BE1029580B1 - Verfahren zur abtrennung und reinigung von hochantimonhaltigem rohzinn - Google Patents
Verfahren zur abtrennung und reinigung von hochantimonhaltigem rohzinn Download PDFInfo
- Publication number
- BE1029580B1 BE1029580B1 BE20225452A BE202205452A BE1029580B1 BE 1029580 B1 BE1029580 B1 BE 1029580B1 BE 20225452 A BE20225452 A BE 20225452A BE 202205452 A BE202205452 A BE 202205452A BE 1029580 B1 BE1029580 B1 BE 1029580B1
- Authority
- BE
- Belgium
- Prior art keywords
- tin
- antimony
- crude
- product
- vacuum
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000000746 purification Methods 0.000 title description 5
- 238000000926 separation method Methods 0.000 title description 4
- 229910052718 tin Inorganic materials 0.000 claims abstract description 84
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 83
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 78
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 72
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- 238000002309 gasification Methods 0.000 claims abstract description 23
- 238000009833 condensation Methods 0.000 claims abstract description 17
- 230000005494 condensation Effects 0.000 claims abstract description 17
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052785 arsenic Inorganic materials 0.000 claims description 20
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 238000005292 vacuum distillation Methods 0.000 description 17
- 229910001245 Sb alloy Inorganic materials 0.000 description 15
- 239000002140 antimony alloy Substances 0.000 description 15
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- 238000011084 recovery Methods 0.000 description 10
- PWBYCFJASNVELD-UHFFFAOYSA-N [Sn].[Sb].[Pb] Chemical compound [Sn].[Sb].[Pb] PWBYCFJASNVELD-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 239000002893 slag Substances 0.000 description 9
- 238000007670 refining Methods 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003295 industrial effluent Substances 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 229910002058 ternary alloy Inorganic materials 0.000 description 2
- 229910000897 Babbitt (metal) Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910020935 Sn-Sb Inorganic materials 0.000 description 1
- 229910008757 Sn—Sb Inorganic materials 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- LKIXMJFYKZVZER-UHFFFAOYSA-N [As].[Sn].[Sb] Chemical compound [As].[Sn].[Sb] LKIXMJFYKZVZER-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- DLISVFCFLGSHAB-UHFFFAOYSA-N antimony arsenic Chemical compound [As].[Sb] DLISVFCFLGSHAB-UHFFFAOYSA-N 0.000 description 1
- KGHMFMDJVUVBRY-UHFFFAOYSA-N antimony copper Chemical compound [Cu].[Sb] KGHMFMDJVUVBRY-UHFFFAOYSA-N 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/02—Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action including acoustic waves
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B25/00—Obtaining tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/02—Obtaining lead by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B25/00—Obtaining tin
- C22B25/02—Obtaining tin by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/02—Obtaining antimony
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/04—Obtaining arsenic
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/16—Dry methods smelting of sulfides or formation of mattes with volatilisation or condensation of the metal being produced
