ZA200404371B - Boron Doped Diamond. - Google Patents
Boron Doped Diamond. Download PDFInfo
- Publication number
- ZA200404371B ZA200404371B ZA200404371A ZA200404371A ZA200404371B ZA 200404371 B ZA200404371 B ZA 200404371B ZA 200404371 A ZA200404371 A ZA 200404371A ZA 200404371 A ZA200404371 A ZA 200404371A ZA 200404371 B ZA200404371 B ZA 200404371B
- Authority
- ZA
- South Africa
- Prior art keywords
- diamond
- less
- layer according
- layer
- diamond layer
- Prior art date
Links
- 239000010432 diamond Substances 0.000 title claims abstract description 137
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 137
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims abstract description 100
- 229910052796 boron Inorganic materials 0.000 title claims abstract description 98
- 239000013078 crystal Substances 0.000 claims abstract description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 77
- 239000007789 gas Substances 0.000 claims description 62
- 238000000034 method Methods 0.000 claims description 56
- 238000005259 measurement Methods 0.000 claims description 48
- 229910052757 nitrogen Inorganic materials 0.000 claims description 40
- 239000000758 substrate Substances 0.000 claims description 38
- 230000007547 defect Effects 0.000 claims description 36
- 238000009826 distribution Methods 0.000 claims description 16
- 239000002019 doping agent Substances 0.000 claims description 14
- 238000001069 Raman spectroscopy Methods 0.000 claims description 9
- 230000005284 excitation Effects 0.000 claims description 7
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 5
- 239000010437 gem Substances 0.000 claims description 3
- 229910001751 gemstone Inorganic materials 0.000 claims description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 30
- 239000000463 material Substances 0.000 description 20
- 230000008569 process Effects 0.000 description 18
- 238000010521 absorption reaction Methods 0.000 description 15
- 125000004429 atom Chemical group 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 238000004817 gas chromatography Methods 0.000 description 10
- 239000012535 impurity Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 230000001419 dependent effect Effects 0.000 description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 7
- 238000007792 addition Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000005136 cathodoluminescence Methods 0.000 description 6
- 238000011065 in-situ storage Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 238000013507 mapping Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000370 acceptor Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000005468 ion implantation Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910052774 Proactinium Inorganic materials 0.000 description 2
- 238000001237 Raman spectrum Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000000155 isotopic effect Effects 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000005424 photoluminescence Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 1
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000005535 acoustic phonon Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- -1 argon ion Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910052805 deuterium Inorganic materials 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001362 electron spin resonance spectrum Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 229910001872 inorganic gas Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000005298 paramagnetic effect Effects 0.000 description 1
- 238000000103 photoluminescence spectrum Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/10—Heating of the reaction chamber or the substrate
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/10—Heating of the reaction chamber or the substrate
- C30B25/105—Heating of the reaction chamber or the substrate by irradiation or electric discharge
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/02—Elements
- C30B29/04—Diamond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Carbon And Carbon Compounds (AREA)
