JP5260540B2 - 液体水性農芸化学製剤 - Google Patents
液体水性農芸化学製剤 Download PDFInfo
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- JP5260540B2 JP5260540B2 JP2009537598A JP2009537598A JP5260540B2 JP 5260540 B2 JP5260540 B2 JP 5260540B2 JP 2009537598 A JP2009537598 A JP 2009537598A JP 2009537598 A JP2009537598 A JP 2009537598A JP 5260540 B2 JP5260540 B2 JP 5260540B2
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- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- YXIIPOGUBVYZIW-UHFFFAOYSA-N pyraflufen Chemical compound ClC1=C(OC(F)F)N(C)N=C1C1=CC(OCC(O)=O)=C(Cl)C=C1F YXIIPOGUBVYZIW-UHFFFAOYSA-N 0.000 description 1
- DDIQWGKUSJOETH-UHFFFAOYSA-N pyrafluprole Chemical compound ClC=1C=C(C(F)(F)F)C=C(Cl)C=1N1N=C(C#N)C(SCF)=C1NCC1=CN=CC=N1 DDIQWGKUSJOETH-UHFFFAOYSA-N 0.000 description 1
- JOOMJVFZQRQWKR-UHFFFAOYSA-N pyrazophos Chemical compound N1=C(C)C(C(=O)OCC)=CN2N=C(OP(=S)(OCC)OCC)C=C21 JOOMJVFZQRQWKR-UHFFFAOYSA-N 0.000 description 1
- ROVGZAWFACYCSP-VUMXUWRFSA-N pyrethrin I Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-VUMXUWRFSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- DEIKMOQTJBGGAX-DJKKODMXSA-N pyriminobac Chemical compound CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(O)=O DEIKMOQTJBGGAX-DJKKODMXSA-N 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 1
- BUHNESFUCHPWED-UHFFFAOYSA-N s-[(4-methoxyphenyl)methyl] n,n-diethylcarbamothioate Chemical compound CCN(CC)C(=O)SCC1=CC=C(OC)C=C1 BUHNESFUCHPWED-UHFFFAOYSA-N 0.000 description 1
- 208000005687 scabies Diseases 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229940125794 sodium channel blocker Drugs 0.000 description 1
- 239000003195 sodium channel blocking agent Substances 0.000 description 1
- QSYAEOJYDZZOHF-UHFFFAOYSA-M sodium;2,4-dichloro-6-nitrophenolate Chemical compound [Na+].[O-]C1=C(Cl)C=C(Cl)C=C1[N+]([O-])=O QSYAEOJYDZZOHF-UHFFFAOYSA-M 0.000 description 1
- 239000007962 solid dispersion Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 208000018556 stomach disease Diseases 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- PQTBTIFWAXVEPB-UHFFFAOYSA-N sulcotrione Chemical compound ClC1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O PQTBTIFWAXVEPB-UHFFFAOYSA-N 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- FZMKKCQHDROFNI-UHFFFAOYSA-N sulfometuron Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 FZMKKCQHDROFNI-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000005936 tau-Fluvalinate Substances 0.000 description 1
- INISTDXBRIBGOC-XMMISQBUSA-N tau-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 description 1
- RJKCKKDSSSRYCB-UHFFFAOYSA-N tebutam Chemical compound CC(C)(C)C(=O)N(C(C)C)CC1=CC=CC=C1 RJKCKKDSSSRYCB-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- 125000004305 thiazinyl group Chemical group S1NC(=CC=C1)* 0.000 description 1
- 125000000437 thiazol-2-yl group Chemical group [H]C1=C([H])N=C(*)S1 0.000 description 1
- 125000004495 thiazol-4-yl group Chemical group S1C=NC(=C1)* 0.000 description 1
- 125000004496 thiazol-5-yl group Chemical group S1C=NC=C1* 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
