CN100511489C - 聚合物固体电解质用组合物、聚合物固体电解质、聚合物固体电解质电池和共聚物 - Google Patents
聚合物固体电解质用组合物、聚合物固体电解质、聚合物固体电解质电池和共聚物 Download PDFInfo
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- CN100511489C CN100511489C CNB2004800259203A CN200480025920A CN100511489C CN 100511489 C CN100511489 C CN 100511489C CN B2004800259203 A CNB2004800259203 A CN B2004800259203A CN 200480025920 A CN200480025920 A CN 200480025920A CN 100511489 C CN100511489 C CN 100511489C
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- 238000006467 substitution reaction Methods 0.000 description 1
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- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
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- 239000005051 trimethylchlorosilane Substances 0.000 description 1
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Images
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
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- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/08—Copolymers of styrene
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- H—ELECTRICITY
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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- Epoxy Resins (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
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| JP321155/2003 | 2003-09-12 |
Publications (2)
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| CN1849674A CN1849674A (zh) | 2006-10-18 |
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| CN (1) | CN100511489C (enExample) |
| WO (1) | WO2005027144A1 (enExample) |
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| KR100739035B1 (ko) * | 2004-11-29 | 2007-07-12 | 삼성에스디아이 주식회사 | 막-전극 어셈블리 및 이를 포함하는 연료전지 시스템 |
| EP1847556B1 (en) * | 2005-01-21 | 2010-12-08 | Nippon Soda Co., Ltd. | Polymer, crosslinked polymer, composition for solid polymer electrolyte, solid polymer electrolyte and adhesive composition |
| ATE490986T1 (de) | 2005-01-21 | 2010-12-15 | Nippon Soda Co | Polymer, vernetztes polymer, zusammensetzung für ein feststoffpolymer-elektrolyt, feststoffpolymer-elektrolyt und klebstoffzusammensetzung |
| KR100612897B1 (ko) * | 2005-05-27 | 2006-08-14 | 삼성에스디아이 주식회사 | 프로톤 전도성 전해질, 그 제조방법 및 이를 이용한 연료전지 |
| JP4860986B2 (ja) * | 2005-11-11 | 2012-01-25 | 日本曹達株式会社 | 接着剤、電極作製用結着剤、及び固体電解質用組成物 |
| KR100723391B1 (ko) * | 2006-01-13 | 2007-05-30 | 삼성에스디아이 주식회사 | 고분자 전해질막 및 이를 구비한 연료전지 |
| WO2008059734A1 (en) * | 2006-11-13 | 2008-05-22 | Canon Kabushiki Kaisha | Polymer electrolyte membrane and method for producing polymer electrolyte membrane |
| JP5207625B2 (ja) * | 2006-12-25 | 2013-06-12 | 三井化学株式会社 | 導電性オレフィン系重合体 |
| JP2009001776A (ja) * | 2007-06-11 | 2009-01-08 | Rohm & Haas Co | 水性エマルジョンポリマー会合性増粘剤 |
| DE102007039535A1 (de) * | 2007-08-21 | 2009-02-26 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Pentablockcopolymeren mit OH-funktionalisierten Blöcken auf (Meth)acrylatbasis |
