CA2529842C - Polyether ester elastic fiber and fabric, clothing using the same - Google Patents
Polyether ester elastic fiber and fabric, clothing using the same Download PDFInfo
- Publication number
- CA2529842C CA2529842C CA2529842A CA2529842A CA2529842C CA 2529842 C CA2529842 C CA 2529842C CA 2529842 A CA2529842 A CA 2529842A CA 2529842 A CA2529842 A CA 2529842A CA 2529842 C CA2529842 C CA 2529842C
- Authority
- CA
- Canada
- Prior art keywords
- polyether ester
- elastic fiber
- fiber
- coefficient
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 210000004177 elastic tissue Anatomy 0.000 title claims abstract description 108
- 150000002148 esters Chemical class 0.000 title claims abstract description 90
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 72
- 229920000570 polyether Polymers 0.000 title claims abstract description 72
- 239000004744 fabric Substances 0.000 title claims abstract description 42
- 238000010521 absorption reaction Methods 0.000 claims abstract description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 48
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 41
- 229920001971 elastomer Polymers 0.000 claims abstract description 24
- 239000000806 elastomer Substances 0.000 claims abstract description 24
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 15
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 58
- 239000003921 oil Substances 0.000 claims description 23
- 125000001931 aliphatic group Chemical group 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 14
- 238000007334 copolymerization reaction Methods 0.000 claims description 14
- 239000002480 mineral oil Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 150000001340 alkali metals Chemical class 0.000 claims description 8
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 8
- 125000000524 functional group Chemical group 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims 1
- 238000002844 melting Methods 0.000 description 23
- 238000000034 method Methods 0.000 description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 238000006068 polycondensation reaction Methods 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 238000009987 spinning Methods 0.000 description 8
- 238000004804 winding Methods 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 5
- 229920001515 polyalkylene glycol Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical group O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- VIBDJEWPNNCFQO-UHFFFAOYSA-N ethane-1,1,2-triol Chemical group OCC(O)O VIBDJEWPNNCFQO-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000003578 releasing effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- YZLGIRGCZODDCE-UHFFFAOYSA-M sodium;3,5-bis(2-hydroxyethoxycarbonyl)benzenesulfonate Chemical compound [Na+].OCCOC(=O)C1=CC(C(=O)OCCO)=CC(S([O-])(=O)=O)=C1 YZLGIRGCZODDCE-UHFFFAOYSA-M 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- IOGGBUVFUGPCLQ-UHFFFAOYSA-N 1-[4-(2-oxoazepane-1-carbonyl)benzoyl]azepan-2-one Chemical compound C=1C=C(C(=O)N2C(CCCCC2)=O)C=CC=1C(=O)N1CCCCCC1=O IOGGBUVFUGPCLQ-UHFFFAOYSA-N 0.000 description 1
- IZTHTNFCHNNDAQ-QXMHVHEDSA-N 11-methyldodecyl (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCCCCC(C)C IZTHTNFCHNNDAQ-QXMHVHEDSA-N 0.000 description 1
- YTPNTTUPPCGZPJ-UHFFFAOYSA-N 11-methyldodecyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C YTPNTTUPPCGZPJ-UHFFFAOYSA-N 0.000 description 1
- HFWHTGSLDKKCMD-UHFFFAOYSA-N 2,2-bis(octanoyloxymethyl)butyl octanoate Chemical compound CCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCC)COC(=O)CCCCCCC HFWHTGSLDKKCMD-UHFFFAOYSA-N 0.000 description 1
