CN101027355A - 金属被覆用聚烯烃系树脂组合物和使用它的树脂薄膜、树脂被覆金属材料 - Google Patents
金属被覆用聚烯烃系树脂组合物和使用它的树脂薄膜、树脂被覆金属材料 Download PDFInfo
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- CN101027355A CN101027355A CNA2005800319482A CN200580031948A CN101027355A CN 101027355 A CN101027355 A CN 101027355A CN A2005800319482 A CNA2005800319482 A CN A2005800319482A CN 200580031948 A CN200580031948 A CN 200580031948A CN 101027355 A CN101027355 A CN 101027355A
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- Prior art keywords
- polyolefin
- coating metal
- resin
- polyolefin resin
- rubber
- Prior art date
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- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-O dodecylazanium Chemical compound CCCCCCCCCCCC[NH3+] JRBPAEWTRLWTQC-UHFFFAOYSA-O 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 1
- WGBBUURBHXLGFM-UHFFFAOYSA-N hexan-2-amine Chemical compound CCCCC(C)N WGBBUURBHXLGFM-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-O hexylazanium Chemical compound CCCCCC[NH3+] BMVXCPBXGZKUPN-UHFFFAOYSA-O 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-O hydron;octadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCC[NH3+] REYJJPSVUYRZGE-UHFFFAOYSA-O 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 1
- 239000005001 laminate film Substances 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000005029 tin-free steel Substances 0.000 description 1
- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 description 1
- XTAZYLNFDRKIHJ-UHFFFAOYSA-O trioctylazanium Chemical compound CCCCCCCC[NH+](CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-O 0.000 description 1
- RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
树脂成分 | 原料名、等级 | MFR(230℃、2.16kg、JIS K6921) |
(A)(A’)(B)(C)(D) | 日本ポリプロピレン社制ノバテツクPP EA7A三井化学社制PPタイプアドマ一QB540ホ一ジュン社制有机改性蒙脱石(MMT)エスベン NX三洋化成工业社制马来酸酐改性PPュ一メツクス1001JSR社制乙烯-丁烯橡胶(EBM)2041P | 1.41.1--8.0 |
树脂成分 | 原料名、等级 | MFR(230℃、2.16kg、JIS K6921) |
(A)(A’)(B)(C)(D) | 日本ポリエチレン社制ノバテツクHDHY331三井化学社制PEタイプアドマ一HB030ホ一ジュン社制有机改性蒙脱石(MMT)エスベン NX三洋化成工业社制马来酸酐改性PPュ一メツクス 2000JSR社制乙烯-丁烯橡胶(EBM)2041P | 1.00.34--8.0 |
组成比(A/B/C/D)质量% | EBM的长轴和短轴 | 透气性 | 翘起(mm) | 端部有无剥离 | 剥离强度(N/cm) | ||
氧气(mol/m2·s·Pa) | 水蒸气(g/m2·24h) | ||||||
实施例1 | 75/5/15/5 | 2以下 | 5.3×10-12 | 1.60 | 7 | 无 | 15.5 |
实施例2 | 65/5/15/15 | 2以下 | 7.2×10-12 | 1.88 | 8.0 | 无 | 14.5 |
实施例3 | 50/5/15/30 | 2以下 | 8.9×10-12 | 2.15 | 9.5 | 无 | 13.5 |
实施例4 | 55/10/30/5 | 2以下 | 4.1×10-12 | 1.01 | 7.2 | 无 | 15.3 |
实施例5 | 90/5/5(A’/B/D) | 2以下 | 5.5×10-12 | 1.71 | 7.6 | 无 | 15.1 |
实施例6 | 75/5/15/5 | 2以下 | 5.1×10-12 | 0.8 | 6.4 | 无 | 15.9 |
实施例7 | 65/5/15/15 | 2以下 | 6.9×10-12 | 0.91 | 7.8 | 无 | 14.3 |
