BR112013033834A2 - composição de céria zircônia alumina com estabilidade térmica melhorada - Google Patents

composição de céria zircônia alumina com estabilidade térmica melhorada

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Publication number
BR112013033834A2
BR112013033834A2 BR112013033834A BR112013033834A BR112013033834A2 BR 112013033834 A2 BR112013033834 A2 BR 112013033834A2 BR 112013033834 A BR112013033834 A BR 112013033834A BR 112013033834 A BR112013033834 A BR 112013033834A BR 112013033834 A2 BR112013033834 A2 BR 112013033834A2
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BR
Brazil
Prior art keywords
composition
hours
calcination
thermal stability
improved thermal
Prior art date
Application number
BR112013033834A
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English (en)
Other versions
BR112013033834B1 (pt
Inventor
Sagar Amod
Schermanz Karl
Original Assignee
Treibacher Ind Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Treibacher Ind Ag filed Critical Treibacher Ind Ag
Publication of BR112013033834A2 publication Critical patent/BR112013033834A2/pt
Publication of BR112013033834B1 publication Critical patent/BR112013033834B1/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C01P2006/13—Surface area thermal stability thereof at high temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

resumo patente de invenção: "composição de céria zircônia alumina com estabilidade térmica melhorada". a presente invenção refere-se a um processo para preparação de uma composição contendo óxidos de al, ce e zr, processo esse que inclui as etapas de (a) preparar uma solução aquosa de uma mistura de sais metálicos de cério, zircônio e alumínio, solução aquosa essa que inclui opcionalmente um ou mais sais de metais terras raras diferentes de cério, (b) adicionar à solução obtida uma base a temperaturas de 0°c a 95°c e precipitar os sais metálicos mistos na forma de hidróxidos ou óxi-hidróxidos, (d) tratar a suspensão aquosa obtida na etapa (b) com um tensoativo, e (e) isolar o precipitado obtido na etapa (d) e tratar o referido precipitado a uma temperatura de 450°c a 1200°c, processo esse que é caracterizado pelo fato que o teor de alumina fica na faixa de 35 a 80% em peso, e a área superficial (bet) da composição obtida, medida de acordo com din (deutsche industrie norm) 66131 após calcinação por 2 horas a 1100°c é de 55 a 80 m2/g; ou é pelo menos 35 m2/g após calcinação por 20 horas a 1100°c; e uma composição contendo óxidos de al, ce e zr, caracterizada pelo fato que o teor de alumínio, calculado como óxido de alumínio fica na faixa de 35 a 80% em peso, e a área superficial (bet) da composição medida de acordo com din (deutsche industrie norm) 66131 por 2 horas a 1100°c é de 55 a 80 m2/g, e/ou é de pelo menos 35 m2/g após calcinação por 20 horas a 1100°c, obtenível ou obtida de acordo com esse processo.
BR112013033834A 2011-07-01 2012-06-12 composição de céria zircônia alumina com estabilidade térmica melhorada e processo de produção da mesma BR112013033834B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11005382A EP2540391A1 (en) 2011-07-01 2011-07-01 Ceria zirconia alumina composition with enhanced thermal stability
PCT/EP2012/061110 WO2013004456A1 (en) 2011-07-01 2012-06-12 Ceria zirconia alumina composition with enhanced thermal stability

Publications (2)

Publication Number Publication Date
BR112013033834A2 true BR112013033834A2 (pt) 2017-02-14
BR112013033834B1 BR112013033834B1 (pt) 2019-12-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013033834A BR112013033834B1 (pt) 2011-07-01 2012-06-12 composição de céria zircônia alumina com estabilidade térmica melhorada e processo de produção da mesma

Country Status (14)

Country Link
US (1) US9475035B2 (pt)
EP (2) EP2540391A1 (pt)
JP (1) JP5938097B2 (pt)
KR (1) KR102032478B1 (pt)
CN (2) CN106964332A (pt)
AR (1) AR086716A1 (pt)
BR (1) BR112013033834B1 (pt)
CA (1) CA2837432A1 (pt)
MX (1) MX361074B (pt)
MY (1) MY169499A (pt)
RU (1) RU2631511C2 (pt)
TW (1) TW201311348A (pt)
WO (1) WO2013004456A1 (pt)
ZA (1) ZA201308809B (pt)

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CN107686134A (zh) * 2017-11-01 2018-02-13 哈尔滨工业大学 一种光学透明的导电玻璃负载的铁钴镍羟基氧化物薄膜的制备方法及其应用
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CN110282643A (zh) * 2019-07-12 2019-09-27 昆明冶金研究院 一种改性氧化铝材料及其制备方法和应用
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CN113897177A (zh) * 2021-09-03 2022-01-07 永州市湘江稀土有限责任公司 一种复合氧化物磨粒及其制备方法
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Also Published As

Publication number Publication date
KR20140033116A (ko) 2014-03-17
EP2540391A1 (en) 2013-01-02
US20140141967A1 (en) 2014-05-22
CN103619468A (zh) 2014-03-05
WO2013004456A1 (en) 2013-01-10
CN106964332A (zh) 2017-07-21
JP5938097B2 (ja) 2016-06-22
US9475035B2 (en) 2016-10-25
MX2013014367A (es) 2014-02-11
BR112013033834B1 (pt) 2019-12-17
MY169499A (en) 2019-04-15
EP2726199A1 (en) 2014-05-07
CA2837432A1 (en) 2013-01-10
CN103619468B (zh) 2016-09-07
AR086716A1 (es) 2014-01-15
MX361074B (es) 2018-11-27
TW201311348A (zh) 2013-03-16
KR102032478B1 (ko) 2019-11-08
RU2631511C2 (ru) 2017-09-25
JP2014520741A (ja) 2014-08-25
RU2014103455A (ru) 2015-08-10
ZA201308809B (en) 2015-08-26
EP2726199B1 (en) 2020-09-30

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