- KKKKCPPTESQGQH-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-yl)-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=NCCO1 KKKKCPPTESQGQH-UHFFFAOYSA-N 0.000 description 1
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 1
- VETJNXLHVDPVOS-UHFFFAOYSA-N 3-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=CC(C(O)=O)=C1 VETJNXLHVDPVOS-UHFFFAOYSA-N 0.000 description 1
- KUEAXNDTBSKPSJ-UHFFFAOYSA-N 3-(2-hydroxyethoxycarbonyl)benzenesulfonic acid Chemical compound OCCOC(=O)C1=CC=CC(S(O)(=O)=O)=C1 KUEAXNDTBSKPSJ-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- 101100278987 Arabidopsis thaliana ECH2 gene Proteins 0.000 description 1
- 229910014033 C-OH Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910014570 C—OH Inorganic materials 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OXPCWUWUWIWSGI-MSUUIHNZSA-N Lauryl oleate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC OXPCWUWUWIWSGI-MSUUIHNZSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- DJNTZVRUYMHBTD-UHFFFAOYSA-N Octyl octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCC DJNTZVRUYMHBTD-UHFFFAOYSA-N 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- CJFLBOQMPJCWLR-UHFFFAOYSA-N bis(6-methylheptyl) hexanedioate Chemical compound CC(C)CCCCCOC(=O)CCCCC(=O)OCCCCCC(C)C CJFLBOQMPJCWLR-UHFFFAOYSA-N 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- QICYQWTZZBCCIA-UHFFFAOYSA-L disodium;3,7-bis(methoxycarbonyl)naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C21 QICYQWTZZBCCIA-UHFFFAOYSA-L 0.000 description 1
- OGTMSWHHHRTOEF-UHFFFAOYSA-L disodium;3,7-dicarboxynaphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].C1=C(C(O)=O)C=C(S([O-])(=O)=O)C2=CC(C(=O)O)=CC(S([O-])(=O)=O)=C21 OGTMSWHHHRTOEF-UHFFFAOYSA-L 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002291 germanium compounds Chemical class 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- AVPYUFDQTKOBNG-UHFFFAOYSA-M lithium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [Li+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 AVPYUFDQTKOBNG-UHFFFAOYSA-M 0.000 description 1
- ZERIVMMUDSPYOZ-UHFFFAOYSA-M lithium;3,7-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [Li+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC=C21 ZERIVMMUDSPYOZ-UHFFFAOYSA-M 0.000 description 1
- GGKPBCOOXDBLLG-UHFFFAOYSA-M lithium;3-carboxy-5-sulfobenzoate Chemical compound [Li+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 GGKPBCOOXDBLLG-UHFFFAOYSA-M 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- BOUFCKNHBCJKDP-UHFFFAOYSA-M potassium;3,5-bis(2-hydroxyethoxycarbonyl)benzenesulfonate Chemical compound [K+].OCCOC(=O)C1=CC(C(=O)OCCO)=CC(S([O-])(=O)=O)=C1 BOUFCKNHBCJKDP-UHFFFAOYSA-M 0.000 description 1
- FJIZBDJKYXYPAE-UHFFFAOYSA-M potassium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [K+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 FJIZBDJKYXYPAE-UHFFFAOYSA-M 0.000 description 1
- DVBBBJFTGOHNHC-UHFFFAOYSA-M potassium;3,5-dicarboxybenzenesulfonate Chemical compound [K+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 DVBBBJFTGOHNHC-UHFFFAOYSA-M 0.000 description 1
- KJNLNBUCZYHGPG-UHFFFAOYSA-M potassium;3,7-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [K+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC=C21 KJNLNBUCZYHGPG-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- SLOMLIJJTAEWQA-UHFFFAOYSA-M sodium;2,6-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=C(C(=O)OC)C=CC2=CC(C(=O)OC)=CC=C21 SLOMLIJJTAEWQA-UHFFFAOYSA-M 0.000 description 1
- LLHSEQCZSNZLRI-UHFFFAOYSA-M sodium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [Na+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 LLHSEQCZSNZLRI-UHFFFAOYSA-M 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- PKAZXAJFBXZMAY-UHFFFAOYSA-M sodium;3,7-bis(methoxycarbonyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=C(C(=O)OC)C=C(S([O-])(=O)=O)C2=CC(C(=O)OC)=CC=C21 PKAZXAJFBXZMAY-UHFFFAOYSA-M 0.000 description 1