- Chemical Vapour Deposition (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0130005.2A GB0130005D0 (en) | 2001-12-14 | 2001-12-14 | Boron doped diamond |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200404371B true ZA200404371B (en) | 2005-06-03 |
Family
ID=9927671
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200404371A ZA200404371B (en) | 2001-12-14 | 2004-06-03 | Boron Doped Diamond. |
Country Status (16)
Country | Link |
---|---|
US (2) | US7160617B2 (ko) |
EP (2) | EP1780315B1 (ko) |
JP (2) | JP5101792B2 (ko) |
KR (1) | KR100847969B1 (ko) |
CN (1) | CN1321227C (ko) |
AT (1) | ATE353108T1 (ko) |
AU (1) | AU2002366413A1 (ko) |
CA (1) | CA2469150C (ko) |
DE (1) | DE60217976T2 (ko) |
ES (1) | ES2279897T3 (ko) |
GB (2) | GB0130005D0 (ko) |
HK (1) | HK1076644A1 (ko) |
IL (2) | IL162354A0 (ko) |
RU (1) | RU2315826C2 (ko) |
WO (1) | WO2003052174A2 (ko) |
ZA (1) | ZA200404371B (ko) |
Families Citing this family (63)
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CZ302228B6 (cs) * | 2000-06-15 | 2011-01-05 | Element Six (Pty) Ltd | Monokrystalická diamantová vrstva pripravená chemickým vylucováním z plynné fáze |
GB2379451B (en) * | 2000-06-15 | 2004-05-05 | Element Six | Thick single crystal diamond layer method for making it and gemstones produced from the layer |
DE10153310A1 (de) * | 2001-10-29 | 2003-05-22 | Infineon Technologies Ag | Photolithographisches Strukturierungsverfahren mit einer durch ein plasmaunterstützes Abscheideeverfahren hergestellten Kohlenstoff-Hartmaskenschicht diamantartiger Härte |
GB0130005D0 (en) | 2001-12-14 | 2002-02-06 | Diamanx Products Ltd | Boron doped diamond |
GB0130004D0 (en) * | 2001-12-14 | 2002-02-06 | Diamanx Products Ltd | Coloured diamond |
JP4711677B2 (ja) * | 2002-09-06 | 2011-06-29 | エレメント シックス リミテッド | 着色されたダイヤモンド |
GB0221949D0 (en) * | 2002-09-20 | 2002-10-30 | Diamanx Products Ltd | Single crystal diamond |
GB0227261D0 (en) | 2002-11-21 | 2002-12-31 | Element Six Ltd | Optical quality diamond material |
GB2424903B (en) * | 2003-12-12 | 2008-06-25 | Element Six Ltd | Method of incorporating a mark in cvd diamond |
KR101240785B1 (ko) * | 2003-12-12 | 2013-03-07 | 엘리멘트 식스 리미티드 | 화학적 증착 다이아몬드에 마크를 통합시키는 방법 |
US7309446B1 (en) * | 2004-02-25 | 2007-12-18 | Metadigm Llc | Methods of manufacturing diamond capsules |
US20100297391A1 (en) * | 2004-02-25 | 2010-11-25 | General Nanotechnoloy Llc | Diamond capsules and methods of manufacture |
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GB0512728D0 (en) * | 2005-06-22 | 2005-07-27 | Element Six Ltd | High colour diamond |
EP2253733B1 (en) * | 2005-06-22 | 2012-03-21 | Element Six Limited | High colour diamond |
GB0513932D0 (en) | 2005-07-08 | 2005-08-17 | Element Six Ltd | Single crystal diamond elements having spherical surfaces |
US20070036896A1 (en) * | 2005-08-09 | 2007-02-15 | Chien-Min Sung | Mosaic diamond substrates |
US20090127565A1 (en) * | 2005-08-09 | 2009-05-21 | Chien-Min Sung | P-n junctions on mosaic diamond substrates |
US9133566B2 (en) | 2005-12-09 | 2015-09-15 | Element Six Technologies Limited | High crystalline quality synthetic diamond |
CN100390316C (zh) * | 2006-01-19 | 2008-05-28 | 上海电机学院 | n型CVD共掺杂金刚石薄膜的制备方法 |
JP5503287B2 (ja) * | 2006-09-05 | 2014-05-28 | エレメント シックス リミテッド | 固体電極 |
US7833581B2 (en) * | 2006-09-11 | 2010-11-16 | The Hong Kong University Of Science And Technology | Method for making a highly stable diamond film on a substrate |
GB0622483D0 (en) | 2006-11-10 | 2006-12-20 | Element Six Ltd | Electrochemical apparatus having a forced flow arrangement |
GB0622482D0 (en) | 2006-11-10 | 2006-12-20 | Element Six Ltd | Diamond electrode |
GB0700984D0 (en) | 2007-01-18 | 2007-02-28 | Element Six Ltd | Polycrystalline diamond elements having convex surfaces |
US9034200B2 (en) | 2007-01-22 | 2015-05-19 | Element Six Limited Technologies Limited | Plasma etching of diamond surfaces |
EP2186649A4 (en) * | 2007-07-27 | 2011-04-06 | Valinmark Inc | METHOD FOR MARKING VALUE ARTICLES |
US20090260396A1 (en) * | 2008-04-16 | 2009-10-22 | Eitan Broukman | Methods for processing ornamental diamonds and corresponding ornamental diamonds |
