ZA200303850B - Oil-in-water emulsion formulation of insecticides. - Google Patents
Oil-in-water emulsion formulation of insecticides. Download PDFInfo
- Publication number
- ZA200303850B ZA200303850B ZA200303850A ZA200303850A ZA200303850B ZA 200303850 B ZA200303850 B ZA 200303850B ZA 200303850 A ZA200303850 A ZA 200303850A ZA 200303850 A ZA200303850 A ZA 200303850A ZA 200303850 B ZA200303850 B ZA 200303850B
- Authority
- ZA
- South Africa
- Prior art keywords
- esters
- oil
- formulation
- pyrethroid
- insecticide
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 58
- 238000009472 formulation Methods 0.000 title claims description 46
- 239000002917 insecticide Substances 0.000 title claims description 25
- 239000007764 o/w emulsion Substances 0.000 title claims description 8
- -1 aliphatic monocarboxylic acids Chemical class 0.000 claims description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 150000002148 esters Chemical class 0.000 claims description 25
- 239000002728 pyrethroid Substances 0.000 claims description 22
- 239000003995 emulsifying agent Substances 0.000 claims description 15
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- 239000002904 solvent Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 241000607479 Yersinia pestis Species 0.000 claims description 10
- 239000005892 Deltamethrin Substances 0.000 claims description 9
- 239000006184 cosolvent Substances 0.000 claims description 9
- 229960002483 decamethrin Drugs 0.000 claims description 9
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 230000000873 masking effect Effects 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 239000007798 antifreeze agent Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000012074 organic phase Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000004150 EU approved colour Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 239000000194 fatty acid Substances 0.000 description 13
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- 229930195729 fatty acid Natural products 0.000 description 11
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- 239000013543 active substance Substances 0.000 description 7
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- 150000001298 alcohols Chemical class 0.000 description 3
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 3
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- 125000004494 ethyl ester group Chemical group 0.000 description 3
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- CNKHSLKYRMDDNQ-UHFFFAOYSA-N halofenozide Chemical compound C=1C=CC=CC=1C(=O)N(C(C)(C)C)NC(=O)C1=CC=C(Cl)C=C1 CNKHSLKYRMDDNQ-UHFFFAOYSA-N 0.000 description 3
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- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- AWYOMXWDGWUJHS-UHFFFAOYSA-N tebupirimfos Chemical compound CCOP(=S)(OC(C)C)OC1=CN=C(C(C)(C)C)N=C1 AWYOMXWDGWUJHS-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 description 1