- 150000003556 thioamides Chemical class 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- WCLDITPGPXSPGV-UHFFFAOYSA-N tricamba Chemical compound COC1=C(Cl)C=C(Cl)C(Cl)=C1C(O)=O WCLDITPGPXSPGV-UHFFFAOYSA-N 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- OOLLAFOLCSJHRE-ZHAKMVSLSA-N ulipristal acetate Chemical compound C1=CC(N(C)C)=CC=C1[C@@H]1C2=C3CCC(=O)C=C3CC[C@H]2[C@H](CC[C@]2(OC(C)=O)C(C)=O)[C@]2(C)C1 OOLLAFOLCSJHRE-ZHAKMVSLSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- JARYYMUOCXVXNK-CSLFJTBJSA-N validamycin A Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-CSLFJTBJSA-N 0.000 description 1
- 150000004669 very long chain fatty acids Chemical class 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Catching Or Destruction (AREA)
Description
(a) 少なくとも一つの農薬;及び
(b) 式Iの少なくとも一つの非イオン性界面活性剤
R1−O−(AO)x−(H) (I)
〔式中、
R1は4〜20の炭素原子を有する直鎖状又は分枝状のアルキル基であり;
AOはエチレンオキシ、プロピレンオキシ又はエチレンオキシ及びプロピレンオキシの混合物であり;そして
xは2〜30の値に相当する〕;及び
(c) 少なくとも一つのイオン性トリスチリルフェニルアルコキシレート;及び
(d) 少なくとも一つの油;及び
(e) 水
を含む製剤であって、
農薬が水相中に懸濁液の形態で存在しており、そして油が農薬を本質的に含まない製剤に関する。
アルコキシル化トリスチリルフェノールを含む農芸化学製剤は公知である。WO 2006/114186 は、油相が農薬を含む油中水型サスポエマルジョンを開示している。EP 0514769 は、除草剤、芳香族溶剤及びエトキシル化トリスチリルフェノールを含むサスポエマルジョンを開示している。サスポエマルジョンという用語は、そこでは、Mulqeen et al., Pesticide Science, 1990, 29, 451-465 により、「一つ以上の活性成分を含有するエマルジョン相と、一つ以上の活性成分を固体分散体の形態で含有する連続相と」の組み合わせと定義されている。US 6,664,213 B1は、農薬活性成分と、HLB値が6〜13.5であって、含有量が組成物基準で10〜50重量%であるポリオキサエチレンアルキルエーテルとを含む液体農薬組成物を開示している。WO 00/78139はカルフェントラゾン-エチル-アニオン性界面活性剤と、水溶性有機化合物と、水とを含み、pHが2〜7である液体除草剤組成物を開示している。
【先行技術文献】
【特許文献】
【特許文献1】 WO 2006/114186
【特許文献2】 EP 0514769
【特許文献3】 US 6,664,213 B1
【特許文献4】 WO 00/78139
【非特許文献】
【非特許文献1】 Mulqeen et al., Pesticide Science, 1990, 29, 451-465
(a) 少なくとも一つの農薬;
(b) 式Iの少なくとも一つの非イオン性界面活性剤
R1−O−(AO)x−(H) (I)
〔式中、
R1は4〜20の炭素原子を有する直鎖状又は分枝状のアルキル基であり;
AOはエチレンオキシ、プロピレンオキシ又はエチレンオキシ及びプロピレンオキシの混合物であり;そして
xは2〜20の値に相当する〕;及び
(c) 少なくとも一つのイオン性トリスチリルフェニルアルコキシレート;及び
(d) 少なくとも一つの油;及び
(e) 水
を含む製剤であって、
農薬が水相中に懸濁液の形態で存在しており、そして油が農薬を本質的に含まない製剤により解決された。
少なくとも一つの農薬(a)の量は、1%から60重量%まで;好ましくは5〜50、最も好ましくは7.5〜30重量%である。式Iの非イオン性界面活性剤(b)の量は、0.5%から30重量%まで;好ましくは2〜5重量%である。イオン性トリスチリルフェニルエトキシレート(c)の量は、0.5%から30重量%まで;好ましくは5〜15重量%である。油(d)の量は、5%から50重量%まで;好ましくは20〜40重量%である。溶剤(f)が存在する場合には、溶剤の量は、5%から50重量%まで、好ましくは20〜40重量%である。非イオン性界面活性剤(g)が製剤中に存在する場合には、エチレンオキシド/プロピレンオキシドブロック共重合体からなる群から選択される非イオン性界面活性剤の量は、0.5%から20重量%までである。
R1−O−(AO)o−(H) (Ia)
〔式中、
R1は上記の意味を有し:そしてoは2〜20の数である〕
である。
R1−O−(EO)n−(PO)m−H (Ib)
〔式中、
R1は上記の意味を有し:そして
mは1〜10の数であり、そして
nは1〜10の数である〕
である。
R1−O−(PO)r−(EO)s−H (Ic)
〔式中、
R1は上記の意味を有し、
rは1〜10の数であり、そして
sは1〜10の数である〕
である。
CH3(CH2)tCH2O(CH2CH2O)u−H (Id)
〔式中、
tは8〜13の数であり、そして
uは6〜17の数である〕
である。
CH3-CH2-CH2-CH2-CH(C2H5)-CH2-(EO)n-(PO)m (Ib-1)
〔式中、
mは1〜5であり;そして
nは1〜5であり;
ここで、nは好ましくは3〜5であり、mは好ましくは1〜2の値である〕;及び式Ic-1のアルコールアルコキシレート
CH3-CH2-CH2-CH2-CH(C2H5)-CH2-(PO)r-(EO)s-H (Ic-1)
〔式中、
rは1〜10、好ましくは6であり;そして
sは1〜10、好ましくは8である〕;及び式Ic-2のアルコールアルコキシレート
CH3-CH2-CH2-CH2-CH(C2H5)-CH2-(PO)r-(EO)s-H (Ic-2)
〔式中、
rは1〜5、好ましくは1〜3であり;そして
sは1〜5、好ましくは2〜4である〕である。
wは3であり、
