EP2742074A4 - Polymers prepared by ring opening/cross metathesis - Google Patents

Polymers prepared by ring opening/cross metathesis

Info

Publication number
EP2742074A4
EP2742074A4 EP12824641.0A EP12824641A EP2742074A4 EP 2742074 A4 EP2742074 A4 EP 2742074A4 EP 12824641 A EP12824641 A EP 12824641A EP 2742074 A4 EP2742074 A4 EP 2742074A4
Authority
EP
European Patent Office
Prior art keywords
ring opening
polymers prepared
cross metathesis
metathesis
cross
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12824641.0A
Other languages
German (de)
French (fr)
Other versions
EP2742074A1 (en
Inventor
Matthew W Holtcamp
John R Hagadorn
Caol P Huff
Matthew S Bedoya
Catherine A Faler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/209,242 external-priority patent/US9181360B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP12824641.0A priority Critical patent/EP2742074A4/en
Publication of EP2742074A1 publication Critical patent/EP2742074A1/en
Publication of EP2742074A4 publication Critical patent/EP2742074A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/16—End groups
    • C08G2261/164—End groups comprising organic end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/16—End groups
    • C08G2261/164—End groups comprising organic end groups
    • C08G2261/1642—End groups comprising organic end groups comprising reactive double bonds or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/72—Derivatisation
    • C08G2261/724—Hydrogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP12824641.0A 2011-08-12 2012-06-25 Polymers prepared by ring opening/cross metathesis Withdrawn EP2742074A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12824641.0A EP2742074A4 (en) 2011-08-12 2012-06-25 Polymers prepared by ring opening/cross metathesis

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/209,242 US9181360B2 (en) 2011-08-12 2011-08-12 Polymers prepared by ring opening / cross metathesis
EP11182277 2011-09-22
EP12824641.0A EP2742074A4 (en) 2011-08-12 2012-06-25 Polymers prepared by ring opening/cross metathesis
PCT/US2012/043985 WO2013025284A1 (en) 2011-08-12 2012-06-25 Polymers prepared by ring opening/cross metathesis

Publications (2)

Publication Number Publication Date
EP2742074A1 EP2742074A1 (en) 2014-06-18
EP2742074A4 true EP2742074A4 (en) 2015-04-01

Family

ID=47715352

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12824641.0A Withdrawn EP2742074A4 (en) 2011-08-12 2012-06-25 Polymers prepared by ring opening/cross metathesis

Country Status (3)

Country Link
EP (1) EP2742074A4 (en)
CN (1) CN103732636B (en)
WO (1) WO2013025284A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2826802B1 (en) * 2012-03-16 2021-03-10 Zeon Corporation Method for producing ring-opening metathesis polymer hydride, and resin composition
MX2015010583A (en) * 2013-02-27 2016-04-07 Materia Inc Metal carbene olefin metathesis two catalyst composition.
US9598531B2 (en) 2013-02-27 2017-03-21 Materia, Inc. Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts
CN112867741B (en) * 2018-09-20 2023-08-01 埃克森美孚化学专利公司 Metathesis catalyst system for polymerizing cycloolefins
CN110170077B (en) * 2019-03-26 2021-09-28 南京理工大学 Polyion type biological lubricant and preparation method thereof
TWI834019B (en) * 2020-01-09 2024-03-01 日商住友電木股份有限公司 Stable mass polymerizable polycycloolefin compositions as 3d printing materials and a method of fabrication thereof
WO2022008946A1 (en) * 2020-07-08 2022-01-13 Centre National De La Recherche Scientifique Optically pure enantiomers of ruthenium complexes and uses thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040131850A1 (en) * 2002-07-23 2004-07-08 Hedden Jerry C. Glass fiber sizing compositions, sized glass fibers, and polyolefin composites
US20050261451A1 (en) * 2004-03-29 2005-11-24 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
WO2012040088A2 (en) * 2010-09-24 2012-03-29 Exxonmobil Chemical Patents, Inc. A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5763349A (en) * 1980-10-03 1982-04-16 Kanegafuchi Chem Ind Co Ltd Composition
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
US5831108A (en) * 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US6465590B1 (en) * 1998-03-30 2002-10-15 California Institute Of Technology Telechelic alkadiene polymers with crosslinkable end groups and methods for making the same
US7329758B1 (en) * 1999-05-24 2008-02-12 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
WO2002079127A1 (en) * 2001-03-30 2002-10-10 California Institute Of Technology Selective ring-opening cross-metathesis of cycloolefins
US7312331B2 (en) * 2005-06-17 2007-12-25 The Regents Of The University Of California Stable cyclic (alkyl)(amino) carbenes as ligands for transition metal catalysts
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
EP2498909B1 (en) * 2009-11-09 2014-08-27 ExxonMobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
US8227371B2 (en) * 2010-09-24 2012-07-24 Exxonmobil Chemical Patents Inc. Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040131850A1 (en) * 2002-07-23 2004-07-08 Hedden Jerry C. Glass fiber sizing compositions, sized glass fibers, and polyolefin composites
US20050261451A1 (en) * 2004-03-29 2005-11-24 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
WO2012040088A2 (en) * 2010-09-24 2012-03-29 Exxonmobil Chemical Patents, Inc. A novel class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BIELAWSKI ET AL: "Living ring-opening metathesis polymerization", PROGRESS IN POLYMER SCIENCE, PERGAMON PRESS, OXFORD, GB, vol. 32, no. 1, 5 February 2007 (2007-02-05), pages 1 - 29, XP005876108, ISSN: 0079-6700, DOI: 10.1016/J.PROGPOLYMSCI.2006.08.006 *
See also references of WO2013025284A1 *

Also Published As

Publication number Publication date
CN103732636B (en) 2016-05-18
CN103732636A (en) 2014-04-16
EP2742074A1 (en) 2014-06-18
WO2013025284A1 (en) 2013-02-21

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RIN1 Information on inventor provided before grant (corrected)

Inventor name: HAGADORN, JOHN, R.

Inventor name: BEDOYA, MATTHEW, S.

Inventor name: HUFF, CAOL, P.

Inventor name: HOLTCAMP, MATTHEW, W.

Inventor name: FALER, CATHERINE, A.

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

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