CN101356201B - 阳离子亲水性硅氧烷基单体 - Google Patents

阳离子亲水性硅氧烷基单体 Download PDF

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Publication number
CN101356201B
CN101356201B CN2006800484111A CN200680048411A CN101356201B CN 101356201 B CN101356201 B CN 101356201B CN 2006800484111 A CN2006800484111 A CN 2006800484111A CN 200680048411 A CN200680048411 A CN 200680048411A CN 101356201 B CN101356201 B CN 101356201B
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monomer
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group
replacement
replace
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Chinese (zh)
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CN101356201A (zh
Inventor
D·施诺兹曼
J·C·萨拉莫内
D·阿蒙
J·昆茨勒
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Bausch and Lomb Inc
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Bausch and Lomb Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
CN2006800484111A 2005-12-21 2006-12-11 阳离子亲水性硅氧烷基单体 Expired - Fee Related CN101356201B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US75243705P 2005-12-21 2005-12-21
US60/752,437 2005-12-21
US11/341,208 US7622512B2 (en) 2005-12-21 2006-01-27 Cationic hydrophilic siloxanyl monomers
US11/341,208 2006-01-27
PCT/US2006/047192 WO2007075320A2 (en) 2005-12-21 2006-12-11 Cationic hydrophilic siloxanyl monomers

Publications (2)

Publication Number Publication Date
CN101356201A CN101356201A (zh) 2009-01-28
CN101356201B true CN101356201B (zh) 2012-08-22

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CN2006800484111A Expired - Fee Related CN101356201B (zh) 2005-12-21 2006-12-11 阳离子亲水性硅氧烷基单体

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US (1) US7622512B2 (US07622512-20091124-C00007.png)
EP (1) EP1969021B1 (US07622512-20091124-C00007.png)
JP (1) JP5280856B2 (US07622512-20091124-C00007.png)
CN (1) CN101356201B (US07622512-20091124-C00007.png)
AT (1) ATE447590T1 (US07622512-20091124-C00007.png)
DE (1) DE602006010244D1 (US07622512-20091124-C00007.png)
ES (1) ES2333985T3 (US07622512-20091124-C00007.png)
WO (1) WO2007075320A2 (US07622512-20091124-C00007.png)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7759408B2 (en) * 2005-12-21 2010-07-20 Bausch & Lomb Incorporated Silicon-containing monomers end-capped with polymerizable cationic hydrophilic groups
US7825273B2 (en) * 2006-01-06 2010-11-02 Bausch & Lomb Incorporated Process for making cationic hydrophilic siloxanyl monomers
US8828420B2 (en) * 2006-01-06 2014-09-09 Bausch & Lomb Incorporated Siloxane prepolymer containing pendant cationic and polymerizable groups
US7960447B2 (en) * 2006-04-13 2011-06-14 Bausch & Lomb Incorporated Cationic end-capped siloxane prepolymer for reduced cross-link density
US7468397B2 (en) * 2006-06-30 2008-12-23 Bausch & Lomb Incorporated Polymerizable siloxane-quaternary amine copolymers
US8105623B2 (en) * 2006-06-30 2012-01-31 Bausch & Lomb Incorporated Fluorinated poly(ether)s end-capped with polymerizable cationic hydrophilic groups
US7579021B2 (en) * 2006-09-27 2009-08-25 Bausch & Lomb Incorporated Drug delivery systems based on degradable cationic siloxanyl macromonomers
US7781558B2 (en) * 2006-09-27 2010-08-24 Bausch & Lomb Incorporated Hydrophilic siloxanyl monomers with pendant polymerizable groups
US7951897B2 (en) * 2007-01-26 2011-05-31 Bausch & Lomb Incorporated Synthesis of cationic siloxane prepolymers
US7934830B2 (en) * 2007-12-03 2011-05-03 Bausch & Lomb Incorporated High water content silicone hydrogels
CN102803350B (zh) 2009-06-15 2015-02-18 帝斯曼知识产权资产管理有限公司 用于医疗应用的磷酸胆碱基两亲性硅酮
JP5668062B2 (ja) * 2010-06-14 2015-02-12 株式会社メニコン イオン性化合物、組成物、硬化物、ハイドロゲル及び眼用レンズ
TWI434865B (zh) 2011-12-29 2014-04-21 Pegavision Corp 親水有機矽高聚物之製造方法
US20160095876A1 (en) 2014-10-01 2016-04-07 Rochal Industries, Llp Composition and kits for inhibition of pathogenic microbial infection and methods of using the same
JP7050583B2 (ja) * 2018-06-04 2022-04-08 信越化学工業株式会社 ポリシロキサンモノマー及びその製造方法
KR20210110843A (ko) * 2018-12-31 2021-09-09 다우 실리콘즈 코포레이션 분지형 유기규소 화합물, 이의 제조 방법, 및 이로 형성된 공중합체
EP3906281A1 (en) 2018-12-31 2021-11-10 Dow Silicones Corporation Composition, method of preparing copolymer, and methods and end uses thereof
JP2022545010A (ja) * 2019-08-22 2022-10-24 アドバンシックス・レジンズ・アンド・ケミカルズ・リミテッド・ライアビリティ・カンパニー 表面活性特性を有するアミノ酸のシロキサン誘導体
CN115087349A (zh) 2019-12-19 2022-09-20 艾德凡斯化学公司 用于农业产品的表面活性剂
JP7416952B2 (ja) * 2019-12-19 2024-01-17 アドバンシックス・レジンズ・アンド・ケミカルズ・リミテッド・ライアビリティ・カンパニー パーソナルケア製品及び化粧製品における使用のための界面活性剤
MX2022007548A (es) * 2019-12-19 2022-09-07 Advansix Resins & Chemicals Llc Tensioactivos para tintas, pinturas, y adhesivos.
EP4076389A1 (en) 2019-12-20 2022-10-26 AdvanSix Resins & Chemicals LLC Surfactants for use in healthcare products
WO2021126714A1 (en) * 2019-12-20 2021-06-24 Advansix Resins & Chemicals Llc Surfactants for cleaning products
EP4085117A1 (en) * 2019-12-31 2022-11-09 AdvanSix Resins & Chemicals LLC Surfactants for oil and gas production
AU2020427412B2 (en) 2020-02-05 2024-04-04 Advansix Resins & Chemicals Llc Surfactants for electronics
US11905351B2 (en) * 2020-04-10 2024-02-20 Envision Biomedical LLC Silicone hydrogel materials
WO2023163986A1 (en) * 2022-02-23 2023-08-31 Advansix Resins & Chemicals Llc Siloxane derivatives of amino acids having surface-active properties

