BR9913192A - Processos para a produção de carbonatos de dialquila, e para a produção de carbonato de dimetila, e, catalisador homogêneo útil para reagir uréia e álcoois primários para produzir carbonatos de dialquila - Google Patents

Processos para a produção de carbonatos de dialquila, e para a produção de carbonato de dimetila, e, catalisador homogêneo útil para reagir uréia e álcoois primários para produzir carbonatos de dialquila

Info

Publication number
BR9913192A
BR9913192A BR9913192-7A BR9913192A BR9913192A BR 9913192 A BR9913192 A BR 9913192A BR 9913192 A BR9913192 A BR 9913192A BR 9913192 A BR9913192 A BR 9913192A
Authority
BR
Brazil
Prior art keywords
del
ins
production
dialkyl carbonates
date
Prior art date
Application number
BR9913192-7A
Other languages
English (en)
Other versions
BR9913192B1 (pt
Inventor
J Yong Ryu
Original Assignee
Catalytic Distillation Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytic Distillation Tech filed Critical Catalytic Distillation Tech
Publication of BR9913192A publication Critical patent/BR9913192A/pt
Publication of BR9913192B1 publication Critical patent/BR9913192B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • B01D3/322—Reboiler specifications
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
    • B01J2231/4288—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using O nucleophiles, e.g. alcohols, carboxylates, esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

"PROCESSOS PARA A PRODUçãO DE CARBONATOS DE DIALQUILA, E PARA A PRODUçãO DE CARBONATO DE DIMETILA, E, CATALISADOR HOMOGêNEO úTIL PARA REAGIR URéIA E áLCOOIS PRIMáRIOS PARA PRODUZIR CARBONATOS DE DIALQUILA". Um processo para produzir carbonatos de dialquila, tais como, carbonato de dimetila, a partir da reação de um álcool primário com uréia na presença de um novo catalisador que é um complexo de organoestanho com um composto doador de elétron de alta ebulição agindo como solvente que são ligandos bidentados que formam adutos 1:1 bidentados e/ou 1:2 monodentados com R'~ 2~SnX~ 2~ (X = C1, R'O, R'COO ou R'COS), R'~ 3~SnX, R'~ 2~SnO, Ph~ 3-n~R'SnX~ n~ ou Ph~ 4-n~SnX~ n~ (em que R'=C~ q~H~ 2q-1~ n = 0,1ou 2 e q = 2 a 12) e misturas destes, tais como, materiais tendo a fórmula geral RO[CH~ 2~(CH~ 2~)~ k~CH~ 2~O]~ m~R, em que cada R é independentemente selecionado de metadas de alquila, alcarila ou araquila C~ 1-12~, k= 0, 1, 2 ou 3 e m = 1, 2, 3, 4 ou 5.
BRPI9913192-7A 1998-08-26 1999-08-10 processo para a produção de carbonatos de dialquila. BR9913192B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/140,435 US5902894A (en) 1998-08-26 1998-08-26 Process for making dialkyl carbonates
PCT/US1999/018108 WO2000012212A1 (en) 1998-08-26 1999-08-10 Process and catalyst for making dialkyl carbonates

Publications (2)

Publication Number Publication Date
BR9913192A true BR9913192A (pt) 2001-05-15
BR9913192B1 BR9913192B1 (pt) 2011-11-01

Family

ID=22491199

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9913192-7A BR9913192B1 (pt) 1998-08-26 1999-08-10 processo para a produção de carbonatos de dialquila.

