CN1017240B - 含有吡唑衍生物的除草剂 - Google Patents
含有吡唑衍生物的除草剂Info
- Publication number
- CN1017240B CN1017240B CN89104508A CN89104508A CN1017240B CN 1017240 B CN1017240 B CN 1017240B CN 89104508 A CN89104508 A CN 89104508A CN 89104508 A CN89104508 A CN 89104508A CN 1017240 B CN1017240 B CN 1017240B
- Authority
- CN
- China
- Prior art keywords
- ome
- och
- coph
- sch
- opr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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- FKERUJTUOYLBKB-UHFFFAOYSA-N pyrazoxyfen Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OCC(=O)C1=CC=CC=C1 FKERUJTUOYLBKB-UHFFFAOYSA-N 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
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- 238000006462 rearrangement reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
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- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
- C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
- C07C205/37—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
- C07C317/46—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
- C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
-
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Abstract
一种式I的吡唑衍生物和它的盐,其特征在于A为烃基;B为氢原子、卤素、烷氧基等;X为烷基、烷氧基、卤素、硝基等:Y为-OR1、-0-L-O-R1等;V为氢原子、卤素原子、或烷基等;W为氢原子、卤素、烷基等;Q为可被卤素等取代的C1-C6烷基、-C(O)R7等。该衍生物可作为选择性除草剂的活性成分,使用广泛,对农作物无植物毒性。
Description
本发明涉及新颖的4-苯甲酰基吡唑衍生物以及含有这类衍生物作为活性组分的选择性除草剂,它们作为高原农田的除草剂尤为有用。
由于多年来对除草剂广泛的研究和开发,各种除草剂已被开发出来并在实践中得到应用,这类除草剂对减少用于控制杂草所需的劳动力作出了贡献,或者对促进农业植物或园艺植物的生长作出了贡献。
即使这样,仍然需要开发一种具有优良除草特性的新的除草剂。特别地,需要开发一种能选择性的控制杂草而对谷类植物无不利影响并能低剂量使用有效的农业或园艺除草剂。但是,常规的除草剂不一定提供这类所需的除草剂特性。
另一方面,4-苯甲酰基吡唑衍生物的某些化合物已知具有除草活性的。例如,吡唑酯(pyrazo-late)(普通名)和吡唑硫(pyrazoxyfen)(普通名)特别可用作水稻田的除草剂。虽然作为水稻田的除草剂显示出优良的除草活剂时,这些化合物作为高原的除草剂是不合适的,因为相对于高原土地的杂草来说,它们的除草活性较弱。在4-苯甲酰基吡唑衍生物中,需要开发一种可有效地用作高原土地除草剂的优良化合物。
本发明提供了一种具有下式的吡唑衍生物,或它的盐:
其中A为C1-C6的烷基、C2-C4的链烯基或C2-C4的炔基;
B为氢原子、C1-C3的烷基、卤素原子、C1-C3的卤代烷基、C1-C4的烷氧基、C1-C3的烷硫基、C2-C4的烷氧基烷基、C2-C4的烷硫基烷基或C2-C4的烷氧基羰基;
X为C1-C6的烷基、C1-C6的烷氧基、卤素原子、硝基、氰基C1-C6的卤代烷基、C2-C6的烷氧基烷基、C2-C6的烷基羰基、C2-C6的烷氧基羰基、独自被卤素或被C1-C6的烷基所取代的氨基羰基、C1-C6的卤代烷氧基、C1-C6的烷硫基或C2-C6的烷硫基烷基;
Y为OR1(其中R1为C3-C8的环烷基、C4-C8环烷基烷基、C3-C6的链烯基、C2-C6的炔基、C1-C6的卤代烷基、C3-C8的卤代环烷基烷基、C3-C6的卤代链烯基、C2-C6的卤代炔基、C2-C6的硝基烷基或者为可被C1-C3烷基、卤素原子、硝基或C1-C3烷氧基取代的苯基)、-O-L-O-R′(其中L为可被C1-C3烷基取代的C1-C6亚烷基、R′的定义同上)、-O-L-OH(其中L的定义同上)、-O-L-O-L-O-R2(其中L的定义同上,R2为一氢原子、C1-C6烷基或为可被C1-C3烷基、卤素、硝基或C1-C3烷氧基取代的苯基)、-O-L-R3(其中L的定义同上,R3为可被C1-C3烷基、卤素原子、硝基或C1-C3烷氧基取代的苯基)、-O-M(其中M为含有不多于两个硫原子或氧原子并通过1至4个碳原子连接而形成的3-6-个环中原子数的脂环基)、-O-L-M(其中L和M的定义同上)、-O-L-NR4R5(其中L的定义同上,R4和R5可相同或不同,各自为氢原子或C1-C6的烷基,或者R4和R5与相邻的氮原子一起形成了一个环)-O-L-COOR4(其中L和R4的定义同上)、-O-CH-CH-COOR4(其中R4的意义同上)、-O-L-CN(其中L的定义同上)、-O-L-C(O)-R2(其中L和R2的定义同上)、-O-L-S(O)n-R4(其中L和R4的定义同上,n为0至2的整数)、-O-COOR4(其中R4的定义同上)、-O-CONR4R5(其中R4和R5的定义同上)、-OP(O)(OR4)(其中R4的定义同上)、-S(O)n
R1(其中R1和n的定义同上)、或者-S(O)n-L-O-R1(其中L、R1和n的定义同上)。
Z为卤素原子、硝基、C1-C3烷氧基、三氟甲基、四氟甲氧基、氰基或-S(O)nR6(其中n的定义同上,R6为C1-C3烷基或C1-C3的卤代烷基);
V为氢原子、卤素原子、C1-C4烷基或C1-C4烷氧基;
W为氢原子、卤素原子、C1-C4的烷基、C1-C4的卤代烷基、C1-C4的烷氧基、C2-C6的烷氧基烷基、C2-C5的烷氧基羰基、C1-C3的卤代烷氧基、硝基、氰基或-S-(O)n-R6(其中n和R6的定义同上);
Q为氢原子、可被卤素原子取代的C1-C6烷基、可被卤素原子取代的C1-C6链烯基、可被卤素原子取代的C1-C6炔基、氰甲基、-C-(O)-R7(其中R′为可被相同的或不同的取代基所取代的苯基,这些取代基选自一组包括由C1-C6的烷基、C1-C6的链烯基、C1-C6的炔基、C1-C6的卤代烷基、C1-C6的卤代链烯基、C1-C6的卤代炔基、卤素原子、硝基和三氟代甲基所组成的组、C1-C6烷基、C1-C6烷氧基或为羟基)、-S(O)2R7(其中R7的定义同上)-P(O)(OR7)2(其中R7定义同上)、-L-C(O)R7(其中L和R7的定义同上)-L-C(O)-N(R8)(R9)(其中L的定义同上,R8和R9可相同或不同为氢原子或C1-C6烷基)、-L-R10(其中L的定义同上,R10为可被相同或不相同取代基所取代的苯基,这些取代基选自一组包括卤素原子、硝基和三氟代甲基组成的组、C1-C6烷基、C1-C6烷氧基或者羟基)、-L-N(R8)(R9)(其中L、R8和R7的定义同上)、-L-OR11(其中L的定义同上、R11为氢原子、C1-C6烷基或C1-C6链烯基)、-L-OC(O)R12(其中L与上述定义相同,R12为C1-C6烷基或C1-C6烷氧基)、-L-S(O)nR11(其中L、n和R11的定义同上)、-L-SC(O)R8(其中L和R8的定义同上)、
其中L1和L1可为相同的或不同的,各自为亚甲基、氧原子或硫原子,R12为氢原子或C1-C3烷基,m为2或3);
本发明也提供了一种选择性的除草剂组合物,它包括至少一种除草有效量的上述所定义的式Ⅰ吡唑衍生物或它的盐以及一种农业载体或稀释剂。
进一步地说,本发明提供了一种可选择性地控制杂草的方法,它包括将上述所定义式Ⅰ的吡唑衍生物或它的盐施用在所需保护的地方。
此外,本发明提供了一种下式的经取代的苯的衍生物:
其中G为羧基、卤代羰基或氰基羰基,X、Y、Z、V和W与上述定义相同。
现在,本发明将参照较佳具体实例详细描述。
在本发明的式Ⅰ化合物中,A、B、X、Y、Z和Q较好分别选自下列取代基(见图1)。
当Q为氢原子时,化合物可很容易地与金属或有机碱形成盐。
作为这类金属,可提及的为钠、钾、钙、锂、钡、镁、铁、铜、镍或锰。
作为这类有机碱,可提及的为甲基胺、二甲胺、三甲胺、乙基胺、二乙胺、三乙胺、正丙胺、二正丙胺、异丙胺、二异丙胺、正丁胺、异丁胺、仲丁胺、叔丁胺、哌啶、吡咯烷、吗啉、吡啶、NN-二甲基苯胺或胆碱。
为了开发出有用的除草剂,在对各种有机化合物的除草剂特性进行研究的进程中,本发明业已发现上述的本发明化合物表现出对窄叶杂草(禾本科杂草和莎草科杂草)以及宽叶杂草有优良的除草性,并且对有用的植物,例如诸如Zea mays(玉米)、Sorq-hum bicolor(芦粟)、Triticum spp(小麦)、Hordeum Vulqare(大麦)和农作物基本上无植物毒性。本发明是在此发明的基础完成的。
在各个土壤治理,土壤综合治理和叶子处理中,本发明的化合物表现出强烈的除草剂活性。另一方面,在土壤处理、土壤综合治理和叶子处理中,应用它对诸如Zea mays(玉米)、Sorqhum bicolor(芦粟)、Triticum spp(小麦)、Hordeum Vulqare(大麦)的农作物不表现出植物毒性。因此,本发明的化合物具有高的选择性,在这些谷类植物的栽培期间,它对于控制杂草是很有效的。也就是说,本发明化合物对诸如Setaria viridis(绿色狐尾状植物)、Echinochloaocrus-qalli(稗)、Amarathus lividus(青灰色苋)、Polyqonum lonqisetum(蓼)Xanthium stru-marium(苍耳)、Abutilon theophrasti(茴麻)和Cy-perus esculenlus(铁茡荠)的有害杂草表现出强烈的除草活性,它在Zea mays(玉米)或Sorqhum bicol-or(芦粟)的栽培期间使用。对禾本科杂草和Cyperus esculentus(铁茡荠)的除草活性相当高,并且十分独特。因此,在Zea mays(玉米)或Sorqhum bicolor
(芦粟)的栽培期间,它通常用于作为敌菌灵均三氮苯型(triazine-type)除草剂的阿特拉津(atranzin-e)或丙腈津(eyanazine)或者用于作为酸酰基苯型的除草剂的草不绿(alachlor)或盖草绿(metolachl-or)。但是,虽然阿特拉津和丙腈津对宽叶杂草显示出高活性但对禾术科杂草则有不良的除草活性,且对Cyperus esculenlus(铁茡荠)的活性十分低。另一方面,虽然草不绿和盖草绿对禾本科杂草的活性很高,但对宽叶杂草具有不良的活性,且对于和Cype-rus esculenlus(铁茡荠)的活性也十分低。因此,只单独施用这类除草剂来除去所有的杂草种类是很困难的。
作为各种研究的结果,本发明者业已发现,本发明的化合物对广范围的杂草表现出优良的除草作用,本发明就是在发现的基础产生的。本发明化合物也有一个特征,即它对于诸如Zea mays(玉米)、Sorqhum bicolor(芦粟)、Teiticum spp(小麦)和Ho-rdeum Vulqare(大麦)的农植物无植物毒性。因此可安全地施用于这些各类植物的田地里。
进一步地说,本发明化合物包括一个在Oryza satira(稻)和Echinochloa crus-qalli(稗)之间显示出选择性的化合物,它也包括对于诸如Goxxypium spp(棉花)、Bata Vulqaris(甜菜)或Clycine max(大豆)的有用植物具有选择性的一个化合物。
此外,已知4-苯甲酰基吡唑衍生物具有优良的除草活性。例如,吡唑酯(普通名)在市场上有售,并广泛地在实际中应用。但是,这些常规的除草剂用于水稻田时受到限制,用于高原土地进其活性极为不良。然而,作为多年来对4-苯甲酰基吡唑衍生物的广泛研究的结果,本发明人最后已发现了本发明的化合物,它在用作上述结构的取代物时同时满足各种条件,应用于高地的各个土壤治理、土壤综合治理和叶子处理时表现出强烈的除草剂活性。已发现本发明的化合物对禾本科杂草和Cyperus esculenlus(铁茡荠)表现出尤为高的活性。
通过下列的任何一个反应可方便地制备本发明的化合物(见图2)。
上述中,A、B、V、W、X、Y、Z和Q和定义同上,E为卤素原子、甲磺酰基氧基或对-甲苯磺酰基氧基。进一步地说,
的互变异构体,可由任一个式子表示。
