MX2017010570A - Proceso para la deshidratacion de compuestos oxigenados. - Google Patents
Proceso para la deshidratacion de compuestos oxigenados.Info
- Publication number
- MX2017010570A MX2017010570A MX2017010570A MX2017010570A MX2017010570A MX 2017010570 A MX2017010570 A MX 2017010570A MX 2017010570 A MX2017010570 A MX 2017010570A MX 2017010570 A MX2017010570 A MX 2017010570A MX 2017010570 A MX2017010570 A MX 2017010570A
- Authority
- MX
- Mexico
- Prior art keywords
- oxide
- sio2
- silica
- dehydration
- ammonia
- Prior art date
Links
- 230000018044 dehydration Effects 0.000 title abstract 4
- 238000006297 dehydration reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 229910021529 ammonia Inorganic materials 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910000069 nitrogen hydride Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 238000010494 dissociation reaction Methods 0.000 abstract 1
- 230000005593 dissociations Effects 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000002484 inorganic compounds Chemical class 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- WKMKTIVRRLOHAJ-UHFFFAOYSA-N oxygen(2-);thallium(1+) Chemical compound [O-2].[Tl+].[Tl+] WKMKTIVRRLOHAJ-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910003438 thallium oxide Inorganic materials 0.000 abstract 1
- 229910001930 tungsten oxide Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/12—Alkadienes
- C07C11/16—Alkadienes with four carbon atoms
- C07C11/167—1, 3-Butadiene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención se refiere a un proceso para la deshidratación de cuando menos un compuesto oxigenado, de preferencia seleccionado a partir de alcoholes saturados, alcoholes insaturados, dioles, éteres, en la presencia de cuando menos un catalizador de deshidratación seleccionado a partir de óxido de cerio (CeO2), óxido de aluminio (y-Al2O3), silicato de aluminio, sílice-alúminas (SiO2-Al2O3), alúminas, zeolitas, resinas sulfonatadas, resinas de intercambio de iones, óxidos de metales (por ejemplo, óxido de lantano, óxido de zirconio, óxido de tungsteno, óxido de talio, óxido de magnesio, óxido de zinc); de cuando menos un agente básico seleccionado a partir de amoníaco (NH3), o a partir de compuestos inorgánicos u orgánicos que contienen nitrógeno capaces de desarrollar amoníaco (NH3) durante dicho proceso de deshidratación; y opcionalmente, de sílice (SiO2), o de cuando menos un catalizador para la disociación de amoníaco (NH3) seleccionado a partir de los catalizadores que comprenden sílice (SiO2), de preferencia de sílice (SiO2).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20150261 | 2015-02-23 | ||
| PCT/IB2016/050926 WO2016135605A1 (en) | 2015-02-23 | 2016-02-22 | Process for the dehydration of oxygenated compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2017010570A true MX2017010570A (es) | 2017-12-07 |
Family
ID=52781174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017010570A MX2017010570A (es) | 2015-02-23 | 2016-02-22 | Proceso para la deshidratacion de compuestos oxigenados. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10894750B2 (es) |
| EP (1) | EP3262019B1 (es) |
| JP (1) | JP6789229B2 (es) |
| CN (1) | CN107108398B (es) |
| BR (1) | BR112017013719B1 (es) |
| MX (1) | MX2017010570A (es) |
| MY (1) | MY186144A (es) |
| RU (1) | RU2701863C2 (es) |