- YGCFNVDNEPLPGM-UHFFFAOYSA-M sodium;3,7-bis(methoxycarbonyl)naphthalene-2-sulfonate Chemical compound [Na+].C1=C(C(=O)OC)C(S([O-])(=O)=O)=CC2=CC(C(=O)OC)=CC=C21 YGCFNVDNEPLPGM-UHFFFAOYSA-M 0.000 description 1
- PXMZGQMCKRIHHE-UHFFFAOYSA-M sodium;3,7-dicarboxynaphthalene-1-sulfonate Chemical compound [Na+].C1=C(C(O)=O)C=C(S([O-])(=O)=O)C2=CC(C(=O)O)=CC=C21 PXMZGQMCKRIHHE-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
- Knitting Of Fabric (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003175788 | 2003-06-20 | ||
| JP2003-175788 | 2003-06-20 | ||
| JP2003-329584 | 2003-09-22 | ||
| JP2003329584 | 2003-09-22 | ||
| PCT/JP2004/008940 WO2004113599A1 (ja) | 2003-06-20 | 2004-06-18 | ポリエーテルエステル弾性繊維及びこれを用いた布帛、衣料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2529842A1 CA2529842A1 (en) | 2004-12-29 |
| CA2529842C true CA2529842C (en) | 2011-07-12 |
Family
ID=33543484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2529842A Expired - Fee Related CA2529842C (en) | 2003-06-20 | 2004-06-18 | Polyether ester elastic fiber and fabric, clothing using the same |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060177655A1 (ko) |
| EP (1) | EP1643019B1 (ko) |
| JP (1) | JP4202361B2 (ko) |
| KR (1) | KR101183498B1 (ko) |
| CA (1) | CA2529842C (ko) |
| DE (1) | DE602004029254D1 (ko) |
| HK (1) | HK1116520A1 (ko) |
| TW (2) | TW200722563A (ko) |
| WO (1) | WO2004113599A1 (ko) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9700077B2 (en) | 2004-03-19 | 2017-07-11 | Nike, Inc. | Article of apparel with variable air permeability |
| US20050208857A1 (en) | 2004-03-19 | 2005-09-22 | Nike, Inc. | Article of apparel incorporating a modifiable textile structure |
| US7437774B2 (en) | 2004-03-19 | 2008-10-21 | Nike, Inc. | Article of apparel incorporating a zoned modifiable textile structure |
| JP2007023417A (ja) * | 2005-07-15 | 2007-02-01 | Teijin Fibers Ltd | 嵩高吸湿弾性糸及びその製造方法 |
| US8187984B2 (en) | 2006-06-09 | 2012-05-29 | Malden Mills Industries, Inc. | Temperature responsive smart textile |
| JP4983138B2 (ja) * | 2006-08-03 | 2012-07-25 | パナソニック株式会社 | 高分子発熱体 |
| US8389100B2 (en) | 2006-08-29 | 2013-03-05 | Mmi-Ipco, Llc | Temperature responsive smart textile |
| JP2008057099A (ja) | 2006-08-29 | 2008-03-13 | Mmi-Ipco Llc | 感温性スマートテキスタイル |
| JP2008069124A (ja) * | 2006-09-15 | 2008-03-27 | Teijin Fibers Ltd | 化粧料 |
| JP4947796B2 (ja) * | 2007-06-08 | 2012-06-06 | 竹本油脂株式会社 | 合成繊維用ストレート型処理剤、これを用いる合成繊維仮撚加工糸の処理方法及び合成繊維仮撚加工糸 |
| JP2009235242A (ja) * | 2008-03-27 | 2009-10-15 | Teijin Fibers Ltd | 共重合ポリエステル及びポリエステル繊維 |
| JP2009235243A (ja) * | 2008-03-27 | 2009-10-15 | Teijin Fibers Ltd | 共重合ポリエステル及びポリエステル繊維 |
| US10039610B2 (en) | 2008-08-08 | 2018-08-07 | Medline Industries, Inc. | Zip strip draping system and methods of manufacturing same |
| US9334608B2 (en) | 2009-10-20 | 2016-05-10 | Teijin Frontier Co., Ltd. | Polyester fiber, method for producing the same, cloth, textile product, and polyester formed article |
| JP5748475B2 (ja) * | 2010-12-24 | 2015-07-15 | 株式会社ムツミテキスタイル | ポリウレタン系弾性繊維からなる丸編地とその製造方法及びその丸編地を用いた伸縮性衣料と伸縮性衣料資材 |
| TW201233858A (en) * | 2010-12-20 | 2012-08-16 | Toray Opelontex Co Ltd | Knitting having elastic fibers, the method for preparation thereof, and stretchable clothes and stretchable cloth materials using the same |
| US10455872B2 (en) | 2011-10-18 | 2019-10-29 | Medline Industries, Inc. | Disposable medical gown |
| USD836297S1 (en) | 2011-10-18 | 2018-12-25 | Medline Industries, Inc. | Medical gown |
| USD785284S1 (en) | 2011-10-18 | 2017-05-02 | Medline Industries, Inc. | Medical gown |