实施例8 | 50/5/15/30 | 2以下 | 8.4×10-12 | 1.1 | 9.1 | 无 | 13.7 |
实施例9 | 55/10/30/5 | 2以下 | 4.0×10-12 | 0.49 | 7.1 | 无 | 15.5 |
实施例10 | 90/5/5(A’/B/D) | 2以下 | 4.9×10-12 | 0.85 | 7.3 | 无 | 14.9 |
比较例1 | 100/0/0/0 | - | 9.1×10-12 | 2.17 | - | - | 不粘附 |
比较例2 | 85/0/15/0 | - | 9.2×10-12 | 2.20 | 30 | 有 | 9.0 |
比较例3 | 80/0/15/5 | 2以下 | 10.6×10-12 | 2.50 | 32 | 有 | 8.9 |
比较例4 | 70/0/15/15 | 2以下 | 15.5×10-12 | 3.63 | 35 | 有 | 8.5 |
比较例5 | 55/0/15/30 | 2以下 | 19.9×10-12 | 4.75 | 38 | 有 | 8.3 |
比较例6 | 80/5/15/0 | - | 5.0×10-12 | 1.55 | 14 | 有(少) | 12.0 |
比较例7 | 100/0/0/0 | - | 8.8×10-12 | 1.51 | - | - | 不粘附 |
比较例8 | 85/0/15/0 | - | 9.1×10-12 | 1.67 | 29 | 有 | 9.2 |
比较例9 | 80/0/15/5 | 2以下 | 9.9×10-12 | 1.88 | 30 | 有 | 9.1 |
比较例10 | 70/0/15/15 | 2以下 | 14.7×10-12 | 2.53 | 33 | 有 | 8.8 |
比较例11 | 55/0/15/30 | 2以下 | 19.0×10-12 | 3.29 | 36 | 有 | 8.5 |
比较例12 | 80/5/15/0 | - | 4.8×10-12 | 2.11 | 13 | 有(少) | 12.2 |
剥离面积(%) | 阴极剥离长(最长剥离长/缺陷半径) | |
实施例11 | 2 | 1.8 |
实施例12 | 10 | 2.4 |
实施例13 | 18 | 3.5 |
实施例14 | 2.1 | 1.9 |
实施例15 | 4 | 2.1 |
实施例11 | 1.8 | 1.6 |
实施例12 | 9.9 | 2.1 |
实施例13 | 17.6 | 3.3 |
实施例14 | 2.0 | 1.7 |
实施例15 | 3.7 | 1.9 |
实施例16 | 1.8 | 1.6 |
实施例17 | 9.9 | 2.1 |
实施例18 | 17.6 | 3.3 |
实施例19 | 2.0 | 1.7 |
实施例20 | 3.7 | 1.9 |
比较例13 | 100 | 7.3 |
比较例14 | 100 | 7.1 |
比较例15 | 100 | 6.4 |
比较例16 | 100 | 6.2 |
比较例17 | 99 | 5.1 |
比较例18 | 98 | 5.0 |
比较例19 | 100 | 7.3 |
比较例20 | 100 | 7.1 |
比较例21 | 100 | 6.4 |
比较例22 | 100 | 6.2 |
比较例23 | 99 | 5.1 |
比较例24 | 98 | 5.0 |
树脂成分 | 原料名、等级 | MFR(230℃、2.16kg、JIS K6921) |
(A)(B)(C)(D) | 日本ポリプ口ピレン社制ノバテツクPP EA7A协和化学工业社制水滑石キヨ一ワ一ド 500三洋化成工业社制马来酸酐改性PPュ一メツクス1001JSR社制乙烯-丁烯橡胶(EBM)2041P | 1.4--8.0 |
树脂成分 | 原料名、等级 | MFR(230℃、2.16kg、JIS K6921) |
(A)(B)(C)(D) | 日本ポリプ口ピレン社制ノバテックPP EA7A岐阜县多治见市产 高岭石三洋化成工业社制马来酸酐改性PPュ一メツクス1001JSR社制乙烯-丁烯橡胶(EBM)2041P | 1.4--8.0 |
EBM的长轴和短轴 | 透气性 | 翘起(mm) | 端部有无剥离 | 剥离强度(N/cm) | ||
氧气(mol/m2·s·Pa) | 水蒸气(g/m2·24h) | |||||
实施例21 | 2以下 | 5.6×10-12 | 1.64 | 8.5 | 无 | 13.9 |
实施例22 | 2以下 | 6.6×10-12 | 1.76 | 9.3 | 无 | 13.7 |
Claims (17)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004275111A JP5030374B2 (ja) | 2004-09-22 | 2004-09-22 | 金属被覆用ポリオレフィン系樹脂組成物及びこれを用いた樹脂フィルム、樹脂被覆金属材料 |
JP275111/2004 | 2004-09-22 | ||
PCT/JP2005/016674 WO2006033250A1 (ja) | 2004-09-22 | 2005-09-05 | 金属被覆用ポリオレフィン系樹脂組成物及びこれを用いた樹脂フィルム、樹脂被覆金属材料 |
Publications (2)
Publication Number | Publication Date |
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CN101027355A true CN101027355A (zh) | 2007-08-29 |
CN101027355B CN101027355B (zh) | 2011-07-13 |