EP2286459A4 (en) * | 2008-05-05 | 2014-03-12 | Carnegie Inst Of Washington | ULTRA-RESISTANT BORDOTIC CRYSTAL DIAMOND |
GB0813491D0 (en) | 2008-07-23 | 2008-08-27 | Element Six Ltd | Diamond Material |
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US20100126406A1 (en) * | 2008-11-25 | 2010-05-27 | Yan Chih-Shiue | Production of Single Crystal CVD Diamond at Rapid Growth Rate |
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US8997900B2 (en) | 2010-12-15 | 2015-04-07 | National Oilwell DHT, L.P. | In-situ boron doped PDC element |
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GB201021913D0 (en) | 2010-12-23 | 2011-02-02 | Element Six Ltd | Microwave plasma reactors and substrates for synthetic diamond manufacture |
GB201021860D0 (en) | 2010-12-23 | 2011-02-02 | Element Six Ltd | A microwave plasma reactor for diamond synthesis |
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GB201121642D0 (en) | 2011-12-16 | 2012-01-25 | Element Six Ltd | Single crtstal cvd synthetic diamond material |
GB201216697D0 (en) | 2012-09-19 | 2012-10-31 | Element Six Ltd | Single crystal chemical vapour deposited synthetic diamond materials having uniform colour |
US9921017B1 (en) | 2013-03-15 | 2018-03-20 | Victor B. Kley | User identification for weapons and site sensing fire control |
CN103938182B (zh) * | 2014-04-08 | 2016-05-04 | 上海交通大学 | 硼氮共掺纳米基定向金刚石薄膜的制备方法 |
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2001
- 2001-12-14 GB GBGB0130005.2A patent/GB0130005D0/en not_active Ceased
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2002
- 2002-12-13 ES ES02790571T patent/ES2279897T3/es not_active Expired - Lifetime
- 2002-12-13 DE DE60217976T patent/DE60217976T2/de not_active Expired - Lifetime
- 2002-12-13 RU RU2004121782/15A patent/RU2315826C2/ru active
- 2002-12-13 EP EP06076850.4A patent/EP1780315B1/en not_active Expired - Lifetime
- 2002-12-13 EP EP02790571A patent/EP1463849B1/en not_active Expired - Lifetime
- 2002-12-13 AT AT02790571T patent/ATE353108T1/de not_active IP Right Cessation
- 2002-12-13 GB GB0415787A patent/GB2400116B/en not_active Expired - Lifetime
- 2002-12-13 CN CNB028267494A patent/CN1321227C/zh not_active Expired - Lifetime
- 2002-12-13 JP JP2003553040A patent/JP5101792B2/ja not_active Expired - Lifetime
- 2002-12-13 IL IL16235402A patent/IL162354A0/xx unknown
- 2002-12-13 KR KR1020047009241A patent/KR100847969B1/ko active IP Right Grant
- 2002-12-13 WO PCT/IB2002/005324 patent/WO2003052174A2/en active IP Right Grant
- 2002-12-13 CA CA002469150A patent/CA2469150C/en not_active Expired - Lifetime
- 2002-12-13 AU AU2002366413A patent/AU2002366413A1/en not_active Abandoned
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2005
- 2005-09-29 HK HK05108599A patent/HK1076644A1/xx not_active IP Right Cessation
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2006
- 2006-12-01 US US11/565,753 patent/US20070092647A1/en not_active Abandoned
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US20070092647A1 (en) | 2007-04-26 |
EP1780315B1 (en) | 2015-04-15 |
DE60217976T2 (de) | 2007-05-24 |
IL162354A0 (en) | 2005-11-20 |
IL162354A (en) | 2009-09-22 |
GB0415787D0 (en) | 2004-08-18 |
WO2003052174A3 (en) | 2003-10-02 |
KR20040077674A (ko) | 2004-09-06 |
ATE353108T1 (de) | 2007-02-15 |
GB0130005D0 (en) | 2002-02-06 |
GB2400116A (en) | 2004-10-06 |
CA2469150A1 (en) | 2003-06-26 |
JP2010222252A (ja) | 2010-10-07 |
HK1076644A1 (en) | 2006-01-20 |
JP2005512928A (ja) | 2005-05-12 |
EP1463849A2 (en) | 2004-10-06 |
CA2469150C (en) | 2009-09-15 |
KR100847969B1 (ko) | 2008-07-22 |
EP1463849B1 (en) | 2007-01-31 |
AU2002366413A1 (en) | 2003-06-30 |
EP1780315A2 (en) | 2007-05-02 |
CN1612955A (zh) | 2005-05-04 |
GB2400116B (en) | 2005-06-22 |
US20040180205A1 (en) | 2004-09-16 |
US7160617B2 (en) | 2007-01-09 |
EP1780315A3 (en) | 2010-02-24 |
RU2004121782A (ru) | 2005-06-10 |
ES2279897T3 (es) | 2007-09-01 |
JP5101792B2 (ja) | 2012-12-19 |
WO2003052174A2 (en) | 2003-06-26 |
RU2315826C2 (ru) | 2008-01-27 |
DE60217976D1 (de) | 2007-03-22 |
CN1321227C (zh) | 2007-06-13 |
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