Country Status (15)

Country Link
US (3) US5902894A (pt)
EP (1) EP1112120B1 (pt)
JP (1) JP4768124B2 (pt)
KR (1) KR100649291B1 (pt)
CN (1) CN1163303C (pt)
AT (1) ATE279983T1 (pt)
AU (1) AU749963B2 (pt)
BR (1) BR9913192B1 (pt)
CA (1) CA2341209C (pt)
DE (1) DE69921339T2 (pt)
ES (1) ES2226425T3 (pt)
ID (1) ID28897A (pt)
RO (1) RO121680B1 (pt)
RU (1) RU2219162C2 (pt)
WO (1) WO2000012212A1 (pt)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6392078B1 (en) * 2000-06-12 2002-05-21 Catalytic Distillation Technologies Process and catalyst for making dialkyl carbonates
JP2001354623A (ja) * 2000-06-12 2001-12-25 Mitsubishi Gas Chem Co Inc ジアルキルカーボネートの製造方法
FR2815274B1 (fr) * 2000-10-13 2002-12-20 Rhodia Chimie Sa Utilisations de derives de l'etain comme catalyseurs de transcarbamatation, compostions de carbamate comportant ledit catalyseur et procedes de transcarbamatation
US6541653B2 (en) * 2001-04-26 2003-04-01 Steven S. C. Chuang Synthesis of carbamate through low pressure heterogeneous oxidative carbonylation of amines
GB2375762B (en) * 2001-05-21 2003-10-01 Fermenta Biotech Ltd Stereospecific synthesis of 2-hydroxy-4-phenyl-butyric acid esters
US6774256B2 (en) * 2001-06-22 2004-08-10 Exxonmobil Chemical Patents Inc. Low corrosive integrated process for preparing dialkyl carbonates
US7084292B2 (en) * 2001-06-22 2006-08-01 Exxonmobil Chemical Patents Inc. Integrated process for preparing dialkyl carbonates with a circulating catalyst
US7049457B2 (en) * 2003-09-05 2006-05-23 Exxonmobil Chemical Patents Inc. Use of an ionic halide free copper catalyst for the production of dialkyl carbonates
DE10341952B4 (de) * 2003-09-11 2008-11-20 Lurgi Gmbh Zwischenprodukt bestehend aus einer Mischung von organischen Carbonaten und Carbamaten und ein Verfahren zu seiner Herstellung
US7074951B2 (en) * 2004-03-12 2006-07-11 Ryu J Yong Process for making dialkyl carbonates
RU2367648C2 (ru) * 2004-04-08 2009-09-20 Каталитик Дистиллейшн Текнолоджиз Способ получения диалкилкарбонатов
CN100395019C (zh) * 2004-08-27 2008-06-18 中国科学院山西煤炭化学研究所 用于由尿素和甲醇合成碳酸二甲酯的催化剂及其制法和应用
WO2008031755A1 (de) * 2006-09-12 2008-03-20 Basf Se Verfahren zur herstellung von isocyanaten
ES2398307T3 (es) * 2007-01-23 2013-03-15 Shell Internationale Research Maatschappij B.V. Proceso para la preparación de un alcanodiol y un carbonato de dialquilo
FR2914641B1 (fr) * 2007-04-06 2009-09-11 Arkema France Procede de co-production de carbonates non cycliques et d'amino-acides
CN101417229B (zh) 2007-10-22 2015-03-11 拜耳材料科技(中国)有限公司 用于有机碳酸酯合成的催化剂、其制备方法及其用途
US7851645B2 (en) * 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
US8110698B2 (en) * 2008-02-11 2012-02-07 Shell Oil Company Process for producing diphenyl carbonate
KR101102537B1 (ko) 2009-07-31 2012-01-04 재단법인 포항산업과학연구원 디알킬카보네이트를 제조하는 방법
IT1396205B1 (it) * 2009-10-13 2012-11-16 Eni Spa Composizione di gasolio comprendente dietil carbonato da bioetanolo.
KR101486483B1 (ko) * 2010-04-13 2015-01-27 에스케이이노베이션 주식회사 폴리(알킬렌 카보네이트)와 다양한 고분자와의 블록 또는 그라프트 공중합체
JP5952384B2 (ja) 2011-04-20 2016-07-13 リサーチ インスティチュート オブ インダストリアル サイエンス アンド テクノロジー ジアルキルカーボネートの製造方法
CN103288645B (zh) * 2012-02-23 2016-03-16 亚申科技研发中心（上海）有限公司 尿素醇解法联产碳酸二甲酯和二甲醚的工艺中分离二甲醚并回收氨的方法
CN103787888B (zh) * 2012-10-30 2017-07-28 亚申科技研发中心（上海）有限公司 一种尿素醇解法制备碳酸二甲酯工艺中的物质分离方法及装置
JP6344134B2 (ja) * 2014-08-18 2018-06-20 三菱瓦斯化学株式会社 ジアルキルカーボネートの製造方法
CN105618147B (zh) * 2014-10-28 2018-10-12 中国石油化工股份有限公司 一种合成碳酸二甲酯的催化剂及其制备方法和应用
CN104744247B (zh) * 2015-03-13 2016-06-22 中国科学院化学研究所 一种碳酸烷基酯的制备方法
CN106478421B (zh) 2015-08-31 2019-09-13 亚申科技(浙江)有限公司 碳酸二甲酯生产工艺
WO2019039317A1 (ja) * 2017-08-21 2019-02-28 三菱瓦斯化学株式会社 ジアルキルカーボネートの製造方法
CN108358786B (zh) 2018-02-01 2021-07-13 雷永诚 一种尿素醇解制备碳酸二烷基酯的方法
WO2020075152A2 (en) 2018-10-11 2020-04-16 Shell Oil Company A composition and uses thereof
CN109603802A (zh) * 2018-12-25 2019-04-12 开封中科新材料有限公司 用于由尿素和甲醇合成碳酸二甲酯的复合型催化剂及其制备方法和应用
IT202000003251A1 (it) 2020-02-18 2021-08-18 Dipharma Francis Srl Preparazione di un analgesico non steroideo