vは1〜60、より好ましくは10〜25、最も好ましくは16であり、AOはEOPO又はEO及びPO部分の混合物、好ましくはEOであり;そして
R2はSO3H又はH2PO3である〕
である。
NR1R2R3 (III)
〔式中、R1、R2及びR3は互いに独立して水素、メチル、エチル又はプロピルであり、好ましくはR1、R2及びR3はエチルである〕)で中和して、R2=SO3X又はHPO3Yを生成することができ、ここで、X及びYは互いに独立してNH4 +、(NR1R2R3)+〔ここで、R1、R2及びR3は上記で定義されるとおりである〕、Na+又はK+である。
R2はSO3H又はH2PO3である〕
が最高に好ましい。
NR1R2R3 (III)
〔式中、R1、R2及びR3は互いに独立して水素、メチル、エチル又はプロピルであり、好ましくはR1、R2及びR3はエチルである〕で中和して、R2=SO3X又はHPO3Yを生成することができ、ここで、X及びYは互いに独立してNH4 +、(NR1R2R3)+〔ここで、R1、R2及びR3は上記で定義されるとおりである〕、又はK+である。
(a) 懸濁液の形態で存在する一つ又は二つの農薬;
(b) 式I、好ましくはIb又はIc、より好ましくはIb-1又はIc-1又はIc-2、最も好ましくはIb-1の少なくとも一つの非イオン性界面活性剤;
(c) 少なくとも一つのイオン性トリスチリルフェニルアルコキシレート、好ましくは式II、より好ましくは式II、最も好ましくは式IIaの化合物;及び
(d) 少なくとも一つの油(ここで、油は農薬を本質的に含まない);及び
(e) 水;及び
(g) エチレンプロピレンオキシドブロック共重合体の群から選択される非イオン性界面活性剤(g)を含み、そして溶剤を含まない。
殺昆虫剤は下記からなる群から選択することができる
A.1. 有機(チオ)リン酸エステル類:アセフェート、アザメチホス、アジンホス−エチル、クロルピリホス、クロルピリホス−メチル、クロルフェンビンホス、ジアジノン、ジクロルボス、ジクロトフォス、ジメトエート、ジスルホトン、エチオン、フェニトロチオン、フェンチオン、イソキサチオン、マラチオン、メタミドフォス、メチダチオン、メチル−パラチオン、メビンフォス、モノクロトフォス、オキシデメトン−メチル、パラオキソン、パラチオン、フェントエート、フォサロン、フォスメト、フォスファミドン、フォレート、フォキシム、ピリミフォス−メチル、プロフェノホス、プロチオホス、スルプロフォス、テトラクロルビンフォス、テルブホス、チアゾフォス、トリクロルホン;
A.2. カルバミン酸エステル類:アラニカルブ、アルジカルブ、ベンジオカルブ、ベンフラカルブ、カルバリル、カルボフラン、カルボスルファン、フェノキシブカルブ、フラチオカルブ、メチオカルブ、メトミル、オキサミル、ピリミカルブ、プロポキスル、チオジカルブ、トリアザメート;
A.3. ピレスロイド類:アレスリン、ビフェンスリン、シフルスリン、シハロスリン、シフェノスリン、シペルメスリン、アルファ−シペルメスリン、ベータ−シペルメスリン、ゼータ−シペルメスリン、デルタメスリン、エスフェンバレレート、エトフェンプロクス、フェンプロパスリン、フェンバレレート、イミプロスリン、ラムダ−シハロスリン、ガンマ−シハロスリン、ペルメスリン、プラレンスリン、ピレスリンI及びII、レスメスリン、シラフルオフェン、タウ−フルバリネート、テフルスリン、テトラメスリン、トラロメスリン、トランスフルスリン、プロフルスリン、ジメフルスリン;
A.4. 成長調節剤:a)キチン合成阻害剤:ベンゾイル尿素類;クロルフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、テフルベンズロン、トリフルムロン;ブプロフェジン、ジオフェノラン、ヘキシチアゾクス、エトキサゾール、クロフェンテジン;b)エクジソン拮抗剤:ハロフェノジド、メトキシフェノジド、テブフェノジド、アザジラキチン;c)幼若ホルモン様物質:ピリプロキシフェン、ヒドロプレン、キノプレン、メトプレン、フェノキシカルブ;d)脂質生合成阻害剤:スピロジクロフェン、スピロメシフェン、スピロテトラマト;
A.5. ニコチン性受容体作動剤/拮抗剤化合物:クロチアニジン、ジノテフラン、イミダクロプリド、チアメトキサム、ニテンピラム、アセタミプリド、チアクロプリド;
式(Γ1)のチアゾール化合物
A.9. METI II及びIII化合物:アセキノシル、フルアクリプリム、ヒドラメチルノン;
A.10. 脱共役剤化合物:クロルフェナピル;
A.11. 酸化的リン酸化阻害剤化合物:シヘキサチン、ジアフェンチウロン、フェンブタチンオキシド、プロパルギット;
A.12. 脱皮かく乱化合物:シロマジン;
A.13. 混合機能オキシダーゼ阻害剤化合物:ピペロニルブトキシド;
A.14. ナトリウムチャンネル遮断剤化合物:インドキサカルブ、メタフルミゾン;
A.15. 各種のもの:ベンクロチアズ、ビフェナゼート、カルタプ、フロニカミド、ピリダリル、ピメトロジン、硫黄、チオシクラム、フルベンダミド、シエノピラフェン、フルピラゾホス、シフルメトフェン、アミドフルメト、式Γ4のアミノキナゾリノン化合物
1.ストロビルリン類、例えばアゾキシストロビン、ジモキシストロビン、エネストロブリン、フルオキサストロビン、クレゾキシム−メチル、メトミノストロビン、ピコキシストロビン、ピラクロストロビン、トリフロキシストロビン、オリザストロビン、(2-クロロ-5-[1-(3-メチルベンゾイルオキシイミノ)エチル]ベンジル)カルバミン酸メチル、 (2-クロロ-5-[1-(6-メチルピリジン-2-イルメチルオキシイミノ)エチル]ベンジル)カルバミン酸メチル、2-(オルト-((2,5-ジメチルフェニルオキシメチレン)フェニル)-3-メトキシアクリル酸メチル;
2.カルボキサミド類、例えば
カルボキシアニリド類:ベナラキシル、ベノダニル、ボスカリド、カルボキシン、メプロニル、フェンフラム、フェンヘキサミド、フルトラニル、フラメトピル、メタラキシル、オフラーセ、オキサジキシル、オキシカルボキシン、ペンチオピラド、チフルザミド、チアジニル、N−(4’−ブロモビフェニル−2−イル)−4−ジフルオロメチル−2−メチルチアゾール−5−カルボキサミド、N−(4’−トリフルオロメチルビフェニル−2−イル)−4−ジフルオロメチル−2−メチルチアゾール−5−カルボキサミド、N−(4’−クロロ−3’−フルオロビフェニル−2−イル)−4−ジフルオロメチル−2−メチルチアゾール−5−カルボキサミド、N−(3’,4’−ジクロロ−4−フルオロビフェニル−2−イル)−3−ジフルオロメチル−1−メチルピラゾール−4−カルボキサミド、N−(2−シアノフェニル)−3,4−ジクロロイソチアゾール−5−カルボキサミド;
カルボン酸モルホリド類:ジメトモルフ、フルモルフ;
ベンゾアミド類:フルメトベル、フルオピコリド(ピコベンズアミド)、ゾキサミド;
