren des Äthylens nach dem Hochdruckverfahren in Rührautoklaven mit praktisch vollständiger Rückvermischung
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4599392A (en) 1983-06-13 1986-07-08 The Dow Chemical Company Interpolymers of ethylene and unsaturated carboxylic acids
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4988781A (en) 1989-02-27 1991-01-29 The Dow Chemical Company Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters
DE3912975A1 (de) * 1989-04-20 1990-11-08 Basf Ag Polyethylen sowie copolymerisate aus ueberwiegenden anteilen von ethylen
DE4132012A1 (de) 1991-09-26 1993-04-01 Basf Ag Ethylenhomopolymerisate und -copolymerisate sowie ein verfahren zu ihrer herstellung
CA2232389A1 (en) 1995-09-29 1997-04-03 Seema V. Karande Cross-linked polyolefinic foams and process for their production
DE69826103T3 (de) * 1998-01-12 2012-07-12 Dow Global Technologies Inc. Äthylenpolymere mittlerer Dichte, Verfahren zur Herstellung dieser Polymere und Verwendung von Carbonyl-haltigen Kettenübertragungsmitteln in diesem Verfahren
US6407191B1 (en) 1998-01-12 2002-06-18 The Dow Chemical Company Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process
US7406537B2 (en) 2002-11-26 2008-07-29 Progress Software Corporation Dynamic subscription and message routing on a topic between publishing nodes and subscribing nodes
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
EP2751146B1 (en) 2011-10-19 2016-01-20 Dow Global Technologies LLC Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006049783A1 (en) 2004-11-02 2006-05-11 Dow Global Technologies Inc. Process for producing low density polyethylene compositions and polymers produced therefrom
WO2010042390A1 (en) 2008-10-07 2010-04-15 Dow Global Technologies Inc. High pressure low density polyethylene resins with improved optical properties produced through the use of highly active chain transfer agents
WO2011075465A1 (en) 2009-12-18 2011-06-23 Dow Global Technology Llc Polymerization process to make low density polyethylene

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102755274B1 (ko) 2024-07-05 2025-01-22 최병렬 압축기와 반응기와 촉매제 기반 에틸렌과 프로판과 고분자 재료 혼합 복합 생산 시스템 및 그 운용방법

Also Published As

Publication number Publication date
KR20180049190A (ko) 2018-05-10
BR112013007510A2 (pt) 2016-11-08
CN103237819B (zh) 2016-10-26
US20130197168A1 (en) 2013-08-01
JP5980214B2 (ja) 2016-08-31
CN103237819A (zh) 2013-08-07
US9234055B2 (en) 2016-01-12
BR112013007510B1 (pt) 2020-10-20
EP2621963B1 (en) 2016-07-06
ES2592184T3 (es) 2016-11-28
KR20140009164A (ko) 2014-01-22
US20160115256A1 (en) 2016-04-28
AR083077A1 (es) 2013-01-30
EP2621963A1 (en) 2013-08-07
US9534064B2 (en) 2017-01-03
WO2012044504A1 (en) 2012-04-05
JP2013543025A (ja) 2013-11-28

Similar Documents

Publication Publication Date Title
KR101911673B1 (ko) 저밀도 폴리에틸렌을 제조하는 중합 방법
JP5873803B2 (ja) 低密度ポリエチレンを製造するための重合法
US10301403B2 (en) Low density ethylene-based polymers with broad molecular weight distributions and low extractables
US9403928B2 (en) Polymerization process to make low density polyethylene
US9765160B2 (en) Tubular low density ethylene-based polymers with improved balance of extractables and melt elasticity
WO2019022974A1 (en) LOW DENSITY ETHYLENE POLYMERS FOR LOW SPEED EXTRUSION COATING OPERATIONS

Legal Events

Date Code Title Description
A107 Divisional application of patent
A201 Request for examination
PA0104 Divisional application for international application

St.27 status event code: A-0-1-A10-A18-div-PA0104

St.27 status event code: A-0-1-A10-A16-div-PA0104

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 8