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2903506A1 (de) * 1979-01-30 1980-08-07 Bayer Ag Verfahren zur herstellung von kohlensaeureestern und seine anwendung zur herstellung von polycarbonaten
DE3112794A1 (de) * 1981-03-31 1982-10-07 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von kohlensaeureestern
US4360477A (en) * 1981-11-09 1982-11-23 General Electric Company Carbonylation of alkanols
US4435595A (en) * 1982-04-26 1984-03-06 Eastman Kodak Company Reactive distillation process for the production of methyl acetate
JPH0237907B2 (ja) * 1982-12-14 1990-08-28 Mitsubishi Gas Chemical Co Tansanesuterunoseizohoho
JPS60202153A (ja) * 1984-03-26 1985-10-12 Toshiba Silicone Co Ltd シリコ−ンゴム用触媒組成物
US4559316A (en) * 1984-09-21 1985-12-17 The Standard Oil Company Copper-zirconium-manganese-containing catalysts
US4851555A (en) * 1984-10-25 1989-07-25 Scientific Design Company, Inc. Process for preparing alkylene oxides from alkylene carbonates
US4601995A (en) * 1985-11-04 1986-07-22 Ashland Oil, Inc. Organo tin catalysts modified with bicyclic amide acetals
US4788083A (en) * 1986-03-27 1988-11-29 Ashland Oil, Inc. Tin or bismuth complex catalysts and trigger cure of coatings therewith
US4939294A (en) * 1989-05-22 1990-07-03 Eastman Kodak Company Preparation of ultra high purity methyl acetate
IT1248687B (it) * 1990-06-04 1995-01-26 Enichem Sintesi Processo per la produzione di dimetilcarbonato ed apparecchiatura adatta allo scopo
JPH0832667B2 (ja) * 1991-02-26 1996-03-29 宇部興産株式会社 炭酸ジメチルの精製法
DE4129316A1 (de) * 1991-09-03 1993-03-04 Bayer Ag Verfahren zur kontinuierlichen herstellung von dialkylcarbonaten
DE4215479A1 (de) * 1992-05-11 1993-11-18 Hoechst Ag Umsetzungsprodukte von Dialkylzinnoxid und mehrwertigen Phenolen
GB2280672A (en) * 1993-08-06 1995-02-08 Exxon Chemical Patents Inc Process for the production of alcohol carbonates
JP3374863B2 (ja) * 1993-08-12 2003-02-10 三菱瓦斯化学株式会社 ジアルキルカーボネートの製造方法
US5565603A (en) * 1993-12-20 1996-10-15 Saleh; Ramzi Y. Process for manufacturing dialkyl carbonate from urea and alcohol
JPH0892167A (ja) * 1994-09-21 1996-04-09 Idemitsu Kosan Co Ltd 芳香族炭酸ジエステルの製造方法
