AU2005228434A1 - Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand - Google Patents
Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand Download PDFInfo
- Publication number
- AU2005228434A1 AU2005228434A1 AU2005228434A AU2005228434A AU2005228434A1 AU 2005228434 A1 AU2005228434 A1 AU 2005228434A1 AU 2005228434 A AU2005228434 A AU 2005228434A AU 2005228434 A AU2005228434 A AU 2005228434A AU 2005228434 A1 AU2005228434 A1 AU 2005228434A1
- Authority
- AU
- Australia
- Prior art keywords
- substituted
- hydrocarbyl
- heteroatom
- hydrocarbylene
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F132/00—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F132/08—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/11—Homopolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2011205218A AU2011205218B2 (en) | 2004-03-29 | 2011-08-08 | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55774204P | 2004-03-29 | 2004-03-29 | |
| US60/557,742 | 2004-03-29 | ||
| US60415804P | 2004-08-23 | 2004-08-23 | |
| US60/604,158 | 2004-08-23 | ||
| PCT/US2005/010548 WO2005094345A2 (en) | 2004-03-29 | 2005-03-29 | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2011205218A Division AU2011205218B2 (en) | 2004-03-29 | 2011-08-08 | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2005228434A1 true AU2005228434A1 (en) | 2005-10-13 |
Family
ID=35064307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2005228434A Abandoned AU2005228434A1 (en) | 2004-03-29 | 2005-03-29 | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US20050261451A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1735352B1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP2007530706A (cg-RX-API-DMAC7.html) |
| AU (1) | AU2005228434A1 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0509322A (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA06011302A (cg-RX-API-DMAC7.html) |
| PL (1) | PL1735352T3 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2005094345A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19815275B4 (de) * | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| EP1603857A4 (en) * | 2003-01-13 | 2006-05-17 | Cargill Inc | PROCESS FOR PRODUCING INDUSTRIAL CHEMICALS |
| US7037987B2 (en) | 2004-03-26 | 2006-05-02 | Rohn And Haas Company | Olefin polymerization catalyst and polymerization process |
| WO2007081987A2 (en) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
| PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
| CN101479283B (zh) * | 2006-06-30 | 2012-07-04 | 弗·哈夫曼-拉罗切有限公司 | 作为复分解反应催化剂的钌络合物 |
| US8067623B2 (en) | 2006-07-12 | 2011-11-29 | Elevance Renewable Sciences, Inc. | Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like |
| US8067610B2 (en) | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
| EP2076483A4 (en) | 2006-10-13 | 2013-12-04 | Elevance Renewable Sciences | METHODS FOR PRODUCING ORGANIC COMPOUNDS BY METATHESIS AND HYDROCYANATION |
| CN102123979A (zh) * | 2006-10-13 | 2011-07-13 | 埃莱文斯可更新科学公司 | 通过烯烃复分解由内烯烃合成末端烯烃的方法 |
| WO2008140468A2 (en) | 2006-10-13 | 2008-11-20 | Elevance Renewable Sciences, Inc. | METHODS OF MAKING α, ω -DICARBOXYLIC ACID ALKENE DERIVATIVES BY METATHESIS |
| EP2104566B1 (en) | 2006-11-21 | 2016-01-27 | California Institute Of Technology | Olefin metathesis initiators bearing thiazol-2-ylidene ligands |
| DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
| JP5547631B2 (ja) * | 2007-06-20 | 2014-07-16 | エージェンシー フォー サイエンス, テクノロジー アンド リサーチ | N−複素環式カルベンメタラサイクル触媒およびその方法 |
| JP5365625B2 (ja) * | 2008-03-31 | 2013-12-11 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| RU2377257C1 (ru) * | 2008-07-31 | 2009-12-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения катализатора метатезисной полимеризации дициклопентадиена |
| RU2393171C1 (ru) * | 2008-12-10 | 2010-06-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Катализатор метатезисной полимеризации дициклопентадиена, способы его получения и способ его полимеризации |
