ZA929215B - Process for the preparation of substituted indenes and their use as ligand systems for metallocene catalysts. - Google Patents

Process for the preparation of substituted indenes and their use as ligand systems for metallocene catalysts.

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Publication number
ZA929215B
ZA929215B ZA929215A ZA929215A ZA929215B ZA 929215 B ZA929215 B ZA 929215B ZA 929215 A ZA929215 A ZA 929215A ZA 929215 A ZA929215 A ZA 929215A ZA 929215 B ZA929215 B ZA 929215B
Authority
ZA
South Africa
Prior art keywords
preparation
metallocene catalysts
iva
compound
image
Prior art date
Application number
ZA929215A
Other languages
English (en)
Inventor
Juergen Rohrmann
Frank Kueber
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of ZA929215B publication Critical patent/ZA929215B/xx

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/67—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having two rings, e.g. tetralones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/675—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
    • C07C2603/20—Acenaphthenes; Hydrogenated acenaphthenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
ZA929215A 1991-11-30 1992-11-27 Process for the preparation of substituted indenes and their use as ligand systems for metallocene catalysts. ZA929215B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4139594 1991-11-30

Publications (1)

Publication Number Publication Date
ZA929215B true ZA929215B (en) 1993-05-27

Family

ID=6446018

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA929215A ZA929215B (en) 1991-11-30 1992-11-27 Process for the preparation of substituted indenes and their use as ligand systems for metallocene catalysts.

Country Status (12)

Country Link
US (4) US6051522A (ja)
EP (1) EP0545304B1 (ja)
JP (2) JP3290218B2 (ja)
KR (1) KR100322976B1 (ja)
AT (1) ATE219494T1 (ja)
AU (1) AU655088B2 (ja)
CA (1) CA2084016C (ja)
DE (1) DE59209962D1 (ja)
ES (1) ES2177523T3 (ja)
RU (1) RU2103250C1 (ja)
TW (1) TW309523B (ja)
ZA (1) ZA929215B (ja)

Families Citing this family (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW294669B (ja) 1992-06-27 1997-01-01 Hoechst Ag
EP0882731A3 (de) * 1992-08-15 2000-05-31 TARGOR GmbH Verbrückte Metallocenverbindungen und ihre Verwendung als Olefinpolymerisationskatalysatore
ES2154664T3 (es) * 1993-11-24 2001-04-16 Targor Gmbh Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores.
EP0668157B1 (de) 1994-02-21 2003-05-21 Basell Polyolefine GmbH Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung
JP3357186B2 (ja) 1994-07-14 2002-12-16 三菱化学株式会社 プロピレンブロック共重合体の製造法
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
US5594081A (en) 1994-07-22 1997-01-14 Mitsubishi Chemical Corporation Catalyst component for the polymerization of α-olefins and a process for preparing α-olefin polymers with use of same
IT1272924B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
JP3946248B2 (ja) * 1995-03-30 2007-07-18 出光興産株式会社 遷移金属化合物、オレフィン重合用触媒及びオレフィン系重合体の製造方法
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
DE19624828C1 (de) * 1996-06-21 1998-03-26 Basf Ag Verfahren zur Herstellung substituierter Benzoindanone
WO1997049712A2 (en) * 1996-06-27 1997-12-31 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
DE19634684C1 (de) * 1996-08-28 1998-03-12 Basf Ag Verfahren zur Herstellung von Indenderivaten
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
DE19729833A1 (de) 1997-07-11 1999-01-14 Clariant Gmbh Polypropylenwachs
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
US6211300B1 (en) 1998-04-10 2001-04-03 Chisso Corporation Propylene-ethylene block copolymer compositions and processes for production thereof
US6025512A (en) * 1999-01-06 2000-02-15 Univation Technologies, Llc Pentafulvene synthesis
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
US6635733B2 (en) * 2000-05-23 2003-10-21 Chisso Corporation Elastomeric polypropylene
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
DE10025412A1 (de) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
WO2002018397A1 (de) * 2000-08-29 2002-03-07 Basell Polypropylen Gmbh VERFAHREN ZUR HERSTELLUNG VON AlKYLVERBRÜCKTEN LIGANDSYSTEMEN UND ÜBERGANGSMETALLVERBINDUNGEN
US6548710B2 (en) 2000-10-31 2003-04-15 Akzo Nobel N.V. Process for preparing 1-indanones
DE60125408T2 (de) * 2000-10-31 2007-09-27 Akzo Nobel N.V. Verfahren zur herstellung von 1-indanonen
JP4687849B2 (ja) * 2001-04-05 2011-05-25 Ｊｘ日鉱日石エネルギー株式会社 高純度ジイソプロピルエーテルおよびその製法
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
ES2361734T3 (es) * 2001-07-19 2011-06-21 Univation Technologies Llc Películas de polietileno con propiedades físicas mejoradas.
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
JP2004536183A (ja) 2001-07-19 2004-12-02 ユニベーション・テクノロジーズ・エルエルシー コモノマー低結合性メタロセン触媒化合物
BR0211288A (pt) 2001-07-19 2004-08-10 Univation Tech Llc Sistemas catalisadores de metaloceno mistos contendo um incorporador de comonÈmero fraco e um incorporador de comonÈmero bom
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
BRPI0513057A (pt) * 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
ATE425983T1 (de) * 2005-08-09 2009-04-15 Borealis Tech Oy Siloxy substituierte metallocenkatalysatoren
WO2007042252A1 (en) * 2005-10-14 2007-04-19 Basell Polyolefine Gmbh Hybrid catalyst systems supported on magnesium halide
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
US7858717B2 (en) 2006-03-17 2010-12-28 Basell Polyolefine Gmbh Metallocene compounds
JP2009533382A (ja) * 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8722833B2 (en) * 2006-12-22 2014-05-13 Basell Polyolefine Gmbh Multimodal polyethylene composition, mixed catalyst and process for preparing the composition
US8227557B2 (en) 2007-03-06 2012-07-24 Basell Polyolefine Gmbh Iron complexes and their use in polymerization processes
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
WO2008150572A1 (en) * 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8133832B2 (en) * 2007-07-27 2012-03-13 Basell Polyolefine Gmbh Catalyst system for polymerization of olefinic monomers, process for preparing polymers, and polymers prepared by the process
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
MY152524A (en) 2008-02-18 2014-10-15 Basell Polyolefine Gmbh Adhesive polymer composition
JP2011528738A (ja) 2008-07-23 2011-11-24 バーゼル・ポリオレフィン・ゲーエムベーハー 両立しないオレフィン重合触媒系間の変移方法
EP2328968B1 (en) 2008-08-29 2017-05-03 Basell Polyolefine GmbH Polyethylene for injection moldings
WO2010034520A1 (en) 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
US8957158B2 (en) 2008-09-25 2015-02-17 Basell Polyolefine Gmbh Impact resistant LLDPE composition and films made thereof
EP2367855B1 (en) 2008-12-23 2012-09-05 Basell Polyolefine GmbH Method for transitioning between incompatible olefin polymerization catalyst systems
JP5807325B2 (ja) 2009-09-30 2015-11-10 住友化学株式会社 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１−ヘキセンの製造方法、エチレン系重合体の製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法
WO2011072851A1 (en) 2009-12-18 2011-06-23 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
PL2563957T3 (pl) 2010-04-30 2018-09-28 Basell Polyolefine Gmbh Polimerowy filament lub włókno
US9029478B2 (en) 2011-02-07 2015-05-12 Equistar Chemicals, Lp High clarity polyethylene films
KR101212637B1 (ko) * 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
US9321945B2 (en) 2011-09-30 2016-04-26 Equistar Chemicals, Lp Systems, methods and compositions for production of tie-layer adhesives
CN103772443A (zh) * 2012-10-24 2014-05-07 中国石油化工股份有限公司 一种桥联茂金属化合物及其制备方法
EP2746320A1 (en) 2012-12-20 2014-06-25 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
CN105593249B (zh) 2013-10-14 2018-10-09 巴塞尔聚烯烃股份有限公司 耐热性提高的聚乙烯
WO2021083309A1 (zh) 2019-10-30 2021-05-06 中国石油化工股份有限公司 一种茂金属化合物及其制备方法和应用
EP4069775B1 (en) 2019-12-03 2024-04-03 Basell Polyolefine GmbH Polyethylene composition for filaments or fibers
WO2021110762A1 (en) 2019-12-03 2021-06-10 Basell Polyolefine Gmbh Polyethylene composition for filaments or fibers
CN111333494B (zh) * 2019-12-10 2023-07-11 武汉海昕药物研究有限公司 6-甲氧基-1-萘满酮的合成方法