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3808179A (en) * 1972-06-16 1974-04-30 Polycon Laboratories Oxygen-permeable contact lens composition,methods and article of manufacture
CN1117739A (zh) * 1993-02-12 1996-02-28 博士伦有限公司 氟硅氧烷水凝胶
US5536861A (en) * 1993-02-09 1996-07-16 Ciba-Geigy Corporation Monomers for producing antimicrobial quaternary group-containing polyers
EP0396364B1 (en) * 1989-05-02 1997-06-11 Bausch & Lomb Incorporated Copolymers of vinyl carbonate and vinyl carbamate as contact lens material

Family Cites Families (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA939378A (en) * 1969-05-15 1974-01-01 Edwin P. Plueddemann Cationic unsaturated amine-functional silane coupling agents
US3884886A (en) * 1973-01-15 1975-05-20 Dow Corning Cationic unsaturated amine-functional silane coupling agents
JPS5028592A (US07622512-20091124-C00007.png) * 1973-07-16 1975-03-24
US4006176A (en) * 1975-04-22 1977-02-01 The Procter & Gamble Company Organosilane compounds
US4005024A (en) * 1975-04-22 1977-01-25 The Procter & Gamble Company Rinse aid composition containing an organosilane
US4189546A (en) * 1977-07-25 1980-02-19 Bausch & Lomb Incorporated Polysiloxane shaped article for use in biomedical applications
US4153641A (en) * 1977-07-25 1979-05-08 Bausch & Lomb Incorporated Polysiloxane composition and contact lens
US4185087A (en) * 1977-12-28 1980-01-22 Union Carbide Corporation Hair conditioning compositions containing dialkylamino hydroxy organosilicon compounds and their derivatives
US4152508A (en) * 1978-02-15 1979-05-01 Polymer Technology Corporation Silicone-containing hard contact lens material
DE2912485A1 (de) 1979-03-29 1980-10-09 Henkel Kgaa Neue quartaere polysiloxanderivate, deren verwendung in haarkosmetika, sowie diese enthaltende haarwasch- und haarbehandlungsmittel
US4260725A (en) * 1979-12-10 1981-04-07 Bausch & Lomb Incorporated Hydrophilic contact lens made from polysiloxanes which are thermally bonded to polymerizable groups and which contain hydrophilic sidechains
US4259467A (en) * 1979-12-10 1981-03-31 Bausch & Lomb Incorporated Hydrophilic contact lens made from polysiloxanes containing hydrophilic sidechains
US4418165A (en) * 1980-06-03 1983-11-29 Dow Corning Corporation Optically clear silicone compositions curable to elastomers
JPS5740742A (en) * 1980-08-23 1982-03-06 Sony Corp Magnetic recording medium
US4388229A (en) * 1981-11-02 1983-06-14 Syntex (U.S.A.) Inc. Contact lens rejuvenating solution
LU84463A1 (fr) * 1982-11-10 1984-06-13 Oreal Polymeres polysiloxanes polyquaternaires
US4472327A (en) * 1983-01-31 1984-09-18 Neefe Charles W Method of making hydrogel cosmetic contact lenses
JPS59179648A (ja) * 1983-03-31 1984-10-12 Kuraray Co Ltd 耐水性組成物
US4495361A (en) * 1983-04-29 1985-01-22 Bausch & Lomb Incorporated Polysiloxane composition with improved surface wetting characteristics and biomedical devices made thereof
US5137448A (en) * 1984-07-31 1992-08-11 Dentsply Research & Development Corp. Dental impression method with photocuring of impression material in light transmissive tray
US4686267A (en) * 1985-10-11 1987-08-11 Polymer Technology Corporation Fluorine containing polymeric compositions useful in contact lenses
DE3676427D1 (de) * 1985-10-14 1991-02-07 Teijin Ltd Fleckenbestaendige polyesterfaser.
US4633003A (en) * 1985-11-25 1986-12-30 Alcon Laboratories, Inc. Siloxane monomers for ophthalmic applications
US4640941A (en) * 1985-11-25 1987-02-03 Alcon Laboratories Hydrogels containing siloxane comonomers
LU86361A1 (fr) * 1986-03-19 1987-11-11 Oreal Composition cosmetique aqueuse a moussage differe pour le traitement des cheveux et de la peau