反应式(1)表示具有合适取代的苯甲酸与5-羟基吡唑在缩合剂和碱存在下在惰性溶剂中反应,以得到4-苯甲酰基-5-羟基吡唑。缩合剂的用量是每摩尔苯甲酸和吡唑为1.0至1.5摩尔。作为缩合剂,可提及N,N′-二环己基碳化二亚胺。溶剂是随意的只要它对反应是惰性的即可。最为理想的溶剂是叔丁醇、叔戊醇或异丙醇。碱不是必不可少的。但是,总的来说,用碱后可提高收得率。对碱没有特殊的限制,但较好的是使用碳酸钾或碳酸钠。反应温度从室温至溶剂的沸点温度,但较好地从50至100℃。
反应时间通常从0.5至20小时。
反应式(2)表示一个反应,其中具有合适取代基的苯甲酰氯和5-羟基吡唑反应形成苯甲酰酯,然后它重排成4-苯甲酰化合物。
苯甲酰酯化作用可在惰性溶剂(诸职芳族烃、脂肪酸酯、卤化烃、醚、乙腈、二甲亚砜或N,N′-二甲基甲酰胺)中进行或者在这类溶剂和水的两相体系中进行或者在适当脱去氯化氢剂(例如,诸如氢氧化钠、氢氧化钾或碳酸氢钠的无机碱或诸如吡啶或三乙胺的在机碱)存在于这类溶剂中的混合物中进行在室温至100℃、10分钟至5小时下进行地反应。
重排反应在诸如无水氯化铝的路易斯酸或碱存在下进行。可用的碱为碳酸钾、氢氧化钙、或碳酸钠。路易斯酸或碱通常用量为1至10摩尔倍数。
不需要溶剂,但是,一些状况下,采用具有适当沸点的溶剂来提高操作效率或得率是有利的。作为这类有利的例子,可提及采用二噁烷、甲苯或二甲苯二甘醇二甲醚。
反应温度通常从50至150℃,反应时间通常为15分钟至30小时。
反应式(3)表示一个反应,其中将苯衍生物、5-羟基吡唑衍生物和四氯化碳在路易斯酸存在下于惰性溶剂中或无溶剂时进行缩合,然后水解以得到4-苯甲酰基-5-羟基吡唑衍生物。作为路易斯酸,较好的是对反应的至少理论量的数量的无水氯化铝或无水溴化铝。溶剂可为任何类型,只要它对于反应是惰性的即可。但是,诸如二氯甲烷、二氯乙烷或四氯乙烷的氯型溶剂较为优选。缩合温度范围从0℃至溶剂的沸点温度,但较好的是从10至
80℃。水解作用是在盐酸或硫酸存在下进行。水解温度较好地是从室温至100℃水解时间通常从0.1至10小时。
反应式(4)表示一个反应,其中将苯甲腈衍生物和5-羟基吡唑衍生物在路易斯酸和碱存在下在惰性溶剂中或无溶剂时进行反应得到4-苯甲酰基-5-羟基吡唑。作为路易斯酸,可采用氯化锌、氧化铝或溴化铝。作为碱,可提及吡啶或三乙胺。路易斯酸和碱的普通用量为1至10摩尔倍量。作为溶剂,可提及二氯甲烷、二氯乙烷或四氯乙烷。反应温度通常从0℃至80℃,较好地是从10至50℃。反应时间从0.5至2小时。
反应式(5)表示一个反应,其中将4-苯甲酰基-5-羟基吡唑与卤化物、甲磺酸酯或对-甲苯磺酸酯进行缩合。
对于此反应,较好的是采用1至3摩尔倍量的脱去卤化氢剂(dehydrohalogenating agent)。作为这样的脱去卤化氢剂,可提及诸如氢氧化钠、氢氧化钾、碳酸钠、碳酸氢钠或碳酸钾的无机碱,或者诸如吡啶或三乙胺的有机碱。
只要溶剂对反应是惰性的,对溶剂别无特别的限制。广范围的溶剂包括芳族烃、脂肪酯酯、卤代烃、醚、酮、脂族烃、乙腈、二甲亚砜和二甲基甲酰胺。
在室温至溶剂沸点温度范围内,可任意选择反应温度,反应时间通常从30分钟至30小时。
反应式(6)表示一个反应,其中4-苯甲酰基5-羟基吡唑通过与卤化剂转变成5-卤代化合物,或者通过甲磺酰氯或对-甲苯磺酰氯转变成甲磺酰酯化合物对-甲苯磺酰酯化合物,然后再与适当的醇或酸缩合。
作为卤化剂,可提及磷酰氯、五氯化磷或亚硫酰氯。
作为溶剂,可采用对反应呈惰性的广泛范围里的溶剂,诸如二甲基甲酰胺。但是,没有任何溶剂也可进行反应。
反应温度较好地从30至150℃,反应时间常常是30分钟至10小时。在某些状况下,通过加入脱去卤化氢剂可以缩短反应时间或者提高得率。
通过加入了脱去卤化氢剂来进行与醇或酸的缩合反应。
作为一种脱去卤化氢剂,可采用诸如氢氧化钠、氢氧化钾、碳酸钠、碳酸钾、醇钠、氢化钠的碱。
溶剂可为对反应呈惰性的任何溶剂(诸如芳族烃、醚、酮或N,N′-二甲基甲酰胺)。在室温至溶剂沸点的温度范围内,选择反应温度。
用作本发明化合物起始物质的经取代的苯衍生物具有新颖的结构,通过将各种已知的合成的适当的结合可容易地制备这些苯的衍生物。例如,苯环中取代基Z为-S(O)nCH3的化合物可根据下列反应式进行制备(见图3)。
上式中,X和Y的定义同上,Hal为卤素原子。
现在,参照实施例对被取代的苯衍生物和吡唑衍生物的制备作详细地描述。但是,应当知道,本发明不被这类特殊实施例所限制。
实施例1
4-(2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酰基)-1-乙基-5-烃基吡唑的制备
(1)2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酸(2-甲氧基)乙酯
将1.2克2-氯代-3-羟基-4-甲磺酰基苯甲酸,1.4克碳酸钾和2.1克2-溴代乙基甲基醚倒入20毫升N,N-二甲基甲酰胺中,并在加热至60到70℃的温度下,反应6至7小时。然后,蒸去溶剂,加入水后,用氯仿萃取反应混合物。用无水硫酸钠干燥,蒸去溶剂得到1.9克上述标题化合物的粗产品。
(2)2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酸。
将1.9克2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酸(2-甲氧基)乙酯的粗产品溶于50毫升乙醇中,向内加入20ml含有1克氢氧化钠的水溶液。混合物在室温下搅拌30分钟。然后,蒸去乙醇,向残留物中加水。用氯仿洗涤混合物,然后用浓盐酸酸化,并用氯仿萃取。萃取物用无水硫酸钠干燥。然后蒸去溶剂得到1.4克上述标题化合物的粗产品。向粗产品内加入正己烷,让混合物静置,从而使所需产品渐结晶析出。
熔点:89-92℃
(3)4-(2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酰基)-1-乙基-5-羟基吡唑
将1.2克2-氯代-4-甲磺酰基-3-(2-甲氧基)乙氧基苯甲酸、0.3克碳酸钾、0.45克1-乙基-5-羟基吡唑和0.77克N,N′-二环己基碳化二亚胺置于40毫升
叔戊醇中,在加热到80至90℃的温度下搅拌4至5小时。蒸去溶剂,向残留物中加入稀碳酸钾水溶液。用氯仿洗涤混合物。用浓盐酸酸化水层,并用氯仿萃取。用无水硫酸钠干燥萃取物。然后,蒸去溶剂得到上述标题化合物的粗产品。粗产品用乙醇重结晶得到0.3克所需的产品。熔点159-160℃
实施例2
4-(3-苄基氧基-2-氯代-4-甲磺酰基苯甲酰基)-1-乙基-5-羟基吡唑的制备
(1)3-苄氧基-2-氯代-4-甲磺酰基苯甲酸苄酯
将1.5克2-氯代-3-羟基-4-甲磺酰基苯甲酸、1.7克碳酸钾和5.1克苄基溴置于50毫升二甲基甲酰按中,将混合物在室温下搅拌过夜,然后在60至70℃的温度下加热3小时。蒸去溶剂,将水加至残留物中。用氯仿萃取混合物。萃取液用无水硫酸钠进行干燥。然后蒸去溶剂得到上述标题化合物的粗产品。粗产品用乙醇重结晶得到2.5克所需的产品。
(2)3-苄氧基-2-氯代-4-甲磺酰基苯甲酸
将2.5克3-苄氧基-2-氯代-4-甲磺酰苯甲酸苄酯置于50毫升乙醇中,向内加入25毫升含有1克氯化钠的水溶液。将混合物在室温下静置30分钟。然后,蒸去乙醇,向残留物中加水。用氯仿洗涤混合物。用浓盐酸酸化水层并用氯仿提取。用无水硫酸钠干燥萃取物。然后蒸去溶剂得到上述标题化合物的粗产品。用乙醇-异丙基醚洗涤粗产品得到1.0克所需的产品。
(3)4-(3-苄氧基-2-氯代-4-甲磺酰基苯甲酰基)乙基-5-羟基吡唑
将1.0克3-苄氧基-2-氯代-4-甲磺酰基苯甲酸、0.23克碳酸钾、0.24克1-乙基-5-羟基吡唑和0.59克N,N′-二环己基碳化二亚胺置于20毫升叔戊醇中,在加热到80至90℃的温度下将混合物搅拌4小时。蒸去溶剂,然后向残留物中加入碳酸钾水溶液。用氯仿洗涤混合物。用浓盐酸酸化水层然后用氯仿萃取。用无水硫酸钠干燥萃取物。然后蒸去溶剂得到上述标题化合物的粗产品。用乙醇将粗产品重结晶得到0.3克所需产物。熔点:162-165℃。
表1和表2列出了根据前面实施例所制备的苯甲酸和吡唑衍生物的物理性质(表1表2见后)
包括前面实施例化合物表3至表8列出了用前面实施例相同方法得到的化合物。但是,本发明不限制于这些化合物。
表3至表8所用的各种符号具有如图4含义。
图4见后
当本发明的化合物被用作农业或园艺除草剂时,它常与合适的载体相混合,例如,诸如粘土、滑石粉、膨润土或硅藻土的固体载体,或者诸如水、芳族烃(诸如苯、甲苯、二甲苯)、氯化烃、醚、酮、酯(诸如乙酸乙酯)或酰胺(诸如二甲基甲酰胺)的液体载体。如果需要,可加入乳化剂、分散剂、悬浮剂、渗透剂铺展剂或稳定剂制得诸如液体配方,浓缩乳剂、可湿粉末、粉剂、颗粒剂或流动剂的任意配方。
进一步地说,如果需要的话,在配制时或在使用除草剂时可将其他除草剂、各种杀虫剂、杀菌剂、植物生长调节剂或增效剂结合进去。
作为其它除草剂与本发明除草剂相结合,可以提到,例如,在农场化学品手册(Farm Chemicals Handbook)(73年版1987)中所揭示的化合物。在这之中,可提到的有,例如阿特拉津、丙腈津、草不绿、盖草绿EPTC、2,4-D、苏灭达、麦草畏、溴苯腈、催迪芬(tridiphane)、异丙隆(isoproturon)、绿麦隆(chlo-rtoluron)、野麦畏、二氟菲尼更(difluphenican)、甲基二氯福普(diclofopmethyl)、二芬唑醌(diphen-zoquat)、甲基咪唑甲苯(imazmethabenzmethyl)、磺苯腈、噻唑隆(methabenzthiazuron)氟氧帕尔(flur-oxypul)、氯代磺隆(chlorsulfuron)和N-〔(4,6′-二(二氟甲氧基)嘧啶-2-基)氨基羰基〕-2-甲氧基羰基苯磺酰胺。在美国专利4,668,277中揭示的N-〔4,6-二甲氧基嘧啶-2-基)氨基羰基〕-3-氯代-4-甲氧基羰基-1-甲基吡唑-5-磺酰胺或N-〔(4,6-二甲氧基嘧啶-2-基)氨基羰基〕-3-溴代-4-甲氧基羰基-1-甲基吡唑-5-磺酰胺,或者在日本特开昭No.223180/1987号公报中揭示的N-〔(4,6-二甲氧基嘧啶-2-基)氨基羰基〕-3-二甲基氨基羰基吡啶-2-磺酰胺也可以结合到本发明的除草剂里。
根据使用地点、使用季节、使用方法,栽培农作物的种类等,其剂量各不相同。但是,总的来说,剂量通常在每公顷活性组分为0.001至10公斤的范围里。
现在,列出含有本发明化合物作为活性组分的除草剂配方实施例。但是,应当了解,本发明不被
这些特殊实施例所限制。在下列配方实施例中,“份数”表示“重量份数”。
配方实施例1:可湿性粉末
本发明化合物1号 60份
zeeklite PFP(由Zeeklite工业株式社 33份
制造的高岭土型粘土的商品名)
Sopol 5039(由东邦化学工业株式会社 5份
制造的非离子型表面活性剂和阴离子
表面活性剂的混合物的商品名)
Carplex(由盐野义制药株式会社制造 2份
的由表面活性剂和优良硅胶粉末组成的凝集
防止剂)
将上述组份均匀研碎并混合形成可湿性粉末。
配方实施例2:浓缩乳剂
本发明化合物1号 1.5份
二甲苯 78.5份
N,N-二甲基甲酰胺 1.5份
Sorpol 2608(由东邦化学工业株式会社 5份
制造的非离子表面活性剂和阴离子表面活性剂混合物的商品名)
将上述组分均匀地混合形成浓缩乳剂
配方实施例3:流动剂
本发明化合物1号 40份
Agrizolc B-710(由花王株式会社制造的阴离子型表面活性剂的商品名) 10份
Runox 1000 C(由东邦化学工业株式会社 0.5份
制造的阴离子表面活性剂的商品名)
1% Rodopol 水(由Rhonc-Poulonc制造
的增厚剂的商品名) 20份
水 29.5份
将上述组分均匀地混合形成流动剂。
配方实施例4:液体配方
本发明化合物1的钠盐
Nippol(由日产化学工业株式会社制造 30份
的非离子表面活性剂的商品名) 10份
水 60份
将上述组分混合均匀得到液体配方。
配方实施例5:液体配方
本发明化合物1的钾盐 30份
Nippol(由日产化学工业株式会社制造
的非离子表面活性剂的商品名) 10份
水 60份
将上述组分混合均匀得到液体配方。
配方实施例6:液体配方
本发明化合物1的钙盐 10份
Nippol(由日产化学工业株式会社制造
的非离子表面活性剂的商品名) 10份
水 60份
将上述组分混合物均匀形成液体配方。
配方实施例7:液体配方
本发明化合物1的异丙胺盐 10份
Sorpol W-150(由东方化学株式会社
制定的非离子表面活性剂的商品名) 10份
水 80份
将上述组分混合物均匀得液体配方。
在使用过程中,将上面的可湿性粉末、浓缩乳剂、流动剂或液体配方用水稀释50至1,000倍使用。使每公顷各自的活性组分每分顷为0.001至5公斤。
本发明的化合物不仅可用于诸如高原地、水稻田和果园的农业和园艺地上,而且也可用于诸如运动场、空地和铁路旁的非农业土地上来控制各种杂草。
根据使用地点、使用季节、栽培农作物的种类等其使用剂量不同。但是,它通常在每公倾0.001至5公斤的范围里。
现在,根据特殊试验例子来说明本发明化合物的除草活性。
试验例1:在土壤治理中,关于除草剂作用的试验
将灭菌的洪积土填到一个长为15cm、22cm宽和6cm的塑料盒中,将Echinochloa crus-qalli(稗)、Setaria Viridis(狗尾草)、Eleusine indica(蟋蟀草)、Diqitaria adscendens(毛地黄)、Panicum dic-hotomiflorum(秋稷)Abutilon theophrasti(茴麻)Amaranthus lividus(苋)Polygonum longisetum(蓼)和Zeamays(玉米)的种子播种下去,并再把Cype-rus esculentus(铁茡荠)块茎利植下去。上面覆上约1.5cm厚的土,然后将除草剂溶液均匀地旋用于土壤的表面,使活性组分以预定浓度分散。用水将前面配方实施例中所述的可湿性粉末、可乳化浓缩物、液体配方或流动剂稀释来制得除草剂溶液,并通过小喷雾器施用于整个土壤的表面。使用除草剂三星期后,在下列标准级别的基础上,确定对每种杂草的除草作用。这里所得的级别列于表9。化合物序