他のカルボキサミド類:カルプロパミド、ジクロシメト、マンジプロパミド、N−(2−(4−[3−(4−クロロフェニル)プロパ−2−インイルオキシ]−3−メトキシフェニル)エチル)−2−メタンスルホニルアミノ−3−メチルブチルアミド、N−(2−(4−[3−(4−クロロフェニル)プロパ−2−インイルオキシ]−3−メトキシフェニル)エチル)−2−エタンスルホニルアミノ−3−メチルブチルアミド;
3.アゾール類、例えば
トリアゾール類:ビテルタノール、ブロムモコナゾール、シプロコナゾール、ジフェンコナゾール、ジニコナゾール、エニルコナゾール、エポキシコナゾール、フェンブコナゾール、フルシラゾール、フルキノコナゾール、フルトリアフォル、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、プロチオコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメノール、トリアジメフォン、トリチコナゾール;
イミダゾール類:シアゾファミド、イマザリル、ペンフラゾエート、プロクロラズ、トリフルミゾール;
ベンズイミダゾール類:ベノミル、カルベンダジンム、フベリダゾール、チアベンダゾール;
その他:エタボキサム、エトリジアゾール、ヒメキサゾール;
4.含窒素ヘテロシクリル化合物、例えば
ピリジン類:フルアジナム、ピリフェノクス、3−[5−(4−クロロフェニル)−2,3−ジメチルイソオキサゾリジン−3−イル]−ピリジン;
ピリミジン類:ブピリメート、シプロジニル、フェリムゾン、フェナリモール、メパニピリム、ヌアリモール、ピリメタニル;
ピペラジン類:トリフォリン;
ピロール類:フルジオキソニル、フェンピクロニル;
モルホリン類:アルジモルフ、ドデモルフ、フェンプロピモルフ、トリデモルフ;
ジカルボキシイミド類:イプロジオン、プロシミドン、ビンクロゾリン
その他:アシベンゾラー−S−メチル、アニラジン、カプタン、カプタフォル、ダゾメト、ジクロメジン、フェンオキサニル、フォルペト、フェンプロピジン、ファモキサドン、フェナミドン、オクチリノン、プロベナゾール、プロキナジド、プロキロン、キノキシフェン、トリシクラゾール、5−クロロ−7−(4−メチルピペリジン−1−イル)−6−(2,4,6−トリフルオロフェニル)−[1,2,4]トリアゾロ[1,5−a]ピリミジン、2−ブトキシ−6−ヨード−3−プロピルクロメン−4−オン、N,N−ジメチル−3−(3−ブロモ−6−フルオロ−2−メチルインドール−1−スルホニル)−[1,2,4]トリアゾール−1−スルホンアミド;
5.カルバメート類及びジチオカルバメート類、例えば
ジチオカルバメート類:フェルバム、マンコゼブ、マネブ、メチラム、メタム、プロピネブ、チラム、ジネブ、ジラム;
カルバメート類:ジエトフェンカルブ、フルベンチアバリカルブ、イプロバリカルブ、プロパモカルブ、3−(4−クロロフェニル)−3−(2−イソプロポキシカルボニルアミノ−3−メチルブチリルアミノ)プロピオン酸メチル、N−(1−(1−(4−シアノフェニル)エタンスルホニル)ブタ−2−イル)カルバミン酸4−フルオロフェニル;
6.他の殺菌剤、例えば
グアニジン類:ドジン、イミノクタジン、グアザチン;
抗生物質:カスガマイシン、ポリオキシン類、ストレプトマイシン、バリダマイシンA;
有機金属化合物:フェンチン塩;
硫黄含有ヘテロシクリル化合物:イソプロチオラン、ジチアノン;
有機リン化合物:エジフェンホス、フォセチル、フォセチル−アルミニウム、イプロベンホス、ピラゾフォス、トルクロホス−メチル、リン酸及びその塩;
有機塩素化合物:チオファネート−メチル、クロロタロニル、ジクロフルアニド、トリルフラニド、フルスルファミド、フタリド、ヘキサクロロベンゼン、ペンシクロン、キントゼン;
ニトロフェニル誘導体:ビナパクリル、ジノカプ、ジノブトン;
無機活性化合物:ボルドー混合物、酢酸銅、水酸化銅、オキシ塩化銅、塩基性硫酸銅、硫黄;
その他:スピロキサミン、シフルフェナミド、シモキサニル、メトラフェノン。
b1) 脂質生合成阻害剤、例えばクロラジホプ、クロジナホプ、クロホプ、シハロホプ、ジクロホプ、フェノキサプロプ、フェノキサプロプ−p、フェンチアプロプ、フルアジホプ、フルアジホプ−P、ハロキシホプ、ハロキシホプ−P、イソキサピリホプ、メタミホプ、プロパキザホプ、キザロホプ、キザロホプ−P、トリホプ、アロキシジム、ブトキシジム、クレトジム、クロプロキシジム、シクロキシジム、プロフォキシジム、セトキシジム、テプラロキシジム、トラルコキシジム、ブチレート、シクロエート、ジアルレート、ジメピペレート、EPTC、エスプロカルブ、エチオレート、イソポリネート、メチオベンカルブ、モリネート、オルベンカルブ、ペブレート、プロスルホカルブ、スルファルレート、チオベンカルブ、チオカルバジル、トリアルレート、ベモレート、ベンフレゼート、エトフメゼート及びベンスリド;
b2) ALS阻害剤、例えばアミドスルフロン、アジムスルフロン、ベンスルフロン、クロリムロン、クロルスルフロン、シノスルフロン、シクロスルファムロン、エタメトスルフロン、エトキシスルフロン、フラザスルフロン、フルピルスルフロン、フォラムスルフロン、ハロスルフロン、イマゾスルフロン、ヨードスルフロン、メソスルフロン、メトスルフロン、ニコスルフロン、オキサスルフロン、ピリミスルフロン、プロスルフロン、ピラゾスルフロン、リムスルフロン、スルホメツロン、スルホスルフロン、チフェンスルフロン、トリアスルフロン、トリベヌロン、トリフロキシスルフロン、トリフルスルフロン、トリトスルフロン、イマザメタベンズ、イマザモクス、イマザピク、イマザピル、イマザキン、イマゼタピル、クロランスラム、ジクロスラム、フロラスラム、フルメトスラム、メトスラム、ペノクススラム、ビスピリバク、ピリミノバク、プロポキシカルバゾン、フルカルバゾン、ピリベンゾキシム、ピリフタリド及びピリチオバク;
b3) 光合成阻害剤、例えばアトラトン、アトラジン、アメトリン、アジプロトリン、シアナジン、シアナトリン、クロラジン、シプラジン、デスメトリン、ジメタメトリン、ジプロペトリン、エグリナジン、イパジン、メソプラジン、メトメトン、メトプロトリン、プロシアジン、プログリナジン、プロメトン、プロメトリン、プロパジン、セブチラジン、セクブメトン、シマジン、シメトン、シメトリン、テルブメトン、テルブチラジン、テルブトリン、トリエタジン、アメトリジオン、アミブジン、ヘキサジノン、イソメチオジン、メタミトロン、メトリブジン、ブロマシル、イソシル、レナシル、テルバシル、ブロムピラゾン、クロリダゾン、ジミダゾン、デスメジファム、フェンイソファム、フェンテルバシル、フェンメジファム−エチル、ベンズチアズロン、ブチウロン、エチジムロン、イソウロン、メタベンズチアズロン、モノイソウロン、テブチウロン、チアザフルロン、アニスロン、ブツロン、クロルブロムロン、クロルエツロン、クロロトルロン、クロロクスロン、ジフェノクスロン、ジメフロン、ジウロン、フェヌロン、フルオメツロン、フルオチウロン、イソプロツロン、リヌロン、メチウロン、メトベンズロン、メトブロムロン、メトクスロン、モノリヌロン、モヌロン、ネブロン、パラフルロン、フェノベンズロン、シヅロン、テトラフルロン、チジアズロン、シペルクアト、ジエタムクアト、ジフェンゾクアト、ジクアト、モルファムクアト、パラクアト、ブロモボニル、ブロモキシニル、クロロキシニル、ヨードボニル、イオキシニル、アミカルバゾン、ブロモフェノキシム、フルメジン、メタゾール、ベンタゾン、プロパニル、ペンタノクロル、ピリデート及びピリダホル;
