MX361074B - Composicion de alumina circona ceria con estabilidad termica mejorada. - Google Patents
Composicion de alumina circona ceria con estabilidad termica mejorada.Info
- Publication number
- MX361074B MX361074B MX2013014367A MX2013014367A MX361074B MX 361074 B MX361074 B MX 361074B MX 2013014367 A MX2013014367 A MX 2013014367A MX 2013014367 A MX2013014367 A MX 2013014367A MX 361074 B MX361074 B MX 361074B
- Authority
- MX
- Mexico
- Prior art keywords
- composition
- hours
- calcining
- aluminium
- thermal stability
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 title 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 title 1
- 238000000034 method Methods 0.000 abstract 4
- 238000001354 calcination Methods 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- 239000004411 aluminium Chemical class 0.000 abstract 2
- 229910052782 aluminium Chemical class 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical class [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical class [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
- C01P2006/13—Surface area thermal stability thereof at high temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Se describe un proceso para la preparación de una composición que comprende óxidos de Al, Ce, y Zr, el proceso comprende los pasos de (a) preparar una solución acuosa de una mezcla de sales metálicas de cerio, circonio y aluminio, la solución acuosa comprende opcionalmente una o más sales de Metales de Tierras Raras distintos al cerio, (b) agregar una base a la solución obtenida a temperaturas de 0°C a 95°C, y precipitar las sales metálicas mezcladas en forma de hidróxidos u oxihidróxidos, (d) tratar la suspensión acuosa obtenida en el paso (b) con un tensioactivo, y (e)aislar el precipitado obtenido en el paso (d), y tratar el precipitado a una temperatura de 450°C a 1200°C, el proceso es caracterizado en que el contenido de alúmina está en el intervalo de 35 a 80% por peso, y el área de superficie (BET) de la composición obtenida, medida de acuerdo a DIN (Deutsche Industrie Norm) 66131 después de la calcinación por 2 horas a 1100°C es de 55 a 80m2/g; o es al menos 35m2/g después de la calcinación por 20 horas a 1100°C; y una composición que comprende óxidos de Al, Ce, Zr caracterizada en que el contenido de aluminio, calculado como óxido de aluminio está en el intervalo de 35 a 80% por peso, y el área de superficie (BET) de la composición medida de acuerdo a DIN (Deutsche Industrie Norm) 66131 por 2 horas a 1100°C es de 55 a 80m2/g, y/o es al menos 35m2/g después de la calcinación por 20 horas a 1100°C obtenible u obtenida de acuerdo a tal proceso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11005382A EP2540391A1 (en) | 2011-07-01 | 2011-07-01 | Ceria zirconia alumina composition with enhanced thermal stability |
| PCT/EP2012/061110 WO2013004456A1 (en) | 2011-07-01 | 2012-06-12 | Ceria zirconia alumina composition with enhanced thermal stability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013014367A MX2013014367A (es) | 2014-02-11 |
| MX361074B true MX361074B (es) | 2018-11-27 |
Family
ID=44509944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013014367A MX361074B (es) | 2011-07-01 | 2012-06-12 | Composicion de alumina circona ceria con estabilidad termica mejorada. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9475035B2 (es) |
| EP (2) | EP2540391A1 (es) |
| JP (1) | JP5938097B2 (es) |
| KR (1) | KR102032478B1 (es) |
| CN (2) | CN106964332A (es) |
| AR (1) | AR086716A1 (es) |
| BR (1) | BR112013033834B1 (es) |
| CA (1) | CA2837432A1 (es) |
| MX (1) | MX361074B (es) |
| MY (1) | MY169499A (es) |
