CA2618780C - Partly oxidized mixed metal hydroxides - Google Patents
Partly oxidized mixed metal hydroxides Download PDFInfo
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- CA2618780C CA2618780C CA2618780A CA2618780A CA2618780C CA 2618780 C CA2618780 C CA 2618780C CA 2618780 A CA2618780 A CA 2618780A CA 2618780 A CA2618780 A CA 2618780A CA 2618780 C CA2618780 C CA 2618780C
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- Prior art keywords
- mixed metal
- powder
- hydroxide
- partly oxidized
- precursor
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- 229910000000 metal hydroxide Inorganic materials 0.000 title claims description 63
- 150000004692 metal hydroxides Chemical class 0.000 title claims description 63
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 37
- 239000002243 precursor Substances 0.000 claims abstract description 37
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- 239000010406 cathode material Substances 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims description 45
- 238000007254 oxidation reaction Methods 0.000 claims description 45
- 239000000843 powder Substances 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 38
- 239000011734 sodium Substances 0.000 claims description 18
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 238000009826 distribution Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 abstract description 56
- 238000000034 method Methods 0.000 abstract description 46
- 230000008569 process Effects 0.000 abstract description 37
- 239000000203 mixture Substances 0.000 abstract description 15
- 229910052804 chromium Inorganic materials 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000011572 manganese Substances 0.000 description 76
- 229910020632 Co Mn Inorganic materials 0.000 description 54
- 229910052751 metal Inorganic materials 0.000 description 39
- 239000002184 metal Substances 0.000 description 39
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- 239000000243 solution Substances 0.000 description 29
- 239000000725 suspension Substances 0.000 description 24
- 239000007795 chemical reaction product Substances 0.000 description 23
- 238000005406 washing Methods 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 19
- 239000012266 salt solution Substances 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- 239000012071 phase Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 15
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 15
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 14
- 229910017052 cobalt Inorganic materials 0.000 description 14
- 239000010941 cobalt Substances 0.000 description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 14
- 229910052759 nickel Inorganic materials 0.000 description 13
- 150000002739 metals Chemical class 0.000 description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 11
- 238000007873 sieving Methods 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000001354 calcination Methods 0.000 description 10
- 150000004679 hydroxides Chemical class 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 230000001376 precipitating effect Effects 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 239000007800 oxidant agent Substances 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 6
- 229910052808 lithium carbonate Inorganic materials 0.000 description 6