号与表2的化合物序号一致。
标准级别:
5:生长控制率多于90%(几乎完全枯萎)
4:生长控制率在70%至90%之间。
3:生长控制率在40%至70之间。
2:生长控制率在20至40之间。
1:生长控制率在5%至20%之间。
0:生长控制率低于5%(几乎无作用)
上述生长控制率是由下列等式计算出来的
生长控制率(%)=(1- (T)/(N) )×100
这里T:处理区域土壤表面上杂草生长的重量。
N:末处理过区域土壤表面上杂草生长的重量。
试验例2:对在叶子处理中,有关除草作用的
试验1
将灭菌过的洪积土填到一个15cm长、22cm宽和6cm高的塑料盒中,将Echinochloa crus-qalli(稗)、Setaria Viridis(狗尾草)、Eleusine indica(蟋蟀草)、Diqitaria adscendens(毛地黄)、Panicum dic-hotomiflorum(秋稷)Xanthium Strumatirum(苍耳)、Abutilon theophrasti(茴麻)Amaranthus lividus(苋)Polyqonum lonqisetum(蓼)和Zea mays(玉米)的种子仔细地点状播种,并再种下Cyperus esculen-tus(铁茡荠)的块茎。然后,在其上面覆上约1.5cm的厚的土层。当各种杂草和谷类植物长出2或3片叶子时,将除草剂溶液均匀地喷在叶子上,使得活性组分达预期浓度。
用水将前面配方实施例中所述的可湿性粉末、乳剂浓缩物、液体配方或流动剂进行稀释以制得除草剂溶液,并通过小喷雾器用于杂草和作物叶子的整个表面。使用除草剂溶液二星期后,根据试验例1中所述的标准级别来确定除草剂对杂草和玉米的除草作用。结果用于表10中,表10中的化合物序号与表2的一致。
试验例3:在叶子处理中,有关除草作用的试验2
将灭菌过和洪积层土填到一个15cm长、22cm宽和6cm高的塑料盒子中,将Veronica Persica、Stell-aria media(繁缕)、Galium spurium、Matricaria matricarioides(香甘菊)、Polygonum persicaria、Lamium purpureum、Solanum niqrum(龙葵)和Tritipcum aestivum(小麦)的种子仔细地点状播种。然后,在其上面覆盖约1.5cm厚的土层。当各种杂草和谷类植物长出2或3利叶子时,将除草剂溶液均匀地喷在叶子上使活性组分达预定浓度。
用水将前面配方实施例中所述的可湿性粉末、浓缩乳剂、液体配方或流动剂进行稀释以制得除草剂溶液,并通过小喷雾器用于杂草Triticum aesti-vum(小麦)的叶子上。使用除草剂溶液二星期后,根据试验例1中所述的标准级别来确定对杂草和小麦的除草作用。结果列于表11中,表11的化合物序号与表2中的化合物序号一致。
在表9、10和11中使用了下列的缩写
剂量:活性组分的剂量(克/公亩)
EC:Echinochloa crus-galli(稗)
SE:Setaria viridis(绿色狐尾状植物)
EL:Eleusine indica(蟋蟀草)
DI:Digitaria adscendens(马唐)
PA:Panicum dichotomiflorum(秋稷)
AB:Abutilon theophrasti(茴麻)
AM:Amaranthus lividus(青灰色苋)
PO:Polygonum longisetum(蓼)
XA:Xanthium strumarium(苍耳)
CY:Cyperus esculentus(铁茡荠)
ZE:Zea mays(玉米)
VE:Veronica persia(芝麻点状婆婆纳)
ST:Stellaria media(繁缕)
GA:Galium spurium(麦瓶草)
MA:Matricaria matricarioides(凤梨草)
PP:Polygonum persicaria(春蓼)
LA:Lamium purpureum(红野芝麻)
SO:Solanum nigrum(龙葵)
TR:Triticum aestivum(小麦)
表9-11见后
在表9和表10中,有下列对比化合物:
对比化合物A:阿特拉津
对比化合物B:草不绿
在表11中有下列对比化合物:
对比化合物C:二氟菲尼更
图1-a
A:Me,Et,n-Pr,i-Pr,CH2CH=CH2,
CH2C≡CH,t-Bu
B:H,Me,Et,n-Pr,i-Pr,Cl,Br,CH2Cl,
CF3,OMe,OEt,OPr-i,SMe,CH2OMe,
CH2SMe,CO2Me,CO2Et
X:Me,Et,n-Pr,i-Pr,n-Bu,i-Bu,s-Bu,
t-Bu,OMe,OEt,OPr-n,OPr-i,OBu-n,
OBu-i,OBu-s,OBu-t,F,Cl,Br,I,
NO2,CN,CH2F,CHF2,CF3,CH2CF3,
CH2Cl,CCl3,CHClMe,CH2CH2Cl,
CHClCH2Cl,CH2Br,CHBrMe,CH2CH2Br,
CH2OMe,CH2OEt,CH2OPr-n,CH2OPr-i,
CH2OBu-n,CH2OBu-i,CH2OBu-s,CH2OBu-t,
CHMeOMe,CHMeOEt,CHMeOPr-n,CHMeOPr-i,
CHMeOBu-n,CHMeOBu-i,CHMeOBu-s,
CHMeOBu-t,CH2CH2OMe,CH2CH2OEt,
图1-b
CH2CH2OPr-i,Ac,COEl,COPr-n,COPr-i,
COOMe,COOEt,COOPr-i,CONHMe,CONHEt,
CONMe2,CONEt2,CONEtMe,OCHF2,OCF3,
OCH2CF3,SMe,SEl,CH2SMe,CH2SEt,
CHMeSMe,CHMeSEt
OCHMeCH=CH2,OCMe2CH=CH2,OCH2CMe=CH2,
OCH2CH=CHMe,OCH2CH=CMe2,OCH2C≡CH,
OCHMeC≡CH,OCMe2C≡CH,OCH2C≡CMe,
OCH2CH2F,OCH2CHF2,OCH2CF3,OCH2CH2Cl,
OCHMeCH2Cl,OCH2CCl3,OCH2CH2CH2Cl,
OCH2CH2CH=CH2,
OCH2CCl=CHCl,OCH2CH2NO2,OPh,OPh-Me-2
OPh-Cl-4,OPh-NO2-4,
OCH2CH2OMe,OCH2CH2OEt,OCH2CH2OPr-n,
图1-c
OCH2CH2OPr-i,OCH2CH2OBu-n,OCH2CH2OBu-i,
OCH2CH2Bu-s,OCH2CH2OBu-t,OCHMeCH2OMe,
OCH2CH2OPh,OCH2CH2OCH2CH2OMe,OCH2CH2OH,
OCH2CH2OCHMeCH2OMe,OCH2Ph,OCHMePh,
OCH2Ph-4-Me,OCH2Ph-4-Cl,OCH2CH2Ph,
OCH2CH2NH2,OCH2CH2NHMe,OCH2CH2NMe2,
OCH2COOEt,OCH2COOPr-n,OCH2COOPr-i,
OCH2COOBu-t,OCHMeCOOMe,OCHMeCOOEt
OCHMeCOOPr-n,OCHMeCOOPr-i,OCHMeCOOBu-t
OCH2CH2CN,OCH2CN,OCHMeCN,OCH2SMe,
OCH2C(O)Ph,OCH2C(O)Me,
OCH2CH2SMe,OCH2CH2SOMe,OCH2CH2SO2Me,
图1-d
OCH2CH2SEt,OCH2CH2SO2Et,OCOOMe,
OCOOEt,OCOOPr-i,OCONM2,OCONHMe,
OCONMe2,OP(O)(OMe)2,OP(O)(OEt)2,
SCH2CF3,SCH2CH2Cl,SCH2CCl3,
,SPh,SCH2CH2OMe,SCH2CH2OEt,
S(O)CH2CH=CH2,S(O)CH2CH≡CH,S(O)CH2CF3,
S(O)Ph,S(O)CH2CH2OMe,S(O)CH2CH2OEt,
S(O)CH2CH2OPr-i,S(O)CH2CH2OPh,
,SO2CH2CH=CH2,SO2CH2C≡CH,
图1-e
SO2Ph,SO2CH2CH2OMe,SO2CH2CH2OEl,
SO2CH2CH2OPr-i,
Z:F,Cl,Br,I,NO2,OMe,OEl,OPr-n,OPr-i,
CF3,CN,SMe,SOMe,SO2Me,SCF3,SOCF3,
SO2CF3
Q:H,Me,Et,n-Pr,i-Pr,n-Bu,i-Bu,s-Bu,
t-Bu,CH2CH2Cl,CH2CF3,CHClMe,
CH2CH2Br,CHClCH2Cl,CH2CH=CH2,
CH2CMe=CH2,CH2CH=CHMe,CH2C≡CH,
CH2CCl=CH2,CH2CN,CH2Ph,CH2Ph-Cl-2,
CH2Ph-Cl-3,CH2Ph-Me-2,
CH2Ph-Me2-2,4,CH2Ph-Me-4,CHMePh,CHEtPh,
CH2Ph-NO2-2,CH2Ph-CF3-3,CH2OMe,CH2OEt,
CH2OH,CHMeOH,CH2NHMe,CH2NMe2,CHMeNMe2,
CH2COPh,CH2COPh-NO2-4,CH2COPh-Me-4,
图1-f
CH2COPh-Cl-4,CH2COPh-Me2-2,4,
CH2COPh-CF3-4,CH2Ac,CH2COEt,CHMeAc,
CH2CO2Me,CH2CO2Et,CH2CO2Pr-n,
CH2CO2Pr-i,CH2CO2Bu-t,CH2CO2H,CHMeCO2H,
CH2CONHMe,CH2CONMe2,CH2CONHEt,CH2CONEt2,
CH2CONPr-n2,CH2OCH2CH=CH2,CH2OAc,
CH2COEt,CH2COPr-i,CH2COBu-t,CH2OCO2Me,
CH2OCO2Et,CH2OCO2Pr-i,CH2OCO2Bu-t,
CH2SMe,CH2SEt,CH2SCH2CH=CH2,CH2SAc,
CH2SCOBu-t,CH2SO2Me,CH2SO2Et,
CH2SO2CH2CH=CH2,CH2NHCH2CH=CH2,
CH2NMeCH2CH=CH2,CH2NHAc,CH2NHCOEt,
CH2NHCO2Me,CH2NHCO2Et,CH2NMeCO2Me,COPh,
COPh-Me-4,COPh-NO2-2,COPh-Cl2-2,4,
Ac,COEt,COPr-n,COPr-i,COBu-n,COBu-t,
COCH2Cl,COCHCl2,COCCl3,COCF3,
COCH2OMe,COCH2OPh,COCH2CH=CHCH3,
CO2Me,CO2Et,CO2Bu-t,CO2Pr-i,CONHMe,
CONMe2,CONHEt,CONEt2,CONPr-n2,
CON(CH2CH=CH2)2,CONMePh,
图1-g
CO2CH2Ph,CO2Ph,SO2Me,SO2Et,
SO2CH2CH=CH2,SO2Ph,SO2Ph-Me-4,
SO2Ph-Cl-4,SO2Ph-(NO2)2-2,4,SO2CF3,
P(=O)(OMe)2,P(=O)(OEt)2,P(=O)(OPr-n)2,
P(=O)(OPr-i)2,P(=S)(OMe)2,P(=S)(OEt)2,
P(=O)OMeOPh,P(=O)(OCH2CH=CH2)2,
P(=O)OPhOCH2CH=CH2
图2-a
图2-b
图2-c
图2-d
图2-e
图3-a
图3-b
表1
X Y Z 熔点 (℃)
Cl
SO2Me 102~107
Cl OCH2CH2OPh SO2Me 147~151
Cl OCH2CH2CH=CH2SO2Me 90~94
Cl OCH2CH=CHMe SO2Me 113~118
Cl OCH2CH2OMe SO2Me 89~92
图4
表3
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表3续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表3续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEl2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表3续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表3续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表3续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表3续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表3续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表3续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表3续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表3续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-i SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表3续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表3续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表3续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表3续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表3续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表3续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表3续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表4
