BR9807851A - Copolìmeros de olefinas a partir de compostos de catalisadores do grupo 4 e bis(arilamido) ligados em ponte - Google Patents

Copolìmeros de olefinas a partir de compostos de catalisadores do grupo 4 e bis(arilamido) ligados em ponte

Info

Publication number
BR9807851A
BR9807851A BR9807851-8A BR9807851A BR9807851A BR 9807851 A BR9807851 A BR 9807851A BR 9807851 A BR9807851 A BR 9807851A BR 9807851 A BR9807851 A BR 9807851A
Authority
BR
Brazil
Prior art keywords
bis
group
olefins
copolymers
catalyst compounds
Prior art date
Application number
BR9807851-8A
Other languages
English (en)
Inventor
Timothy Daniel Shaffer
Kevin Richard Squire
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of BR9807851A publication Critical patent/BR9807851A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Patente de Invenção: <B>"COPOLìMEROS DE OLEFINAS A PARTIR DE COMPOSTO DE CATALISADORES DO GRUPO 4 E BIS(ARILAMIDO) LIGADOS EM PONTE"<D>. é descrito um processo para preparação de copolímeros substancialmente aleatórios de olefinas contendo monómeros de olefinas geminalmente dissubstituídas. Os monómeros de olefinas geminalmente dissubstituídas podem ser representados pela fórmula genérica R~ 1~=R~ 2~(R~ 3~)(R~ 4~), onde R~ 1~ é CH~ 2~ , R~ 2~ é C e R~ 3~ e R~ 4~ são independemente, essencialmente grupos hidrocarbila lineares tendo de 1 a 30 átomos de carbono ou mais, e contendo um átomo de carbono ligado diretamente a R~ 2~. Os copolímeros podem ser preparados pondo-se em contato pelo menos um monómero de olefina gemicalmente dissubstituída e um ou mais comonómeros selecionados a partir do grupo consistindo de etileno, e C~ 3~-C~ 20<244>- olefinas, opcionalmente com um ou mais outros monómeros polimerizáveis por coordenação, com um sistema catalisador de coordenação ativo contendo um componente de catalisador do Grupo 4 e bis(arilamido) ligado em ponte.
BR9807851-8A 1997-02-24 1998-02-23 Copolìmeros de olefinas a partir de compostos de catalisadores do grupo 4 e bis(arilamido) ligados em ponte BR9807851A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/803,687 US6100354A (en) 1997-02-24 1997-02-24 Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
PCT/US1998/003499 WO1998037109A1 (en) 1997-02-24 1998-02-23 Olefin copolymers from bridged bis(arylamido) group 4 catalyst compounds

Publications (1)

Publication Number Publication Date
BR9807851A true BR9807851A (pt) 2000-02-22

Family

ID=25187182

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9807851-8A BR9807851A (pt) 1997-02-24 1998-02-23 Copolìmeros de olefinas a partir de compostos de catalisadores do grupo 4 e bis(arilamido) ligados em ponte

Country Status (10)

Country Link
US (1) US6100354A (pt)
EP (1) EP0963384B1 (pt)
JP (1) JP2001512521A (pt)
KR (1) KR100531533B1 (pt)
CN (1) CN100389131C (pt)
BR (1) BR9807851A (pt)
CA (1) CA2278282C (pt)
DE (1) DE69817542T2 (pt)
ES (1) ES2201445T3 (pt)
WO (1) WO1998037109A1 (pt)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998034961A1 (fr) * 1997-02-07 1998-08-13 Mitsui Chemicals, Inc. Catalyseur de polymerisation d'olefines et procede de preparation de polymeres olefiniques
US6586646B1 (en) 1997-06-20 2003-07-01 Pennzoil-Quaker State Company Vinylidene-containing polymers and uses thereof
US6124513A (en) 1997-06-20 2000-09-26 Pennzoil-Quaker State Company Ethylene-alpha-olefin polymers, processes and uses
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
AU751049B2 (en) * 1998-04-15 2002-08-08 Shell Internationale Research Maatschappij B.V. Catalyst system for alpha-olefin oligomerization
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
DE60038900D1 (de) 1999-12-20 2008-06-26 Exxonmobil Chem Patents Inc Verfahren zur herstellung von polyolefinen mittels verträgter ionischer katalysatoren
KR20010082913A (ko) * 2000-02-22 2001-08-31 박찬구 아미도계 ｉｖ족 금속 착화합물을 이용한 폴리이소부텐의제조방법
GB0102440D0 (en) 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
EP1788002A4 (en) * 2004-08-27 2009-08-19 Mitsui Chemicals Inc OLEFINIC POLYMERIZATION CATALYSTS, PROCESS FOR PRODUCING OLEFIN POLYMERS, OLEFIN COPOLYMERS, NEW TRANSITION METAL COMPOUNDS, AND PROCESSES FOR PRODUCING TRANSITION METAL COMPOUNDS

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JPH0710900B2 (ja) * 1982-06-18 1995-02-08 エクソン リサーチ アンド エンヂニアリング コムパニー 中級蒸留物燃料油用流動性改良剤
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DE3444111A1 (de) * 1984-12-04 1986-06-05 Basf Ag, 6700 Ludwigshafen Anorganische fuellstoffe fuer reaktivkunststoffsysteme
US4774301A (en) * 1987-06-08 1988-09-27 The Dow Chemical Company Zirconium containing catalysts and method of use
US5039766A (en) * 1988-06-28 1991-08-13 Sumitomo Chemical Company, Limited Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system
EP0569388B1 (en) * 1990-12-27 1996-03-13 Exxon Chemical Patents Inc. An amido transition metal compound and a catalyst system for the production of isotactic polypropylene
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JP2888639B2 (ja) * 1992-04-20 1999-05-10 エクソン・ケミカル・パテンツ・インク エチレン／分枝鎖オレフィンのコポリマー
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US5763556A (en) * 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins

Also Published As

Publication number Publication date
DE69817542D1 (de) 2003-10-02
CA2278282A1 (en) 1998-08-27
KR100531533B1 (ko) 2005-11-28
JP2001512521A (ja) 2001-08-21
WO1998037109A1 (en) 1998-08-27
CN100389131C (zh) 2008-05-21
CN1257511A (zh) 2000-06-21
US6100354A (en) 2000-08-08
ES2201445T3 (es) 2004-03-16
KR20000075567A (ko) 2000-12-15
EP0963384B1 (en) 2003-08-27
DE69817542T2 (de) 2004-06-24
CA2278282C (en) 2007-07-31
EP0963384A1 (en) 1999-12-15

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