b4) プロトポルフィリノーゲン−IXオキシダーゼ阻害剤、例えばアシフルオルフェン、ビフェノクス、クロメトキシフェン、クロルニトロフェン、エトキシフェン、フルオロジフェン、フルオログリコフェン、フルオロニトロフェン、フォメサフェン、フリロキシフェン、ハロサフェン、ラクトフェン、ニトロフェン、ニトロフルオルフェン、オキシフルオルフェン、フルアゾレート、ピラフルフェン、シニドン−エチル、フルミクロラク、フルミオキサジン、フルミプロピン、フルチアセト、チジアジミン、オキサジアゾン、オキサジアルギル、アザフェニジン、カルフェントラゾン、スルフェントラゾン、ペントキサゾン、ベンズフェンジアゾン、ブタフェナシル、ピラクロニル、プロフルアゾール、フルフェンピル、ニピラクロフェン及びエトニプロミド;
b5) 漂白除草剤、例えばメトフルラゾン、ノルフルラゾン、フルフェニカン、ジフルフェニカン、ピコリナフェン、ベンフルブタミド、フルリドン、フルロクロリドン、フルルタモン、メソトリオン、スルコトリオン、イソキサクロルトール、イソキサフルトール、ベンゾフェナプ、ピラゾリネート、ピラゾキシフェン、ベンゾビシクロン、アミトロール、クロマゾン、アクロニフェン、4−(3−トリフルオロメチルフェノキシ)− 2−(4−トリフルオロメチルフェニル)ピリミジン、そしてまた式IIの3−ヘテロシクリル置換ベンゾイル誘導体(WO 96/26202、WO 97/41116、WO 97/41117 及び WO 97/41118 参照)
R8、R10は水素、ハロゲン、C1−C6−アルキル、C1−C6−ハロアルキル、C1−C6−アルコキシ、C1−C6−ハロアルコキシ、C1−C6−アルキルチオ、C1−C6−アルキルスルフィニル又はC1−C6−アルキルスルホニルであり;
R9は例えばチアゾール-2-イル、チアゾール-4-イル、チアゾール-5-イル、イソオキサゾール-3-イル、イソオキサゾール-4-イル、イソオキサゾール-5-イル、4,5-ジヒドロイソオキサゾール-3-イル、4,5-ジヒドロイソオキサゾール-4-イル及び 4,5-ジヒドロイソオキサゾール-5-イルからなる群から選択されるヘテロ環式基であり、ここで、上記の九つの基は非置換であってよく、又はハロゲン、C1−C4−アルキル、アルキルC1−C4−アルコキシ、C1−C4−ハロアルキル、C1−C4−ハロアルコキシ若しくはC1−C4−アルキルチオで一置換若しくは多置換されていてよく、例えば一、二、三若しくは四置換されていてよく;
R11は水素、ハロゲン又はC1−C6−アルキルであり;
R12はC1−C6−アルキルであり;
R13は水素又はC1−C6−アルキルである〕。
b7) グルタミンシンターゼ阻害剤、例えばグルフォシネート及びビラナフォス;
b8) DHPシンターゼ阻害剤、例えばアスラム;
b9) 有糸分裂阻害剤、例えばベンフルラリン、ブトラリン、ジニトラミン、エタルフルラリン、フルクロラリン、イソプロパリン、メタルプロパリン、ニトラリン、オリザリン、ペンジメタリン、プロジアミン、プロフルラリン、トリフルラリン、アミプロホス−メチル、ブタミホス、ジチオピル、チアゾピル、プロピザミド、テブタム、クロルタル、カルベタミド、クロルプロファム、クロプロファム及びプロファム;
b10) VLCFA阻害剤、例えばアセトクロル、アラクロル、ブタクロル、ブテナクロル、デラクロルジエタチル、ジメタクロル、ジメテナミド、ジメテナミド−P、メタザクロル、メトラクロル、S−メトラクロル、プレチラクロル、プロパクロル、プロピソクロル、プリナクロル、テルブクロル、テニルクロル、キシラクロル、アルリドクロル、CDEA、エプロナズ、ジフェナミド、ナプロパミド、ナプロアニリド、ペトキサミド、フルフェナセト、メフェナセト、フェントラザミド、アニロホス、ピペロフォス、カフェンストロール、インダノファン及びトリジファン;
b11) セルロース生合成の阻害剤、例えばジクロベニル、クロルチアミド、イソキサベン及びフルポキサム;
b12) 脱共役除草剤、例えばジノフェネート、ジノプロプ、ジノサム、ジノセブ、ジノテブ、DNOC、エチノフェン及びメジノテルブ;
b13) オーキシン除草剤、例えばクロメプロプ、2,4−D、2,4,5−T、MCPA、MCPAチオエチル、ジクロプロプ、ジクロプロプ−P、メコプロプ、メコプロプ−P、2,4−DB、MCPB、クロラムベン、ジカムバ、2,3,6−TBA、トリカムバ、キンクロラク、キンメラク、クロピラリド、フルロキシピル、ピクロラム、トリクロピル及びベナゾリン;
b14) オーキシン輸送阻害剤、例えばナプタラム、ジフルフェンゾピル;
b15) ベンゾイルプロプ、フラムプロプ、フラムプロプ−M、ブロモブチド、クロルフルレノール、シンメチリン、メチルダイムロン、エトベンザニド、フォサミン、メタム、ピリブチカルブ、オキサジクロメホン、ダゾメト、トリアジフラム及び臭化メチル。
カルバミン酸エステル類、例えばアラニカルブ、ベンフラカルブ、カルバリル、カルボスルファン、フェノキシカルブ、フラチオカルブ、インドキサカルブ、メチオカルブ、メトミル、オキサミル、ピリミカルブ、プロポクスル、チオジカルブ、トリアザメート;
ピレスロイド類、例えばビフェンスリン、シフルスリン、シペルメスリン、アルファ−シペルメスリン、デルタメスリン、エスフェンバレレート、エトフェンプロクス、フェンプロパスリン、フェンバレレート、シハロスリン、ラムダ−シハロスリン、ペルメスリン、シラフルオフェン、タウ−フルバリネート、テフルスリン、トラロメスリン、ゼータ−シペルメスリン;
節足動物成長調節剤、例えば
キチン合成阻害剤:ベンゾイル尿素類:クロルフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、テフルベンズロン、トリフルムロン;ブプロフェジン、ジオフェノラン、ヘキシチアゾクス、エトキサゾール、クロフェンテジン;
b)エクジソン拮抗剤:ハロフェノジド、メトキシフェノジド、テブフェノジド;
c)幼若ホルモン様物質:ピリプロキシフェン、メトプレン、フェノキシカルブ;
d)脂質生合成阻害剤:スピロジクロフェン;
ネオニコチノイド類、例えばアセタミプリド、クロチアニジン、フロニカミド、イミダクロプリド、ニテンピラム、チアクロプリド、チアメトキサム、ジネトフラン;
