CA2867524C - Polyesters and fibers made therefrom - Google Patents
Polyesters and fibers made therefrom Download PDFInfo
- Publication number
- CA2867524C CA2867524C CA2867524A CA2867524A CA2867524C CA 2867524 C CA2867524 C CA 2867524C CA 2867524 A CA2867524 A CA 2867524A CA 2867524 A CA2867524 A CA 2867524A CA 2867524 C CA2867524 C CA 2867524C
- Authority
- CA
- Canada
- Prior art keywords
- fiber
- polymer
- ptf
- range
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Multicomponent Fibers (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261618449P | 2012-03-30 | 2012-03-30 | |
| US61/618,449 | 2012-03-30 | ||
| PCT/US2013/034735 WO2013149222A1 (en) | 2012-03-30 | 2013-03-30 | Polyesters and fibers made therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2867524A1 CA2867524A1 (en) | 2013-10-03 |
| CA2867524C true CA2867524C (en) | 2021-02-09 |
Family
ID=48142954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2867524A Active CA2867524C (en) | 2012-03-30 | 2013-03-30 | Polyesters and fibers made therefrom |
Country Status (16)
| Country | Link |
|---|---|
| US (5) | US20150111450A1 (enExample) |
| EP (2) | EP2831317B1 (enExample) |
| JP (2) | JP2015518093A (enExample) |
| KR (1) | KR20140143414A (enExample) |
| CN (2) | CN111574696A (enExample) |
| AU (1) | AU2013237797B2 (enExample) |
| CA (1) | CA2867524C (enExample) |
| DK (1) | DK2831317T3 (enExample) |
| ES (1) | ES2879549T3 (enExample) |
| HK (1) | HK1208059A1 (enExample) |
| IN (1) | IN2014DN07006A (enExample) |
| MY (1) | MY168710A (enExample) |
| NZ (1) | NZ628958A (enExample) |
| PL (1) | PL2831317T3 (enExample) |
| SG (1) | SG11201405174YA (enExample) |
| WO (1) | WO2013149222A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012108523A1 (de) * | 2012-09-12 | 2014-05-28 | Continental Reifen Deutschland Gmbh | Verstärkungscord für elastomere Erzeugnisse, insbesondere für einen Fahrzeugluftreifen, und Fahrzeugluftreifen |
| MX384939B (es) * | 2013-06-20 | 2025-03-14 | Furanix Technologies Bv | Un procedimiento para la preparación de una fibra, una fibra y un hilo hecho con dicha fibra. |
| DE102013223496A1 (de) * | 2013-11-18 | 2015-05-21 | Tesa Se | Neuartiges Polyester geeignet zur Herstellung von Trägermaterialien für Klebebändern |
| CN110229478B (zh) * | 2013-12-20 | 2022-01-25 | 纳幕尔杜邦公司 | 聚(2,5-呋喃二甲酸1,3-丙二醇酯)(ptf)的成核结晶及其制品 |
| MX380350B (es) * | 2014-04-30 | 2025-03-12 | Stichting Wageningen Res | Poliesteres y copoliesteres termoplasticos de furanoato de poliisoidida y un uso de los mismos en envasado de llenado en caliente. |
| FR3020812B1 (fr) | 2014-05-09 | 2016-06-10 | Roquette Freres | Polyesters aromatiques thermoplastiques comprenant des motifs tetrahydrofuranedimethanol |
| FR3020811B1 (fr) * | 2014-05-09 | 2016-06-10 | Roquette Freres | Polyesters aromatiques thermoplastiques comprenant des motifs tetrahydrofuranedimethanol et acide furanedicarboxylique |
| NL2015265B1 (en) * | 2015-08-04 | 2017-02-21 | Furanix Technologies Bv | Polyester composition. |
| JP6659006B2 (ja) * | 2015-09-08 | 2020-03-04 | 株式会社ブリヂストン | Pef原糸の製造方法 |
| JP6659007B2 (ja) * | 2015-09-08 | 2020-03-04 | 株式会社ブリヂストン | タイヤ用繊維、ゴム・繊維複合体及びタイヤ |
| JP2017053060A (ja) * | 2015-09-08 | 2017-03-16 | 株式会社ブリヂストン | Pef原糸の製造方法、pef原糸及びタイヤ |
| JP6659008B2 (ja) * | 2015-09-08 | 2020-03-04 | 株式会社ブリヂストン | タイヤ用繊維、ゴム・繊維複合体及びタイヤ |
| WO2017091435A1 (en) * | 2015-11-24 | 2017-06-01 | Archer Daniels Midland Company | Oligomerizations of fdca and glycols in a one-pot esterification-transesterification process catalyzed by homogeneous organometallic lewis acids |
| EP3408308B1 (de) | 2016-01-26 | 2020-03-18 | Basf Se | Verfahren zur herstellung furan-basierter polyester |