- 239000010496 thistle oil Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000583 toxicological profile Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 241000701366 unidentified nuclear polyhedrosis viruses Species 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00126276A EP1210877A1 (en) | 2000-12-01 | 2000-12-01 | Oil-in-water emulsion formulation of insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200303850B true ZA200303850B (en) | 2004-04-21 |
Family
ID=8170545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200303850A ZA200303850B (en) | 2000-12-01 | 2003-05-19 | Oil-in-water emulsion formulation of insecticides. |
Country Status (34)
| Country | Link |
|---|---|
| US (2) | US20020098221A1 (bg) |
| EP (2) | EP1210877A1 (bg) |
| JP (1) | JP4303963B2 (bg) |
| CN (1) | CN1286366C (bg) |
| AR (1) | AR031444A1 (bg) |
| AT (1) | ATE272941T1 (bg) |
| AU (2) | AU2002234523B2 (bg) |
| BG (1) | BG66227B1 (bg) |
| BR (1) | BR0115873A (bg) |
| CA (1) | CA2436199C (bg) |
| CU (1) | CU23192A3 (bg) |
| CZ (1) | CZ300087B6 (bg) |
| DE (1) | DE60104887T2 (bg) |
| DK (1) | DK1339281T3 (bg) |
| DZ (1) | DZ3432A1 (bg) |
| EC (1) | ECSP034633A (bg) |
| ES (1) | ES2223935T3 (bg) |
| HU (1) | HU229964B1 (bg) |
| IL (1) | IL156215A0 (bg) |
| MA (1) | MA25858A1 (bg) |
| MD (1) | MD3068C2 (bg) |
| MX (1) | MXPA03004877A (bg) |
| MY (1) | MY127187A (bg) |
| PL (1) | PL203263B1 (bg) |
| PT (1) | PT1339281E (bg) |
| RU (1) | RU2284107C2 (bg) |
| SI (1) | SI1339281T1 (bg) |
| SK (1) | SK287502B6 (bg) |
| TR (1) | TR200402144T4 (bg) |
| TW (1) | TWI280099B (bg) |
| UA (1) | UA73820C2 (bg) |
| UY (1) | UY27048A1 (bg) |
| WO (1) | WO2002043488A1 (bg) |
| ZA (1) | ZA200303850B (bg) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1372385A1 (en) * | 2001-03-30 | 2004-01-02 | Rhodia Inc. | Aqeuous suspension of nanoparticles comprising an agrochemical active ingredient |
| IL148684A (en) * | 2002-03-14 | 2006-12-31 | Yoel Sasson | Pesticidal composition |
| US20040166083A1 (en) * | 2003-02-26 | 2004-08-26 | The Andrew Jergens Company | Personal care water-in-oil emulsion products |
| DE102004026938A1 (de) * | 2004-06-01 | 2005-12-22 | Bayer Cropscience Gmbh | Schaumarme wäßrige Formulierungen für den Pflanzenschutz |
| AU2005239726C1 (en) * | 2004-12-14 | 2010-11-18 | Sumitomo Chemical Company, Limited | Pesticidal composition comprising pyriproxyfen |
| US20080125480A1 (en) * | 2004-12-30 | 2008-05-29 | Cheminova A/S | Oil-In-Water Formulation Of Avermectins |
| TWI402034B (zh) * | 2005-07-28 | 2013-07-21 | Dow Agrosciences Llc | 具有被層狀液晶覆膜包覆之油球之水包油乳化劑之農用組成物 |
| AR056808A1 (es) * | 2005-11-18 | 2007-10-24 | Cheminova As | Formulacion de aceite en agua de avermectinas |
| KR101424829B1 (ko) * | 2006-03-24 | 2014-08-01 | 바스프 에스이 | 농약 제제 |
| JP5260540B2 (ja) | 2006-11-22 | 2013-08-14 | ビーエーエスエフ ソシエタス・ヨーロピア | 液体水性農芸化学製剤 |
| PL2184993T3 (pl) * | 2007-08-08 | 2012-03-30 | Basf Se | Wodne mikroemulsje zawierające owadobójcze związki organiczne |
| EP2070415A1 (en) * | 2007-12-11 | 2009-06-17 | Bayer CropScience AG | Active compound combinations |
| MX338895B (es) * | 2008-02-04 | 2016-05-04 | Dow Agrosciences Llc | Emulsiones de aceite en agua estabilizadas que incluyen ingredientes activos agricolamente. |