| EP2280033B1 (en) | 2008-05-22 | 2014-03-12 | Limited Liability Company "United Research and Development Centre" | Dicyclopentadiene metathesis polymerisation catalyst |
| RU2375379C1 (ru) * | 2008-05-22 | 2009-12-10 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Катализатор метатезисной полимеризации дициклопентадиена, способ его получения (варианты) и способ его полимеризации |
| JP2012518040A (ja) * | 2009-02-18 | 2012-08-09 | ヘンケル コーポレイション | 熱スイッチ可能なルテニウム開始剤 |
| CN102803433A (zh) * | 2009-05-05 | 2012-11-28 | 斯特潘公司 | 用于提高石油采收率的磺化内烯烃表面活性剂 |
| EP2255877B1 (en) * | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
| RU2402572C1 (ru) * | 2009-07-09 | 2010-10-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения полидициклопентадиена и материалов на его основе |
| RU2409420C1 (ru) * | 2009-08-21 | 2011-01-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена и способ его получения |
| WO2011043893A2 (en) * | 2009-10-08 | 2011-04-14 | The Regents Of The University Of California | Molecular metal-oxo catalysts for generating hydrogen from water |
| RU2436801C1 (ru) * | 2010-05-27 | 2011-12-20 | Закрытое Акционерное Общество "Сибур Холдинг" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена (варианты) и способ получения полидициклопентадиена (варианты) |
| CN103415546A (zh) * | 2011-03-08 | 2013-11-27 | 日本瑞翁株式会社 | 聚合性组合物、树脂成形体及层叠体 |
| US8993819B2 (en) | 2011-07-12 | 2015-03-31 | Basf Se | Process for preparing cycloheptene |
| US9181360B2 (en) | 2011-08-12 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening / cross metathesis |
| WO2013025284A1 (en) * | 2011-08-12 | 2013-02-21 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening/cross metathesis |
| WO2013134192A1 (en) * | 2012-03-05 | 2013-09-12 | California Institute Of Technology | Syntheses of z-olefin-containing lepidopteran insect pheromones |
| EP2639219B1 (en) * | 2012-03-14 | 2016-08-10 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts and precursors for their preparation |
| US9598531B2 (en) | 2013-02-27 | 2017-03-21 | Materia, Inc. | Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts |
| CA2902451C (en) * | 2013-02-27 | 2021-05-25 | Materia, Inc. | Metal carbene olefin metathesis two catalyst composition |
| MY184011A (en) | 2013-07-03 | 2021-03-17 | Materia Inc | Liquid molding compositions |
| US9382354B2 (en) | 2013-11-22 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyesters containing polyolefin arms |
| WO2015076958A1 (en) * | 2013-11-22 | 2015-05-28 | Exxonmobil Chemical Patents Inc. | Novel polyesters containing polyolefin arms |
| RU2545176C1 (ru) * | 2014-01-29 | 2015-03-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Катализатор метатезисной полимеризации дициклопентадиена и способ его получения |
| RU2545179C1 (ru) * | 2014-01-29 | 2015-03-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Катализатор метатезисной полимеризации дициклопентадиена в форме рутениевого комплекса и способ его получения |
| RU2560151C1 (ru) * | 2014-01-29 | 2015-08-20 | Открытое акционерное общество "Нефтяная компания Роснефть" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена в форме катионного комплекса и способ его получения |
| CN113307830A (zh) * | 2015-09-24 | 2021-08-27 | 优美科股份公司及两合公司 | 金属卡宾烯烃易位催化剂 |
| PL3377465T3 (pl) | 2015-11-18 | 2024-02-12 | Provivi, Inc. | Wytwarzanie pochodnych olefin tłuszczowych przez metatezę olefin |
| BR112018010108A2 (pt) | 2015-11-18 | 2018-11-21 | Provivi Inc | micro-organismos para a produção de ferormônios de inseto e compostos relacionados |
| CA3006976A1 (en) | 2015-12-10 | 2017-06-15 | California Institute Of Technology | Olefin metathesis catalysts |
| US11214818B2 (en) | 2016-06-06 | 2022-01-04 | Provivi, Inc. | Semi-biosynthetic production of fatty alcohols and fatty aldehydes |
| CN114106057B (zh) * | 2016-10-19 | 2023-06-23 | 优美科股份公司及两合公司 | Ru亚烷基络合物的合成与表征 |
| WO2018150379A2 (en) | 2017-02-17 | 2018-08-23 | Provivi, Inc. | Synthesis of pheromones and related materials via olefin metathesis |