| CA3039502A1 (en) * | 2016-10-05 | 2018-04-12 | Furanix Technologies B.V. | Process for the production of a solid-state polymerized poly(tetramethylene-2,5-furan dicarboxylate) polymer and polymer thus produced |
| EP3526272B1 (en) * | 2016-10-14 | 2023-08-23 | Covation Inc. | Process for preparing poly(trimethylene furandicarboxylate) |
| KR102860983B1 (ko) * | 2018-06-18 | 2025-09-16 | 아처 다니엘 미드랜드 캄파니 | 바이오-기반 중합체를 형성하기 위한 단량체 및 다른 반응물의 색상 안정화 |
| KR102144067B1 (ko) * | 2018-11-30 | 2020-08-28 | 주식회사 휴비스 | 폴리에틸렌프라노에이트 수지를 함유하는 폴리에스테르계 복합섬유 |
| RU2760519C1 (ru) * | 2020-12-02 | 2021-11-26 | Нина Владимировна Смирнова | Способ получения ненасыщенных полиэфирных смол |
| CN112760740B (zh) * | 2021-01-18 | 2022-12-23 | 中国科学院宁波材料技术与工程研究所 | 生物基2,5-呋喃二甲酸基共聚酯纤维及其制法与应用 |
| CA3206100A1 (en) * | 2021-01-22 | 2022-07-28 | Macleon, LLC | Optical fiber cable and system and method of distributing ultra high power using the same |
| CN115246924B (zh) * | 2021-06-02 | 2024-04-12 | 四川大学 | 一种生物降解型含呋喃基团的共聚酯及其制备与纺丝方法 |
| JP7440926B2 (ja) * | 2021-06-18 | 2024-02-29 | 平岡織染株式会社 | 産業資材シート |
| JP7545734B2 (ja) * | 2021-07-27 | 2024-09-05 | 平岡織染株式会社 | 産業用複合シート |
| US20230124025A1 (en) | 2021-09-27 | 2023-04-20 | University Of Massachusetts | Compositions and methods for biodegradable, biomass-based polyesters |
| JP7545738B2 (ja) * | 2021-10-08 | 2024-09-05 | 平岡織染株式会社 | 軟質塩化ビニル系樹脂複合シート |
| CN118895576B (zh) * | 2024-09-30 | 2025-02-11 | 上海德福伦新材料科技有限公司 | 一种聚呋喃二甲酸乙二醇酯纤维的制备方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB621971A (en) * | 1946-11-12 | 1949-04-25 | James Gordon Napier Drewitt | Improvements in polymers |
| US3671379A (en) | 1971-03-09 | 1972-06-20 | Du Pont | Composite polyester textile fibers |
| JPH075731B2 (ja) * | 1991-02-26 | 1995-01-25 | ヘキスト・アクチェンゲゼルシャフト | 芳香族コポリアミド,それらの製法、および造形構造物の製造のためのそれらの使用 |
| US5340909A (en) | 1991-12-18 | 1994-08-23 | Hoechst Celanese Corporation | Poly(1,3-propylene terephthalate) |
| EP0587022A3 (de) * | 1992-09-05 | 1995-03-01 | Hoechst Ag | Vollorientiertes Polyestergarn und Verfahren zu seiner Herstellung. |
| DE4430634A1 (de) | 1994-08-29 | 1996-03-07 | Hoechst Ag | Verfahren zur Herstellung thermostabiler, farbneutraler, antimonfreier Polyester und die danach herstellbaren Produkte |
| TW462977B (en) | 1996-06-28 | 2001-11-11 | Toray Industries | Resin compositions, processes for producing thereby, and process for producing titanium oxide |
| DE19705249A1 (de) | 1997-02-12 | 1998-08-13 | Zimmer Ag | Verfahren zur Herstellung von Polypropylenterphthalat |
| US6063495A (en) * | 1998-04-23 | 2000-05-16 | Hna Holdings, Inc. | Polyester fiber and methods for making same |
| DE69932090T3 (de) | 1998-10-30 | 2010-07-01 | Asahi Kasei Kabushiki Kaisha | Polyesterharz-zusammensetzung und fasern |
| JP5446121B2 (ja) * | 2007-04-24 | 2014-03-19 | 三菱化学株式会社 | フラン構造を含むポリエステル |
| JP5371259B2 (ja) * | 2008-02-20 | 2013-12-18 | キヤノン株式会社 | ポリエステル樹脂、その製造方法、成形品用組成物及び成形品 |
| IT1387503B (it) * | 2008-05-08 | 2011-04-13 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
| NL2002382C2 (en) * | 2008-12-30 | 2010-07-01 | Furanix Technologies Bv | A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers. |
| JP5618040B2 (ja) * | 2009-04-27 | 2014-11-05 | 独立行政法人産業技術総合研究所 | バイオベース原料を用いた高分子量脂肪族ポリエステルエーテルおよびその製造方法 |
| JP5351612B2 (ja) * | 2009-06-02 | 2013-11-27 | キヤノン株式会社 | ポリエステル、その製造方法、及び成形品 |
| JP5517494B2 (ja) * | 2009-06-03 | 2014-06-11 | キヤノン株式会社 | ポリエステル、その製造方法、及び成形品 |
| IT1399032B1 (it) * | 2009-11-06 | 2013-04-05 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
| US20110124839A1 (en) * | 2009-11-25 | 2011-05-26 | Canon Kabushiki Kaisha | Flame-retardant polyester copolymer, and production process and molded article thereof |
