BR112016026512A2 - Processo para a produção de alquenóis e uso dos mesmos para a produção de 1,3-butadieno - Google Patents

Processo para a produção de alquenóis e uso dos mesmos para a produção de 1,3-butadieno

Info

Publication number
BR112016026512A2
BR112016026512A2 BR112016026512A BR112016026512A BR112016026512A2 BR 112016026512 A2 BR112016026512 A2 BR 112016026512A2 BR 112016026512 A BR112016026512 A BR 112016026512A BR 112016026512 A BR112016026512 A BR 112016026512A BR 112016026512 A2 BR112016026512 A2 BR 112016026512A2
Authority
BR
Brazil
Prior art keywords
production
alkenols
butadiene
butanediol
diol
Prior art date
Application number
BR112016026512A
Other languages
English (en)
Inventor
Cesana Alberto
Ramello Stefano
Spano Guido
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of BR112016026512A2 publication Critical patent/BR112016026512A2/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA A PRODUÇÃO DE ALQUENÓIS E USO DOS MESMOS PARA A PRODUÇÃO DE 1,3-BUTADIENO. A presente invenção refere-se ao processo para a produção de alquenóis compreendendo a desidratação de ao menos um diol na presença de ao menos um catalisador à base de óxido de cério, onde o dito catalisador à base de óxido de cério é obtido por precipitação, na presença de ao menos uma base, de ao menos um composto contendo cério. Preferencialmente, o dito diol pode ser um butanodiol, mais preferencialmente, 1,3-butanodiol, ainda mais preferencialmente, bio-1,3-butanodiol derivado de processos de biossíntese. Os ditos alquenóis podem ser vantajosamente usados para a produção de 1,3-butadieno, em particular de bio-1,3-butadieno.
BR112016026512A 2014-05-16 2015-05-15 Processo para a produção de alquenóis e uso dos mesmos para a produção de 1,3-butadieno BR112016026512A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI20140897 2014-05-16
PCT/IB2015/053592 WO2015173780A1 (en) 2014-05-16 2015-05-15 Process for the production of alkenols and use thereof for the production of 1,3-butadiene

Publications (1)

Publication Number Publication Date
BR112016026512A2 true BR112016026512A2 (pt) 2017-08-15

Family

ID=51220686

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112016026512A BR112016026512A2 (pt) 2014-05-16 2015-05-15 Processo para a produção de alquenóis e uso dos mesmos para a produção de 1,3-butadieno

Country Status (14)

Country Link
US (1) US9862664B2 (pt)
EP (1) EP3142785B1 (pt)
JP (1) JP6804300B2 (pt)
CN (1) CN106414383B (pt)
BR (1) BR112016026512A2 (pt)
DK (1) DK3142785T3 (pt)
ES (1) ES2924482T3 (pt)
HU (1) HUE059279T2 (pt)
MX (1) MX2016013269A (pt)
PL (1) PL3142785T3 (pt)
PT (1) PT3142785T (pt)
RU (1) RU2695786C2 (pt)
TW (1) TWI659946B (pt)
WO (1) WO2015173780A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016135609A1 (en) * 2015-02-23 2016-09-01 Versalis S.P.A. Process for the production of dienes
JP6456231B2 (ja) * 2015-04-27 2019-01-23 昭和電工株式会社 ジエン化合物の製造方法
JP6684635B2 (ja) * 2016-04-06 2020-04-22 昭和電工株式会社 ジエン化合物の製造方法
JP6684641B2 (ja) * 2016-04-26 2020-04-22 昭和電工株式会社 共役ジエン化合物の製造方法及びアリル型不飽和アルコールの脱水触媒
JP6656074B2 (ja) * 2016-04-26 2020-03-04 昭和電工株式会社 アリル型不飽和アルコールの脱水による共役ジエン化合物の製造方法
WO2018040058A1 (en) * 2016-09-02 2018-03-08 Rhodia Operations Dehydration of diols
IT201600105178A1 (it) * 2016-10-19 2018-04-19 Versalis Spa Procedimento per la produzione di dieni
US10639621B2 (en) * 2018-03-05 2020-05-05 Qatar University Nanoporous cerium oxide with interconnected pores for catalysis and a cost-effective method of preparing thereof
DK3853197T3 (da) 2018-09-21 2024-02-12 Versalis Spa Fremgangsmåde til bio-1,3-butandiol-oprensning fra en fermenterinsbouillon
IT201900015069A1 (it) 2019-08-27 2021-02-27 Versalis Spa Catalizzatore comprendente coke e procedimento per la produzione di dieni.
CN110465298B (zh) * 2019-08-29 2022-01-28 湘潭大学 一种用于糖类发酵产物abe直接制备长碳链化合物的催化剂及其制备方法
IT201900025000A1 (it) 2019-12-20 2021-06-20 Versalis Spa Procedimento per la produzione di dieni.
CN113385212B (zh) * 2021-06-11 2022-12-27 上海巽田科技股份有限公司 用于制备烯醇的非金属掺杂的碳基催化剂及使用其制备烯醇的方法
CN115894171B (zh) * 2022-11-17 2024-04-16 凯瑞环保科技股份有限公司 一种醋酸仲丁酯加氢制备仲丁醇的方法

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DE1908620A1 (de) 1969-02-21 1970-09-03 Basf Ag Verfahren zur Herstellung modifizierter Polyolefinwachse
FR2044085A5 (pt) * 1969-05-08 1971-02-19 Raffinage Cie Francaise
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Also Published As

Publication number Publication date
ES2924482T3 (es) 2022-10-07
CN106414383B (zh) 2019-10-25
RU2016140173A (ru) 2018-06-20
HUE059279T2 (hu) 2022-11-28
US20170057893A1 (en) 2017-03-02
JP6804300B2 (ja) 2020-12-23
CN106414383A (zh) 2017-02-15
RU2695786C2 (ru) 2019-07-26
PL3142785T3 (pl) 2022-08-22
EP3142785A1 (en) 2017-03-22
WO2015173780A1 (en) 2015-11-19
RU2016140173A3 (pt) 2018-09-21
US9862664B2 (en) 2018-01-09
TW201602068A (zh) 2016-01-16
MX2016013269A (es) 2017-02-22
JP2017520511A (ja) 2017-07-27
EP3142785B1 (en) 2022-06-29
DK3142785T3 (da) 2022-08-01
PT3142785T (pt) 2022-07-29
TWI659946B (zh) 2019-05-21

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B12B Appeal against refusal [chapter 12.2 patent gazette]