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表4续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表4续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEt2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表4续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表4续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表4续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表4续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表4续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表4续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表4续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表4续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-i SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表4续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表4续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表4续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表4续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表4续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表4续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表4续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表5
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表5续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表5续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEt2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表5续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表5续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表5续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表5续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表5续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表5续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表5续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表5续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-l SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表5续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表5续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表5续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表5续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表5续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表5续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表5续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表6
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表6续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表6续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEt2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表6续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表6续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表6续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表6续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表6续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表6续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表6续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表6续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-i SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表6续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表6续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表6续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表6续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表6续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表6续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表6续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表7
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表7续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表7续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEt2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表7续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表7续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表7续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表7续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表7续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表7续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表7续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表7续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-i SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表7续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表7续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表7续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表7续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表7续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表7续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表7续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表8
X Y Z Q
Me Y1 SO2Me H
Me Y2 SO2Me H
Me Y3 SO2Me H
Me Y4 SO2Me H
Me Y5 SO2Me H
Me Y6 SO2Me H
Me Y7 SO2Me H
Me OCH2CH=CH2SO2Me H
Me OCHMeCH=CH2SO2Me H
Me OCMe2CH=CH2SO2Me H
Me OCH2CMe=CH2SO2Me H
Me OCH2CH=CHMe SO2Me H
Me OCH2CH=CMe2SO2Me H
Me OCH2CH2CH=CH2SO2Me H
Me OCH2C≡CH SO2Me H
Me OCHMeC≡CH SO2Me H
Me OCMe2C≡CH SO2Me H
Me OCH2C≡CMe SO2Me H
Me OCH2CH2F SO2Me H
Me OCH2CHF2SO2Me H
Me OCH2CF3SO2Me H
Me OCH2CH2Cl SO2Me H
Me OCH2CCl3SO2Me H
Me OCHMeCH2Cl SO2Me H
Me OCH2CH2CH2Cl SO2Me H
Me OCH2CH2Br SO2Me H
Me Y8 SO2Me H
表8续
X Y Z Q
Me OCH2CCl=CH2SO2Me H
Me OCH2CCl=CHCl SO2Me H
Me OCH2CH2NO2SO2Me H
Me OPh SO2Me H
Me OPh-Me-2 SO2Me H
Me OPh-Cl-4 SO2Me H
Me OPh-NO2-4 SO2Me H
Me OCH2CH2OMe SO2Me H
Me OCH2CH2OEt SO2Me H
Me OCH2CH2OPr-n SO2Me H
Me OCH2CH2OPr-i SO2Me H
Me OCH2CH2OBu-n SO2Me H
Me OCH2CH2OBu-i SO2Me H
Me OCH2CH2OBu-s SO2Me H
Me OCH2CH2OBu-t SO2Me H
Me OCH2CH2-Y4 SO2Me H
