BR9914717A - Matalocenos em ponte para copolimerização de olefinas - Google Patents
Matalocenos em ponte para copolimerização de olefinasInfo
- Publication number
- BR9914717A BR9914717A BR9914717-3A BR9914717A BR9914717A BR 9914717 A BR9914717 A BR 9914717A BR 9914717 A BR9914717 A BR 9914717A BR 9914717 A BR9914717 A BR 9914717A
- Authority
- BR
- Brazil
- Prior art keywords
- polymerization
- bridge
- catalyst
- atom
- olefin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10532998P | 1998-10-23 | 1998-10-23 | |
| US13106799P | 1999-04-26 | 1999-04-26 | |
| PCT/US1999/024944 WO2000024793A1 (en) | 1998-10-23 | 1999-10-22 | Bridged metallocenes for olefin copolymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9914717A true BR9914717A (pt) | 2001-07-10 |
Family
ID=26802468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9914717-3A BR9914717A (pt) | 1998-10-23 | 1999-10-22 | Matalocenos em ponte para copolimerização de olefinas |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6528670B1 (enExample) |
| EP (1) | EP1196464B9 (enExample) |
| JP (1) | JP4689829B2 (enExample) |
| KR (1) | KR100568839B1 (enExample) |
| CN (1) | CN1138796C (enExample) |
| AT (1) | ATE284422T1 (enExample) |
| AU (1) | AU757241B2 (enExample) |
| BR (1) | BR9914717A (enExample) |
| CA (1) | CA2345628C (enExample) |
| DE (1) | DE69922548T2 (enExample) |
| ES (1) | ES2233109T3 (enExample) |
| HK (1) | HK1041705A1 (enExample) |
| MX (1) | MXPA01003978A (enExample) |
| RU (1) | RU2232766C2 (enExample) |
| WO (1) | WO2000024793A1 (enExample) |
Families Citing this family (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2263497T3 (es) * | 1999-10-22 | 2006-12-16 | Exxonmobil Chemical Patents Inc. | Complejos cationicos de carbenio adecuados para catalizadores de polimerizacion. |
| US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
| US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
| JP4610859B2 (ja) * | 2002-09-27 | 2011-01-12 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| AU2003211542B8 (en) | 2002-09-27 | 2009-08-13 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
| KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
| EP1589044A3 (en) | 2003-08-11 | 2006-02-15 | ExxonMobil Chemical Patents Inc. | Polymers of ethylene and, optionally, copolymerizable esters, films using such polymers and stretch hood packaging processes using such films |
| US8263722B2 (en) * | 2004-03-24 | 2012-09-11 | Exxonmobil Chemical Patents Inc. | Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers |
| KR20070061567A (ko) * | 2004-03-31 | 2007-06-13 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조 방법 |
| WO2006044149A1 (en) * | 2004-10-13 | 2006-04-27 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
| RU2410388C2 (ru) * | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
| EP1734059A1 (en) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Carbon-bridged cyclopentadienyl-fluorenyl ligands |
| EP1994065A1 (en) * | 2006-03-02 | 2008-11-26 | Exxonmobil Chemical Patents Inc. | Process for producing propylene copolymers |
| KR101395970B1 (ko) | 2006-05-17 | 2014-05-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 고온 폴리에틸렌 용액 중합 방법 |