DE3705121A1 (de) * 1987-02-18 1988-09-01 Goldschmidt Ag Th Polyquaternaere polysiloxan-polymere, deren herstellung und verwendung in kosmetischen zubereitungen
US5006622A (en) * 1987-04-02 1991-04-09 Bausch & Lomb Incorporated Polymer compositions for contact lenses
DE3719086C1 (de) * 1987-06-06 1988-10-27 Goldschmidt Ag Th Diquartaere Polysiloxane,deren Herstellung und Verwendung in kosmetischen Zubereitungen
US4798889A (en) * 1987-11-13 1989-01-17 Dow Corning Corporation Method for stabilizing unsaturated organosilicone compositions
US5128408A (en) * 1987-11-16 1992-07-07 Toyo Boseki Kabushiki Kaisha Gas-permeable material with excellent compatibility with blood
US5039458A (en) * 1987-12-21 1991-08-13 W. R. Grace & Co.-Conn. Method of making a hydrophilic, biocompatible, protein non-adsorptive contact lens
US4910277A (en) * 1988-02-09 1990-03-20 Bambury Ronald E Hydrophilic oxygen permeable polymers
US5070170A (en) * 1988-02-26 1991-12-03 Ciba-Geigy Corporation Wettable, rigid gas permeable, substantially non-swellable contact lens containing block copolymer polysiloxane-polyoxyalkylene backbone units, and use thereof
DE3837811C1 (US07622512-20091124-C00007.png) * 1988-11-08 1990-04-26 Th. Goldschmidt Ag, 4300 Essen, De
US5034461A (en) * 1989-06-07 1991-07-23 Bausch & Lomb Incorporated Novel prepolymers useful in biomedical devices
US5064613A (en) * 1989-11-03 1991-11-12 Dow Corning Corporation Solid antimicrobial
US5013459A (en) * 1989-11-09 1991-05-07 Dow Corning Corporation Opthalmic fluid dispensing method
DE69216100T2 (de) * 1991-09-12 1997-06-12 Bausch & Lomb Benetzungsfaehige silikon-hydrogel-zusammensetzungen und verfahren zu deren herstellung
FR2682090B1 (fr) * 1991-10-03 1993-12-31 Holzstoff Holding Sa Systeme-reservoir pour diffusion prolongee d'un principe actif.
US5358995A (en) * 1992-05-15 1994-10-25 Bausch & Lomb Incorporated Surface wettable silicone hydrogels
US5260000A (en) * 1992-08-03 1993-11-09 Bausch & Lomb Incorporated Process for making silicone containing hydrogel lenses
US5374662A (en) * 1993-03-15 1994-12-20 Bausch & Lomb Incorporated Fumarate and fumaramide siloxane hydrogel compositions
US5340583A (en) * 1993-05-06 1994-08-23 Allergan, Inc. Antimicrobial lenses and lens care systems
US5393330A (en) * 1993-06-30 1995-02-28 Osi Specialties, Inc. Cationic emulsions of alkylalkoxysilanes
US5451651A (en) * 1993-12-17 1995-09-19 Bausch & Lomb Incorporated Urea and urethane monomers for contact lens materials
US5760100B1 (en) * 1994-09-06 2000-11-14 Ciba Vision Corp Extended wear ophthalmic lens
TW585882B (en) * 1995-04-04 2004-05-01 Novartis Ag A method of using a contact lens as an extended wear lens and a method of screening an ophthalmic lens for utility as an extended-wear lens
FR2736262B1 (fr) * 1995-07-07 1997-09-26 Oreal Compositions cosmetiques detergentes a usage capillaire et utilisation de ces dernieres
CN1084335C (zh) * 1995-12-07 2002-05-08 博士伦公司 用于降低硅氧烷水凝胶的模量的单体单元
JP2000502329A (ja) * 1995-12-07 2000-02-29 ボシュ アンド ロム インコーポレイテッド 低含水ポリマー性シリコーン組成物のモジュラスを低減するために有用なモノマーユニット
JP3484591B2 (ja) 1995-12-28 2004-01-06 東レ株式会社 プラスチック成形品、その製造方法および光学物品
JP3859723B2 (ja) * 1996-03-04 2006-12-20 オーエスアイ スペシャルティーズ インコーポレーテッド シリコーンアミノポリアルキレンオキシドブロックコポリマー
JP3715021B2 (ja) * 1996-04-09 2005-11-09 Ｊｓｒ株式会社 液状硬化性樹脂組成物
DE19627204A1 (de) * 1996-07-05 1998-01-08 Basf Ag Kosmetische oder pharmazeutische Mittel zur Anwendung auf der Haut
US5707435A (en) 1996-10-16 1998-01-13 Dow Corning Corporation Ammonium siloxane emulsions and their use as fiber treatment agents