Me OCHMeCH2OMe SO2Me H
Me OCH2CHMeOMe SO2Me H
Me OCH2CH2OPh SO2Me H
Me OCH2CH2OCH2CH2OMe SO2Me H
Me OCH2CH2OCH2CH2OPr-i SO2Me H
Me OCH2CH2OCHMeCH2OMe SO2Me H
Me OCH2CH2OH SO2Me H
Me OCH2Ph SO2Me H
Me OCHMePh SO2Me H
Me OCH2CH2Ph SO2Me H
Me OCH2Ph-2-Cl SO2Me H
Me OCH2Ph-3-Me SO2Me H
Me OCH2Ph-4-OMe SO2Me H
Me OCH2Ph-4-NO2SO2Me H
Me Y9 SO2Me H
Me Y10 SO2Me H
Me Y11 SO2Me H
Me Y12 SO2Me H
Me Y13 SO2Me H
Me Y14 SO2Me H
Me Y15 SO2Me H
Me Y16 SO2Me H
Me Y17 SO2Me H
Me Y18 SO2Me H
表8续
X Y Z Q
Me OCH2CH2NH2SO2Me H
Me OCH2CH2NHMe SO2Me H
Me OCH2CH2NHPr-i SO2Me H
Me OCH2CH2NMe2SO2Me H
Me OCH2CH2NEt2SO2Me H
Me Y19 SO2Me H
Me OCH2COOMe SO2Me H
Me OCH2COOEt SO2Me H
Me OCH2COOPr-i SO2Me H
Me OCH2COOBu-i SO2Me H
Me OCH2COOBu-t SO2Me H
Me OCH2COO-Y4 SO2Me H
Me OCHMeCOOMe SO2Me H
Me OCHMeCOOEt SO2Me H
Me OCHMeCOOPr-i SO2Me H
Me OCH2CH2CN SO2Me H
Me OCH2SMe SO2Me H
Me OCH2CH2SMe SO2Me H
Me OCH2CH2S(O)Me SO2Me H
Me OCH2CH2SO2Me SO2Me H
Me OCH2CH2SPr-i SO2Me H
Me OCH2CH2S(O)Pr-i SO2Me H
Me OCH2CH2SO2Pr-i SO2Me H
Me OCOOMe SO2Me H
Me OCOOPr-i SO2Me H
Me OCONH2SO2Me H
Me OCONHMe SO2Me H
Me OCONMe2SO2Me H
Me OP(O)(OMe)2SO2Me H
Me Y20 SO2Me H
Me SCH2CH=CH2SO2Me H
Me SCH2CH=CMe2SO2Me H
Me SCH2C≡CH SO2Me H
Me SCH2CF3SO2Me H
Me SCH2CCl3SO2Me H
Me Y21 SO2Me H
Me SPh SO2Me H
Me SCH2CH2OMe SO2Me H
Me SCH2CH2OEt SO2Me H
Me SCH2CH2OPr-i SO2Me H
表8续
X Y Z Q
Me Y22 SO2Me H
Me S(O)CH2CH=CH2SO2Me H
Me S(O)CH2CH=CMe2SO2Me H
Me S(O)CH2C≡CH SO2Me H
Me S(O)CH2CH2Cl SO2Me H
Me Y23 SO2Me H
Me SO2CH2CH=CH2SO2Me H
Me SO2CH2CH=CMe2SO2Me H
Me SO2CH2C≡CH SO2Me H
Me SO2CH2CF3SO2Me H
Me SO2CH2CH2Cl SO2Me H
Me Y24 SO2Me H
Me Y25 SO2Me H
Me SO2Ph SO2Me H
Me SO2CH2CH2OMe SO2Me H
Me SO2CH2CH2OEt SO2Me H
Me SO2CH2CH2OPr-i SO2Me H
Me OCH2CH2OMe SO2Me CH2Ph
Me OCH2CH2OEt SO2Me CH2Ph
Me OCH2CH2OPr-i SO2Me CH2Ph
Me OCHMeCH2OMe SO2Me CH2Ph
Me OCH2CH2SMe SO2Me CH2Ph
Me OCH2CH2S(O)Me SO2Me CH2Ph
Me OCH2CH2SO2Me SO2Me CH2Ph
Me OCH2CH2SPr-i SO2Me CH2Ph
Me OCH2CH2S(O)Pr-i SO2Me CH2Ph
Me OCH2CH2SO2Pr-i SO2Me CH2Ph
Me SCH2CH2OMe SO2Me CH2Ph
Me SCH2CH2OPr-i SO2Me CH2Ph
Me SO2CH2CH2OMe SO2Me CH2Ph
Me SO2CH2CH2OPr-i SO2Me CH2Ph
Me OCH2CH2OMe SO2Me CH2COPh
Me OCH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2SMe SO2Me CH2COPh
Me OCH2CH2SOMe SO2Me CH2COPh
Me OCH2CH2SO2Me SO2Me CH2COPh
Me OCH2CH2SPr-i SO2Me CH2COPh
Me OCH2CH2SO2Pr-i SO2Me CH2COPh
Me SCH2CH2OMe SO2Me CH2COPh
Me SCH2CH2OPr-i SO2Me CH2COPh
表8续
X Y Z Q
Me SO2CH2CH2OMe SO2Me CH2COPh
Me SO2CH2CH2OPr-i SO2Me CH2COPh
Me OCH2CH2OMe Cl H
Me OCH2CH2OEt Cl H
Me OCH2CH2OPr-i Cl H
Me OCHMeCH2OMe Cl H
Me OCH2COOMe Cl H
Me OCH2CH2SMe Cl H
Me OCH2CH2SO2Me Cl H
Me SCH2CH2OMe Cl H
Me SO2CH2CH2OMe Cl H
Me OCH2CH2OMe Cl CH2Ph
Me OCH2CH2SMe Cl CH2Ph
Me OCH2CH2SOMe Cl CH2Ph
Me OCH2CH2SO2Me Cl CH2Ph
Me SCH2CH2OMe Cl CH2Ph
Me SO2CH2CH2OMe Cl CH2Ph
Me OCH2CH2OMe Cl CH2COPh
Me OCH2CH2SMe Cl CH2COPh
Me OCH2CH2SO2Me Cl CH2COPh
Me SCH2CH2OMe Cl CH2COPh
Me SCH2CH2OEt Cl CH2COPh
Me SO2CH2CH2OMe Cl CH2COPh
Cl Y1 SO2Me H
Cl Y2 SO2Me H
Cl Y3 SO2Me H
Cl Y4 SO2Me H
Cl Y5 SO2Me H
Cl Y6 SO2Me H
Cl Y7 SO2Me H
Cl OCH2CH=CH2SO2Me H
Cl OCHMeCH=CH2SO2Me H
Cl OCMe2CH=CH2SO2Me H
Cl OCH2CMe=CH2SO2Me H
Cl OCH2CH=CHMe SO2Me H
Cl OCH2CH=CMe2SO2Me H
Cl OCH2CH2CH=CH2SO2Me H
Cl OCH2C≡CH SO2Me H
Cl OCHMeC≡CH SO2Me H
Cl OCMe2C≡CH SO2Me H
表8续
X Y Z Q
Cl OCH2C≡CMe SO2Me H
Cl OCH2CH2F SO2Me H
Cl OCH2CHF2SO2Me H
Cl OCH2CF3SO2Me H
Cl OCH2CH2Cl SO2Me H
Cl OCH2CCl3SO2Me H
Cl OCHMeCH2Cl SO2Me H
Cl OCH2CH2CH2Cl SO2Me H
Cl OCH2CH2Br SO2Me H
Cl Y8 SO2Me H
Cl OCH2CCl=CH2SO2Me H
Cl OCH2CCl=CHCl SO2Me H
Cl OCH2CH2NO2SO2Me H
Cl OPh SO2Me H
Cl OPh-Me-2 SO2Me H
Cl OPh-Cl-4 SO2Me H
Cl OPh-NO2-4 SO2Me H
Cl OCH2CH2OMe SO2Me H
Cl OCH2CH2OEt SO2Me H
Cl OCH2CH2OPr-n SO2Me H
Cl OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OBu-n SO2Me H
Cl OCH2CH2OBu-i SO2Me H
Cl OCH2CH2OBu-s SO2Me H
Cl OCH2CH2OBu-t SO2Me H
Cl OCH2CH2-Y4 SO2Me H
Cl OCHMeCH2OMe SO2Me H
Cl OCH2CHMeOMe SO2Me H
Cl OCH2CH2OPh SO2Me H
Cl OCH2CH2OCH2CH2OMe SO2Me H
Cl OCH2CH2OCH2CH2OPr-i SO2Me H
Cl OCH2CH2OCHMeCH2OMe SO2Me H
Cl OCH2CH2OH SO2Me H
Cl OCH2Ph SO2Me H
Cl OCHMePh SO2Me H
Cl OCH2CH2Ph SO2Me H
Cl OCH2Ph-2-Cl SO2Me H
Cl OCH2Ph-3-Me SO2Me H
Cl OCH2Ph-4-OMe SO2Me H
Cl OCH2Ph-4-NO2SO2Me H
表8续
X Y Z Q
Cl Y9 SO2Me H
Cl Y10 SO2Me H
Cl Y11 SO2Me H
Cl Y12 SO2Me H
Cl Y13 SO2Me H
Cl Y14 SO2Me H
Cl Y15 SO2Me H
Cl Y16 SO2Me H
Cl Y17 SO2Me H
Cl Y18 SO2Me H
Cl OCH2CH2NH2SO2Me H
Cl OCH2CH2NHMe SO2Me H
Cl OCH2CH2NHPr-i SO2Me H
Cl OCH2CH2NMe2SO2Me H
Cl OCH2CH2NEt2SO2Me H
Cl Y19 SO2Me H
Cl OCH2COOMe SO2Me H
Cl OCH2COOEt SO2Me H
Cl OCH2COOPr-i SO2Me H
Cl OCH2COOBu-i SO2Me H
Cl OCH2COOBu-t SO2Me H
Cl OCH2COO-Y4 SO2Me H
Cl OCHMeCOOMe SO2Me H
Cl OCHMeCOOEt SO2Me H
Cl OCHMeCOOPr-i SO2Me H
Cl OCH2CH2CN SO2Me H
Cl OCH2SMe SO2Me H
Cl OCH2CH2SMe SO2Me H
Cl OCH2CH2S(O)Me SO2Me H
Cl OCH2CH2SO2Me SO2Me H
Cl OCH2CH2SPr-i SO2Me H
Cl OCH2CH2S(O)Pr-i SO2Me H
Cl OCH2CH2SO2Pr-i SO2Me H
Cl OCOOMe SO2Me H
Cl OCOOPr-i SO2Me H
Cl OCONH2SO2Me H
Cl OCONHMe SO2Me H
Cl OCONMe2SO2Me H
Cl OP(O)(OMe)2SO2Me H
Cl Y20 SO2Me H
表8续
X Y Z Q
Cl SCH2CH=CH2SO2Me H
Cl SCH2CH=CMe2SO2Me H
Cl SCH2C≡CH SO2Me H
Cl SCH2CF3SO2Me H
Cl SCH2CCl3SO2Me H
Cl Y21 SO2Me H
Cl SPh SO2Me H
Cl SCH2CH2OMe SO2Me H
Cl SCH2CH2OEt SO2Me H
Cl SCH2CH2OPr-i SO2Me H
Cl Y22 SO2Me H
Cl S(O)CH2CH=CH2SO2Me H
Cl S(O)CH2CH=CMe2SO2Me H
Cl S(O)CH2C≡CH SO2Me H
Cl S(O)CH2CH2Cl SO2Me H
Cl Y23 SO2Me H
Cl SO2CH2CH=CH2SO2Me H
Cl SO2CH2CH=CMe2SO2Me H
Cl SO2CH2C≡CH SO2Me H
Cl SO2CH2CF3SO2Me H
Cl SO2CH2CH2Cl SO2Me H
Cl Y24 SO2Me H
Cl Y25 SO2Me H
Cl SO2Ph SO2Me H
Cl SO2CH2CH2OMe SO2Me H
Cl SO2CH2CH2OEt SO2Me H
Cl SO2CH2CH2OPr-i SO2Me H
Cl OCH2CH2OMe SO2Me CH2Ph
Cl OCH2CH2OEt SO2Me CH2Ph
Cl OCH2CH2OPr-i SO2Me CH2Ph
Cl OCHMeCH2OMe SO2Me CH2Ph
Cl OCH2CH2SMe SO2Me CH2Ph
Cl OCH2CH2S(O)Me SO2Me CH2Ph
Cl OCH2CH2SO2Me SO2Me CH2Ph
Cl OCH2CH2SPr-i SO2Me CH2Ph
Cl OCH2CH2S(O)Pr-i SO2Me CH2Ph
Cl OCH2CH2SO2Pr-i SO2Me CH2Ph
Cl SCH2CH2OMe SO2Me CH2Ph
Cl SCH2CH2OPr-i SO2Me CH2Ph