| EP1903061A1 (en) * | 2006-09-25 | 2008-03-26 | Total Petrochemicals Research Feluy | Preparation of diphenyl-bridged substituted cyclopentadienyl-fluorenyl ligands |
| EP2083046A1 (en) | 2008-01-25 | 2009-07-29 | ExxonMobil Chemical Patents Inc. | Thermoplastic elastomer compositions |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| FR2934599B1 (fr) * | 2008-07-29 | 2012-12-21 | Arkema France | Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations |
| US8378042B2 (en) * | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
| CN102762782A (zh) | 2009-12-23 | 2012-10-31 | 英威达技术有限公司 | 包含抗粘添加剂的弹性纤维 |
| CN107411883A (zh) | 2009-12-23 | 2017-12-01 | 英威达技术有限公司 | 包括聚烯烃弹性纤维的弹力制品 |
| CN104264305B (zh) | 2009-12-23 | 2019-09-17 | 英威达技术有限公司 | 包含聚烯烃弹性纤维的织物 |
| MX2012007399A (es) | 2009-12-23 | 2012-07-17 | Invista Tech Sarl | Fibra elastica de poliolefina. |
| US8425847B2 (en) | 2010-01-14 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
| CN102190749B (zh) * | 2010-03-05 | 2013-02-20 | 中国石油天然气股份有限公司 | 一种乙烯/α-烯烃共聚合的方法 |
| JP6355815B2 (ja) * | 2014-03-21 | 2018-07-11 | エクソンモービル・ケミカル・パテンツ・インク | エチレンプロピレンコポリマーを製造する方法 |
| US10336845B2 (en) | 2014-09-30 | 2019-07-02 | Exxonmobil Chemical Patents Inc. | Low ethylene amorphous propylene-ethylene-diene terpolymer compositions |
| CN107148446B (zh) | 2015-01-14 | 2020-06-16 | 埃克森美孚化学专利公司 | 聚合物组合物及其生产方法 |
| CN107667123B (zh) * | 2015-04-20 | 2020-09-01 | 埃克森美孚化学专利公司 | 聚乙烯组合物 |
| US10640583B2 (en) | 2015-04-20 | 2020-05-05 | Exxonmobil Chemical Patents, Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
| EP3307794B1 (en) | 2015-06-15 | 2019-02-27 | ExxonMobil Chemical Patents Inc. | Process for continuous solution polymerization |
| KR102034973B1 (ko) | 2015-09-29 | 2019-10-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 스파이럴 열교환기를 사용하는 중합 |
| CN108602928B (zh) | 2016-02-12 | 2022-01-28 | 埃克森美孚化学专利公司 | 环烯烃共聚物及其制备方法 |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| CN109641988B (zh) | 2016-07-14 | 2021-09-14 | 埃克森美孚化学专利公司 | 双金属茂催化的双峰共聚物组合物 |
| WO2018022263A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Polymerization processes using high molecular weight polyhydric quenching agents |
| EP3541823B1 (en) | 2016-11-18 | 2020-12-30 | Borealis AG | Catalysts |
| EP3555148B1 (en) | 2016-12-15 | 2023-04-05 | Borealis AG | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| WO2018108917A1 (en) * | 2016-12-15 | 2018-06-21 | Borealis Ag | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| CN110352195B (zh) | 2016-12-29 | 2022-11-11 | 博里利斯股份公司 | 催化剂 |
| US10508179B2 (en) | 2017-02-28 | 2019-12-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM |
| US10730978B2 (en) | 2017-04-10 | 2020-08-04 | Exxonmobil Chemical Patents Inc. | Linear ethylene cyclic olefin polymers |
| CN111032772B (zh) | 2017-06-14 | 2022-07-15 | 埃克森美孚化学专利公司 | 用于交联应用的乙烯共聚物共混物 |
| US10683376B2 (en) * | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| US10995166B2 (en) * | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| KR102455607B1 (ko) * | 2017-11-10 | 2022-10-14 | 한화솔루션 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
| US11008449B2 (en) | 2017-11-14 | 2021-05-18 | Exxonmobil Chemical Patents Inc. | Bimodal ethylene, alpha-olefin, and diene polymers using dual organometallic catalysts |