| HUE028708T2 (en) | 2008-03-25 | 2016-12-28 | Dow Agrosciences Llc | Oil-in-water emulsions containing stabilized agricultural active ingredients |
| KR20100134075A (ko) * | 2008-04-30 | 2010-12-22 | 베일런트 유.에스.에이. 코포레이션 | 신규한 피리프록시펜 조성물 |
| MX2010011884A (es) | 2008-05-02 | 2010-12-06 | Basf Se | Microemulsion mejorada que tiene un amplio rango de aplicacion. |
| EP2309847A2 (de) * | 2008-07-24 | 2011-04-20 | Basf Se | Öl-in-wasser emulsion umfassend lösungsmittel, wasser, tensid und pestizid |
| US9149416B1 (en) * | 2008-08-22 | 2015-10-06 | Wellmark International | High deposition cleansing system |
| WO2010036882A1 (en) * | 2008-09-29 | 2010-04-01 | The Hartz Mountain Corporation | Photo-stable pest control |
| UA106213C2 (ru) | 2008-10-10 | 2014-08-11 | Басф Се | Жидкие препараты для защиты растений, содержащие пираклостробин |
| TW201018400A (en) * | 2008-10-10 | 2010-05-16 | Basf Se | Liquid aqueous plant protection formulations |
| US20110054007A1 (en) | 2009-08-28 | 2011-03-03 | E.I. Du Pont De Nemours And Company | Compositions and methods to control insect pests |
| CN201712857U (zh) | 2010-05-10 | 2011-01-19 | S.C.约翰逊父子公司 | 用于挥发性材料的散发装置及其壳体和散发片 |
| UY33443A (es) * | 2010-06-19 | 2012-01-31 | Bayer Animal Health Gmbh | Preparacion que contiene ectoparasiticida para la formacion de emulsion espontanea |
| WO2012028583A1 (de) | 2010-09-03 | 2012-03-08 | Bayer Cropscience Ag | Deltamethrin enthaltende formulierungen |
| EP2446743B1 (en) * | 2010-10-26 | 2014-06-04 | Cognis IP Management GmbH | Biocide compositions comprising esters of ethoxylated alcohols |
| JP5620230B2 (ja) * | 2010-11-09 | 2014-11-05 | 住友化学株式会社 | 動物外部寄生虫防除組成物 |
| EP2457890A1 (en) * | 2010-11-29 | 2012-05-30 | Cognis IP Management GmbH | Biocide compositions comprising alkoxylation products of isoamyl alcohol derivatives |
| AU2011336820B2 (en) * | 2010-12-03 | 2015-06-11 | Indorama Ventures Oxides Llc | Low toxicity, low odor, low volatility solvent for agricultural chemical formulations |
| GB201107040D0 (en) | 2011-04-26 | 2011-06-08 | Syngenta Ltd | Formulation component |
| GB201107039D0 (en) * | 2011-04-26 | 2011-06-08 | Syngenta Ltd | Formulation component |
| WO2013054194A1 (en) | 2011-10-13 | 2013-04-18 | Amril Ag | A formulated solvent composition for pesticide |
| EP2797419A4 (en) * | 2011-12-28 | 2015-10-07 | Sumitomo Chemical Co | COMPOSITION FOR CONTROLLING PESTS |
| JP2013230992A (ja) * | 2012-04-27 | 2013-11-14 | Osaka Seiyaku:Kk | 水系動物用害虫阻害剤 |
| BR112014028367A2 (pt) | 2012-05-16 | 2017-07-18 | Bayer Cropscience Ag | formulação inseticida de óleo-em-água (o/w). |
| US9278151B2 (en) | 2012-11-27 | 2016-03-08 | S.C. Johnson & Son, Inc. | Volatile material dispenser |
| US9205163B2 (en) | 2012-11-27 | 2015-12-08 | S.C. Johnson & Son, Inc. | Volatile material dispenser |
| WO2014119519A1 (ja) * | 2013-01-29 | 2014-08-07 | 日産化学工業株式会社 | 乳化安定性に優れる農薬乳化性組成物 |
| GB2511318B (en) * | 2013-02-27 | 2015-12-30 | Rotam Agrochem Int Co Ltd | Agrochemical composition comprising pesticidally active pyrazole derivative with polyether adhesion promoter |
| MX369750B (es) | 2013-03-14 | 2019-11-20 | Pioneer Hi Bred Int | Composiciones y metodos para controlar plagas de insectos. |