| SA (1) | SA517381940B1 (es) |
| WO (1) | WO2016135605A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6456231B2 (ja) * | 2015-04-27 | 2019-01-23 | 昭和電工株式会社 | ジエン化合物の製造方法 |
| DK3853197T3 (da) | 2018-09-21 | 2024-02-12 | Versalis Spa | Fremgangsmåde til bio-1,3-butandiol-oprensning fra en fermenterinsbouillon |
| US11260367B2 (en) * | 2018-12-12 | 2022-03-01 | Instituto Nacional De Tecnologia | Catalytic system and process for the production of light olefins from ethanol |
| CN113365966A (zh) | 2019-01-28 | 2021-09-07 | 积水化学工业株式会社 | 乙醇 |
| IT201900015069A1 (it) * | 2019-08-27 | 2021-02-27 | Versalis Spa | Catalizzatore comprendente coke e procedimento per la produzione di dieni. |
| CN110665490A (zh) * | 2019-09-30 | 2020-01-10 | 成都欣华源科技有限责任公司 | 一种制备α-烯烃的方法、催化剂及该催化剂的制备方法 |
| CN114621061B (zh) * | 2020-12-10 | 2023-04-07 | 中国科学院大连化学物理研究所 | 一种低温合成二甘醇的方法 |
| CN113754509A (zh) * | 2021-09-10 | 2021-12-07 | 中山大学 | 一种烯丙醇类化合物制备单一立体构型的共轭二烯的方法 |
| IT202200018231A1 (it) | 2022-09-07 | 2024-03-07 | Versalis Spa | Metodo per la preparazione di amidine da n-(alchil lattami) |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2420477A (en) | 1942-11-12 | 1947-05-13 | Nat Agrol Company Inc | Production of butadiene by method of dehydration |
| US2373153A (en) * | 1943-04-22 | 1945-04-10 | Air Reduction | Production of butadiene |
| US2426678A (en) | 1943-04-27 | 1947-09-02 | Us Ind Chemicals Inc | Revivification of phosphate catalysts |
| US2399164A (en) | 1944-06-13 | 1946-04-30 | Celanese Corp | Dehydration process |
| GB1225559A (es) | 1968-12-19 | 1971-03-17 | ||
| FR2041003A1 (es) | 1969-04-22 | 1971-01-29 | Raffinage Cie Francaise | |
| GB1460226A (en) | 1974-12-07 | 1976-12-31 | Golosman E Z | Catalyst for dissociation of ammonia method for preparing same and method for dissociation of ammonia with said catalyst |
| US4260845A (en) | 1980-01-21 | 1981-04-07 | Phillips Petroleum Company | Alcohol dehydration employing a zinc aluminate catalyst |
| SU910187A1 (ru) * | 1980-06-13 | 1982-03-07 | Московский Ордена Ленина,Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Государственный Университет Им. М.В.Ломоносова | Катализатор дл дегидратации н-бутилового спирта и способ его приготовлени |
| SG118141A1 (en) * | 2001-07-16 | 2006-01-27 | Kuraray Co | Process for producing alpha-olefin |
| US6797851B2 (en) | 2001-08-30 | 2004-09-28 | Exxonmobil Chemical Patents Inc. | Two catalyst process for making olefin |
| CA2524940A1 (en) * | 2005-10-31 | 2007-04-30 | Nova Chemicals Corporation | Conversion of ethers to olefins |
| EP1954655A1 (en) * | 2005-11-29 | 2008-08-13 | BP Chemicals Limited | Process for producing olefins |
| DE102006040433A1 (de) * | 2006-08-29 | 2008-03-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Isoolefinen |
| US7829751B2 (en) * | 2006-10-27 | 2010-11-09 | Exxonmobil Chemical Patents, Inc. | Processes for converting oxygenates to olefins using aluminosilicate catalysts |
| CN100554228C (zh) * | 2006-11-02 | 2009-10-28 | 中国石油化工股份有限公司 | 乙醇脱水制乙烯的生产方法 |
| US8395008B2 (en) * | 2008-01-14 | 2013-03-12 | Catalytic Distillation Technologies | Process and catalyst for cracking of ethers and alcohols |
| JP2012501338A (ja) | 2008-08-27 | 2012-01-19 | ヴァイレント エナジー システムズ インク． | バイオマスからの液体燃料の合成 |
| MY154353A (en) * | 2008-11-28 | 2015-05-29 | Total Petrochemicals Res Feluy | Purfication of alcohols prior to their use in the presence of an acid catalyst |
