CN102471181A - 甲烷的氧化偶联方法 - Google Patents

甲烷的氧化偶联方法 Download PDF

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Publication number
CN102471181A
CN102471181A CN2010800290822A CN201080029082A CN102471181A CN 102471181 A CN102471181 A CN 102471181A CN 2010800290822 A CN2010800290822 A CN 2010800290822A CN 201080029082 A CN201080029082 A CN 201080029082A CN 102471181 A CN102471181 A CN 102471181A
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catalyzer
weight
methane
oxidative coupling
family
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Chinese (zh)
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S·钦塔
J·托尔曼
J·R·巴特勒
J·亨特
T·里维斯
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Fina Technology Inc
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Fina Technology Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2010800290822A 2009-06-29 2010-06-25 甲烷的氧化偶联方法 Pending CN102471181A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/494,117 US8912381B2 (en) 2009-06-29 2009-06-29 Process for the oxidative coupling of methane
US12/494,117 2009-06-29
PCT/US2010/039887 WO2011008464A1 (en) 2009-06-29 2010-06-25 Process for the oxidative coupling of methane

Publications (1)

Publication Number Publication Date
CN102471181A true CN102471181A (zh) 2012-05-23

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Country Status (9)

Country Link
US (1) US8912381B2 (https=)
EP (1) EP2448888A4 (https=)
JP (1) JP2012532104A (https=)
KR (1) KR20120109998A (https=)
CN (1) CN102471181A (https=)
AU (1) AU2010273876A1 (https=)
EA (1) EA201270073A1 (https=)
TW (1) TW201119979A (https=)
WO (1) WO2011008464A1 (https=)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104619677A (zh) * 2012-07-18 2015-05-13 西北大学 形成乙烯
CN107646027A (zh) * 2015-06-08 2018-01-30 沙特基础全球技术有限公司 甲烷氧化偶联的低入口温度
CN108025287A (zh) * 2015-06-08 2018-05-11 沙特基础全球技术有限公司 使用La-Ce催化剂的甲烷氧化偶联
CN109663587A (zh) * 2018-11-30 2019-04-23 中国科学院山西煤炭化学研究所 一种纳米甲烷氧化偶联催化剂及其制备方法和应用
CN110655437A (zh) * 2014-01-08 2020-01-07 鲁玛斯技术有限责任公司 乙烯成液体的系统和方法
CN113813949A (zh) * 2020-06-18 2021-12-21 中国石油化工股份有限公司 含铈的催化剂及其制备方法和应用
CN113813950A (zh) * 2020-06-19 2021-12-21 中国石油化工股份有限公司 含钾的催化剂及其制备方法和应用
CN115487840A (zh) * 2021-06-18 2022-12-20 中国石油化工股份有限公司 含有碳酸氧镧的催化剂的制备方法和应用

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US8450546B2 (en) * 2009-06-29 2013-05-28 Fina Technology, Inc. Process for the oxidative coupling of hydrocarbons
US8399726B2 (en) 2010-04-20 2013-03-19 Fina Technology Inc Reactors and processes for the oxidative coupling of hydrocarbons
EP2576046B1 (en) 2010-05-24 2014-11-19 Siluria Technologies, Inc. Method for producing ethylene from methane using a polycrystalline nanowire catalyst
WO2012162526A2 (en) 2011-05-24 2012-11-29 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
US9403737B2 (en) 2011-07-18 2016-08-02 Northwestern University Forming ethylene
US8962517B2 (en) 2011-11-29 2015-02-24 Siluria Technologies, Inc. Nanowire catalysts and methods for their use and preparation
US9133079B2 (en) 2012-01-13 2015-09-15 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
CA2874526C (en) 2012-05-24 2022-01-18 Siluria Technologies, Inc. Oxidative coupling of methane systems and methods
CA3125016C (en) 2012-05-24 2024-04-30 Lummus Technology Llc Catalytic forms and formulations
US9670113B2 (en) 2012-07-09 2017-06-06 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
CA2902192C (en) 2013-03-15 2021-12-07 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
CN103350002A (zh) * 2013-07-19 2013-10-16 上海中科高等研究院 催化甲烷氧化偶联制乙烷和乙烯的氧化物纳米棒催化剂及其制法及其应用
EP3074119B1 (en) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2935946C (en) 2014-01-09 2022-05-03 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3137211A2 (en) 2014-05-02 2017-03-08 Siluria Technologies, Inc. Heterogeneous catalysts
US9751079B2 (en) 2014-09-17 2017-09-05 Silura Technologies, Inc. Catalysts for natural gas processes
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
TW201634430A (zh) * 2015-03-26 2016-10-01 陶氏全球科技責任有限公司 烷酸烷酯之氣相產生
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US10625244B2 (en) 2015-07-15 2020-04-21 Sabic Global Technologies, B.V. Silver promoted catalysts for oxidative coupling of methane
US20170107162A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
US11458458B2 (en) 2017-03-22 2022-10-04 Sabic Global Technologies, B.V. Mixed oxides catalysts for oxidative coupling of methane
HUE064375T2 (hu) 2017-05-23 2024-03-28 Lummus Technology Inc Metán oxidatív csatolási folyamatainak integrálása
AU2018298234B2 (en) 2017-07-07 2022-11-17 Lummus Technology Llc Systems and methods for the oxidative coupling of methane
RU2761985C1 (ru) * 2018-08-09 2021-12-14 Сабик Глоубл Текнолоджиз, Б.В. Смешанные оксидные катализаторы окислительной конденсации метана
WO2020160258A1 (en) * 2019-01-30 2020-08-06 Lummus Technology Llc Catalysts for oxidative coupling of methane
WO2021050208A1 (en) * 2019-09-10 2021-03-18 Sabic Global Technologies, B.V. Highly selective mixed oxide catalyst for oxidative coupling of methane
CN113800994A (zh) * 2020-06-17 2021-12-17 中国石油化工股份有限公司 甲烷氧化偶联反应与乙烷催化脱氢反应耦合制备乙烯的方法和系统
JP7437701B2 (ja) 2020-09-25 2024-02-26 三菱重工業株式会社 部分酸化カップリング触媒、並びに、この触媒を用いたオレフィン製造装置及びオレフィン製造方法
CN114605217B (zh) * 2020-12-08 2023-05-16 中国科学院大连化学物理研究所 一种甲烷氧化偶联制乙烯的方法
CN114605215B (zh) * 2020-12-08 2023-06-06 中国科学院大连化学物理研究所 甲烷氧化偶联制乙烯的方法
TW202313528A (zh) 2021-08-31 2023-04-01 美商祿幕斯科技有限責任公司 用於執行甲烷的氧化耦合的方法及系統
CN117920185B (zh) * 2022-10-14 2026-02-06 中国石油化工股份有限公司 催化剂及其制备方法和应用

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