BR112013001018A2 - material zeolítico de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, catalisador, processo para a preparação de qualquer material zeolítico zsm-34 contendo cobre, uso de catalisador, sistema de tratamento de gás de escapamento, e, método de reduzir seletivamente óxidos de nitrogênio nox - Google Patents

material zeolítico de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, catalisador, processo para a preparação de qualquer material zeolítico zsm-34 contendo cobre, uso de catalisador, sistema de tratamento de gás de escapamento, e, método de reduzir seletivamente óxidos de nitrogênio nox

Info

Publication number
BR112013001018A2
BR112013001018A2 BR112013001018A BR112013001018A BR112013001018A2 BR 112013001018 A2 BR112013001018 A2 BR 112013001018A2 BR 112013001018 A BR112013001018 A BR 112013001018A BR 112013001018 A BR112013001018 A BR 112013001018A BR 112013001018 A2 BR112013001018 A2 BR 112013001018A2
Authority
BR
Brazil
Prior art keywords
copper
zsm
catalyst
zeolitic material
erionite
Prior art date
Application number
BR112013001018A
Other languages
English (en)
Inventor
Ivor Bull
Ulrich Müller
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=45469862&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112013001018(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Se filed Critical Basf Se
Publication of BR112013001018A2 publication Critical patent/BR112013001018A2/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/52—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
    • B01J29/56—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/202—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

material zeolíetico de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, catalisador, processo para a preparação de qualquer material zeolítico zsm-34 contendo cobre, uso de catalisador, sistema de tratamento de gás de escapamento, e, método de reduzir seletivamente ócidos de ntirogênio nox. é descrito um material zeolítivo de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, que tem uma razão em mol de sílica para alumina que varia de cerca de 4 a cerca de 50 e um teor de cobre, reportado como cuo, que varia de cerca de 1 a cerca de 10% em peso, com base no peso total do material zeolítico calcinado, e um teor de metal alcalino, reportado como o óxido de metal, menor que cerca de 0,7% em peso.
BR112013001018A 2010-07-15 2011-07-13 material zeolítico de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, catalisador, processo para a preparação de qualquer material zeolítico zsm-34 contendo cobre, uso de catalisador, sistema de tratamento de gás de escapamento, e, método de reduzir seletivamente óxidos de nitrogênio nox BR112013001018A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10169692 2010-07-15
PCT/IB2011/053126 WO2012007914A2 (en) 2010-07-15 2011-07-13 Copper containing zsm-34, off and/or eri zeolitic material for selective reduction of nox

Publications (1)

Publication Number Publication Date
BR112013001018A2 true BR112013001018A2 (pt) 2016-05-24

Family

ID=45469862

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013001018A BR112013001018A2 (pt) 2010-07-15 2011-07-13 material zeolítico de ofretita (off) e/ou erionita (eri), zsm-34 contendo cobre, catalisador, processo para a preparação de qualquer material zeolítico zsm-34 contendo cobre, uso de catalisador, sistema de tratamento de gás de escapamento, e, método de reduzir seletivamente óxidos de nitrogênio nox

Country Status (7)

Country Link
EP (1) EP2593212B2 (pt)
JP (1) JP5902682B2 (pt)
KR (1) KR20130041943A (pt)
CN (1) CN103118764A (pt)
BR (1) BR112013001018A2 (pt)
IN (1) IN2013CN00093A (pt)
WO (1) WO2012007914A2 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103167907A (zh) 2010-07-15 2013-06-19 巴斯夫欧洲公司 用于选择性还原NOx的含铜ZSM-34、OFF和/或ERI沸石材料
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
US9782761B2 (en) 2013-10-03 2017-10-10 Ford Global Technologies, Llc Selective catalytic reduction catalyst
GB2528737B (en) * 2014-03-24 2019-01-23 Johnson Matthey Plc Method for treating exhaust gas
GB2539753B (en) * 2015-03-25 2017-06-14 Johnson Matthey Plc Noble metal-OFF Framework Type passive NOx adsorber and use thereof
US11224868B2 (en) 2016-02-01 2022-01-18 Umicore Ag & Co. Kg Method for the removal of nitrous oxide from off gas in presence of catalyst comprising an Fe-AEI zeolite material essentially free of alkali metal
US10343925B2 (en) * 2016-02-12 2019-07-09 Hyundai Motor Company Method for preparing zeolite catalyst
EP3205398A1 (en) 2016-02-12 2017-08-16 Hyundai Motor Company Method for preparing zeolite catalyst
JP2022532115A (ja) * 2019-05-09 2022-07-13 ビーエーエスエフ コーポレーション 炭酸銅を含む選択的触媒還元触媒

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NL238953A (pt) † 1958-05-08
NZ185397A (en) * 1976-11-04 1979-12-11 Mobil Oil Corp Crystalline aluminosilicate zeolites and use as catalysts
US4086186A (en) 1976-11-04 1978-04-25 Mobil Oil Corporation Crystalline zeolite ZSM-34 and method of preparing the same
FR2575741B1 (fr) * 1985-01-09 1990-03-16 Inst Francais Du Petrole Obtention d'une offretite synthetique riche en silice. application a la production d'hydrocarbures riches en olefines legeres par transformation du methanol et/ou de dimethylether
JPH0639415B2 (ja) * 1988-03-11 1994-05-25 軽質留分新用途開発技術研究組合 プロピレンを主成分とする低級オレフィンの製造方法
JP3242126B2 (ja) * 1991-06-17 2001-12-25 日石三菱株式会社 窒素酸化物の除去方法
JP2004167306A (ja) * 2002-11-18 2004-06-17 Ict:Kk 排ガス浄化用触媒および排ガス浄化方法
CN1189245C (zh) * 2003-03-27 2005-02-16 南开大学 用于汽车尾气处理的催化剂及制备方法
CN101018604B (zh) * 2004-07-15 2010-12-08 日挥通用株式会社 含有有机氮化合物废气的净化用催化剂及该废气的净化方法
JP4722429B2 (ja) * 2004-08-20 2011-07-13 出光興産株式会社 金属担持ゼオライト成型体の製造方法及び該ゼオライトを含有する硫黄化合物除去用吸着剤
WO2007070639A2 (en) 2005-12-14 2007-06-21 Basf Catalysts Llc Zeolite catalyst with improved nox reduction in scr
KR101965943B1 (ko) * 2007-04-26 2019-04-04 존슨 맛쎄이 퍼블릭 리미티드 컴파니 전이 금속／제올라이트 ｓｃｒ 촉매
US10583424B2 (en) † 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios

Also Published As

Publication number Publication date
CN103118764A (zh) 2013-05-22
EP2593212A2 (en) 2013-05-22
WO2012007914A3 (en) 2012-03-08
JP5902682B2 (ja) 2016-04-13
JP2013535317A (ja) 2013-09-12
WO2012007914A2 (en) 2012-01-19
EP2593212B1 (en) 2015-12-16
IN2013CN00093A (pt) 2015-07-03
KR20130041943A (ko) 2013-04-25
EP2593212A4 (en) 2014-02-12
EP2593212B2 (en) 2021-06-02

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

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