AR083874A1 - 5-halogenopirazol(tio)carboxamidas - Google Patents

5-halogenopirazol(tio)carboxamidas

Info

Publication number
AR083874A1
AR083874A1 ARP110104251A AR083874A1 AR 083874 A1 AR083874 A1 AR 083874A1 AR P110104251 A ARP110104251 A AR P110104251A AR 083874 A1 AR083874 A1 AR 083874A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
optionally substituted
compound
represents hydrogen
Prior art date
Application number
Other languages
English (en)
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR083874A1 publication Critical patent/AR083874A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La presente se refiere a 5-halógenopirazol(tio)carboxamidas, su procedimiento de preparación, su uso como agentes activos fungicidas, particularmente en forma de composiciones fungicidas, y métodos para el control de hongos fitopatógenos, especialmente de plantas, usando estos compuestos o composiciones.Reivindicación 1: Un compuesto 1-metil-3-dihalógenometil-5-halógenopirazol(tio)carboxamida de fórmula (1) en la que T representa un átomo de oxígeno o azufre; R representa hidrógeno, alquil C1-6-sulfonilo, alcoxi C1-4-alquilo C1-4, haloalquil C1-4-sulfonilo, haloalcoxi C1-4-alquilo C1-4 o formilo; Hal1 y Hal2 representan independientemente entre sí cloro o flúor; Q representa Q1, Q2, Q3, Q4, Q5, ó Q6; L representa un compuesto del grupo de fórmulas (2), donde en enlace marcado por * está unido a la amida, mientras que el enlace marcado # está unido a Q; R1 representa hidrógeno, halógeno, alquilo C1-4 o haloalquilo C1-4; Q1 representa el compuesto de formula (3), donde el enlace marcado # está unido a L; R2 representa hidrógeno, alquilo C1-4, cicloalquilo C3-6, haloalquilo C1-4 o fenilo opcionalmente sustituido; Z1 representa -CR3R4R5 o -SiR3R4R5; s representa 0, 1, 2 ó 3; t representa 0 ó 1; R3 representa hidrógeno, ciano, alquilo C1-8, o haloalquilo C1-6; R4, R5 independientemente entre sí representan hidrógeno, alquilo C1-8, haloalquilo C1-6; o R3 y R4 junto con el átomo de carbono al que están unidos forman un anillo saturado o insaturado, carbocíclico o heterocíclico de 3 a 6 miembros opcionalmente sustituido; Q2 representa el compuesto de fórmula (4) donde el enlace marcado # está unido a L; R6 representa hidrógeno, alquilo C1-4, cicloalquilo C3-6, haloalquilo C1-4 o fenilo opcionalmente sustituido; R7 representa hidrógeno, alquilo C1-4 o haloalquilo C1-4; Z2 representa hidrógeno, -CR8R9R10 o -SiR8R9R10; u representa 0, 1 ó 2; R8 representa hidrógeno, ciano, alquilo C1-8, o haloalquilo C1-6; o R7 y R8 junto con los átomos de carbono a los que están unidos forman un anillo saturado o insaturado carbocíclico opcionalmente sustituido de 3 a 6 miembros; R9, R10 independientemente entre sí representan hidrógeno, alquilo C1-8, o haloalquilo C1-6; o R8 y R9 junto con el átomo de carbono al que están unidos forman un anillo saturado o insaturado carbocíclico opcionalmente sustituido de 3 a 6 miembros; Q3 representa el compuesto de formula (5), donde el enlace marcado # está unido a L; R11 representa hidrógeno o halógeno; R12 representa hidrógeno o halógeno; R13 representa alquilo C2-12 opcionalmente sustituido, alquenilo C2-12 opcionalmente sustituido, alquinilo C2-12 opcionalmente sustituido, cicloalquilo C3-12 opcionalmente sustituido, fenilo o heterociclilo opcionalmente sustituido; Q4 representa el compuesto de formula (6) donde el enlace marcado # está unido a L; R14, R15 y R16 representan independientemente entre sí halógeno, ciano, nitro, alquilo C1-6, alquenilo C2-6, alcoxi C1-4, alquil C1-4-sulfanilo, alquil C1-4-sulfonilo, cicloalquilo C3-6, o representan haloalquilo C1-4, haloalcoxi C1-4, haloalquil C1-4-sulfanilo o haloalquil C1-4-sulfonilo que tienen en casa caso de 1 a 5 átomos de halógeno; Q5 representa el compuesto de formula (7), donde el enlace marcado # está unido a L; Q6 representa el compuesto de formula (8), donde R17 representa hidrógeno o flúor; donde, a menos que se indique otra cosa, un grupo o un sustituyente que está sustituido de acuerdo con la presente está sustituido con uno o más grupos seleccionados de la lista que consiste en halógeno; nitro, ciano, alquilo C1-12; haloalquilo C1-6 que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alcoxi C1-6; haloalcoxi C1-6 que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquil C1-6-sulfanilo; haloalquil C1-6-sulfanilo que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquil C1-6-sulfonilo; haloalquil C1-6-sulfonilo que tiene de 1 a 9 átomos de halógeno iguales o diferentes; alquenilo C2-12; alquinilo C2-12; cicloalquilo C3-7; fenilo; tri(alquil C1-8)sililo; tri(alquil C1-8)sililo-alquilo C1-8.
ARP110104251 2010-11-15 2011-11-14 5-halogenopirazol(tio)carboxamidas AR083874A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP10191265 2010-11-15

Publications (1)

Publication Number Publication Date
AR083874A1 true AR083874A1 (es) 2013-03-27

Family

ID=44925560

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP110104251 AR083874A1 (es) 2010-11-15 2011-11-14 5-halogenopirazol(tio)carboxamidas

Country Status (8)

Country Link
US (1) US20130231303A1 (es)
EP (1) EP2640191A1 (es)
JP (1) JP2013543858A (es)
CN (1) CN103369962A (es)
AR (1) AR083874A1 (es)
BR (1) BR112013012081A2 (es)
MX (1) MX2013005410A (es)
WO (1) WO2012065945A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015014307A2 (pt) 2012-12-19 2017-07-11 Bayer Cropscience Ag difluorometil-nicotínico- tetrahidronaftil carboxamidas
MX2015007710A (es) 2012-12-19 2015-09-23 Bayer Cropscience Ag Indanilcarboxamidas difluorometil-nicotinicas.
WO2015039877A1 (en) * 2013-09-20 2015-03-26 Bayer Cropscience Ag Process for preparing 5-fluoro-1-alkyl-3-fluoroalkyl-1h-pyrazole-4-carbaldehyde
WO2015063086A1 (en) 2013-10-30 2015-05-07 Bayer Cropscience Ag Benzocyclobutane(thio) carboxamides
JP6911143B2 (ja) 2018-11-07 2021-07-28 福建永晶科技股▲ふん▼有限公司Ｆｕｊｉａｎ Ｙｏｎｇｊｉｎｇ Ｔｅｃｈｎｏｌｏｇｙ Ｃｏ．， Ｌｔｄ ピラゾール又はピリミジノンの新しい製造方法

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