- 239000011163 secondary particle Substances 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 229910005576 NibM1 Inorganic materials 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000000975 co-precipitation Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000012798 spherical particle Substances 0.000 description 5
- 239000011149 active material Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000012527 feed solution Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 4
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000003570 air Substances 0.000 description 3
- 239000006182 cathode active material Substances 0.000 description 3
- SEVNKUSLDMZOTL-UHFFFAOYSA-H cobalt(2+);manganese(2+);nickel(2+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mn+2].[Co+2].[Ni+2] SEVNKUSLDMZOTL-UHFFFAOYSA-H 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 description 3
- 239000012086 standard solution Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- 229910032387 LiCoO2 Inorganic materials 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- 229910018060 Ni-Co-Mn Inorganic materials 0.000 description 2
- 229910018209 Ni—Co—Mn Inorganic materials 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000007600 charging Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- -1 comprising Ni Chemical class 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000320 mechanical mixture Substances 0.000 description 2
- 235000019394 potassium persulphate Nutrition 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910006025 NiCoMn Inorganic materials 0.000 description 1
- IQNRLBUERLDDJA-UHFFFAOYSA-N O(O)O.[Co].[Mn].[Ni] Chemical compound O(O)O.[Co].[Mn].[Ni] IQNRLBUERLDDJA-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010325 electrochemical charging Methods 0.000 description 1
- 238000010326 electrochemical discharging Methods 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
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- C01G51/00—Compounds of cobalt
- C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
- C01G51/82—Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements
-
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- C01G53/40—Complex oxides containing nickel and at least one other metal element
-
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
-
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- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
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- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C01P2006/40—Electric properties
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Iron (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005038158 | 2005-08-12 | ||
| DE102005038158.8 | 2005-08-12 | ||
| PCT/EP2006/007816 WO2007019986A1 (de) | 2005-08-12 | 2006-08-08 | Anorganische verbindungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2618780A1 CA2618780A1 (en) | 2007-02-22 |
| CA2618780C true CA2618780C (en) | 2015-10-20 |
Family
ID=37106922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2618780A Active CA2618780C (en) | 2005-08-12 | 2006-08-08 | Partly oxidized mixed metal hydroxides |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US20090302267A1 (enExample) |
| EP (1) | EP1912899B1 (enExample) |
| JP (2) | JP5353239B2 (enExample) |
| KR (1) | KR101306532B1 (enExample) |
| CN (2) | CN101282911A (enExample) |
| CA (1) | CA2618780C (enExample) |
| TW (1) | TW200718651A (enExample) |
| WO (1) | WO2007019986A1 (enExample) |
Families Citing this family (36)
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|---|---|---|---|---|
