CA2529842A1 - Polyether ester elastic fiber and fabric, clothing using the same - Google Patents
Polyether ester elastic fiber and fabric, clothing using the same Download PDFInfo
- Publication number
- CA2529842A1 CA2529842A1 CA002529842A CA2529842A CA2529842A1 CA 2529842 A1 CA2529842 A1 CA 2529842A1 CA 002529842 A CA002529842 A CA 002529842A CA 2529842 A CA2529842 A CA 2529842A CA 2529842 A1 CA2529842 A1 CA 2529842A1
- Authority
- CA
- Canada
- Prior art keywords
- polyether ester
- elastic fiber
- fiber according
- ester elastic
- crystal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004177 elastic tissue Anatomy 0.000 title claims abstract 22
- 150000002148 esters Chemical class 0.000 title claims abstract 19
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract 18
- 229920000570 polyether Polymers 0.000 title claims abstract 18
- 239000004744 fabric Substances 0.000 title claims abstract 3
- 238000010521 absorption reaction Methods 0.000 claims abstract 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920001971 elastomer Polymers 0.000 claims abstract 4
- 239000000806 elastomer Substances 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims abstract 4
- 239000002184 metal Substances 0.000 claims abstract 4
- -1 polybutylene terephthalate Polymers 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract 2
- 238000002844 melting Methods 0.000 claims 6
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 239000003921 oil Substances 0.000 claims 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- 239000002480 mineral oil Substances 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 238000003795 desorption Methods 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Abstract
An elastic fiber which is made of a polyether ester elastomer comprising polybutylene terephthalate as the hard segment and polyoxyethylene glycol as the soft segment and containing a specific metal organosulfonate in a state copolymerized therewith and exhibits a moisture absorption of 5% or above at 35~C and 95%RH and an elongation on water absorption of 10 % or above. Since the elastic fiber is excellent in moisture absorption characteristics and stretches and shrinks remarkably and reversibly in accordance with the absorption and desorption of water, comfortable fabrics can be made of the elastic fiber. Further, the elastic fiber is recyclable.
Claims (13)
1. A polyether ester elastic fiber comprising a polyether ester elastomer containing polybutylene terephthalate as a hard segment and polyoxyethylene glycol as a soft segment, characterized by having a coefficient of moisture absorption of not less than 5 % at 35°C and at a RH of 95 % and a coefficient of water absorption extension of not less than 10 %.
2. The polyether ester elastic fiber according to Claim 1, wherein the polyether ester elastomer is copolymerized with a metal organic sulfonate represented by the following general formula (1), and the intrinsic viscosity of the elastic fiber is not less than 0.9.
(wherein, R1 represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group, X1 represents an ester-forming functional group, X2 represents an ester-forming functional group identical to or different from X1 or a hydrogen atom, M1 represents an alkali metal or an alkaline earth metal, j represents 1 or 2).
(wherein, R1 represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group, X1 represents an ester-forming functional group, X2 represents an ester-forming functional group identical to or different from X1 or a hydrogen atom, M1 represents an alkali metal or an alkaline earth metal, j represents 1 or 2).
3. The polyether ester elastic fiber according to Claim 2, wherein the shrinkage percentage of the elastic fiber in boiling water is not less than %.
4. The polyether ester elastic fiber according to Claim 2, wherein the metal organic sulfonate is a compound represented by the following general formula (2).
(wherein, R2 represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group, M2 represents an alkali metal or an alkaline earth metal).
(wherein, R2 represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group, M2 represents an alkali metal or an alkaline earth metal).
5. The polyether ester elastic fiber according to Claim 2, wherein the copolymerization quantity of the metal organic sulfonate is in a range of 0.1 to 20 percent by mole based on the acid component constituting the polyether ester elastomer.