| EP2424975B1 (en) | 2009-04-30 | 2016-07-06 | Genomatica, Inc. | Organisms for the production of 1,3-butanediol |
| EP2448899B1 (en) * | 2009-07-01 | 2016-11-23 | Dow Global Technologies LLC | Process to prepare olefins from aliphatic alcohols |
| JP2011084550A (ja) * | 2009-09-17 | 2011-04-28 | Sumitomo Chemical Co Ltd | 二重結合を有する化合物の製造方法 |
| US8710288B2 (en) * | 2010-03-31 | 2014-04-29 | Dow Global Technologies Llc | Process to increase selectivity to ethylene in oxygenates-to-olefins conversions |
| WO2011161045A1 (en) * | 2010-06-23 | 2011-12-29 | Total Petrochemicals Research Feluy | Dehydration of alcohols on poisoned acidic catalysts |
| AU2012273177A1 (en) | 2011-06-22 | 2013-05-02 | Genomatica, Inc. | Microorganisms for producing 1,3-butanediol and methods related thereto |
| FR2977581B1 (fr) * | 2011-07-04 | 2013-08-02 | Rhodia Operations | Composition consistant en un oxyde mixte de cerium et de zirconium a reductibilite elevee, procede de preparation et utilisation dans le domaine de la catalyse |
| ES2868140T3 (es) | 2011-08-03 | 2021-10-21 | Total Res & Technology Feluy | Procedimiento de conversión de al menos un alcohol en olefinas ligeras |
| IN2014CN01258A (es) | 2011-08-19 | 2015-04-24 | Genomatica Inc | |
| IN2014CN02584A (es) | 2011-09-08 | 2015-08-07 | Genomatica Inc | |
| FR3001728B1 (fr) * | 2013-02-04 | 2015-11-13 | Adisseo France Sas | Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool |
| ITMI20132069A1 (it) | 2013-12-11 | 2015-06-12 | Versalis Spa | Procedimento per la produzione di zuccheri da biomassa |
| JP6542234B2 (ja) * | 2014-02-03 | 2019-07-10 | バテル メモリアル インスティチュート | ２，３−ブタンジオールのブタジエンへの変換 |
| US9517984B2 (en) * | 2014-04-04 | 2016-12-13 | Battelle Memorial Institute | Conversion of 2,3-butanediol to 2-butanol, olefins and fuels |
| US20160184810A1 (en) * | 2014-12-29 | 2016-06-30 | White Dog Labs, Inc. | Dehydration catalyst and method of making and using the same |
-
2016
- 2016-02-22 WO PCT/IB2016/050926 patent/WO2016135605A1/en active Application Filing
- 2016-02-22 CN CN201680005528.5A patent/CN107108398B/zh active Active
- 2016-02-22 JP JP2017543382A patent/JP6789229B2/ja active Active
- 2016-02-22 MX MX2017010570A patent/MX2017010570A/es unknown
- 2016-02-22 MY MYPI2017702994A patent/MY186144A/en unknown
- 2016-02-22 RU RU2017130690A patent/RU2701863C2/ru active
- 2016-02-22 BR BR112017013719-4A patent/BR112017013719B1/pt active IP Right Grant
- 2016-02-22 EP EP16712502.0A patent/EP3262019B1/en active Active
- 2016-02-22 US US15/540,399 patent/US10894750B2/en active Active
-
2017
- 2017-07-18 SA SA517381940A patent/SA517381940B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN107108398A (zh) | 2017-08-29 |
| BR112017013719A2 (pt) | 2018-03-13 |
| RU2701863C2 (ru) | 2019-10-02 |
| US10894750B2 (en) | 2021-01-19 |
| US20180002249A1 (en) | 2018-01-04 |
| EP3262019A1 (en) | 2018-01-03 |
| JP2018510848A (ja) | 2018-04-19 |
| BR112017013719B1 (pt) | 2022-04-12 |
| RU2017130690A3 (es) | 2019-03-25 |
| EP3262019C0 (en) | 2024-07-31 |
| EP3262019B1 (en) | 2024-07-31 |
| CN107108398B (zh) | 2023-10-10 |
| MY186144A (en) | 2021-06-26 |
| SA517381940B1 (ar) | 2021-03-31 |
| JP6789229B2 (ja) | 2020-11-25 |
| WO2016135605A1 (en) | 2016-09-01 |
| RU2017130690A (ru) | 2019-03-25 |
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