US5707434A (en) * 1996-10-16 1998-01-13 Dow Corning Corporation Water soluble ammonium siloxane compositions and their use as fiber treatment agents
US5725736A (en) * 1996-10-25 1998-03-10 Kimberly-Clark Worldwide, Inc. Tissue containing silicone betaines
CA2223905C (en) * 1996-12-06 2008-08-26 Toray Industries, Inc. Plastic articles for medical use
DE19718634A1 (de) * 1997-05-02 1998-11-05 Wacker Chemie Gmbh Strahlungs- oder thermischhärtende Organosiloxanmassen mit (Methyl)styrolgruppen
US6013711A (en) * 1997-06-18 2000-01-11 Ck Witco Corporation Hydrophilic polysiloxane compositions
US5844026A (en) * 1997-06-30 1998-12-01 Ciba Specialty Chemicals Corporation N,N',N''-tris{2,4-bis Hydrocarbyloxy-2,2,6,6-tetra-methylpiperidin-4-yl)alkylamino!-s-triazin-6-yl}-3,3'-ethylenediiminodipropylamines, their isomers and bridged derivatives and polymer compositions stabilized therewith
US6822016B2 (en) * 2001-09-10 2004-11-23 Johnson & Johnson Vision Care, Inc. Biomedical devices containing internal wetting agents
US5962548A (en) * 1998-03-02 1999-10-05 Johnson & Johnson Vision Products, Inc. Silicone hydrogel polymers
US6849671B2 (en) * 1998-03-02 2005-02-01 Johnson & Johnson Vision Care, Inc. Contact lenses
JPH11302331A (ja) * 1998-04-20 1999-11-02 Kuraray Co Ltd 耐水性組成物
JP2000017031A (ja) * 1998-06-29 2000-01-18 Shin Etsu Chem Co Ltd 放射線硬化型樹脂組成物
ATE277109T1 (de) * 1998-07-17 2004-10-15 Biocompatibles Uk Ltd Verfahren zur herstellung von beschichteten geformten polymeren gegenständen
EP1000959B1 (de) * 1998-11-14 2003-04-16 Goldschmidt AG Polyetherquatfunktionelle Polysiloxane
WO2000054587A1 (en) * 1999-03-16 2000-09-21 Coating Systems Laboratories, Inc. Antimicrobial skin preparations containing organosilane quaternaries
JP3982114B2 (ja) * 1999-06-21 2007-09-26 東レ株式会社 眼用レンズ用モノマー、眼用レンズ用ポリマーおよびそれを用いたコンタクトレンズ
US6649722B2 (en) * 1999-12-10 2003-11-18 Novartis Ag Contact lens
DE10036677A1 (de) * 2000-07-27 2002-02-14 Wacker Chemie Gmbh Wässrige Zusammensetzungen
DE10051258A1 (de) * 2000-10-16 2002-04-25 Goldschmidt Rewo Gmbh & Co Kg Verwendung von quaternären Polysiloxanen in Waschmittelformulierungen
JP4012680B2 (ja) * 2000-10-26 2007-11-21 信越化学工業株式会社 有機ケイ素化合物
US6534184B2 (en) * 2001-02-26 2003-03-18 Kion Corporation Polysilazane/polysiloxane block copolymers
US6815074B2 (en) * 2001-05-30 2004-11-09 Novartis Ag Polymeric materials for making contact lenses
DE10141356A1 (de) * 2001-08-23 2003-03-06 Goldschmidt Ag Th UV-Licht absorbierende quartäre Polysiloxane
US6607717B1 (en) * 2001-10-24 2003-08-19 Dow Corning Corporation Silicon based quaternary ammonium functional compositions and their applications
US6482969B1 (en) * 2001-10-24 2002-11-19 Dow Corning Corporation Silicon based quaternary ammonium functional compositions and methods for making them
US6730767B2 (en) * 2001-11-02 2004-05-04 Bausch & Lomb Incorporated High refractive index aromatic-based siloxane monofunctional macromonomers
US6852793B2 (en) * 2002-06-19 2005-02-08 Bausch & Lomb Incorporated Low water content, high refractive index, flexible, polymeric compositions
US6787603B2 (en) * 2002-11-27 2004-09-07 Dow Corning Corporation Method of making emulsion containing quaternary ammonium functional silanes and siloxanes
MXPA05012496A (es) * 2003-05-22 2006-05-25 Coating Systems Lab Inc Recubrimientos de amonio cuaternario organosilano antimicrobiano.
US20070149428A1 (en) * 2005-12-14 2007-06-28 Bausch & Lomb Incorporated Method of Packaging a Lens
US7759408B2 (en) * 2005-12-21 2010-07-20 Bausch & Lomb Incorporated Silicon-containing monomers end-capped with polymerizable cationic hydrophilic groups