| JP4846309B2 (ja) * | 2005-09-09 | 2011-12-28 | 株式会社田中化学研究所 | ニッケルマンガンコバルト複合酸化物の製造方法 |
| JP5109423B2 (ja) * | 2007-03-19 | 2012-12-26 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質およびその製造方法 |
| DE102007039471A1 (de) | 2007-08-21 | 2009-02-26 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
| DE102007049108A1 (de) * | 2007-10-12 | 2009-04-16 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien |
| HUE060257T2 (hu) * | 2008-04-03 | 2023-02-28 | Lg Energy Solution Ltd | Új prekurzor lítium kompozit átmenetifém-oxid elõállítására |
| CN106395918A (zh) * | 2009-10-22 | 2017-02-15 | 户田工业株式会社 | 镍-钴-锰类化合物颗粒粉末和锂复合氧化物颗粒粉末及其制造方法和非水电解质二次电池 |
| US20120231340A1 (en) * | 2009-11-20 | 2012-09-13 | Sumitomo Chemical Company, Limited | Transition-metal-containing hydroxide and lithium-containing metal oxide |
| JP5747918B2 (ja) * | 2010-08-09 | 2015-07-15 | 日本ゼオン株式会社 | 二次電池用多孔膜、製造方法、及び用途 |
| KR101839170B1 (ko) * | 2010-09-06 | 2018-03-15 | 스미또모 가가꾸 가부시키가이샤 | 리튬 복합 금속 산화물 및 그의 제조 방법 |
| EP2619140B1 (en) | 2010-09-22 | 2016-05-11 | Freeport Cobalt Oy | Mixed metal oxidized hydroxide and method for production |
| KR101432628B1 (ko) * | 2010-09-30 | 2014-08-22 | 에스케이이노베이션 주식회사 | 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지 |
| JP5316726B2 (ja) | 2011-06-07 | 2013-10-16 | 住友金属鉱山株式会社 | ニッケル複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および、非水系電解質二次電池 |
| EP2871161B1 (en) * | 2012-07-09 | 2019-03-13 | LG Chem, Ltd. | Precursor for preparing lithium composite transition metal oxide, method for preparing same, and method for preparing a lithium composite transition metal oxide |
| WO2014061653A1 (ja) * | 2012-10-17 | 2014-04-24 | 戸田工業株式会社 | Ｌｉ－Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池 |
| KR102168979B1 (ko) * | 2012-10-17 | 2020-10-22 | 도다 고교 가부시끼가이샤 | Li-Ni 복합 산화물 입자 분말 및 비수전해질 이차 전지 |
| JP2014139119A (ja) * | 2012-12-20 | 2014-07-31 | Tosoh Corp | ニッケル−コバルト−マンガン系複合酸化物及びその製造方法、並びにその用途 |
| CN103178263A (zh) * | 2013-02-21 | 2013-06-26 | 湖南桑顿新能源有限公司 | 一种镍钴铝酸锂正极材料的制备方法 |
| JP6136604B2 (ja) * | 2013-06-10 | 2017-05-31 | 住友金属鉱山株式会社 | ニッケルコバルト複合水酸化物粒子の製造方法 |
| JP6186919B2 (ja) | 2013-06-17 | 2017-08-30 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6044463B2 (ja) | 2013-06-19 | 2016-12-14 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6357928B2 (ja) * | 2013-07-18 | 2018-07-18 | 東ソー株式会社 | ニッケル−マンガン系複合オキシ水酸化物及びその製造方法、並びにその用途 |
| TWI636613B (zh) | 2013-07-18 | 2018-09-21 | 日商東曹股份有限公司 | 鎳－錳系複合氧氫氧化物及其製造方法、以及其用途 |
| WO2016013674A1 (ja) * | 2014-07-25 | 2016-01-28 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物粒子およびその製造方法 |
| KR20160083616A (ko) * | 2014-12-31 | 2016-07-12 | 삼성에스디아이 주식회사 | 리튬이차전지용 양극 활물질의 전구체, 그 제조방법, 리튬이차전지용 양극 활물질, 그 제조방법, 및 상기 양극 활물질을 포함하는 리튬이차전지 |
| JP5967264B2 (ja) * | 2015-05-22 | 2016-08-10 | 住友金属鉱山株式会社 | 非水系電解質二次電池の正極活物質の製造方法 |
| KR101768374B1 (ko) | 2016-04-29 | 2017-08-14 | 주식회사 엘지화학 | 복합 전이금속산화물계 전구체 및 이의 제조방법, 상기 전구체를 이용한 양극활물질 |
| EP3281915B1 (en) | 2016-08-10 | 2019-02-20 | Umicore | Precursors for lithium transition metal oxide cathode materials for rechargeable batteries |
| WO2018167533A1 (en) | 2017-03-14 | 2018-09-20 | Umicore | Precursors for cathode material with improved secondary battery performance and method to prepare the precursors |
| JP7220849B2 (ja) * | 2017-12-13 | 2023-02-13 | 住友金属鉱山株式会社 | ニッケル含有水酸化物およびその製造方法 |
| KR20190106638A (ko) | 2018-03-09 | 2019-09-18 | 주식회사 엘지화학 | 리튬 이차전지 |
| WO2019172637A2 (ko) | 2018-03-09 | 2019-09-12 | 주식회사 엘지화학 | 리튬 이차전지 |
