CN100584891C - 接枝于聚合物的亚砜或砜 - Google Patents
接枝于聚合物的亚砜或砜 Download PDFInfo
- Publication number
- CN100584891C CN100584891C CN200610141648A CN200610141648A CN100584891C CN 100584891 C CN100584891 C CN 100584891C CN 200610141648 A CN200610141648 A CN 200610141648A CN 200610141648 A CN200610141648 A CN 200610141648A CN 100584891 C CN100584891 C CN 100584891C
- Authority
- CN
- China
- Prior art keywords
- alkyl
- group
- alkylidene group
- hydrogen
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920000642 polymer Polymers 0.000 title abstract description 41
- 150000003462 sulfoxides Chemical class 0.000 title description 13
- 150000003457 sulfones Chemical class 0.000 title description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 FLOW IMPROVERS Substances 0.000 claims description 248
- 150000001875 compounds Chemical class 0.000 claims description 115
- 239000001257 hydrogen Substances 0.000 claims description 80
- 229910052739 hydrogen Inorganic materials 0.000 claims description 80
- 150000002431 hydrogen Chemical class 0.000 claims description 63
- 239000001301 oxygen Substances 0.000 claims description 53
- 229910052760 oxygen Inorganic materials 0.000 claims description 53
- 239000000203 mixture Substances 0.000 claims description 48
- 239000000126 substance Substances 0.000 claims description 48
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 37
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 28
- 239000005864 Sulphur Substances 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 150000001721 carbon Chemical group 0.000 claims description 22
- 230000003647 oxidation Effects 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 22
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 230000000996 additive effect Effects 0.000 claims description 15
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- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
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- 150000003254 radicals Chemical class 0.000 description 15
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- 229920000578 graft copolymer Polymers 0.000 description 12
- 229960001866 silicon dioxide Drugs 0.000 description 12
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
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- 239000000741 silica gel Substances 0.000 description 11
- 229910002027 silica gel Inorganic materials 0.000 description 11
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 10
- 239000012141 concentrate Substances 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- LWLSVNFEVKJDBZ-UHFFFAOYSA-N N-[4-(trifluoromethoxy)phenyl]-4-[[3-[5-(trifluoromethyl)pyridin-2-yl]oxyphenyl]methyl]piperidine-1-carboxamide Chemical compound FC(OC1=CC=C(C=C1)NC(=O)N1CCC(CC1)CC1=CC(=CC=C1)OC1=NC=C(C=C1)C(F)(F)F)(F)F LWLSVNFEVKJDBZ-UHFFFAOYSA-N 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 9
- 125000002947 alkylene group Chemical group 0.000 description 9
- 150000002118 epoxides Chemical class 0.000 description 9
- 238000003810 ethyl acetate extraction Methods 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 239000004700 high-density polyethylene Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 description 9
- 235000011152 sodium sulphate Nutrition 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
- 235000006708 antioxidants Nutrition 0.000 description 8
- 239000012964 benzotriazole Substances 0.000 description 8
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- 239000007859 condensation product Substances 0.000 description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 229940038384 octadecane Drugs 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 7
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- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 7
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- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 7
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 6
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- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 6