| US11046793B2 (en) | 2018-02-22 | 2021-06-29 | Exxonmobil Chemical Patents Inc. | Silica quenching agents for use in polymerization process |
| US10654949B2 (en) | 2018-02-22 | 2020-05-19 | Exxonmobil Chemical Patents Inc. | High molecular weight functionalized olefin copolymer quenching agent |
| US11142593B2 (en) | 2018-02-22 | 2021-10-12 | Exxonmobil Chemical Patents Inc. | Lecithin quenching agent |
| US11542346B2 (en) | 2018-03-19 | 2023-01-03 | Borealis Ag | Catalysts for olefin polymerization |
| EP3814388A1 (en) | 2018-06-28 | 2021-05-05 | Borealis AG | Catalysts |
| US11466149B2 (en) | 2018-07-23 | 2022-10-11 | Exxonmobil Chemical Patents Inc. | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom |
| CN112703210B (zh) | 2018-07-23 | 2022-10-28 | 埃克森美孚化学专利公司 | 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品 |
| SG11202102663QA (en) | 2018-09-19 | 2021-04-29 | Exxonmobil Chemical Patents Inc | Devolatilization processes |
| CN112805289B (zh) * | 2018-11-06 | 2024-09-06 | 陶氏环球技术有限责任公司 | 烷烃可溶的非茂金属预催化剂 |
| US11248113B2 (en) | 2018-11-30 | 2022-02-15 | Exxonmobil Chemical Patents Inc. | Cyclic olefin copolymers and films prepared therefrom |
| WO2020167399A1 (en) | 2019-02-11 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Biphasic polymerization processes and ethylene-based polyolefins therefrom |
| EP3763745A1 (en) * | 2019-07-10 | 2021-01-13 | Borealis AG | High temperature solution process for the copolymerization of alpha-olefins |
| US20230002525A1 (en) | 2019-12-17 | 2023-01-05 | Exxonmobil Chemical Patents Inc. | Solution Polymerization Process for Making High-Density Polyethylene with Long-Chain Branching |
| CN115916892A (zh) | 2020-07-02 | 2023-04-04 | 国际人造丝公司 | 含有茂金属多峰共聚物橡胶的热塑性硫化橡胶组合物及其制造方法 |
| KR102897897B1 (ko) * | 2020-09-30 | 2025-12-08 | 보레알리스 게엠베하 | 개선된 용융 및 유리 전이 온도를 갖는 에틸렌 코폴리머 |
| US20230295354A1 (en) * | 2020-09-30 | 2023-09-21 | Borealis Ag | Ethylene copolymers with improved melting and glass transition temperature |
| WO2022114635A1 (ko) * | 2020-11-25 | 2022-06-02 | 한화솔루션 주식회사 | 전이금속 화합물, 이를 포함하는 촉매 및 이들의 제조방법 |
| WO2022260891A1 (en) | 2021-06-11 | 2022-12-15 | Exxonmobil Chemical Patents Inc. | Processes for making polypropylene random copolymers and products made therefrom |
| EP4437014A1 (en) | 2021-11-23 | 2024-10-02 | ExxonMobil Chemical Patents Inc. | Plants and processes for forming polymers |
| WO2023114813A1 (en) | 2021-12-17 | 2023-06-22 | Exxonmobil Chemical Patents Inc. | Processes for making propylene-based copolymers having broad cds and mwds |
| KR102888044B1 (ko) * | 2022-01-13 | 2025-11-18 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| KR102831436B1 (ko) * | 2022-01-13 | 2025-07-09 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| KR20250049337A (ko) | 2022-08-09 | 2025-04-11 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 디페닐실란 가교 c1 대칭 촉매의 제조 방법 및 이로부터 제조된 중합체 |
| WO2024073260A1 (en) | 2022-09-28 | 2024-04-04 | Exxonmobil Chemical Patents Inc. | Ethylene copolymers for photovoltaic cells |
| CN115572341B (zh) * | 2022-11-04 | 2024-04-23 | 大连万慷工业科技有限公司 | 一类功能化聚烯烃弹性体及其制备方法 |