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3808179A (en) * 1972-06-16 1974-04-30 Polycon Laboratories Oxygen-permeable contact lens composition,methods and article of manufacture
EP0396364B1 (en) * 1989-05-02 1997-06-11 Bausch & Lomb Incorporated Copolymers of vinyl carbonate and vinyl carbamate as contact lens material
US5536861A (en) * 1993-02-09 1996-07-16 Ciba-Geigy Corporation Monomers for producing antimicrobial quaternary group-containing polyers
CN1117739A (zh) * 1993-02-12 1996-02-28 博士伦有限公司 氟硅氧烷水凝胶
CN1273978A (zh) * 1993-02-12 2000-11-22 博士伦有限公司 氟硅氧烷水凝胶

Also Published As

Publication number Publication date
ATE447590T1 (de) 2009-11-15
CN101356201A (zh) 2009-01-28
ES2333985T3 (es) 2010-03-03
US7622512B2 (en) 2009-11-24
DE602006010244D1 (de) 2009-12-17
EP1969021B1 (en) 2009-11-04
JP5280856B2 (ja) 2013-09-04
WO2007075320A3 (en) 2007-08-16
JP2009521546A (ja) 2009-06-04
EP1969021A2 (en) 2008-09-17
US20070142583A1 (en) 2007-06-21
WO2007075320A2 (en) 2007-07-05

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