| USD791434S1 (en) | 2011-10-18 | 2017-07-11 | Medline Industries, Inc. | Medical gown |
| USD774729S1 (en) | 2011-10-18 | 2016-12-27 | Medline Industries, Inc. | Medical gown |
| CA144409S (en) | 2011-10-18 | 2013-06-18 | Medline Ind Inc | Medical gown |
| USD863727S1 (en) | 2011-10-18 | 2019-10-22 | Medline Industries, Inc. | Medical gown |
| USD821704S1 (en) | 2011-10-18 | 2018-07-03 | Medline Industries, Inc. | Medical gown |
| USD779156S1 (en) | 2011-10-18 | 2017-02-21 | Medline Industries, Inc. | Medical gown |
| US10441010B2 (en) | 2011-10-18 | 2019-10-15 | Medline Industries, Inc. | Disposable medical gown |
| KR101494319B1 (ko) | 2013-07-30 | 2015-02-23 | 주식회사 휴비스 | 영구압축 변형율이 낮은 열접착 섬유 |
| US11116263B2 (en) | 2013-11-21 | 2021-09-14 | Medline Industries, Inc. | Gown for self-donning while maintaining sterility and methods therefor |
| KR102291563B1 (ko) * | 2014-12-30 | 2021-08-19 | 코오롱플라스틱 주식회사 | 3d 프린팅용 조성물 및 이를 이용한 3d 프린터용 필라멘트 |
| KR102400353B1 (ko) * | 2015-04-13 | 2022-05-24 | 주식회사 휴비스 | 수분전이 특성에 의한 자율 통기조절기능이 향상된 탄성섬유 |
| KR101822643B1 (ko) | 2015-12-28 | 2018-01-30 | 주식회사 휴비스 | 폴리에스테르계 탄성부직포를 이용한 의류용 신축심지 |
| WO2019172108A1 (ja) * | 2018-03-07 | 2019-09-12 | 株式会社クラレ | 溶融異方性芳香族ポリエステルマルチフィラメント |
| KR101970598B1 (ko) * | 2018-06-15 | 2019-05-17 | (주) 정산인터내셔널 | 폴리에스테르-에테르 블록공중합체의 원사를 이용한 투명성이 강화된 원단 및 그 제조방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR870001132B1 (ko) * | 1983-04-14 | 1987-06-09 | 도오요오 보오세끼 가부시끼가이샤 | 제전성섬유 및 그 제조방법 |
| JPH073029B2 (ja) * | 1986-03-28 | 1995-01-18 | 東レ株式会社 | 吸水性ウエツブの製造法 |
| US4906729A (en) * | 1988-08-05 | 1990-03-06 | E. I. Du Pont De Nemours And Company | Thermoplastic copolyetherester elastomers |
| JPH08209459A (ja) * | 1995-02-07 | 1996-08-13 | Nippon Ester Co Ltd | ポリエーテルエステル系弾性糸の製造法 |
| JP3577362B2 (ja) * | 1995-06-12 | 2004-10-13 | 帝人ファイバー株式会社 | 抄紙用熱接着性繊維及び紙 |
| JP3592842B2 (ja) * | 1996-07-08 | 2004-11-24 | 帝人ファイバー株式会社 | ポリエステル系弾性繊維及びそれからなる伸縮性湿式不織布 |
| JPH11279883A (ja) | 1998-03-24 | 1999-10-12 | Mitsubishi Rayon Co Ltd | ポリエステル複合糸 |
| JP2000073232A (ja) * | 1998-08-26 | 2000-03-07 | Nippon Ester Co Ltd | 吸湿性ポリエステル繊維 |
| CN1254580C (zh) * | 2000-07-31 | 2006-05-03 | 三洋化成工业株式会社 | 用于弹性纤维的纺丝油剂 |
| JP4064149B2 (ja) * | 2002-05-17 | 2008-03-19 | 帝人ファイバー株式会社 | エラストマー組成物及びそれよりなる繊維 |
-
2004
- 2004-06-18 EP EP04746409A patent/EP1643019B1/en not_active Expired - Lifetime
- 2004-06-18 JP JP2005507293A patent/JP4202361B2/ja not_active Expired - Lifetime
- 2004-06-18 CA CA2529842A patent/CA2529842C/en not_active Expired - Fee Related
- 2004-06-18 WO PCT/JP2004/008940 patent/WO2004113599A1/ja active Application Filing
- 2004-06-18 KR KR1020057024465A patent/KR101183498B1/ko active IP Right Grant
- 2004-06-18 TW TW095148263A patent/TW200722563A/zh unknown
- 2004-06-18 US US10/561,155 patent/US20060177655A1/en not_active Abandoned
- 2004-06-18 TW TW093117766A patent/TWI285688B/zh not_active IP Right Cessation
- 2004-06-18 DE DE602004029254T patent/DE602004029254D1/de not_active Expired - Lifetime
-
2008
- 2008-05-19 HK HK08105508.6A patent/HK1116520A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1643019A1 (en) | 2006-04-05 |
| WO2004113599A1 (ja) | 2004-12-29 |
| JP4202361B2 (ja) | 2008-12-24 |
| HK1116520A1 (en) | 2008-12-24 |
| DE602004029254D1 (de) | 2010-11-04 |
| KR20060021910A (ko) | 2006-03-08 |
| TW200722563A (en) | 2007-06-16 |
| KR101183498B1 (ko) | 2012-09-20 |
| EP1643019B1 (en) | 2010-09-22 |
| US20060177655A1 (en) | 2006-08-10 |
| TWI285688B (en) | 2007-08-21 |
| CA2529842A1 (en) | 2004-12-29 |
| EP1643019A4 (en) | 2007-09-05 |
| JPWO2004113599A1 (ja) | 2006-07-20 |
| TW200502451A (en) | 2005-01-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20150618 |