並びにエチプロール、フィプロニル、メタフルマゾン、N−R’−2,2−ジハロ−1−R’’シクロ−プロパンカルボキサミド−2−(2,6−ジクロロ−α,α,α−トリ−フルオロ−p−トリル)ヒドラゾン又はN−R’−2,2−ジ(R’’’)プロピオンアミド−2−(2,6−ジクロロ−α,α,α−トリフルオロ−p−トリル)−ヒドラゾン〔ここで、R’はメチル又はエチルであり、ハロはクロロ又はブロモであり、R’’は水素又はメチルであり、そしてR’’’はメチル又はエチルである〕、アバメクチン、アセキノシル、アミトラズ、アザジラクチン、ビフェナゼート、バチルス・チューリンゲンシス (Bacillus thuringiensis)、枯草菌 (Bacillus subtilis)、カルタプ、クロルフェナピル、クロルジメホルム、シロマジン、ジアフェンチウロン、ジオフェノラン、エマメクチン、エンドスルファン、フェナザキン、フォルメタネート、塩酸フォルメタネート、ヒドラメチルノン、インドキサカルブ、4-{(2Z)−2−({[4−(トリフルオロ−メトキシ)アニリノ]カルボニル}ヒドラゾノ)−2-[3−(トリフルオロメチル)フェニル]エチル}ベンゾ−ニトリル、ピリダベン、ピリダリル、ピメトロジン、スピノサド、硫黄、テブフェンピラド及びチオシクラムである。
イネ、野菜、ダイズ、キャノーラ/ナタネ及びサトウダイコンおけるアルテルナリア属(Alternaria)の種、サトウダイコン及び野菜におけるアファノマイセス属(Aphanomyces)の種、トウモロコシ、穀草類、イネ及びシバフ (turf) におけるビポラリス属(Bipolaris)及びドレシュレラ属(Drechslera)の種、穀草類におけるブルメリア・グラミニス(Blumeria graminis)(ウドンコ病)、イチゴ、野菜、観賞植物及びブドウのつるにおけるボトリチス・シネレア(Botrytis cinerea)(灰色かび病)、レタスにおけるブレミア・ラクツケ(Bremia lactucae)、トウモロコシ、ダイズ、びサトウダイコンにおけるセルコスポラ属(Cercospora)の種、トウモロコシ、穀草類又はイネにおけるコクリオボルス属(Cochliobolus)の種(例えば穀草類におけるコクリオボルス・サチブス(Cochliobolus sativus)及びイネにおけるコクリオボルス・ミヤベアヌス(Cochliobolus miyabenus))、ダイズ及びワタにおけるコレトトリクム属(Colletotricum)の種、トウモロコシ、穀草類及びトウモロコシにおけるドレシュレラ属(Drechslera)の種、トウモロコシにおけるエクセロヒルム属(Exserohilum)の種、キュウリにおけるエリシフェ・シコラセアルム(Erysiphe cichoracearum)及びスフェロテカ・フリギネア(Sphaerotheca fuliginea)、ブドウのつるにおけるエリシフェ・ネカトル(Erysiphe necator)、種々の植物におけるフザリウム属(Fusarium)及びベルチシリウム属(Verticillium)の種、穀草類におけるゲウマノマイセス・グラミニス(Gaeumanomyces graminis)、穀草類及びイネにおけるギベレラ属(Gibberella)の種(例えばイネにおけるギベレラ・フジクロイ(Gibberella fujikuroi)、穀草類におけるギベレラ・ゼアエ(Gibberella zeae))、イネにおける穀粒染色コンプレックス、穀草類におけるミクロドキウム・ニバレ(Microdochium nivale)、穀草類、バナナ及びラッカセイにおけるマイコスフェレラ属(Mycosphaerella)の種、ダイズにおけるファコプサラ・パキリジ(Phakopsara pachyrhizi)及びファコプサラ・メイボミエ(Phakopsara meibomiae)、ダイズ及びヒマワリにおけるフォモプシス属(Phomopsis)の種、ジャガイモ及びトマトにおけるフィトフトラ・インフェスタンス(Phytophthora infestans)、ブドウのつるにおけるプラスモパラ・ビチコラ(Plasmopara viticola)、リンゴにおけるポドスフェラ・ロイコトリカ(Podosphaera leucotricha)、コムギ又はオオムギにおけるシュードセルコスポレラ・ヘルコトリコイデス(Pseudocercosporella herpotrichoides)、ホップ及びキュウリにおけるシュードペロノスポラ属(Pseudoperonospora)の種、穀草類及びトウモロコシにおけるプッチニア属(Puccinia)の種、穀草類におけるピレノフォラ属(Pyrenophora)の種、イネにおけるピリクラリア・オリゼ(Pyricularia oryzae)、イネ、トウモロコシ、ワタ、キャノーラ、ナタネ、ヒマワリ、サトウダイコン、野菜、シバフ、ナッツ類及び他の種々の植物におけるコクリオボルス・ミヤベアヌス(Cochliobolus miyabenus)及びコクリオボルス・サカキイ(Corticium sasakii)(リゾクトニア・ソラニ (Rhizoctonia solani))、フザリウム・セミテクツム(Fusarium semitectum(及び/又はモニリホルメ(moniliforme))、セルコスポラ・オリゼ(Cercospora oryzae)、サロクラジウム・オリゼ(Sarocladium oryzae)、S.アテヌアツム(S. attenuatum)、エンチロマ・オリゼ(Entyloma oryzae)、ギベレラ・フジクロイ(Gibberella fujikuroi)(バカネ(bakanae))、穀粒染色コンプレックス(種々の病原菌)、ビポラリス属(Bipolaris)の種、ドレシュレラ属の種、並びにピチウム属及びリゾクトニア属の種、ジャガイモにおけるリゾクトニア・ソラニ、キャノーラ/ナタネ及びヒマワリにおけるスクレロチニア属(Sclerotinia)の種、コムギにおけるセプトリア・トリチシ(Septoria tritici)及びスタゴノスポラ・ノドルム(Stagonospora nodorum)、ブドウのつるにおけるウンシヌラ・ネカトル(Uncinula necator)、トウモロコシにおけるスファセロテカ・レイリニア(Sphacelotheca reilinia)、ダイズ及びワタにおけるチエバリオプシス属(Thievaliopsis)の種、穀草類におけるチレチア属(Tilletia)の種、穀草類、トウモロコシ及びサトウダイコンにおけるウスチラゴ属(Ustilago)の種、並びにリンゴ及びナシにおけるベンツリア属(Venturia)の種(疥癬);
害虫という用語は、下記の節足動物及び線虫を包含するが、それらに限定されない:
ヤスデ類(倍脚綱(Diplopoda))、例えばブラニウルス属(Blaniulus)の種、
アリ類(膜翅目(Hymenoptera))、例えばアッタ・カピグアラ (Atta capiguara)、アッタ・セファロテス (Atta cephalotes)、アッタ・レビガタ (Atta laevigata)、アッタ・ロブスタ (Atta robusta)、アッタ・セクスデンス (Atta sexdens)、アッタ・テキサナ (Atta texana)、モノモリウム・ファラオニス (Monomorium pharaonis)、ソレノプシス・ゲミナタ (Solenopsis geminata)、ソレノプシス・インビクタ (Solenopsis invicta)、収穫アリ属 (Pogonomyrmex) の種及びフェイドール・メガセファラ (Pheidole megacephala)、
