CN101679556B - 超溶液均相丙烯聚合 - Google Patents

超溶液均相丙烯聚合 Download PDF

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Publication number
CN101679556B
CN101679556B CN2008800170876A CN200880017087A CN101679556B CN 101679556 B CN101679556 B CN 101679556B CN 2008800170876 A CN2008800170876 A CN 2008800170876A CN 200880017087 A CN200880017087 A CN 200880017087A CN 101679556 B CN101679556 B CN 101679556B
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propylene
diluent
polymer product
propylene monomer
reactor
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Expired - Fee Related
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Chinese (zh)
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CN101679556A (zh
Inventor
P·布兰特
G·L·卡斯蒂
G·基斯
R·A·库克
J·R·拉特纳
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
CN2008800170876A 2007-06-04 2008-04-07 超溶液均相丙烯聚合 Expired - Fee Related CN101679556B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US93300707P 2007-06-04 2007-06-04
US60/933,007 2007-06-04
US12/098,907 2008-04-07
PCT/US2008/059567 WO2008150572A1 (en) 2007-06-04 2008-04-07 Super-solution homogeneous propylene polymerization
US12/098,907 US8058371B2 (en) 2002-09-20 2008-04-07 Super-solution homogeneous propylene polymerization

Publications (2)

Publication Number Publication Date
CN101679556A CN101679556A (zh) 2010-03-24
CN101679556B true CN101679556B (zh) 2012-06-06

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CN2008800170876A Expired - Fee Related CN101679556B (zh) 2007-06-04 2008-04-07 超溶液均相丙烯聚合

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Country Link
US (1) US8058371B2 (enExample)
EP (1) EP2160419B1 (enExample)
JP (1) JP2010529253A (enExample)
CN (1) CN101679556B (enExample)
ES (1) ES2446294T3 (enExample)
WO (1) WO2008150572A1 (enExample)

Families Citing this family (16)

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US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
JP5060791B2 (ja) * 2007-01-26 2012-10-31 独立行政法人森林総合研究所 木材の乾燥方法、木材への薬剤浸透方法及び乾燥装置
WO2008150572A1 (en) 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US9127096B2 (en) * 2010-10-18 2015-09-08 California Institute Of Technology Methods and systems for synthesis of an ultra high molecular weight polymer
CN102464748B (zh) * 2010-11-16 2013-07-03 中国石油化工股份有限公司 一种丙烯共聚物大分子单体及其制备方法
ES3018472T3 (es) 2014-03-28 2025-05-16 Mitsui Chemicals Inc Copolímero de etileno/alfa-olefina y aceite lubricante
JP6824744B2 (ja) * 2014-04-30 2021-02-03 アランセオ・シンガポール・プライヴェート・リミテッド 新規なブチルゴムの製造のための希釈剤としての２，３，３，３−テトラフルオロ−１−プロペン
BR112017014077B1 (pt) * 2014-12-29 2021-10-26 Braskem S.A. Processo para tratamento de nanopartículas de agente de enchimento mineral, nanopartículas e uso de nanopartículas
US9896525B2 (en) 2015-04-29 2018-02-20 Exxonmobil Chemical Patents Inc. Homogeneous polymerization process using evaporative cooling
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018080701A1 (en) * 2016-10-26 2018-05-03 Exxonmobil Chemical Patents Inc. Single-site catalyst polyolefin polymerization process
US11760814B2 (en) 2020-03-03 2023-09-19 Exxonmobil Chemical Patents Inc. 1,5 diazabicyclooctane ligand systems and methods therewith

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