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- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
- C07C317/04—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
- C07C317/10—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/24—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/25—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/64—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton
- C07C323/65—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton containing sulfur atoms of sulfone or sulfoxide groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/20—Incorporating sulfur atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Epoxy Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6592001 | 2001-04-06 | ||
| CH659/2001 | 2001-04-06 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028077962A Division CN100406524C (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1966584A CN1966584A (zh) | 2007-05-23 |
| CN100584891C true CN100584891C (zh) | 2010-01-27 |
Family
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Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
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| CN200610141648A Expired - Fee Related CN100584891C (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
| CN2006101416471A Expired - Fee Related CN1966492B (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
| CNB028077962A Expired - Fee Related CN100406524C (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006101416471A Expired - Fee Related CN1966492B (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
| CNB028077962A Expired - Fee Related CN100406524C (zh) | 2001-04-06 | 2002-03-26 | 接枝于聚合物的亚砜或砜 |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US7160955B2 (https=) |
| EP (1) | EP1373196A2 (https=) |
| JP (2) | JP4938206B2 (https=) |
| KR (1) | KR100873718B1 (https=) |
| CN (3) | CN100584891C (https=) |
| BR (1) | BR0208689A (https=) |
| CA (1) | CA2440839C (https=) |
| CZ (1) | CZ20032671A3 (https=) |
| HR (1) | HRP20030800A2 (https=) |
| HU (1) | HUP0303740A3 (https=) |
| MX (1) | MXPA03009105A (https=) |
| NZ (1) | NZ528592A (https=) |
| PL (1) | PL363620A1 (https=) |
| RS (1) | RS77403A (https=) |
| RU (1) | RU2291874C2 (https=) |
| SK (1) | SK12322003A3 (https=) |
| TW (1) | TWI230149B (https=) |
| UA (1) | UA76141C2 (https=) |
| WO (1) | WO2002081432A2 (https=) |
| ZA (1) | ZA200306720B (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003271662A1 (en) * | 2002-10-07 | 2004-04-23 | Ciba Specialty Chemicals Holding Inc. | Graftable 4-amino-3-sulfinyl-substitued diphenylamine stabilizers for vulcanizates |
| AU2004212161A1 (en) | 2003-02-14 | 2004-08-26 | Ciba Specialty Chemicals Holding Inc. | Graftable hindered amine light stabilizers |
| JP5520483B2 (ja) * | 2005-09-21 | 2014-06-11 | チバ ホールディング インコーポレーテッド | 改善された加工性を有する充填ゴム配合物 |
| RU2356728C2 (ru) * | 2007-02-21 | 2009-05-27 | Людмила Карповна Семенова | Способ изготовления плит из композиционного материала |
| US8609753B2 (en) | 2010-01-29 | 2013-12-17 | Zeon Corporation | Acrylic rubber composition and cross-linked rubber product |
| EP2530076B1 (en) | 2010-01-29 | 2016-11-09 | Zeon Corporation | Fused heterocyclic compound and composition |
| JP6264144B2 (ja) * | 2014-03-27 | 2018-01-24 | Jsr株式会社 | 重合体、感放射線性樹脂組成物及びレジストパターン形成方法 |
| EP4282922A3 (en) * | 2014-08-05 | 2024-02-21 | Miyoshi Oil & Fat Co., Ltd. | Additive for imparting ultraviolet absorptivity and/or high refractive index to matrix, and resin member using same |
| EP3189045B1 (en) | 2014-08-11 | 2022-02-09 | Sun Pharmaceutical Industries Limited | Novel salts of nilotinib and polymorphs thereof |
| CN114106033B (zh) * | 2021-12-02 | 2024-02-27 | 山东阳谷华泰化工股份有限公司 | 一种3-烃基丙基硫醚基三乙氧基硅烷及其制备方法和应用 |
| CN115417990B (zh) * | 2022-08-18 | 2023-08-29 | 宁夏清研高分子新材料有限公司 | 一种高流动性的聚砜聚合物及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4021468A (en) * | 1973-09-06 | 1977-05-03 | Ciba-Geigy Corporation | Thiaalkyl phenols |