Cl SO2CH2CH2OMe SO2Me CH2Ph
表8续
X Y Z Q
Cl SO2CH2CH2OPr-i SO2Me CH2Ph
Cl OCH2CH2OMe SO2Me CH2COPh
Cl OCH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2SMe SO2Me CH2COPh
Cl OCH2CH2SOMe SO2Me CH2COPh
Cl OCH2CH2SO2Me SO2Me CH2COPh
Cl OCH2CH2SPr-i SO2Me CH2COPh
Cl OCH2CH2SO2Pr-i SO2Me CH2COPh
Cl SCH2CH2OMe SO2Me CH2COPh
Cl SCH2CH2OPr-i SO2Me CH2COPh
Cl SO2CH2CH2OMe SO2Me CH2COPh
Cl SO2CH2CH2OPr-i SO2Me CH2COPh
Cl OCH2CH2OMe Cl H
Cl OCH2CH2OEt Cl H
Cl OCH2CH2OPr-i Cl H
Cl OCHMeCH2OMe Cl H
Cl OCH2COOMe Cl H
Cl OCH2CH2SMe Cl H
Cl OCH2CH2SO2Me Cl H
Cl SCH2CH2OMe Cl H
Cl SO2CH2CH2OMe Cl H
Cl OCH2CH2OMe Cl CH2Ph
Cl OCH2CH2SMe Cl CH2Ph
Cl OCH2CH2SOMe Cl CH2Ph
Cl OCH2CH2SO2Me Cl CH2Ph
Cl SCH2CH2OMe Cl CH2Ph
Cl SO2CH2CH2OMe Cl CH2Ph
Cl OCH2CH2OMe Cl CH2COPh
Cl OCH2CH2SMe Cl CH2COPh
Cl OCH2CH2SO2Me Cl CH2COPh
Cl SCH2CH2OMe Cl CH2COPh
Cl SCH2CH2OEt Cl CH2COPh
Cl SO2CH2CH2OMe Cl CH2COPh
OMe Y1 SO2Me H
OMe Y2 SO2Me H
OMe Y3 SO2Me H
OMe Y4 SO2Me H
OMe Y5 SO2Me H
OMe Y6 SO2Me H
OMe Y7 SO2Me H
表8续
X Y Z Q
OMe OCH2CH=CH2SO2Me H
OMe OCHMeCH=CH2SO2Me H
OMe OCMe2CH=CH2SO2Me H
OMe OCH2CMe=CH2SO2Me H
OMe OCH2CH=CHMe SO2Me H
OMe OCH2CH=CMe2SO2Me H
OMe OCH2CH2CH=CH2SO2Me H
OMe OCH2C≡CH SO2Me H
OMe OCHMeC≡CH SO2Me H
OMe OCMe2C≡CH SO2Me H
OMe OCH2C≡CMe SO2Me H
OMe OCH2CH2F SO2Me H
OMe OCH2CHF2SO2Me H
OMe OCH2CF3SO2Me H
OMe OCH2CH2Cl SO2Me H
OMe OCH2CCl3SO2Me H
OMe OCHMeCH2Cl SO2Me H
OMe OCH2CH2CH2Cl SO2Me H
OMe OCH2CH2Br SO2Me H
OMe Y8 SO2Me H
OMe OCH2CCl=CH2SO2Me H
OMe OCH2CCl=CHCl SO2Me H
OMe OCH2CH2NO2SO2Me H
OMe OPh SO2Me H
OMe OPh-Me-2 SO2Me H
OMe OPh-Cl-4 SO2Me H
OMe OPh-NO2-4 SO2Me H
OMe OCH2CH2OMe SO2Me H
OMe OCH2CH2OEt SO2Me H
OMe OCH2CH2OPr-n SO2Me H
OMe OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OBu-n SO2Me H
OMe OCH2CH2OBu-i SO2Me H
OMe OCH2CH2OBu-s SO2Me H
OMe OCH2CH2OBu-t SO2Me H
OMe OCH2CH2-Y4 SO2Me H
OMe OCHMeCH2OMe SO2Me H
OMe OCH2CHMeOMe SO2Me H
OMe OCH2CH2OPh SO2Me H
OMe OCH2CH2OCH2CH2OMe SO2Me H
表8续
X Y Z Q
OMe OCH2CH2OCH2CH2OPr-i SO2Me H
OMe OCH2CH2OCHMeCH2OMe SO2Me H
OMe OCH2CH2OH SO2Me H
OMe OCH2Ph SO2Me H
OMe OCHMePh SO2Me H
OMe OCH2CH2Ph SO2Me H
OMe OCH2Ph-2-Cl SO2Me H
OMe OCH2Ph-3-Me SO2Me H
OMe OCH2Ph-4-OMe SO2Me H
OMe OCH2Ph-4-NO2SO2Me H
OMe Y9 SO2Me H
OMe Y10 SO2Me H
OMe Y11 SO2Me H
OMe Y12 SO2Me H
OMe Y13 SO2Me H
OMe Y14 SO2Me H
OMe Y15 SO2Me H
OMe Y16 SO2Me H
OMe Y17 SO2Me H
OMe Y18 SO2Me H
OMe OCH2CH2NH2SO2Me H
OMe OCH2CH2NHMe SO2Me H
OMe OCH2CH2NHPr-i SO2Me H
OMe OCH2CH2NMe2SO2Me H
OMe OCH2CH2NEt2SO2Me H
OMe Y19 SO2Me H
OMe OCH2COOMe SO2Me H
OMe OCH2COOEt SO2Me H
OMe OCH2COOPr-i SO2Me H
OMe OCH2COOBu-i SO2Me H
OMe OCH2COOBu-t SO2Me H
OMe OCH2COO-Y4 SO2Me H
OMe OCHMeCOOMe SO2Me H
OMe OCHMeCOOEt SO2Me H
OMe OCHMeCOOPr-i SO2Me H
OMe OCH2CH2CN SO2Me H
OMe OCH2SMe SO2Me H
OMe OCH2CH2SMe SO2Me H
OMe OCH2CH2S(O)Me SO2Me H
OMe OCH2CH2SO2Me SO2Me H
表8续
X Y Z Q
OMe OCH2CH2SPr-i SO2Me H
OMe OCH2CH2S(O)Pr-i SO2Me H
OMe OCH2CH2SO2Pr-i SO2Me H
OMe OCOOMe SO2Me H
OMe OCOOPr-i SO2Me H
OMe OCONH2SO2Me H
OMe OCONHMe SO2Me H
OMe OCONMe2SO2Me H
OMe OP(O)(OMe)2SO2Me H
OMe Y20 SO2Me H
OMe SCH2CH=CH2SO2Me H
OMe SCH2CH=CMe2SO2Me H
OMe SCH2C≡CH SO2Me H
OMe SCH2CF3SO2Me H
OMe SCH2CCl3SO2Me H
OMe Y21 SO2Me H
OMe SPh SO2Me H
OMe SCH2CH2OMe SO2Me H
OMe SCH2CH2OEt SO2Me H
OMe SCH2CH2OPr-i SO2Me H
OMe Y22 SO2Me H
OMe S(O)CH2CH=CH2SO2Me H
OMe S(O)CH2CH=CMe2SO2Me H
OMe S(O)CH2C≡CH SO2Me H
OMe S(O)CH2CH2Cl SO2Me H
OMe Y23 SO2Me H
OMe SO2CH2CH=CH2SO2Me H
OMe SO2CH2CH=CMe2SO2Me H
OMe SO2CH2C≡CH SO2Me H
OMe SO2CH2CF3SO2Me H
OMe SO2CH2CH2Cl SO2Me H
OMe Y24 SO2Me H
OMe Y25 SO2Me H
OMe SO2Ph SO2Me H
OMe SO2CH2CH2OMe SO2Me H
OMe SO2CH2CH2OEt SO2Me H
OMe SO2CH2CH2OPr-i SO2Me H
OMe OCH2CH2OMe SO2Me CH2Ph
OMe OCH2CH2OEt SO2Me CH2Ph
OMe OCH2CH2OPr-i SO2Me CH2Ph
表8续
X Y Z Q
OMe OCHMeCH2OMe SO2Me CH2Ph
OMe OCH2CH2SMe SO2Me CH2Ph
OMe OCH2CH2S(O)Me SO2Me CH2Ph
OMe OCH2CH2SO2Me SO2Me CH2Ph
OMe OCH2CH2SPr-i SO2Me CH2Ph
OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
OMe SCH2CH2OMe SO2Me CH2Ph
OMe SCH2CH2OPr-i SO2Me CH2Ph
OMe SO2CH2CH2OMe SO2Me CH2Ph
OMe SO2CH2CH2OPr-i SO2Me CH2Ph
OMe OCH2CH2OMe SO2Me CH2COPh
OMe OCH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2SMe SO2Me CH2COPh
OMe OCH2CH2SOMe SO2Me CH2COPh
OMe OCH2CH2SO2Me SO2Me CH2COPh
OMe OCH2CH2SPr-i SO2Me CH2COPh
OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
OMe SCH2CH2OMe SO2Me CH2COPh
OMe SCH2CH2OPr-i SO2Me CH2COPh
OMe SO2CH2CH2OMe SO2Me CH2COPh
OMe SO2CH2CH2OPr-i SO2Me CH2COPh
OMe OCH2CH2OMe Cl H
OMe OCH2CH2OEt Cl H
OMe OCH2CH2OPr-i Cl H
OMe OCHMeCH2OMe Cl H
OMe OCH2COOMe Cl H
OMe OCH2CH2SMe Cl H
OMe OCH2CH2SO2Me Cl H
OMe SCH2CH2OMe Cl H
OMe SO2CH2CH2OMe Cl H
OMe OCH2CH2OMe Cl CH2Ph
OMe OCH2CH2SMe Cl CH2Ph
OMe OCH2CH2SOMe Cl CH2Ph
OMe OCH2CH2SO2Me Cl CH2Ph
OMe SCH2CH2OMe Cl CH2Ph
OMe SO2CH2CH2OMe Cl CH2Ph
OMe OCH2CH2OMe Cl CH2COPh
OMe OCH2CH2SMe Cl CH2COPh
OMe OCH2CH2SO2Me Cl CH2COPh
表8续
X Y Z Q
OMe SCH2CH2OMe Cl CH2COPh
OMe SCH2CH2OEt Cl CH2COPh
OMe SO2CH2CH2OMe Cl CH2COPh
CH2OMe Y1 SO2Me H
CH2OMe Y2 SO2Me H
CH2OMe Y3 SO2Me H
CH2OMe Y4 SO2Me H
CH2OMe Y5 SO2Me H
CH2OMe Y6 SO2Me H
CH2OMe Y7 SO2Me H
CH2OMe OCH2CH=CH2SO2Me H
CH2OMe OCHMeCH=CH2SO2Me H
CH2OMe OCMe2CH=CH2SO2Me H
CH2OMe OCH2CMe=CH2SO2Me H
CH2OMe OCH2CH=CHMe SO2Me H
CH2OMe OCH2CH=CMe2SO2Me H
CH2OMe OCH2CH2CH=CH2SO2Me H
CH2OMe OCH2C≡CH SO2Me H
CH2OMe OCHMeC≡CH SO2Me H
CH2OMe OCMe2C≡CH SO2Me H
CH2OMe OCH2C≡CMe SO2Me H
CH2OMe OCH2CH2F SO2Me H
CH2OMe OCH2CHF2SO2Me H
CH2OMe OCH2CF3SO2Me H
CH2OMe OCH2CH2Cl SO2Me H
CH2OMe OCH2CCl3SO2Me H
CH2OMe OCHMeCH2Cl SO2Me H
CH2OMe OCH2CH2CH2Cl SO2Me H
CH2OMe OCH2CH2Br SO2Me H
CH2OMe Y8 SO2Me H
CH2OMe OCH2CCl=CH2SO2Me H
CH2OMe OCH2CCl=CHCl SO2Me H
CH2OMe OCH2CH2NO2SO2Me H
CH2OMe OPh SO2Me H
CH2OMe OPh-Me-2 SO2Me H
CH2OMe OPh-Cl-4 SO2Me H
CH2OMe OPh-NO2-4 SO2Me H
CH2OMe OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OEt SO2Me H
CH2OMe OCH2CH2OPr-n SO2Me H
表8续
X Y Z Q
CH2OMe OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OBu-n SO2Me H