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CN2005800319482A Expired - Fee Related CN101027355B (zh) | 2004-09-22 | 2005-09-05 | 金属被覆用聚烯烃系树脂组合物和使用它的树脂薄膜、树脂被覆金属材料 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9074083B2 (zh) |
JP (1) | JP5030374B2 (zh) |
KR (1) | KR100855751B1 (zh) |
CN (1) | CN101027355B (zh) |
TW (1) | TWI292770B (zh) |
WO (1) | WO2006033250A1 (zh) |
Cited By (1)
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CN111491796A (zh) * | 2017-12-21 | 2020-08-04 | Posco公司 | 层压有钢板和导入官能团的塑料层的复合材料及其制造方法 |
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DE102006035660B4 (de) * | 2006-07-31 | 2009-08-20 | Voestalpine Stahl Gmbh | Korrosionsschutzschicht mit verbesserten Eigenschaften und Verfahren zu ihrer Herstellung |
RU2452794C2 (ru) * | 2007-11-22 | 2012-06-10 | Эльхад Халидович Нагиев | Полимерное ингибированное изделие многоразового применения |
JP5597529B2 (ja) * | 2010-03-18 | 2014-10-01 | トヨタ紡織株式会社 | 熱可塑性樹脂組成物の製造方法 |
EP2692793B1 (en) * | 2011-03-31 | 2016-09-14 | UBE Industries, Ltd. | Polyolefin resin composition molded body having high scratch resistance |
JP6085932B2 (ja) * | 2012-09-28 | 2017-03-01 | Jfeスチール株式会社 | ポリエチレン被覆鋼材、及びエポキシ樹脂プライマー層形成材料 |
EP3230363B1 (en) * | 2014-12-11 | 2021-09-22 | SABIC Global Technologies B.V. | Polymer compositions for thermal spray coating |
KR102350805B1 (ko) | 2021-05-20 | 2022-01-14 | 주식회사 코팅코리아 | 수도용 강관의 내면 코팅용 개질 폴리에틸렌 분체 수지 조성물 |
KR102515678B1 (ko) * | 2023-01-09 | 2023-03-30 | 대한강관 주식회사 | 재활용 탄성체를 함유하고 방수 및 부식방지를 위한 강관 보호용 복합 피복필름 및 이를 이용한 피복 강관 |
PL443654A1 (pl) * | 2023-02-01 | 2024-04-22 | Boryszew Spółka Akcyjna | Kompozycja podkładu adhezyjnego do tworzyw sztucznych oraz sposób jej wytwarzania |
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2004
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- 2005-09-05 CN CN2005800319482A patent/CN101027355B/zh not_active Expired - Fee Related
- 2005-09-05 US US11/662,770 patent/US9074083B2/en not_active Expired - Fee Related
- 2005-09-05 KR KR1020077006503A patent/KR100855751B1/ko active IP Right Grant
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111491796A (zh) * | 2017-12-21 | 2020-08-04 | Posco公司 | 层压有钢板和导入官能团的塑料层的复合材料及其制造方法 |
CN111491796B (zh) * | 2017-12-21 | 2022-06-10 | Posco公司 | 层压有钢板和导入官能团的塑料层的复合材料及其制造方法 |
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US9074083B2 (en) | 2015-07-07 |
US20080075962A1 (en) | 2008-03-27 |
JP2006089558A (ja) | 2006-04-06 |
KR100855751B1 (ko) | 2008-09-03 |
KR20070053774A (ko) | 2007-05-25 |
CN101027355B (zh) | 2011-07-13 |
JP5030374B2 (ja) | 2012-09-19 |
TW200619313A (en) | 2006-06-16 |
WO2006033250A1 (ja) | 2006-03-30 |
TWI292770B (en) | 2008-01-21 |
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