6. The polyether ester elastic fiber according to Claim 1, wherein the elastic fiber has two crystal-melting peaks in a DSC curved line obtained with a differential scanning calorimeter, has a Hm1 / Hm2 ratio of the height Hm1 of the crystal-melting peak on the lower temperature side / the height Hm2 of the crystal-melting peak on the higher temperature side in a range of 0.6 to 1.2, and has a breaking elongation of not less than 400 %.
7. The polyether ester elastic fiber according to Claim 6, wherein the temperature Tm1 of the crystal-melting peak on the lower temperature side and the temperature Tm2 of the crystal-melting peak on the higher temperature side among the two crystal-melting peaks satisfy the following expression.
200°C~Tm1<Tm2~225°C
200°C~Tm1<Tm2~225°C
8. The polyether ester elastic fiber according to one of Claims 1, 2 and 6, wherein the ratio of the hard segment : the soft segment is in a range of 30 : 70 to 70 : 30 based on weight.
9. The polyether ester elastic fiber according to one of Claims 1, 2 and 6, wherein a finishing oil in which at least one lubricant selected from the group consisting of mineral oils, silicones and aliphatic esters and an ether-based or ester-based nonionic surfactant occupy 70 to 100 percent by weight and 0 to 30 percent by weight, respectively, of said finishing oil is adhered to the surface of the elastic fiber in an amount of 0.5 to 5.0 percent by weight based on the weight of said fiber.
10. The polyether ester elastic fiber according to Claim 9, wherein the viscosity of the finishing oil at 30°C is 5×10 -6 to 4 × 10 -5 m2/s.
11. A fabric in whose at least one portion the polyether ester elastic fibers according to one of Claims 1, 2 and 6 are used.
12. Clothing in whose at least one portion the polyether ester elastic fibers according to one of Claims 1, 2 and 6 are used.
13. Underwear, sportswear, lining, pantyhose, or socks in whose at least one portion the polyether ester elastic fibers according to one of Claims 1, 2 and 6 are used.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003175788 | 2003-06-20 | ||
| JP2003-175788 | 2003-06-20 | ||
| JP2003329584 | 2003-09-22 | ||
| JP2003-329584 | 2003-09-22 | ||
| PCT/JP2004/008940 WO2004113599A1 (en) | 2003-06-20 | 2004-06-18 | Polyether ester elastic fiber and fabrics and clothes made by using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2529842A1 true CA2529842A1 (en) | 2004-12-29 |
| CA2529842C CA2529842C (en) | 2011-07-12 |
Family
ID=33543484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2529842A Expired - Fee Related CA2529842C (en) | 2003-06-20 | 2004-06-18 | Polyether ester elastic fiber and fabric, clothing using the same |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060177655A1 (en) |
| EP (1) | EP1643019B1 (en) |
| JP (1) | JP4202361B2 (en) |
| KR (1) | KR101183498B1 (en) |
| CA (1) | CA2529842C (en) |
| DE (1) | DE602004029254D1 (en) |
| HK (1) | HK1116520A1 (en) |
| TW (2) | TW200722563A (en) |
| WO (1) | WO2004113599A1 (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9700077B2 (en) | 2004-03-19 | 2017-07-11 | Nike, Inc. | Article of apparel with variable air permeability |