| CN101471453B (zh) * | 2007-12-26 | 2010-12-08 | 财团法人工业技术研究院 | 胶态高分子电解液前体组合物及包含其的二次电池 |
| JP2010235689A (ja) * | 2009-03-30 | 2010-10-21 | Sekisui Chem Co Ltd | 無機微粒子分散用バインダー樹脂、無機微粒子分散ペースト組成物及び無機微粒子分散シート |
| JP5481229B2 (ja) * | 2010-02-26 | 2014-04-23 | 日本曹達株式会社 | 網目状ポリマー及びそれを使用したゲル電解質 |
| US20130316234A1 (en) * | 2011-01-06 | 2013-11-28 | Mitsubishi Rayon Co., Ltd. | Modifier for polyvinylidene fluoride, binder resin composition for battery, electrode for secondary battery and battery |
| EP2743280B1 (en) * | 2011-08-10 | 2018-10-10 | JSR Corporation | Polymer, surface hydrophilizing agent containing said polymer, and manufacturing method for substrate having hydrophilic surface |
| CN102956365A (zh) * | 2011-08-18 | 2013-03-06 | 海洋王照明科技股份有限公司 | 电解液及其配制方法 |
| CN103159890B (zh) * | 2011-12-17 | 2015-11-25 | 清华大学 | 固体电解质的制备方法 |
| CN103159889B (zh) * | 2011-12-17 | 2015-11-25 | 清华大学 | 互穿网络聚合物及其制备方法 |
| US8947855B2 (en) | 2012-06-28 | 2015-02-03 | Empire Technology Development Llc | Copolymer electrochemical double layer capacitor |
| JP6311721B2 (ja) * | 2012-12-13 | 2018-04-18 | 東レ株式会社 | マルチブロックコポリマーおよびポリマー電解質材料 |
| KR102161266B1 (ko) * | 2013-08-30 | 2020-09-29 | 삼성전자주식회사 | 리튬 이차 전지용 전해질 및 이를 포함하는 리튬 이차 전지 |
| DE102013219602A1 (de) * | 2013-09-27 | 2015-04-16 | Robert Bosch Gmbh | Herstellungsverfahren für Lithium-Zellen-Funktionsschicht |
| JP6059743B2 (ja) * | 2014-02-17 | 2017-01-11 | 富士フイルム株式会社 | 固体電解質組成物、これを用いた電池用電極シートおよび全固体二次電池、ならびにそれらの製造方法 |
| JP6407314B2 (ja) * | 2015-02-12 | 2018-10-17 | 富士フイルム株式会社 | 全固体二次電池、これに用いる固体電解質組成物および電池用電極シートならびに電池用電極シートおよび全固体二次電池の製造方法 |
| CN105646918B (zh) * | 2016-02-03 | 2018-07-13 | 北京大学 | 基于可交联高分子材料的稳定纳米图案的制备和调控方法 |
| CN106098382A (zh) * | 2016-08-31 | 2016-11-09 | 湖南艾华集团股份有限公司 | 一种高压叠片式铝电解电容器及其制备方法 |
| JP6744928B2 (ja) * | 2017-02-16 | 2020-08-19 | 富士フイルム株式会社 | 固体電解質組成物、固体電解質含有シート及びその製造方法、全固体二次電池及びその製造方法、並びに、ポリマー及びその非水溶媒分散物 |
| JP7095683B2 (ja) * | 2017-03-28 | 2022-07-05 | 日本ゼオン株式会社 | 非水系二次電池電極用バインダー組成物、非水系二次電池電極用スラリー組成物、非水系二次電池用電極および非水系二次電池、並びに、非水系二次電池用電極の製造方法 |
| CN108666138B (zh) * | 2017-03-29 | 2020-12-29 | 东莞东阳光科研发有限公司 | 一种650-700v铝电解电容器用电解液 |
| CN108878151B (zh) * | 2017-05-09 | 2021-03-26 | 东莞市东阳光电容器有限公司 | 一种700-750v铝电解电容器用电解液 |
| WO2018229560A1 (en) * | 2017-06-16 | 2018-12-20 | National Research Council Of Canada | Solid polymer electrolyte for batteries |
| KR102529492B1 (ko) * | 2017-11-17 | 2023-05-04 | 현대자동차주식회사 | 전고체 전지의 제조 방법 및 이에 의해 제조된 전고체 전지 |
| CN108878959B (zh) * | 2018-06-14 | 2020-09-25 | 北京工业大学 | 一种有机无机复合固态电解质的制备及其应用 |
| WO2020054889A1 (ko) * | 2018-09-13 | 2020-03-19 | 주식회사 그리너지 | 고체 고분자 전해질, 이를 포함하는 전극 구조체 및 전기화학소자, 그리고 고체 고분자 전해질 막의 제조방법 |
| CN109494411B (zh) * | 2018-10-31 | 2021-08-31 | 中南大学 | 一种低温柔性聚合物固态电解质及其制备方法和应用 |
| US12054573B2 (en) * | 2020-02-05 | 2024-08-06 | Bridgestone Corporation | Functionalized polymers having thermoresponsive behavior |
| CN112271326B (zh) * | 2020-10-09 | 2022-03-29 | 中国科学院青岛生物能源与过程研究所 | 一种具有水清除功能的聚合物电解质及其应用 |