| RU (1) | RU2631511C2 (es) |
| TW (1) | TW201311348A (es) |
| WO (1) | WO2013004456A1 (es) |
| ZA (1) | ZA201308809B (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20170076657A (ko) * | 2014-09-05 | 2017-07-04 | 네오 퍼포먼스 메터리얼즈 (싱가포르) 프라이베이트 리미티드 | 다공성 세륨 및 지르코늄을 포함하는 산화물 |
| JP6325010B2 (ja) * | 2016-01-28 | 2018-05-16 | 第一稀元素化学工業株式会社 | アルミナ系複合酸化物及びその製造方法 |
| JP6615060B2 (ja) * | 2016-07-15 | 2019-12-04 | 株式会社豊田中央研究所 | 排ガス浄化用触媒担体の製造方法 |
| WO2018115436A1 (fr) * | 2016-12-23 | 2018-06-28 | Rhodia Operations | Oxyde mixte résistant au vieillissement à base de cérium, de zirconium, d'aluminium et de lanthane pour convertisseur catalytique automobile |
| WO2019003424A1 (ja) * | 2017-06-30 | 2019-01-03 | 第一稀元素化学工業株式会社 | アルミナ系複合酸化物及びその製造方法 |
| CN107686134A (zh) * | 2017-11-01 | 2018-02-13 | 哈尔滨工业大学 | 一种光学透明的导电玻璃负载的铁钴镍羟基氧化物薄膜的制备方法及其应用 |
| FR3075777A1 (fr) * | 2017-12-22 | 2019-06-28 | Rhodia Operations | Hydrate d'aluminium poreux |
| CN108083333A (zh) * | 2017-12-25 | 2018-05-29 | 山东磊宝锆业科技股份有限公司 | 一种利用固体废锆制备锆铝复合粉体的方法 |
| WO2019131176A1 (ja) * | 2017-12-28 | 2019-07-04 | ユミコア日本触媒株式会社 | 水素製造用触媒及びこれを用いた排ガス浄化用触媒 |
| WO2019160124A1 (en) * | 2018-02-15 | 2019-08-22 | Sumitomo Chemical Company, Limited | Inorganic oxide |
| CN108640151B (zh) * | 2018-06-11 | 2020-07-14 | 东南大学 | 含铝氧化锆空心微球及其制备方法 |
| CN110282643A (zh) * | 2019-07-12 | 2019-09-27 | 昆明冶金研究院 | 一种改性氧化铝材料及其制备方法和应用 |
| RU2755558C2 (ru) * | 2019-12-06 | 2021-09-17 | Федеральное государственное автономное образовательное учреждение высшего образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" | Способ синтеза композиции на основе оксида алюминия и твердого раствора оксидов церия и циркония |
| TW202134364A (zh) * | 2020-01-31 | 2021-09-16 | 美商恩特葛瑞斯股份有限公司 | 用於研磨硬質材料之化學機械研磨(cmp)組合物 |
| CN111760567A (zh) * | 2020-06-28 | 2020-10-13 | 江苏国盛新材料有限公司 | 一种具有增强的热稳定性的氧化铈氧化锆氧化铝组合物 |
| CN113897177A (zh) * | 2021-09-03 | 2022-01-07 | 永州市湘江稀土有限责任公司 | 一种复合氧化物磨粒及其制备方法 |
| CN116102049A (zh) * | 2022-12-28 | 2023-05-12 | 常州市卓群纳米新材料有限公司 | 一种高纯纳米氧化钕的制备方法 |
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| IT1271312B (it) * | 1994-12-21 | 1997-05-27 | Enirisorse Spa | Procedimento sol-gel per ottenere sfere,microsfere o rivestimenti di monoliti a forma cellulare,costituiti da ossido di zirconio puro o misto ad altri ossidi,utili come catalizzatori o supporti per catalizzatori |
| DE69728341T2 (de) * | 1996-10-07 | 2004-12-30 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Verbundoxid, Verbundoxidträger und Katalysator |
| JP3262044B2 (ja) * | 1996-10-07 | 2002-03-04 | 株式会社豊田中央研究所 | 複合酸化物担体および複合酸化物含有触媒 |
| JP4053623B2 (ja) * | 1996-12-27 | 2008-02-27 | 阿南化成株式会社 | ジルコニウム−セリウム系複合酸化物及びその製造方法 |
| EP1046423B8 (en) * | 1999-04-23 | 2007-11-21 | Umicore AG & Co. KG | Layered noble metal-containing exhaust gas catalyst and its preparation |
| EP1172139B1 (en) | 2000-07-14 | 2006-10-11 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Catalyst for purifying exhaust gas |
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| ATE477216T1 (de) * | 2003-04-30 | 2010-08-15 | Magnesium Elektron Ltd | Verfahren zur herstellung von zirkonoxiden und zirkonium enthaltenden mischoxiden |
| JP2005104799A (ja) | 2003-10-01 | 2005-04-21 | Toyota Central Res & Dev Lab Inc | 複合酸化物及び排ガス浄化用触媒 |
| JP2005246477A (ja) * | 2004-02-04 | 2005-09-15 | Tie:Kk | 金属板給送装置 |
| JP4483348B2 (ja) * | 2004-03-02 | 2010-06-16 | 株式会社豊田中央研究所 | 触媒 |
| FR2867769B1 (fr) * | 2004-03-17 | 2006-05-05 | Rhodia Chimie Sa | Composition a base d'oxydes de zirconium, de cerium et d'etain, preparation et utilisation comme catalyseur |