| JP7262230B2 (ja) * | 2019-01-22 | 2023-04-21 | 株式会社田中化学研究所 | 非水電解質二次電池用複合水酸化物小粒子 |
| KR20220043199A (ko) * | 2019-08-06 | 2022-04-05 | 가부시끼가이샤 다나까 가가꾸 겡뀨쇼 | 니켈 복합 수산화물 입자, 니켈 복합 수산화물 입자를 전구체로 한 양극 활물질 및 양극 활물질의 제조 방법 |
| KR102667663B1 (ko) * | 2021-09-10 | 2024-05-22 | 주식회사 엘지에너지솔루션 | 리튬 이차 전지용 양극 활물질 분말, 이의 제조 방법, 리튬 이차 전지용 양극, 및 리튬 이차 전지 |
| US20240400411A1 (en) * | 2023-05-31 | 2024-12-05 | Sylvatex, Inc. | Method for the Manufacture of Cathode Materials |
| KR20250053587A (ko) * | 2023-10-13 | 2025-04-22 | (주)에코프로머티리얼즈 | 리튬 이차 전지용 양극 활물질 전구체 및 이의 제조 방법 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2803104B1 (fr) * | 1999-12-23 | 2002-03-15 | Cit Alcatel | Electrode au nickel non frittee pour generateur electrochimique secondaire a electrolyte alcalin |
| US6350543B2 (en) * | 1999-12-29 | 2002-02-26 | Kimberly-Clark Worldwide, Inc. | Manganese-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries |
| JP3976482B2 (ja) * | 2000-08-08 | 2007-09-19 | 三洋電機株式会社 | アルカリ蓄電池用正極活物質の製造方法およびこの正極活物質を用いたニッケル電極ならびにこのニッケル電極を用いたアルカリ蓄電池 |
| JP2002201028A (ja) * | 2000-11-06 | 2002-07-16 | Tanaka Chemical Corp | 高密度コバルトマンガン共沈水酸化ニッケル及びその製造法 |
| US20020053663A1 (en) * | 2000-11-06 | 2002-05-09 | Tanaka Chemical Corporation | High density cobalt-manganese coprecipitated nickel hydroxide and process for its production |
| JP4710225B2 (ja) * | 2001-09-03 | 2011-06-29 | 株式会社Ｇｓユアサ | ニッケル電極材料の製造方法 |
| JP2003346795A (ja) * | 2002-03-19 | 2003-12-05 | Tanaka Chemical Corp | 電解酸化によるオキシ水酸化ニッケルの製造方法 |
| NZ520452A (en) | 2002-10-31 | 2005-03-24 | Lg Chemical Ltd | Anion containing mixed hydroxide and lithium transition metal oxide with gradient of metal composition |
| CN100381365C (zh) * | 2003-04-17 | 2008-04-16 | 清美化学股份有限公司 | 含锂-镍-钴-锰复合氧化物及锂二次电池用正极活性物质用原料和它们的制造方法 |
| JP4412936B2 (ja) * | 2003-07-31 | 2010-02-10 | パナソニック株式会社 | オキシ水酸化コバルトおよびその製造方法ならびにそれを用いたアルカリ蓄電池 |
-
2006
- 2006-08-08 US US11/990,273 patent/US20090302267A1/en not_active Abandoned
- 2006-08-08 CN CNA2006800336317A patent/CN101282911A/zh active Pending
- 2006-08-08 CN CN201510386454.1A patent/CN105129870A/zh active Pending
- 2006-08-08 JP JP2008525463A patent/JP5353239B2/ja active Active
- 2006-08-08 WO PCT/EP2006/007816 patent/WO2007019986A1/de not_active Ceased
- 2006-08-08 KR KR1020087005942A patent/KR101306532B1/ko active Active
- 2006-08-08 CA CA2618780A patent/CA2618780C/en active Active
- 2006-08-08 EP EP06776660A patent/EP1912899B1/de active Active
- 2006-08-10 TW TW095129295A patent/TW200718651A/zh unknown
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2012
- 2012-06-04 US US13/487,477 patent/US20120305861A1/en not_active Abandoned
- 2012-11-01 JP JP2012241931A patent/JP5716001B2/ja active Active
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2016
- 2016-09-16 US US15/267,167 patent/US10326133B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US10326133B2 (en) | 2019-06-18 |
| US20170033358A1 (en) | 2017-02-02 |
| EP1912899A1 (de) | 2008-04-23 |
| KR101306532B1 (ko) | 2013-09-09 |
| TW200718651A (en) | 2007-05-16 |
| JP2013056827A (ja) | 2013-03-28 |
| US20120305861A1 (en) | 2012-12-06 |
| JP5716001B2 (ja) | 2015-05-13 |
| KR20080043347A (ko) | 2008-05-16 |
| CA2618780A1 (en) | 2007-02-22 |
| US20090302267A1 (en) | 2009-12-10 |
| CN105129870A (zh) | 2015-12-09 |
| WO2007019986A1 (de) | 2007-02-22 |
| JP5353239B2 (ja) | 2013-11-27 |
| JP2009515799A (ja) | 2009-04-16 |
| EP1912899B1 (de) | 2012-10-10 |
| CN101282911A (zh) | 2008-10-08 |
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