CH2OMe OCH2CH2OBu-i SO2Me H
CH2OMe OCH2CH2OBu-s SO2Me H
CH2OMe OCH2CH2OBu-t SO2Me H
CH2OMe OCH2CH2-Y4 SO2Me H
CH2OMe OCHMeCH2OMe SO2Me H
CH2OMe OCH2CHMeOMe SO2Me H
CH2OMe OCH2CH2OPh SO2Me H
CH2OMe OCH2CH2OCH2CH2OMe SO2Me H
CH2OMe OCH2CH2OCH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OCHMeCH2OMe SO2Me H
CH2OMe OCH2CH2OH SO2Me H
CH2OMe OCH2Ph SO2Me H
CH2OMe OCHMePh SO2Me H
CH2OMe OCH2CH2Ph SO2Me H
CH2OMe OCH2Ph-2-Cl SO2Me H
CH2OMe OCH2Ph-3-Me SO2Me H
CH2OMe OCH2Ph-4-OMe SO2Me H
CH2OMe OCH2Ph-4-NO2SO2Me H
CH2OMe Y9 SO2Me H
CH2OMe Y10 SO2Me H
CH2OMe Y11 SO2Me H
CH2OMe Y12 SO2Me H
CH2OMe Y13 SO2Me H
CH2OMe Y14 SO2Me H
CH2OMe Y15 SO2Me H
CH2OMe Y16 SO2Me H
CH2OMe Y17 SO2Me H
CH2OMe Y18 SO2Me H
CH2OMe OCH2CH2NH2SO2Me H
CH2OMe OCH2CH2NHMe SO2Me H
CH2OMe OCH2CH2NHPr-i SO2Me H
CH2OMe OCH2CH2NMe2SO2Me H
CH2OMe OCH2CH2NEt2SO2Me H
CH2OMe Y19 SO2Me H
CH2OMe OCH2COOMe SO2Me H
CH2OMe OCH2COOEt SO2Me H
CH2OMe OCH2COOPr-i SO2Me H
CH2OMe OCH2COOBu-i SO2Me H
表8续
X Y Z Q
CH2OMe OCH2COOBu-t SO2Me H
CH2OMe OCH2COO-Y4 SO2Me H
CH2OMe OCHMeCOOMe SO2Me H
CH2OMe OCHMeCOOEt SO2Me H
CH2OMe OCHMeCOOPr-i SO2Me H
CH2OMe OCH2CH2CN SO2Me H
CH2OMe OCH2SMe SO2Me H
CH2OMe OCH2CH2SMe SO2Me H
CH2OMe OCH2CH2S(O)Me SO2Me H
CH2OMe OCH2CH2SO2Me SO2Me H
CH2OMe OCH2CH2SPr-i SO2Me H
CH2OMe OCH2CH2S(O)Pr-i SO2Me H
CH2OMe OCH2CH2SO2Pr-i SO2Me H
CH2OMe OCOOMe SO2Me H
CH2OMe OCOOPr-i SO2Me H
CH2OMe OCONH2SO2Me H
CH2OMe OCONHMe SO2Me H
CH2OMe OCONMe2SO2Me H
CH2OMe OP(O)(OMe)2SO2Me H
CH2OMe Y20 SO2Me H
CH2OMe SCH2CH=CH2SO2Me H
CH2OMe SCH2CH=CMe2SO2Me H
CH2OMe SCH2C≡CH SO2Me H
CH2OMe SCH2CF3SO2Me H
CH2OMe SCH2CCl3SO2Me H
CH2OMe Y21 SO2Me H
CH2OMe SPh SO2Me H
CH2OMe SCH2CH2OMe SO2Me H
CH2OMe SCH2CH2OEt SO2Me H
CH2OMe SCH2CH2OPr-i SO2Me H
CH2OMe Y22 SO2Me H
CH2OMe S(O)CH2CH=CH2SO2Me H
CH2OMe S(O)CH2CH=CMe2SO2Me H
CH2OMe S(O)CH2C≡CH SO2Me H
CH2OMe S(O)CH2CH2Cl SO2Me H
CH2OMe Y23 SO2Me H
CH2OMe SO2CH2CH=CH2SO2Me H
CH2OMe SO2CH2CH=CMe2SO2Me H
CH2OMe SO2CH2C≡CH SO2Me H
CH2OMe SO2CH2CF3SO2Me H
表8续
X Y Z Q
CH2OMe SO2CH2CH2Cl SO2Me H
CH2OMe Y24 SO2Me H
CH2OMe SO2Ph SO2Me H
CH2OMe SO2CH2CH2OMe SO2Me H
CH2OMe SO2CH2CH2OEt SO2Me H
CH2OMe SO2CH2CH2OPr-i SO2Me H
CH2OMe OCH2CH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2OEt SO2Me CH2Ph
CH2OMe OCH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCHMeCH2OMe SO2Me CH2Ph
CH2OMe OCH2CH2SMe SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Me SO2Me CH2Ph
CH2OMe OCH2CH2SO2Me SO2Me CH2Ph
CH2OMe OCH2CH2SPr-i SO2Me CH2Ph
CH2OMe OCH2CH2S(O)Pr-i SO2Me CH2Ph
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2Ph
CH2OMe SCH2CH2OMe SO2Me CH2Ph
CH2OMe SCH2CH2OPr-i SO2Me CH2Ph
CH2OMe SO2CH2CH2OMe SO2Me CH2Ph
CH2OMe SO2CH2CH2OPr-i SO2Me CH2Ph
CH2OMe OCH2CH2OMe SO2Me CH2COPh
CH2OMe OCH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SMe SO2Me CH2COPh
CH2OMe OCH2CH2SOMe SO2Me CH2COPh
CH2OMe OCH2CH2SO2Me SO2Me CH2COPh
CH2OMe OCH2CH2SPr-i SO2Me CH2COPh
CH2OMe OCH2CH2SO2Pr-i SO2Me CH2COPh
CH2OMe SCH2CH2OMe SO2Me CH2COPh
CH2OMe SCH2CH2OPr-i SO2Me CH2COPh
CH2OMe SO2CH2CH2OMe SO2Me CH2COPh
CH2OMe SO2CH2CH2OPr-i SO2Me CH2COPh
CH2OMe OCH2CH2OMe Cl H
CH2OMe OCH2CH2OEt Cl H
CH2OMe OCH2CH2OPr-i Cl H
CH2OMe OCHMeCH2OMe Cl H
CH2OMe OCH2COOMe Cl H
CH2OMe OCH2CH2SMe Cl H
CH2OMe OCH2CH2SO2Me Cl H
CH2OMe SCH2CH2OMe Cl H
CH2OMe SO2CH2CH2OMe Cl H
表8续
X Y Z Q
CH2OMe OCH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2SMe Cl CH2Ph
CH2OMe OCH2CH2SOMe Cl CH2Ph
CH2OMe OCH2CH2SO2Me Cl CH2Ph
CH2OMe SCH2CH2OMe Cl CH2Ph
CH2OMe SO2CH2CH2OMe Cl CH2Ph
CH2OMe OCH2CH2OMe Cl CH2COPh
CH2OMe OCH2CH2SMe Cl CH2COPh
CH2OMe OCH2CH2SO2Me Cl CH2COPh
CH2OMe SCH2CH2OMe Cl CH2COPh
CH2OMe SCH2CH2OEt Cl CH2COPh
CH2OMe SO2CH2CH2OMe Cl CH2COPh
表9
剂量 EC SE EL DI PA AB AM PO CY ZE
化合物序号
g/are
1 5 5 5 5 5 5 5 5 5 0
1 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
4 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
6 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
7 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
11 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
18 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
19 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 0
20 2 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 0
对比化合物A 4 3 1 3 3 1 4 5 5 0 0
8 4 2 4 4 2 5 5 5 0 0
16 5 3 5 5 3 5 5 5 1 1
对比化合物B 4 5 5 5 5 5 1 1 1 2 0
8 5 5 5 5 5 2 2 2 3 0
16 5 5 5 5 5 3 3 3 4 1
表10
剂量 EC SE EL DI PA AB AM PO XA CY ZE
化合物序号
g/are
1 5 5 5 5 5 5 5 5 5 5 0
1 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
4 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
6 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
7 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
11 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
18 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
19 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
1 5 5 5 5 5 5 5 5 5 5 0
20 2 5 5 5 5 5 5 5 5 5 5 0
4 5 5 5 5 5 5 5 5 5 5 0
对比化合物B 4 3 1 2 3 0 3 5 5 4 0 0
8 4 2 3 4 1 5 5 5 5 0 1
16 5 3 4 5 2 5 5 5 5 1 2
对比化合物A 4 4 3 3 4 3 0 2 2 0 1 0
8 4 4 4 4 4 1 3 3 1 2 1
16 5 5 5 5 5 2 4 4 2 3 2
表11
剂量 VE ST GA MA PP LA SO TR
化合物序号
g/are
0.5 5 5 5 5 5 5 5 0
1 1 5 5 5 5 5 5 5 0
2 5 5 5 5 5 5 5 0
0.5 5 5 5 5 5 5 5 0
7 1 5 5 5 5 5 5 5 0
2 5 5 5 5 5 5 5 0
0.5 5 5 5 5 5 5 5 0
11 1 5 5 5 5 5 5 5 0
2 5 5 5 5 5 5 5 0
0.5 5 5 5 5 5 5 5 0
18 1 5 5 5 5 5 5 5 0
2 5 5 5 5 5 5 5 0
对比化合物C 1 4 4 3 2 4 2 4 0
2 5 5 4 4 5 4 5 1
Claims (1)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17675888 | 1988-07-15 | ||
JP176758/88 | 1988-07-15 | ||
JP176758/1988 | 1988-07-15 | ||
JP2603089 | 1989-02-03 | ||
JP26030/89 | 1989-02-03 | ||
JP26030/1989 | 1989-02-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1039586A CN1039586A (zh) | 1990-02-14 |
CN1017240B true CN1017240B (zh) | 1992-07-01 |
Family
ID=26363753
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN89104508A Expired CN1017240B (zh) | 1988-07-15 | 1989-06-29 | 含有吡唑衍生物的除草剂 |