| US4287320A (en) * | 1974-08-01 | 1981-09-01 | Minnesota Mining And Manufacturing Company | Composition of fluoroelastomer and diorganosulfuroxide |
| US5258433A (en) * | 1990-08-28 | 1993-11-02 | Ciba-Geigy Corporation | Sulfoxides of alkylthiomethylphenols |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB922367A (en) * | 1960-11-23 | 1963-03-27 | Monsanto Chemicals | Rubber-resin blends having improved processability |
| US3235532A (en) * | 1961-12-08 | 1966-02-15 | Exxon Research Engineering Co | Polyolefins stabilized by a combination of boric acid, phenolic compounds, and sulfur containing compounds |
| US3226357A (en) * | 1962-09-11 | 1965-12-28 | Nat Distillers Chem Corp | Polyolefins stabilized with derivatives of xylylene thioethers |
| DE1288604B (de) * | 1966-08-18 | 1969-02-06 | Advance Prod Gmbh | Stabilisieren von organischen Stoffen gegen Zersetzung durch Sauerstoff in der Waerme |
| US3480581A (en) * | 1966-10-20 | 1969-11-25 | Nat Distillers Chem Corp | Enhancement of resistance of olefin polymers to heat deterioration |
| JPS4946145B1 (https=) * | 1970-03-31 | 1974-12-07 | ||
| JPS4946144B1 (https=) * | 1970-03-31 | 1974-12-07 | ||
| US4001299A (en) * | 1974-12-12 | 1977-01-04 | Ciba-Geigy Corporation | Hindered hydroxyphenylalkanoates of substituted isopropanols |
| JPS62121448A (ja) * | 1985-11-22 | 1987-06-02 | Dainippon Ink & Chem Inc | 光重合性組成物 |
| RU2017715C1 (ru) * | 1991-12-18 | 1994-08-15 | Исмагилов Фоат Ришатович | Способ получения диалкилсульфидов |
| JP3111714B2 (ja) * | 1992-12-21 | 2000-11-27 | 住友化学工業株式会社 | 安定化有機材料組成物 |
| EP0642056A3 (en) * | 1993-09-02 | 1995-08-02 | Minnesota Mining & Mfg | Photothermographic elements. |
| DE69514604T2 (de) * | 1994-10-04 | 2000-06-21 | Aventis Research & Technologies Gmbh & Co Kg | Verfahren zur Herstellung von Polymeren aus Alpha, Omega ungesättigten konjugierten Verbindungen |
| JPH11513676A (ja) | 1995-10-19 | 1999-11-24 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | フェノール基および芳香族アミン基を含む酸化防止剤 |
| RU2261258C2 (ru) * | 1999-10-18 | 2005-09-27 | Циба Спешиалти Кемикалз Холдинг Инк. | Композиция стабилизированного эластомера, стабилизатор, способ стабилизации эластомеров и способ предотвращения обесцвечивания субстратов |
| JP4815160B2 (ja) * | 2005-06-28 | 2011-11-16 | 株式会社Lixil | 手摺 |
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2002
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- 2002-03-26 RU RU2003130643/04A patent/RU2291874C2/ru not_active IP Right Cessation
- 2002-03-26 NZ NZ528592A patent/NZ528592A/en unknown
- 2002-03-26 HR HR20030800A patent/HRP20030800A2/xx not_active Application Discontinuation
- 2002-03-26 RS YUP-774/03A patent/RS77403A/sr unknown
- 2002-03-26 HU HU0303740A patent/HUP0303740A3/hu unknown
- 2002-03-26 CA CA2440839A patent/CA2440839C/en not_active Expired - Fee Related
- 2002-03-26 SK SK1232-2003A patent/SK12322003A3/sk not_active Application Discontinuation
- 2002-03-26 WO PCT/EP2002/003381 patent/WO2002081432A2/en not_active Ceased
- 2002-03-26 CN CN200610141648A patent/CN100584891C/zh not_active Expired - Fee Related
- 2002-03-26 CN CN2006101416471A patent/CN1966492B/zh not_active Expired - Fee Related
- 2002-03-26 PL PL02363620A patent/PL363620A1/xx not_active Application Discontinuation
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- 2002-03-26 UA UA2003109062A patent/UA76141C2/uk unknown
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2003
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2006
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2008
- 2008-11-04 JP JP2008283767A patent/JP2009108071A/ja not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4021468A (en) * | 1973-09-06 | 1977-05-03 | Ciba-Geigy Corporation | Thiaalkyl phenols |
| US4287320A (en) * | 1974-08-01 | 1981-09-01 | Minnesota Mining And Manufacturing Company | Composition of fluoroelastomer and diorganosulfuroxide |
| US5258433A (en) * | 1990-08-28 | 1993-11-02 | Ciba-Geigy Corporation | Sulfoxides of alkylthiomethylphenols |
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