CA2133231A1 (en) * 1994-09-29 1996-03-30 Kuen-Yuan Hwang Process for preparing carbonate compounds
JP3881386B2 (ja) * 1994-10-21 2007-02-14 多摩化学工業株式会社 炭酸ジアルキルの製造方法
US5545600A (en) * 1994-12-21 1996-08-13 Knudsen; George A. Process for the preparation of dialkyltin dialkoxide
US5759941A (en) * 1995-02-10 1998-06-02 Exxon Chemical Patents Inc Process for the preparation of dialkyltin dialkoxide from alkyl carbamate and alcohol
JP3136950B2 (ja) * 1995-05-12 2001-02-19 宇部興産株式会社 炭酸ジメチルの連続製造方法
JPH10109960A (ja) * 1996-10-04 1998-04-28 Idemitsu Kosan Co Ltd 脂肪族炭酸ジエステル類の製造方法
JP3994457B2 (ja) * 1996-11-22 2007-10-17 三菱瓦斯化学株式会社 アリールカーボネートの製造方法
JP3944658B2 (ja) * 1996-11-22 2007-07-11 三菱瓦斯化学株式会社 ジアリールカーボネートの製造方法
US5980445A (en) * 1996-11-22 1999-11-09 Mitsubishi Gas Chemical Company, Inc. Process for producing diaryl carbonate
US5877336A (en) * 1996-12-31 1999-03-02 Bridgestone Corporation Synthesis of tributyltin lithium
JPH10218842A (ja) * 1997-02-04 1998-08-18 Mitsubishi Gas Chem Co Inc ジアルキルカーボネートの製造方法
JP3968534B2 (ja) * 1997-08-18 2007-08-29 三菱瓦斯化学株式会社 ジアルキルカーボネートの製造方法
US6031122A (en) * 1997-03-17 2000-02-29 Mitsubishi Gas Chemical Company, Inc. Process for producing dialkyl carbonate
JP3876939B2 (ja) * 1997-03-17 2007-02-07 三菱瓦斯化学株式会社 ジアルキルカーボネートの製造方法
AU1830499A (en) * 1997-12-23 1999-07-12 Ppg Industries Ohio, Inc. Catalysts for epoxy-acid coating compositions

Also Published As

Publication number Publication date
KR100649291B1 (ko) 2006-11-24
RO121680B1 (ro) 2008-02-28
EP1112120A4 (en) 2002-07-03
WO2000012212A1 (en) 2000-03-09
JP2002523477A (ja) 2002-07-30
CA2341209C (en) 2007-10-30
DE69921339D1 (de) 2004-11-25
JP4768124B2 (ja) 2011-09-07
USRE37337E1 (en) 2001-08-21
EP1112120B1 (en) 2004-10-20
CA2341209A1 (en) 2000-03-09
CN1163303C (zh) 2004-08-25
KR20010072949A (ko) 2001-07-31
US5902894A (en) 1999-05-11
RU2219162C2 (ru) 2003-12-20
BR9913192B1 (pt) 2011-11-01
ATE279983T1 (de) 2004-11-15
AU749963B2 (en) 2002-07-04
AU5552799A (en) 2000-03-21
EP1112120A1 (en) 2001-07-04
US6010976A (en) 2000-01-04
ES2226425T3 (es) 2005-03-16
DE69921339T2 (de) 2005-10-13
ID28897A (id) 2001-07-12
CN1313788A (zh) 2001-09-19

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