| RU2548500C2 (ru) * | 2013-08-21 | 2015-04-20 | Биогард Инвестментс Лтд. | Инсектицидная композиция |
| WO2015085377A1 (pt) * | 2013-12-11 | 2015-06-18 | Oxiteno S.A. Indústria E Comércio | Alquil éster de ácido policarboxílico derivado de álcool ramificado e linear de fonte vegetal, e, uso de um alquil éster em formulações agroquímicas |
| WO2016044092A1 (en) | 2014-09-17 | 2016-03-24 | Pioneer Hi Bred International Inc | Compositions and methods to control insect pests |
| US9497971B2 (en) * | 2015-02-24 | 2016-11-22 | Bayer Cropscience Lp | Non-volatile organic compound pesticide formulations |
| CN107529763B (zh) | 2015-03-11 | 2021-08-20 | 先锋国际良种公司 | Pip-72的杀昆虫组合及使用方法 |
| US10647995B2 (en) | 2015-06-16 | 2020-05-12 | Pioneer Hi-Bred International, Inc. | Compositions and methods to control insect pests |
| FR3048852B1 (fr) * | 2016-03-17 | 2019-09-06 | Oleon Nv | Concentre comprenant un mel et un ester d'acide gras et de polyethylene glycol de hlb superieur ou egal a 12 |
| US20190185867A1 (en) | 2016-06-16 | 2019-06-20 | Pioneer Hi-Bred International, Inc. | Compositions and methods to control insect pests |
| WO2018013333A1 (en) | 2016-07-12 | 2018-01-18 | Pioneer Hi-Bred International, Inc. | Compositions and methods to control insect pests |
| US20190390219A1 (en) | 2017-02-08 | 2019-12-26 | Pioneer Hi-Bred International, Inc. | Insecticidal combinations of plant derived insecticidal proteins and methods for their use |
| US10172359B2 (en) * | 2017-05-17 | 2019-01-08 | Sergeant's Pet Care Products, Inc. | Solvent system for use with spot-on pesticide compositions |
| AR111838A1 (es) * | 2017-05-30 | 2019-08-21 | Arysta Lifescience Inc | Dispersión oleosa herbicida que contiene un fitoprotector |
| US20200165626A1 (en) | 2017-10-13 | 2020-05-28 | Pioneer Hi-Bred International, Inc. | Virus-induced gene silencing technology for insect control in maize |
| WO2020049493A1 (en) | 2018-09-06 | 2020-03-12 | Pi Industries Ltd. | Stable agrochemical composition |
| AU2021390291A1 (en) * | 2020-12-01 | 2023-06-29 | Sumitomo Chemical Company, Limited | Liquid agrochemical composition |
| BR112024001526A2 (pt) * | 2021-09-29 | 2024-04-30 | Firmenich & Cie | Produtos para controle de artrópode |
| WO2023176613A1 (ja) * | 2022-03-14 | 2023-09-21 | 日本化薬株式会社 | 農薬乳化性組成物 |
| EP4245139A1 (en) * | 2022-03-15 | 2023-09-20 | Centre national de la recherche scientifique | Compositions comprising a botanical extract as insecticidal agent |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4469675A (en) * | 1981-11-30 | 1984-09-04 | Zoecon Corporation | Pesticidal formulation |
| FR2624761B1 (fr) * | 1987-12-17 | 1993-10-08 | Roussel Uclaf | Granules a base de polymeres hydrophiles sur lesquels sont absorbes une formulation aqueuse renfermant un ou plusieurs principes actifs |
| FR2643223B1 (fr) * | 1989-02-17 | 1991-12-13 | Roussel Uclaf | Nouvelles emulsions aqueuses concentrees, leur procede de preparation et leur application dans le domaine pesticide |
| US5466458A (en) * | 1992-03-09 | 1995-11-14 | Roussel Uclaf | Emulsified spray formulations |