| US7437774B2 (en) | 2004-03-19 | 2008-10-21 | Nike, Inc. | Article of apparel incorporating a zoned modifiable textile structure |
| US20050208857A1 (en) | 2004-03-19 | 2005-09-22 | Nike, Inc. | Article of apparel incorporating a modifiable textile structure |
| JP2007023417A (en) * | 2005-07-15 | 2007-02-01 | Teijin Fibers Ltd | Moisture-absorbing bulky elastic yarn and method for producing the same |
| US8187984B2 (en) | 2006-06-09 | 2012-05-29 | Malden Mills Industries, Inc. | Temperature responsive smart textile |
| JP4983138B2 (en) * | 2006-08-03 | 2012-07-25 | パナソニック株式会社 | Polymer heating element |
| JP2008057099A (en) | 2006-08-29 | 2008-03-13 | Mmi-Ipco Llc | Temperature responsive smart textile |
| US8389100B2 (en) | 2006-08-29 | 2013-03-05 | Mmi-Ipco, Llc | Temperature responsive smart textile |
| JP2008069124A (en) * | 2006-09-15 | 2008-03-27 | Teijin Fibers Ltd | Cosmetic |
| JP4947796B2 (en) * | 2007-06-08 | 2012-06-06 | 竹本油脂株式会社 | Synthetic fiber straight-twisting agent, synthetic fiber false twisted yarn processing method using the same, and synthetic fiber false twisted yarn |
| JP2009235243A (en) * | 2008-03-27 | 2009-10-15 | Teijin Fibers Ltd | Copolyester and polyester fiber |
| JP2009235242A (en) * | 2008-03-27 | 2009-10-15 | Teijin Fibers Ltd | Copolyester and polyester fiber |
| US10039610B2 (en) | 2008-08-08 | 2018-08-07 | Medline Industries, Inc. | Zip strip draping system and methods of manufacturing same |
| KR101748895B1 (en) | 2009-10-20 | 2017-06-19 | 데이진 프론티아 가부시키가이샤 | Polyester fibers, process for production of the polyester fibers, cloth, fiber product, and polyester molded article |
| TW201233858A (en) * | 2010-12-20 | 2012-08-16 | Toray Opelontex Co Ltd | Knitting having elastic fibers, the method for preparation thereof, and stretchable clothes and stretchable cloth materials using the same |
| JP5748475B2 (en) * | 2010-12-24 | 2015-07-15 | 株式会社ムツミテキスタイル | Circular knitted fabric made of polyurethane elastic fiber, method for producing the same, and elastic clothing and elastic clothing material using the circular knitted fabric |
| USD774729S1 (en) | 2011-10-18 | 2016-12-27 | Medline Industries, Inc. | Medical gown |
| USD821704S1 (en) | 2011-10-18 | 2018-07-03 | Medline Industries, Inc. | Medical gown |
| USD836297S1 (en) | 2011-10-18 | 2018-12-25 | Medline Industries, Inc. | Medical gown |
| CA144409S (en) | 2011-10-18 | 2013-06-18 | Medline Ind Inc | Medical gown |
| US10455872B2 (en) | 2011-10-18 | 2019-10-29 | Medline Industries, Inc. | Disposable medical gown |
| USD785284S1 (en) | 2011-10-18 | 2017-05-02 | Medline Industries, Inc. | Medical gown |
| USD863727S1 (en) | 2011-10-18 | 2019-10-22 | Medline Industries, Inc. | Medical gown |
| US10441010B2 (en) | 2011-10-18 | 2019-10-15 | Medline Industries, Inc. | Disposable medical gown |
| USD791434S1 (en) | 2011-10-18 | 2017-07-11 | Medline Industries, Inc. | Medical gown |
| USD779156S1 (en) | 2011-10-18 | 2017-02-21 | Medline Industries, Inc. | Medical gown |
| KR101494319B1 (en) | 2013-07-30 | 2015-02-23 | 주식회사 휴비스 | Hot Melt Adhesive Fiber Having Lower Compression Set |
| US11116263B2 (en) | 2013-11-21 | 2021-09-14 | Medline Industries, Inc. | Gown for self-donning while maintaining sterility and methods therefor |