| WO2025034262A1 (en) | 2023-08-07 | 2025-02-13 | ExxonMobil Technology and Engineering Company | Ethylene copolymer compositions and articles made thereof |
| WO2025136494A1 (en) | 2023-12-20 | 2025-06-26 | ExxonMobil Technology and Engineering Company | Ethylene copolymers for photovoltaic cells |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
| DE3916553A1 (de) * | 1989-05-20 | 1990-11-22 | Hoechst Ag | Syndio- isoblockpolymer und verfahren zu seiner herstellung |
| EP0481480B1 (en) | 1990-10-17 | 1995-01-25 | Idemitsu Kosan Company Limited | Process for producing propylene based oligomers |
| EP0513380B2 (en) | 1990-11-30 | 2011-02-23 | Idemitsu Kosan Company Limited | Process for producing olefinic polymer |
| JP3193066B2 (ja) | 1991-05-02 | 2001-07-30 | 三菱化学株式会社 | プロピレンランダム共重合体の製造法 |
| US5401817A (en) | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
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| US6313240B1 (en) | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
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-
1999
- 1999-10-22 RU RU2001113445/04A patent/RU2232766C2/ru not_active IP Right Cessation
- 1999-10-22 BR BR9914717-3A patent/BR9914717A/pt not_active IP Right Cessation
- 1999-10-22 AT AT99974265T patent/ATE284422T1/de not_active IP Right Cessation
- 1999-10-22 KR KR1020017004930A patent/KR100568839B1/ko not_active Expired - Fee Related
- 1999-10-22 AU AU13212/00A patent/AU757241B2/en not_active Ceased
- 1999-10-22 DE DE69922548T patent/DE69922548T2/de not_active Expired - Lifetime
- 1999-10-22 JP JP2000578362A patent/JP4689829B2/ja not_active Expired - Lifetime
- 1999-10-22 EP EP99974265A patent/EP1196464B9/en not_active Expired - Lifetime
- 1999-10-22 CA CA2345628A patent/CA2345628C/en not_active Expired - Fee Related
- 1999-10-22 ES ES99974265T patent/ES2233109T3/es not_active Expired - Lifetime
- 1999-10-22 WO PCT/US1999/024944 patent/WO2000024793A1/en not_active Ceased
- 1999-10-22 MX MXPA01003978A patent/MXPA01003978A/es not_active IP Right Cessation
- 1999-10-22 US US09/426,099 patent/US6528670B1/en not_active Expired - Lifetime
- 1999-10-22 HK HK02103341.8A patent/HK1041705A1/zh unknown
- 1999-10-22 CN CNB998123811A patent/CN1138796C/zh not_active Expired - Lifetime
-
2002
- 2002-03-07 US US10/092,660 patent/US6506857B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6506857B2 (en) | 2003-01-14 |
| EP1196464A1 (en) | 2002-04-17 |
| KR100568839B1 (ko) | 2006-04-10 |
| CA2345628A1 (en) | 2000-05-04 |
| MXPA01003978A (es) | 2003-06-06 |
| AU1321200A (en) | 2000-05-15 |
| CN1138796C (zh) | 2004-02-18 |
| KR20010099705A (ko) | 2001-11-09 |
| JP2002528463A (ja) | 2002-09-03 |
| US20020137959A1 (en) | 2002-09-26 |
| CA2345628C (en) | 2010-02-16 |
| ATE284422T1 (de) | 2004-12-15 |
| WO2000024793A8 (en) | 2001-10-11 |
| US6528670B1 (en) | 2003-03-04 |
| EP1196464B9 (en) | 2005-03-23 |
| JP4689829B2 (ja) | 2011-05-25 |
| RU2232766C2 (ru) | 2004-07-20 |
| CN1328580A (zh) | 2001-12-26 |
| EP1196464B1 (en) | 2004-12-08 |
| DE69922548D1 (de) | 2005-01-13 |
| WO2000024793A1 (en) | 2000-05-04 |
| DE69922548T2 (de) | 2006-01-05 |
| ES2233109T3 (es) | 2005-06-01 |
| AU757241B2 (en) | 2003-02-06 |
| HK1041705A1 (zh) | 2002-07-19 |
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