| FR2689729B1 (fr) * | 1992-04-09 | 1994-06-03 | Roussel Uclaf | Nouvelles compositions pesticides renfermant un pyrethrinouide. |
| FR2721800B1 (fr) * | 1994-07-01 | 1997-12-26 | Roussel Uclaf | Nouveaux concentres emulsionnables renfermant un u plussieurs pesticides |
| US6068849A (en) * | 1997-07-14 | 2000-05-30 | Henkel Corporation | Surfactants for use in agricultural formulations |
| ATE308878T1 (de) * | 1999-01-29 | 2005-11-15 | Entschäumer enthaltendes pflanzenschutzmittel- emulsionskonzentrat |
-
2000
- 2000-12-01 EP EP00126276A patent/EP1210877A1/en not_active Withdrawn
-
2001
- 2001-11-23 AU AU2002234523A patent/AU2002234523B2/en not_active Ceased
- 2001-11-23 ES ES01985335T patent/ES2223935T3/es not_active Expired - Lifetime
- 2001-11-23 AU AU3452302A patent/AU3452302A/xx active Pending
- 2001-11-23 RU RU2003119547/15A patent/RU2284107C2/ru active
- 2001-11-23 MX MXPA03004877A patent/MXPA03004877A/es active IP Right Grant
- 2001-11-23 IL IL15621501A patent/IL156215A0/xx not_active IP Right Cessation
- 2001-11-23 WO PCT/EP2001/013658 patent/WO2002043488A1/en active IP Right Grant
- 2001-11-23 SI SI200130210T patent/SI1339281T1/xx unknown
- 2001-11-23 UA UA2003066037A patent/UA73820C2/uk unknown
- 2001-11-23 TW TW090129087A patent/TWI280099B/zh not_active IP Right Cessation
- 2001-11-23 PL PL366224A patent/PL203263B1/pl unknown
- 2001-11-23 TR TR2004/02144T patent/TR200402144T4/xx unknown
- 2001-11-23 CN CNB018198341A patent/CN1286366C/zh not_active Expired - Fee Related
- 2001-11-23 MD MDA20030132A patent/MD3068C2/ro not_active IP Right Cessation
- 2001-11-23 CA CA002436199A patent/CA2436199C/en not_active Expired - Fee Related
- 2001-11-23 AT AT01985335T patent/ATE272941T1/de active
- 2001-11-23 BR BR0115873-2A patent/BR0115873A/pt not_active Application Discontinuation
- 2001-11-23 SK SK665-2003A patent/SK287502B6/sk not_active IP Right Cessation
- 2001-11-23 CZ CZ20031482A patent/CZ300087B6/cs not_active IP Right Cessation
- 2001-11-23 HU HU0303290A patent/HU229964B1/hu unknown
- 2001-11-23 PT PT01985335T patent/PT1339281E/pt unknown
- 2001-11-23 DE DE60104887T patent/DE60104887T2/de not_active Expired - Lifetime
- 2001-11-23 DZ DZ013432A patent/DZ3432A1/fr active
- 2001-11-23 JP JP2002545478A patent/JP4303963B2/ja not_active Expired - Fee Related
- 2001-11-23 EP EP01985335A patent/EP1339281B1/en not_active Expired - Lifetime
- 2001-11-23 DK DK01985335T patent/DK1339281T3/da active
- 2001-11-29 US US09/997,043 patent/US20020098221A1/en not_active Abandoned
- 2001-11-29 AR ARP010105564A patent/AR031444A1/es unknown
- 2001-11-30 UY UY27048A patent/UY27048A1/es unknown
- 2001-11-30 MY MYPI20015472A patent/MY127187A/en unknown
-
2003
- 2003-05-19 ZA ZA200303850A patent/ZA200303850B/en unknown
- 2003-05-21 BG BG107833A patent/BG66227B1/bg unknown
- 2003-05-23 MA MA27176A patent/MA25858A1/fr unknown
- 2003-05-27 CU CU20030124A patent/CU23192A3/es not_active IP Right Cessation
- 2003-05-30 EC EC2003004633A patent/ECSP034633A/es unknown
-
2004
- 2004-09-08 US US10/936,238 patent/US20050042245A1/en not_active Abandoned
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