| KR102291563B1 (en) * | 2014-12-30 | 2021-08-19 | 코오롱플라스틱 주식회사 | Composition for 3D Printing and Filament for 3D Printer |
| KR102400353B1 (en) * | 2015-04-13 | 2022-05-24 | 주식회사 휴비스 | Self-ventilated elastomer fiber by moisture sensitive mechanism |
| KR101822643B1 (en) | 2015-12-28 | 2018-01-30 | 주식회사 휴비스 | Stretching The Core With A Polyester-Based Elastic Non-woven Fabric |
| JP7042328B2 (en) * | 2018-03-07 | 2022-03-25 | 株式会社クラレ | Melt Anisotropy Aromatic Polyester Multifilament |
| KR101970598B1 (en) * | 2018-06-15 | 2019-05-17 | (주) 정산인터내셔널 | Textile with enhanced transparency using yarn of polyester-ether block copolymer and manufacturing method thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR870001132B1 (en) * | 1983-04-14 | 1987-06-09 | 도오요오 보오세끼 가부시끼가이샤 | Antistatic fiber containing polyoxyalkylene glycol |
| JPH073029B2 (en) * | 1986-03-28 | 1995-01-18 | 東レ株式会社 | Method for manufacturing absorbent web |
| US4906729A (en) * | 1988-08-05 | 1990-03-06 | E. I. Du Pont De Nemours And Company | Thermoplastic copolyetherester elastomers |
| JPH08209459A (en) * | 1995-02-07 | 1996-08-13 | Nippon Ester Co Ltd | Production of polyetherester elastic yarn |
| JP3577362B2 (en) * | 1995-06-12 | 2004-10-13 | 帝人ファイバー株式会社 | Thermal adhesive fiber and paper for papermaking |
| JP3592842B2 (en) * | 1996-07-08 | 2004-11-24 | 帝人ファイバー株式会社 | Polyester elastic fiber and stretchable wet nonwoven fabric comprising the same |
| JPH11279883A (en) | 1998-03-24 | 1999-10-12 | Mitsubishi Rayon Co Ltd | Polyester conjugate yarn |
| JP2000073232A (en) * | 1998-08-26 | 2000-03-07 | Nippon Ester Co Ltd | Moisture-absorbing polyester fiber |
| WO2002010500A1 (en) * | 2000-07-31 | 2002-02-07 | Sanyo Chemical Industries, Ltd. | Lubricants for elastic fiber |
| JP4064149B2 (en) * | 2002-05-17 | 2008-03-19 | 帝人ファイバー株式会社 | Elastomer composition and fiber comprising the same |
-
2004
- 2004-06-18 CA CA2529842A patent/CA2529842C/en not_active Expired - Fee Related
- 2004-06-18 TW TW095148263A patent/TW200722563A/en unknown
- 2004-06-18 KR KR1020057024465A patent/KR101183498B1/en active IP Right Grant
- 2004-06-18 EP EP04746409A patent/EP1643019B1/en not_active Not-in-force
- 2004-06-18 WO PCT/JP2004/008940 patent/WO2004113599A1/en active Application Filing
- 2004-06-18 US US10/561,155 patent/US20060177655A1/en not_active Abandoned
- 2004-06-18 JP JP2005507293A patent/JP4202361B2/en active Active
- 2004-06-18 TW TW093117766A patent/TWI285688B/en active
- 2004-06-18 DE DE602004029254T patent/DE602004029254D1/en active Active
-
2008
- 2008-05-19 HK HK08105508.6A patent/HK1116520A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| HK1116520A1 (en) | 2008-12-24 |
| JPWO2004113599A1 (en) | 2006-07-20 |
| KR101183498B1 (en) | 2012-09-20 |
| EP1643019A1 (en) | 2006-04-05 |
| EP1643019B1 (en) | 2010-09-22 |
| KR20060021910A (en) | 2006-03-08 |
| DE602004029254D1 (en) | 2010-11-04 |
| JP4202361B2 (en) | 2008-12-24 |
| US20060177655A1 (en) | 2006-08-10 |
| WO2004113599A1 (en) | 2004-12-29 |
| EP1643019A4 (en) | 2007-09-05 |
| TWI285688B (en) | 2007-08-21 |
| CA2529842C (en) | 2011-07-12 |
| TW200502451A (en) | 2005-01-16 |
| TW200722563A (en) | 2007-06-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20150618 |