| GB0428557D0 (en) * | 2004-12-30 | 2005-02-09 | Magnesium Elektron Ltd | Thermally stable doped and undoped porous aluminium oxides and nanocomposite CeO -ZrO and A1 O containing mixed oxides |
| GB0428555D0 (en) | 2004-12-30 | 2005-02-09 | Magnesium Elektron Ltd | Composite material for automotive catalyst applications and method of manufacturing |
| CN100360222C (zh) | 2005-03-30 | 2008-01-09 | 四川大学 | 铈锆铝基储氧材料及其制备方法 |
| WO2007093593A1 (fr) | 2006-02-17 | 2007-08-23 | Rhodia Operations | Composition a base d'oxydes de zirconium, de cerium, d'yttrium, de lanthane et d'une autre terre rare, procede de preparation et utilisation en catalyse |
| JP4760625B2 (ja) * | 2006-09-06 | 2011-08-31 | マツダ株式会社 | 排ガス浄化用触媒装置 |
| JP4928931B2 (ja) | 2006-12-20 | 2012-05-09 | 日本電工株式会社 | セリア−ジルコニア系複合酸化物及びその製造方法 |
| DE502007004776D1 (de) | 2007-03-19 | 2010-09-30 | Umicore Ag & Co Kg | Palladium-Rhodium Einfachschicht Katalysator |
| JP4423570B2 (ja) * | 2007-03-30 | 2010-03-03 | 株式会社豊田中央研究所 | 改質用触媒担体及びその製造方法 |
| CN101112683A (zh) * | 2007-06-27 | 2008-01-30 | 山东齐鲁华信实业有限公司 | 一种介孔结构铈锆铝复合氧化物固溶体及其制备方法 |
| CN101249459B (zh) * | 2008-03-14 | 2010-11-17 | 福州大学化肥催化剂国家工程研究中心 | 汽车尾气净化器高性能纳米组合催化涂层材料及其制备方法 |
| CN101745375B (zh) * | 2008-12-15 | 2013-01-09 | 比亚迪股份有限公司 | 铈锆铝基复合氧化物材料及其制备方法 |
| EP2223905A1 (en) | 2009-02-27 | 2010-09-01 | Treibacher Industrie AG | Novel zirconia ceria compositions |
| CN101690890A (zh) * | 2009-09-23 | 2010-04-07 | 中国海洋石油总公司 | 一种高热稳定性铈基储氧材料的制备方法 |
| JP5256232B2 (ja) * | 2009-12-08 | 2013-08-07 | トヨタ自動車株式会社 | アルミナ−セリア複合酸化物微粒子の合成方法 |
| CA2827107C (en) * | 2010-11-16 | 2021-06-22 | Rhodia Operations | Porous inorganic composite oxide |
-
2011
- 2011-07-01 EP EP11005382A patent/EP2540391A1/en not_active Ceased
-
2012
- 2012-06-12 EP EP12729459.3A patent/EP2726199B1/en active Active
- 2012-06-12 WO PCT/EP2012/061110 patent/WO2013004456A1/en active Application Filing
- 2012-06-12 US US14/128,067 patent/US9475035B2/en active Active
- 2012-06-12 RU RU2014103455A patent/RU2631511C2/ru active
- 2012-06-12 KR KR1020137032968A patent/KR102032478B1/ko active IP Right Grant
- 2012-06-12 CN CN201610839364.8A patent/CN106964332A/zh active Pending
- 2012-06-12 JP JP2014517570A patent/JP5938097B2/ja active Active
- 2012-06-12 MX MX2013014367A patent/MX361074B/es active IP Right Grant
- 2012-06-12 CN CN201280032493.6A patent/CN103619468B/zh active Active
- 2012-06-12 CA CA2837432A patent/CA2837432A1/en not_active Abandoned
- 2012-06-12 BR BR112013033834A patent/BR112013033834B1/pt not_active IP Right Cessation
- 2012-06-12 MY MYPI2013702404A patent/MY169499A/en unknown
- 2012-06-14 TW TW101121337A patent/TW201311348A/zh unknown
- 2012-06-22 AR ARP120102237A patent/AR086716A1/es active IP Right Grant
-
2013
- 2013-11-22 ZA ZA2013/08809A patent/ZA201308809B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140033116A (ko) | 2014-03-17 |
| EP2540391A1 (en) | 2013-01-02 |
| US20140141967A1 (en) | 2014-05-22 |
| CN103619468A (zh) | 2014-03-05 |
| WO2013004456A1 (en) | 2013-01-10 |
| CN106964332A (zh) | 2017-07-21 |
| JP5938097B2 (ja) | 2016-06-22 |
| US9475035B2 (en) | 2016-10-25 |
| MX2013014367A (es) | 2014-02-11 |
| BR112013033834B1 (pt) | 2019-12-17 |
| MY169499A (en) | 2019-04-15 |
| EP2726199A1 (en) | 2014-05-07 |
| CA2837432A1 (en) | 2013-01-10 |
| CN103619468B (zh) | 2016-09-07 |
| AR086716A1 (es) | 2014-01-15 |
| BR112013033834A2 (pt) | 2017-02-14 |
| TW201311348A (zh) | 2013-03-16 |
| KR102032478B1 (ko) | 2019-11-08 |
| RU2631511C2 (ru) | 2017-09-25 |
| JP2014520741A (ja) | 2014-08-25 |
| RU2014103455A (ru) | 2015-08-10 |
| ZA201308809B (en) | 2015-08-26 |
| EP2726199B1 (en) | 2020-09-30 |
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