| CN119465289B (zh) * | 2024-11-07 | 2025-07-01 | 氢和元泰(常州)新材料科技有限公司 | 阴离子交换膜及其制备方法、应用和电解装置 |
Family Cites Families (21)
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| US5196484A (en) * | 1986-10-27 | 1993-03-23 | The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland | Polymeric ion conductors |
| JPH01240998A (ja) | 1988-03-22 | 1989-09-26 | Fujitsu Ltd | 伝搬遅延時間算出方式 |
| JPH03196407A (ja) | 1989-12-26 | 1991-08-27 | Ube Ind Ltd | イオン伝導性固体電解質 |
| JPH05120912A (ja) * | 1991-10-30 | 1993-05-18 | Matsushita Electric Ind Co Ltd | 高分子固体電解質 |
| JP3105137B2 (ja) * | 1993-08-18 | 2000-10-30 | 信越化学工業株式会社 | 複合固体電解質 |
| JP3000844B2 (ja) | 1994-02-16 | 2000-01-17 | 信越化学工業株式会社 | 電極組成物 |
| JPH1045994A (ja) * | 1996-08-07 | 1998-02-17 | Fukoku Co Ltd | 固体電解質 |
| US6096234A (en) * | 1997-01-23 | 2000-08-01 | Shin-Etsu Chemical Co., Ltd. | Cross-linked polymer solid electrolyte, method of manufacturing cross-linked solid polymer electrolyte, composite solid electrolyte, and thin solid cell employing composite solid electrolyte |
| JP3392687B2 (ja) | 1997-02-21 | 2003-03-31 | 信越化学工業株式会社 | ブロック−グラフト共重合体およびこれを用いて作製した高分子固体電解質 |
| JP3569612B2 (ja) | 1997-07-25 | 2004-09-22 | 信越化学工業株式会社 | ブロック−グラフト共重合体およびこれを用いて作製した自己架橋型高分子固体電解質ならびにその製造方法 |
| JPH11240998A (ja) * | 1998-02-25 | 1999-09-07 | Jsr Corp | ブロックコポリマー組成物 |
| US6361901B1 (en) * | 1998-07-23 | 2002-03-26 | Massachusetts Institute Of Technology | Self-doped microphase separated block copolymer electrolyte |
| SE518564C2 (sv) * | 1999-12-20 | 2002-10-22 | Ericsson Telefon Ab L M | Polymer elektrolyt, battericell innefattande elektrolyten, förfarande för framställning av elektrolyten samt användning av elektrolyten och battericellen |
| JP4491103B2 (ja) | 1999-12-27 | 2010-06-30 | 株式会社Kri | 多分岐高分子、その製造方法、固体電解質及び電気化学素子 |
| WO2002033765A2 (en) * | 2000-10-18 | 2002-04-25 | Du Pont-Mitsui Polychemicals Co., Ltd | Gel-type polymer electrolyte and use thereof |
| JP2002216845A (ja) | 2001-01-18 | 2002-08-02 | Nippon Synthetic Chem Ind Co Ltd:The | 高分子固体電解質及びそれを用いた電気化学素子、二次電池 |
| JP2002260441A (ja) * | 2001-03-06 | 2002-09-13 | Ube Ind Ltd | 高分子固体電解質及びその製造方法 |
| GB0114197D0 (en) * | 2001-06-11 | 2001-08-01 | Syngenta Ltd | Reactive polymeric surfactants |
| JP2003045226A (ja) * | 2001-07-26 | 2003-02-14 | Ube Ind Ltd | 高分子電解質及びその製造方法 |
| JP2003217594A (ja) * | 2002-01-18 | 2003-07-31 | Nissan Motor Co Ltd | イオン電池用電極及びその製造方法 |
| JP4155882B2 (ja) * | 2002-07-23 | 2008-09-24 | 日本曹達株式会社 | 高分子固体電解質 |
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| EP2341510B1 (en) | 2012-10-31 |
| CN1849674A (zh) | 2006-10-18 |
| US7678860B2 (en) | 2010-03-16 |
| EP1667168A4 (en) | 2009-03-04 |
| WO2005027144A1 (ja) | 2005-03-24 |
| KR100779895B1 (ko) | 2007-11-28 |
| EP1667168A1 (en) | 2006-06-07 |
| EP2341510A1 (en) | 2011-07-06 |
| KR20060106820A (ko) | 2006-10-12 |
| JP2005089510A (ja) | 2005-04-07 |
| US20070040145A1 (en) | 2007-02-22 |
| JP4562364B2 (ja) | 2010-10-13 |
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