Country Status (13)
Country | Link |
---|---|
US (2) | US4986845A (zh) |
EP (1) | EP0352543B1 (zh) |
KR (1) | KR0128286B1 (zh) |
CN (1) | CN1017240B (zh) |
AT (1) | ATE112271T1 (zh) |
BR (1) | BR8903486A (zh) |
CA (1) | CA1338788C (zh) |
DE (1) | DE68918524T2 (zh) |
DK (1) | DK170439B1 (zh) |
ES (1) | ES2064388T3 (zh) |
HU (1) | HU205912B (zh) |
IL (1) | IL90819A (zh) |
RU (2) | RU1792280C (zh) |
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DE19946853A1 (de) | 1999-09-30 | 2001-04-05 | Bayer Ag | Substituierte Arylketone |
WO2001053275A2 (de) * | 2000-01-17 | 2001-07-26 | Bayer Aktiengesellschaft | Substituierte arylketone |
DE10037149A1 (de) * | 2000-07-29 | 2002-02-07 | Bayer Ag | Substituierte Arylketone |
DE10043074A1 (de) * | 2000-09-01 | 2002-03-14 | Aventis Cropscience Gmbh | Herbizid wirksame Benzoylcyclohexandione |
EP1387831A1 (de) * | 2001-05-09 | 2004-02-11 | Bayer CropScience AG | Substituierte arylketone |
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DE10138577A1 (de) * | 2001-05-21 | 2002-11-28 | Bayer Ag | Substituierte Benzoylpyrazole |
DE10206792A1 (de) * | 2002-02-19 | 2003-08-28 | Bayer Cropscience Ag | Substituierte Arylketone |
DE10209645A1 (de) * | 2002-03-05 | 2003-09-18 | Bayer Cropscience Ag | Substituierte Arylketone |
DE10235945A1 (de) | 2002-08-06 | 2004-02-19 | Bayer Cropscience Gmbh | 3-Aminocarbonyl substituierte Benzoylpyrazolone |
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AR056889A1 (es) | 2005-12-15 | 2007-10-31 | Ishihara Sangyo Kaisha | Compuestos benzoilpirazol y herbicidas que los contienen |
UA94003C2 (uk) | 2006-11-28 | 2011-03-25 | Ишихара Санджай Кайша, Лтд. | Сполуки бензоїлпіразолу, гербіцид на їх основі та спосіб боротьби з небажаними рослинами |
JP5420169B2 (ja) * | 2006-12-27 | 2014-02-19 | 石原産業株式会社 | ベンゾイルピラゾール系化合物を含有する除草剤 |
JP5416354B2 (ja) * | 2007-02-02 | 2014-02-12 | 石原産業株式会社 | ベンゾイルピラゾール系化合物を含有する除草性組成物 |
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DE102007026875A1 (de) | 2007-06-11 | 2008-12-24 | Bayer Cropscience Ag | 3-Cyclopropyl-4-(3-thiobenzoyl)pyrazole und ihre Verwendung als Herbizide |
JP5449855B2 (ja) | 2008-05-20 | 2014-03-19 | 石原産業株式会社 | ピラゾール系化合物、それらの製造方法及びそれらを含有する除草剤 |
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BR112012001943B1 (pt) * | 2009-07-29 | 2017-11-14 | Bayer Intellectual Property Gmbh | 4- (3-alkyltibenzoyl) pyrazoles, herbicide composition, method for control of undesired plants and use of 4- (3-alkyltybenzoyl) pyrazoles |
CN102812024B (zh) | 2010-03-23 | 2015-01-21 | 巴斯夫欧洲公司 | 具有除草作用的取代吡啶 |
AR081526A1 (es) | 2010-03-23 | 2012-10-03 | Basf Se | Piridazinas sustituidas que tienen accion herbicida |
KR20130051932A (ko) | 2010-03-23 | 2013-05-21 | 바스프 에스이 | 제초 작용을 갖는 치환된 피리도티아진 |
CN102858780A (zh) | 2010-03-23 | 2013-01-02 | 巴斯夫欧洲公司 | 具有除草作用的取代哒嗪 |
EP2550279A1 (en) | 2010-03-23 | 2013-01-30 | Basf Se | Pyrazinothiazines having herbicidal action |
WO2011117195A1 (en) | 2010-03-23 | 2011-09-29 | Basf Se | Substituted pyridines having herbicidal action |
DK2595963T3 (en) | 2010-07-21 | 2015-02-16 | Bayer Ip Gmbh | 4- (4-haloalkyl-3-thiobenzoyl) pyrazoles and their use as herbicides |
US8877683B2 (en) | 2010-12-23 | 2014-11-04 | Basf Se | Substituted pyridines having herbicidal activity |
WO2012168241A1 (en) | 2011-06-09 | 2012-12-13 | Basf Se | Substituted pyrazines having herbicidal activity |
BR112013030822A2 (pt) | 2011-06-09 | 2016-08-16 | Basf Se | composto de piridina substituída da fórmula i, composição e método para controlar a vegetação indesejada |
CN104379588A (zh) | 2012-06-01 | 2015-02-25 | 巴斯夫欧洲公司 | 具有除草活性的取代吡啶化合物 |
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CN108264484A (zh) * | 2016-12-30 | 2018-07-10 | 浙江省化工研究院有限公司 | 一种带醚结构的取代的苯基酮类化合物、其制备方法及应用 |
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-
1989
- 1989-06-21 US US07/369,523 patent/US4986845A/en not_active Ceased
- 1989-06-29 CN CN89104508A patent/CN1017240B/zh not_active Expired
- 1989-06-30 IL IL9081989A patent/IL90819A/en not_active IP Right Cessation
- 1989-06-30 CA CA000604603A patent/CA1338788C/en not_active Expired - Fee Related
- 1989-07-11 ES ES89112691T patent/ES2064388T3/es not_active Expired - Lifetime
- 1989-07-11 EP EP89112691A patent/EP0352543B1/en not_active Expired - Lifetime
- 1989-07-11 AT AT89112691T patent/ATE112271T1/de not_active IP Right Cessation
- 1989-07-11 DE DE68918524T patent/DE68918524T2/de not_active Expired - Fee Related
- 1989-07-14 BR BR898903486A patent/BR8903486A/pt not_active Application Discontinuation
- 1989-07-14 RU SU4614419A patent/RU1792280C/ru active
- 1989-07-14 HU HU893573A patent/HU205912B/hu not_active IP Right Cessation
- 1989-07-14 DK DK349289A patent/DK170439B1/da not_active IP Right Cessation
- 1989-07-14 KR KR1019890010068A patent/KR0128286B1/ko not_active IP Right Cessation
-
1991
- 1991-12-03 RU SU915010216A patent/RU2042667C1/ru not_active IP Right Cessation
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1992
- 1992-09-18 US US07/946,900 patent/USRE34779E/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
HUT51256A (en) | 1990-04-28 |
IL90819A (en) | 1994-06-24 |
IL90819A0 (en) | 1990-01-18 |
US4986845A (en) | 1991-01-22 |
DE68918524D1 (de) | 1994-11-03 |
EP0352543B1 (en) | 1994-09-28 |
HU205912B (en) | 1992-07-28 |
DK349289A (da) | 1990-01-16 |
DK349289D0 (da) | 1989-07-14 |
DK170439B1 (da) | 1995-09-04 |
EP0352543A1 (en) | 1990-01-31 |
AU618609B2 (en) | 1992-01-02 |
ES2064388T3 (es) | 1995-02-01 |
KR900001657A (ko) | 1990-02-27 |
CA1338788C (en) | 1996-12-10 |
DE68918524T2 (de) | 1995-05-04 |
RU2042667C1 (ru) | 1995-08-27 |
KR0128286B1 (ko) | 1998-04-02 |
CN1039586A (zh) | 1990-02-14 |
RU1792280C (ru) | 1993-01-30 |
ATE112271T1 (de) | 1994-10-15 |
BR8903486A (pt) | 1990-03-13 |
USRE34779E (en) | 1994-11-08 |
AU3800589A (en) | 1990-01-25 |
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