| CN110914442B (zh) | 2017-05-17 | 2025-02-18 | 普罗维维股份有限公司 | 用于产生昆虫信息素及相关化合物的微生物 |
| JP7416428B2 (ja) | 2017-12-01 | 2024-01-17 | ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド | 立体規則性環拡大メタセシス重合のための組成物および方法 |
| CN109794292B (zh) * | 2019-01-10 | 2021-12-07 | 天津大学 | Z-选择性钌卡宾烯烃复分解催化剂及其制备方法与应用 |
| PL429476A1 (pl) | 2019-04-02 | 2020-10-05 | Apeiron Synthesis Spółka Akcyjna | Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin |
| US12440831B2 (en) * | 2019-11-11 | 2025-10-14 | The Trustees of the California State University | Longer-lived ruthenium olefin metathesis catalysts supported by hemi-labile carbene ligands |
| CN115996901A (zh) | 2020-05-29 | 2023-04-21 | 埃克森美孚化学专利公司 | 由聚合物生产环状烯烃及其再聚合的方法 |
| CN111777647A (zh) * | 2020-07-31 | 2020-10-16 | 山东京博中聚新材料有限公司 | 一种共轭二烯烃聚合物中碳-碳双键的连续氢化生产装置和方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| WO1996004289A1 (en) | 1992-04-03 | 1996-02-15 | California Institute Of Technology | High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| DE69818240T2 (de) | 1997-03-06 | 2004-07-01 | Ciba Speciality Chemicals Holding Inc. | Neue katalysatoren |
| KR100569620B1 (ko) * | 1997-06-27 | 2006-04-11 | 시바 스페셜티 케미칼스 홀딩 인크. | 루테늄 및 오스뮴 촉매 |
| EP1036081B1 (en) * | 1997-12-04 | 2002-07-17 | Ciba SC Holding AG | Heterocyclyl ligand containing ruthenium and osmium catalysts |
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| US6107420A (en) | 1998-07-31 | 2000-08-22 | California Institute Of Technology | Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes |
| MXPA01012033A (es) | 1999-05-24 | 2002-11-04 | California Inst Of Techn | Catalizador de metatesis de metal-carbeno basado en inidazolidina. |
| US6921735B2 (en) * | 2000-08-10 | 2005-07-26 | The Trustees Of Boston College | Recyclable metathesis catalysts |
| US6759537B2 (en) | 2001-03-23 | 2004-07-06 | California Institute Of Technology | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
| WO2002079127A1 (en) * | 2001-03-30 | 2002-10-10 | California Institute Of Technology | Selective ring-opening cross-metathesis of cycloolefins |
| EP1421121A4 (en) * | 2001-08-29 | 2007-05-23 | California Inst Of Techn | RING-OPENING METETHESEPOLYMERIZATION OF BROKEN BICYCLIC AND POLYCLYCLINIC OLEFINS WITH TWO OR MORE HETEROATOMES |
| EP1501784B1 (en) * | 2002-04-29 | 2019-03-13 | Dow Global Technologies LLC | Integrated chemical processes for industrial utilization of seed oils |
-
2005
- 2005-03-29 EP EP05743168.6A patent/EP1735352B1/en not_active Expired - Lifetime
- 2005-03-29 BR BRPI0509322-8A patent/BRPI0509322A/pt not_active Application Discontinuation
- 2005-03-29 WO PCT/US2005/010548 patent/WO2005094345A2/en not_active Ceased
- 2005-03-29 JP JP2007506479A patent/JP2007530706A/ja not_active Withdrawn
- 2005-03-29 PL PL05743168T patent/PL1735352T3/pl unknown
- 2005-03-29 MX MXPA06011302A patent/MXPA06011302A/es active IP Right Grant
- 2005-03-29 AU AU2005228434A patent/AU2005228434A1/en not_active Abandoned
- 2005-03-29 US US11/094,102 patent/US20050261451A1/en not_active Abandoned
-
2011
- 2011-12-08 JP JP2011269459A patent/JP5622711B2/ja not_active Expired - Fee Related
-
2013
- 2013-02-27 US US13/779,190 patent/US8871879B2/en not_active Expired - Lifetime
-
2014
- 2014-09-26 US US14/497,387 patent/US9238709B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20130296511A1 (en) | 2013-11-07 |
| US20050261451A1 (en) | 2005-11-24 |
| JP5622711B2 (ja) | 2014-11-12 |
| WO2005094345A3 (en) | 2006-06-22 |
| EP1735352A4 (en) | 2011-05-11 |
| US20150141603A1 (en) | 2015-05-21 |
| MXPA06011302A (es) | 2007-01-16 |
| US8871879B2 (en) | 2014-10-28 |
| EP1735352B1 (en) | 2019-08-21 |
| BRPI0509322A (pt) | 2007-09-04 |
| US9238709B2 (en) | 2016-01-19 |
| JP2007530706A (ja) | 2007-11-01 |
| WO2005094345A2 (en) | 2005-10-13 |
| PL1735352T3 (pl) | 2020-06-29 |
| JP2012082435A (ja) | 2012-04-26 |
| EP1735352A2 (en) | 2006-12-27 |
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