| IT1400121B1 (it) * | 2010-05-24 | 2013-05-17 | Novamont Spa | Copoliestere alifatico-aromatico e sue miscele. |
| CN101899145B (zh) * | 2010-07-28 | 2012-07-11 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
| US20130023608A1 (en) * | 2011-07-20 | 2013-01-24 | Patti Jean Kellett | Bio-Polymers In Multicomponent Fibers |
| BRPI1106661A2 (pt) * | 2011-09-30 | 2013-08-27 | Univ Rio De Janeiro | processo para produÇço de resinas À base de poli(2,5-furanodicarboxilato de etileno), resinas À base de poli (2,5-furanodicarboxilato de etileno) e uso das referidas resinas |
| US20130095270A1 (en) * | 2011-10-14 | 2013-04-18 | Eastman Chemical Company | Polyester compositions containing furandicarboxylic acid or an ester thereof, cyclobutanediol and cyclohexanedimethanol |
| WO2013062408A1 (en) * | 2011-10-24 | 2013-05-02 | Furanix Technologies B.V. | A process for preparing a polymer product having a 2,5-furandicarboxylate moiety within the polymer backbone to be used in bottle, film or fibre applications |
-
2013
- 2013-03-30 NZ NZ628958A patent/NZ628958A/en not_active IP Right Cessation
- 2013-03-30 WO PCT/US2013/034735 patent/WO2013149222A1/en not_active Ceased
- 2013-03-30 US US14/385,903 patent/US20150111450A1/en not_active Abandoned
- 2013-03-30 CA CA2867524A patent/CA2867524C/en active Active
- 2013-03-30 CN CN202010430189.3A patent/CN111574696A/zh active Pending
- 2013-03-30 EP EP13717633.5A patent/EP2831317B1/en active Active
- 2013-03-30 EP EP21169994.7A patent/EP3907312A1/en not_active Withdrawn
- 2013-03-30 ES ES13717633T patent/ES2879549T3/es active Active
- 2013-03-30 KR KR1020147030117A patent/KR20140143414A/ko not_active Abandoned
- 2013-03-30 AU AU2013237797A patent/AU2013237797B2/en not_active Ceased
- 2013-03-30 MY MYPI2014002403A patent/MY168710A/en unknown
- 2013-03-30 JP JP2015503668A patent/JP2015518093A/ja active Pending
- 2013-03-30 PL PL13717633T patent/PL2831317T3/pl unknown
- 2013-03-30 CN CN201380017948.1A patent/CN104395512B/zh active Active
- 2013-03-30 IN IN7006DEN2014 patent/IN2014DN07006A/en unknown
- 2013-03-30 HK HK15108559.9A patent/HK1208059A1/xx unknown
- 2013-03-30 DK DK13717633.5T patent/DK2831317T3/da active
- 2013-03-30 SG SG11201405174YA patent/SG11201405174YA/en unknown
-
2018
- 2018-05-30 JP JP2018102939A patent/JP6726231B2/ja active Active
-
2019
- 2019-04-25 US US16/394,545 patent/US20190249338A1/en not_active Abandoned
-
2022
- 2022-05-06 US US17/738,891 patent/US20220275538A1/en not_active Abandoned
-
2023
- 2023-03-31 US US18/129,542 patent/US20230235486A1/en not_active Abandoned
-
2024
- 2024-03-05 US US18/595,938 patent/US20240209548A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140143414A (ko) | 2014-12-16 |
| EP3907312A1 (en) | 2021-11-10 |
| US20230235486A1 (en) | 2023-07-27 |
| CN111574696A (zh) | 2020-08-25 |
| US20190249338A1 (en) | 2019-08-15 |
| HK1208059A1 (en) | 2016-02-19 |
| AU2013237797B2 (en) | 2017-08-24 |
| WO2013149222A1 (en) | 2013-10-03 |
| SG11201405174YA (en) | 2014-09-26 |
| JP6726231B2 (ja) | 2020-07-22 |
| AU2013237797A1 (en) | 2014-09-11 |
| ES2879549T3 (es) | 2021-11-22 |
| US20150111450A1 (en) | 2015-04-23 |
| PL2831317T3 (pl) | 2021-10-04 |
| NZ628958A (en) | 2016-02-26 |
| DK2831317T3 (da) | 2021-09-06 |
| CN104395512B (zh) | 2020-06-16 |
| US20220275538A1 (en) | 2022-09-01 |
| CN104395512A (zh) | 2015-03-04 |
| US20240209548A1 (en) | 2024-06-27 |
| EP2831317A1 (en) | 2015-02-04 |
| IN2014DN07006A (enExample) | 2015-04-10 |
| MY168710A (en) | 2018-11-29 |
| EP2831317B1 (en) | 2021-06-02 |
| JP2018150668A (ja) | 2018-09-27 |
| JP2015518093A (ja) | 2015-06-25 |
| CA2867524A1 (en) | 2013-10-03 |
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