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/04—Refining by applying a vacuum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110854401.3A CN113737007B (zh) | 2021-07-28 | 2021-07-28 | 一种高锑粗锡分离提纯的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BE1029580A1 BE1029580A1 (de) | 2023-02-03 |
| BE1029580B1 true BE1029580B1 (de) | 2023-05-30 |
Family
ID=78729271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE20225452A BE1029580B1 (de) | 2021-07-28 | 2022-06-10 | Verfahren zur abtrennung und reinigung von hochantimonhaltigem rohzinn |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2024508599A (ja) |
| CN (1) | CN113737007B (ja) |
| BE (1) | BE1029580B1 (ja) |
| WO (1) | WO2023005810A1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113737007B (zh) * | 2021-07-28 | 2023-03-17 | 昆明理工大学 | 一种高锑粗锡分离提纯的方法 |
| CN114774704B (zh) * | 2022-04-20 | 2023-09-15 | 柳州华锡有色设计研究院有限责任公司 | 一种利用锡精炼渣生产低铅锡基巴氏合金的方法 |
| CN114807620B (zh) * | 2022-04-21 | 2024-04-26 | 昆明理工大学 | 一种铅锑砷三元合金真空气化-定向冷凝分离的设备及其方法 |
| CN115259220A (zh) * | 2022-07-25 | 2022-11-01 | 云南锡业锡化工材料有限责任公司 | 一种三锡酸二锑的制备方法 |
| CN116411175B (zh) * | 2023-06-12 | 2023-08-25 | 昆明理工大学 | 一种复杂粗铅火法精炼方法 |
| CN116426766B (zh) * | 2023-06-12 | 2023-08-29 | 昆明理工大学 | 一种复杂粗铅提银的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1156184A (zh) * | 1996-10-18 | 1997-08-06 | 昆明理工大学 | 含锑粗锡分离锑的方法 |
| WO2020157167A2 (en) * | 2019-01-30 | 2020-08-06 | Metallo Belgium | Improved tin production |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005002984A (ja) * | 2003-01-09 | 2005-01-06 | Hiroyasu Tanigawa | 各種竪型全動翼蒸気ガスタービン合体機関 |
| CN101696475B (zh) | 2009-10-29 | 2012-08-01 | 昆明理工大学 | 一种分离铅锡锑三元合金的方法 |
| CN101781711A (zh) * | 2010-03-29 | 2010-07-21 | 广西华锡集团股份有限公司 | 多元合金馏分分步冷凝和底流或馏分再蒸馏的真空蒸馏炉 |
| CN102492861B (zh) * | 2011-12-29 | 2014-07-02 | 昆明理工大学 | 一种粗锡火法精炼的方法 |
| CN104561595A (zh) * | 2014-12-08 | 2015-04-29 | 广西泰星电子焊接材料有限公司 | 粗锡真空精炼除锑的方法 |
| CN104651625A (zh) * | 2015-02-05 | 2015-05-27 | 昆明理工大学 | 一种含锑粗锡合金真空蒸馏脱除锑铅砷的方法 |
| CN104651627A (zh) * | 2015-02-05 | 2015-05-27 | 昆明鼎邦科技有限公司 | 一种锡锑合金真空蒸馏分离锑的方法 |
| CN104651626A (zh) * | 2015-02-05 | 2015-05-27 | 昆明鼎邦科技有限公司 | 一种锡铅锑砷合金真空蒸馏分离锡的方法 |
| CN206232790U (zh) * | 2016-12-09 | 2017-06-09 | 郴州万墨环保科技有限公司 | 一种铜阳极泥真空还原脱铅锑铋硒碲砷的环保生产系统 |
| CN107217145A (zh) * | 2016-12-09 | 2017-09-29 | 郴州万墨环保科技有限公司 | 一种铜阳极泥真空还原脱铅锑铋硒碲砷的方法 |
| CN111607708B (zh) * | 2020-07-14 | 2022-02-11 | 湖南金马冶金技术开发有限公司 | 一种高砷合金连续真空蒸馏脱砷工艺及系统 |
| CN112176196B (zh) * | 2020-10-12 | 2022-05-27 | 昆明理工大学 | 一种金银铜合金分离提纯的方法 |
| CN113737007B (zh) * | 2021-07-28 | 2023-03-17 | 昆明理工大学 | 一种高锑粗锡分离提纯的方法 |
-
2021
- 2021-07-28 CN CN202110854401.3A patent/CN113737007B/zh active Active
-
2022
- 2022-06-10 BE BE20225452A patent/BE1029580B1/de active IP Right Grant
- 2022-07-22 WO PCT/CN2022/107214 patent/WO2023005810A1/zh active Application Filing
- 2022-07-22 JP JP2023541919A patent/JP2024508599A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1156184A (zh) * | 1996-10-18 | 1997-08-06 | 昆明理工大学 | 含锑粗锡分离锑的方法 |
| WO2020157167A2 (en) * | 2019-01-30 | 2020-08-06 | Metallo Belgium | Improved tin production |
Also Published As
| Publication number | Publication date |
|---|---|
| BE1029580A1 (de) | 2023-02-03 |
| WO2023005810A1 (zh) | 2023-02-02 |
| CN113737007B (zh) | 2023-03-17 |
| JP2024508599A (ja) | 2024-02-28 |
| CN113737007A (zh) | 2021-12-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Patent granted |
Effective date: 20230530 |