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT344153B (de) * 1974-10-29 1978-07-10 Hexachimie Verfahren zur herstellung neuer 2-alkyl-5-indanessigsaeure- und -alkylester-derivate
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US5654248A (en) * 1986-08-26 1997-08-05 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing alpha-olefins and process for polymerization
US5700749A (en) * 1986-09-24 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
ATE133690T1 (de) * 1987-04-03 1996-02-15 Fina Technology Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke.
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
EP0355289A1 (en) * 1988-07-01 1990-02-28 ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) Accelerometer
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
JP2835729B2 (ja) * 1988-10-24 1998-12-14 チッソ株式会社 オレフィン重合体の製造方法
EP0769505B1 (en) * 1988-12-26 2000-05-10 Mitsui Chemicals, Inc. Olefin copolymers and processes for preparing same
JPH02208213A (ja) * 1989-02-07 1990-08-17 Koa Oil Co Ltd 圧縮弾性にすぐれた炭素質成形体の製造方法
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
CA2027145C (en) * 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
CA2027123C (en) * 1989-10-30 2001-09-04 Michael J. Elder Metallocene catalysts for polymerization of olefins
EP0426643B1 (en) * 1989-10-30 1995-12-27 Fina Research S.A. Process for the preparation of metallocenes
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE59104869D1 (de) * 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
EP0485821B1 (de) * 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
ES2091273T3 (es) * 1990-11-12 1996-11-01 Hoechst Ag Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
DE4104931A1 (de) * 1991-02-18 1992-08-20 Hoechst Ag Verfahren zur herstellung substituierter indene
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
DE4120006A1 (de) * 1991-06-18 1992-12-24 Basf Ag Durch vorpolymerisation getraegerte katalysatorsysteme zur herstellung von polyalk-1-enen
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒
TW300901B (ja) * 1991-08-26 1997-03-21 Hoechst Ag
TW318184B (ja) * 1991-11-30 1997-10-21 Hoechst Ag
ATE141609T1 (de) * 1991-11-30 1996-09-15 Hoechst Ag Metallocene mit benzokondensierten indenylderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
EP0582194B1 (de) * 1992-08-03 1998-05-06 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
EP0882731A3 (de) * 1992-08-15 2000-05-31 TARGOR GmbH Verbrückte Metallocenverbindungen und ihre Verwendung als Olefinpolymerisationskatalysatore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0812854B2 (en) * 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4436113A1 (de) * 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung

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RU2103250C1 (ru) 1998-01-27
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AU655088B2 (en) 1994-12-01
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CA2084016A1 (en) 1993-05-31
US6051522A (en) 2000-04-18
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AU2972792A (en) 1993-06-03
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US5852142A (en) 1998-12-22

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