甲虫類(鞘翅目(Coleoptera))、例えばアグリルス・シヌアツス (Agrilus sinuatus)、アグリオテス・リニアツス (Agriotes lineatus)、アグリオテス・オブスクルス (Agriotes obscurus) 及び他のアグリオテス属の種、アンフィマルス・ソルスチチアリス(Amphimallus solstitialis)、アニサンドルス・ジスパー (Anisandrus dispar)、アントノムス・グランジス (Anthonomus grandis)、アントノムス・ポモルム (Anthonomus pomorum)、アトマリア・リニアリス (Atomaria linearis)、ブラプスチヌス属 (Blapstinus) の種、ブラストファグス・ピニペルダ (Blastophagus piniperda)、ブリトファガ・ウンダタ (Blitophaga undata)、ボチノデレス・プンシベントリス (Bothynoderes punciventris)、ブルクス・ルフィマヌス (Bruchus rufimanus)、ブルクス、ピソルム (Bruchus pisorum)、ブルクス・レンチス (Bruchus lentis)、ビスチスクス・ベツレ (Byctiscus betulae)、カシダ・ネブロサ (Cassida nebulosa)、セロトマ・トリフルカタ (Cerotoma trifurcata)、シュートリンクス・アシミリス (Ceuthorrhynchus assimilis)、シュートリンクス・ナピ (Ceuthorrhynchus napi)、ケトクネマ・チビアリス (Chaetocnema tibialis)、コノデルス・ベスペルチヌス (Conoderus vespertinus) 及び他のコノデルス属の種、コノリンクス・メンジクス (Conorhynchus mendicus)、クリオセリス・アスパラギ (Crioceris asparagi)、シリンドロコプツルス・アドスペルスス (Cylindrocopturus adspersus)、ジアブチカ(ロンギコルニス)・バルベリ (Diabrotica (longicornis) barberi)、ジアブロチカ・セミ−プンクタータ (Diabrotica semi-punctata)、ジアブロチカ・スペシオサ (Diabrotica speciosa)、ジアブロチカ・ウンデシムプンクタータ (Diabrotica undecimpunctata)、ジアブロチカ・ビルギフェラ (Diabrotica virgifera) 及び他のジアブロチカ属の種、エレオデス属 (Eleodes) の種、エピラクナ・バリベスチス (Epilachna varivestis)、エピトリクス・ヒルチペンニス (Epitrix hirtipennis)、ユーチノボトルス・ブラシリエンシス (Eutinobothrus brasiliensis)、ヒロビウス・アビエチス (Hylobius abietis)、ヒペラ・ブルンネイペンニス (Hypera brunneipennis)、ヒペラ・ポスチカ (Hypera postica)、イプス・タイポグラフス (Ips typographus)、レマ・ビリニアタ (Lema bilineata)、レマ・メラノプス (Lema melanopus)、レプチノタルサ・デセムリニアタ (Leptinotarsa decemlineata)、リモニウス・カリフォルニクス (Limonius californicus) 及び他のリモニウス属の種、メリゲテス・エネウス (Meligethes aeneus)、メロロンタ・ヒポカスタニ (Melolontha hippocastani)、メロロンタ・メロロンタ (Melolontha melolontha)、オウレマ・オリゼ (Oulema oryzae)、オルチオリンクス・スルカツス (Ortiorrhynchus sulcatus)、オリゾファグス・オリゼ (Oryzophagus oryzae)、オチオリンクス・オバツス (Otiorrhynchus ovatus)、オウレマ・オリゼ (Oulema oryzae)、フェドン・コクレアリエ (Phaedon cochleariae)、フィロトレタ・クリソセファラ (Phyllotreta chrysocephala)、フィロファガ・クヤバナ (Phyllophaga cuyabana) 及び他のフィロファガ属の種、フィロペルタ・ホルチコラ (Phyllopertha horticola)、フィロトレタ・ネモルム (Phyllotreta nemorum)、フィロトレタ・ストリオラタ (Phyllotreta striolata) 及び他のフィロトレタ属の種、ポリリア・ヤポニカ (Popillia japonica)、プロメコプス・カリニコリス (Promecops carinicollis)、プレモトリペス・ボラズ (Premnotrypes voraz)、サイリオデス属(Psylliodes) の種、シトナ・リニアツス (Sitona lineatus)、シトフィルス・グラナリア (Sitophilus granaria)、ステネクス・ピングイス (Sternechus pinguis)、ステルネクス・スブシグナツス (Sternechus subsignatus)、並びにタニメクス・パリアツス (Tanymechus palliatus) 及び他のタニメクス属の種、
ハエ類(双翅目(Diptera))、例えばアグロミザ・オリゼ (Agromyza oryzea)、クリソミヤ・ベジアナ (Chrysomya bezziana)、クリソミヤ・ホミニボラクス (Chrysomya hominivorax)、クリソミア・マセラリア (Chrysomya macellaria)、コンタリニア・ソルギコラ (Contarinia sorghicola)、コルジロビア・アントロポファガ (Cordylobia anthropophaga)、ダクス・ククルビテ (Dacus cucurbitae)、ダクス・オレエ (Dacus oleae)、ダシノイラ・ブラシケ (Dasineura brassicae)、デリア・アンチク (Delia antique)、エリア・コアルクタータ (Delia coarctata)、デリア・プラツゥラ (Delia platura)、デリア・ラジクム (Delia radicum)、ファニア・カニクラリス (Fannia canicularis)、ガステロフィルス・インテスチナリス (Gasterophilus intestinalis)、ゲオミザ・トリプンクタータ (Geomyza Tripunctata)、グロシナ・モルシタンス (Glossina morsitans)、ヘマトビア・イリタンス (Haematobia irritans)、ハプロジプロシス・エクエストリス (Haplodiplosis equestris)、ハイポデルマ・リニアタ (Hypoderma lineata)、リリオミザ・サチベ (Liriomyza sativae)、リリオミザ・トリフォリイ (Liriomyza trifolii)、ルシリア・カプリナ (Lucilia caprina)、ルシリア・クプリナ (Lucilia cuprina)、ルシリア・セリカータ (Lucilia sericata)、リコリア・ペクトラリス (Lycoria pectoralis)、マイエチオラ・デストラクター(Mayetiola destructor)、ムシナ・スタブランス (Muscina stabulans)、エストルス・オビス (Oestrus ovis)、オポミザ・フルオルム (Opomyza florum)、オシネラ・フリット (Oscinella frit)、ペゴミヤ・フィゾシアミ (Pegomya hysocyami)、フォルビア・アンチクア (Phorbia antiqua)、フォビア・ブラシケ (Phorbia brassicae)、フォビア・コアルクタータ (Phorbia coarctata)、プロゴニヤ・レイオシアニイ (Progonya leyoscianii)、プシラ・ロゼ (Psila rosae)、ラゴレチス・セラシ (Rhagoletis cerasi)、ラゴレチス・ポモネラ (Rhagoletis pomonella)、タバヌス・ボビヌス (Tabanus bovinus)、テタノプス・ミオペフォルミス (Tetanops myopaeformis)、チプラ・オレラセア (Tipula oleracea) 及びチプラ・パルドサ (Tipula paludosa);
異翅類昆虫(異翅目(Heteroptera))、例えばアクロステルヌム・ヒラレ (Acrosternum hilare)、ブリスス・ロイコプテルス (Blissus leucopterus)、オオヨコバイ科 (Cicadellidae)、例えばエムポアスカ・ファベ (Empoasca fabae)、ハムシ科 (Chrysomelidae)、シルトペルチス・ノタツス (Cyrtopeltis notatus)、デルパーシデ科 (Delpahcidae)、ジスデルクス・シングラツス (Dysdercus cingulatus)、ジスデルクス・インテルメジウス (Dysdercus intermedius)、ユーリガステル・インテグリセプス (Eurygaster integriceps)、ユーシスツス・イムピクチベントリス (Euschistus impictiventris)、レプトグロスス・フィロプス (Leptoglossus phyllopus)、リグス・リネオラリス (Lygus lineolaris)、リグス・プラテンシス (Lygus pratensis)、ネフォテチクス属 (Nephotettix) の種、ネザラ・ビリドゥラ (Nezara viridula)、カメムシ科 (Pentatomidae)、ピエスマ・クアドラータ (Piesma quadrata)、ソルベア・インスラリス (Solubea insularis) 及びチアンタ・ペルジトル (Thyanta perditor);
アブラムシ類及び他の同翅目昆虫(同翅目(Homoptera))、例えばアシルトシフォン・オノブリキス (Acyrthosiphon onobrychis)、アデルゲス・ラリキス (Adelges laricis)、アフィドゥラ・ナスツルチイ (Aphidula nasturtii)、アフィス・ファベ (Aphis fabae)、アフィス・フォルベシ (Aphis forbesi)、アフィス・グリシネス (Aphis glycines)、アフィス・ゴシピイ (Aphis gossypii)、アフィス・グロスラリエ (Aphis grossulariae)、アフィス・ポミ (Aphis pomi)、アフィス・シュナイデリ (Aphis schneideri)、アフィス・スピレコラ (Aphis spiraecola)、アフィス・サンブキ (Aphis sambuci)、アシルトシフォン・ピスム (Acyrthosiphon pisum)、オーラコルサム・ソラニ (Aulacorthum solani)、ブラキカウドゥス・カルドゥイ (Brachycaudus cardui)、ブラキカウドゥス・ベリクリシ (Brachycaudus helichrysi)、ブラキカウドゥス・ペリシケ (Brachycaudus persicae)、ブラキカウドゥス・プルニコラ (Brachycaudus prunicola)、 ブレビコリネ・ブラシケ (Brevicoryne brassicae)、カピトフォルス・ホルニ (Capitophorus horni)、セロシファ・ゴシピイ (Cerosipha gossypii)、ケトシフォン・フラゲフォリイ (Chaetosiphon fragaefolii)、クリプロミズス・リビス (Cryptomyzus ribis)、ドレイフシア・ノルドマンニアネ (Dreyfusia nordmannianae)、ドレイフシア・ピセエ (Dreyfusia piceae)、ジサフィス・ラジコラ (Dysaphis radicola)、ジサウラコルスム・シュードソラニ (Dysaulacorthum pseudosolani)、ジサフィス・プランタギネア (Dysaphis plantaginea)、ジサフィス・ピリ (Dysaphis pyri)、エンポアスカ・ファベ (Empoasca fabae)、 ヒアロプテルス・プルニ (Hyalopterus pruni)、ヒペロミズス・ラクツケ (Hyperomyzus lactucae)、マクロシフム・アベネ (Macrosiphum avenae)、マクロシフム・ユーフォルビエ (Macrosiphum euphorbiae)、マクロシフォン・ロゼ (Macrosiphon rosae)、メゴウラ・ビシエ (Megoura viciae)、メラナフィス・ピラリウス (Melanaphis pyrarius)、メトポロフィウム・ジロドゥム (Metopolophium dirhodum)、ミゾデス (Myzodes)ミズス (Myzus)・ペリシケ (persicae)、ミズス・アスカロニクス (Myzus ascalonicus)、ミズス・セラシ (Myzus cerasi)、ミズス・バリアンス (Myzus varians)、ナソノビア・リビス−ニグリ (Nasonovia ribis-nigri)、ニラパルバタ・ルゲンス (Nilaparvata lugens)、ペムフィグス・ブルサリウス (Pemphigus bursarius)、ペムフィグス・ポプリベネ (Pemphigus populivenae) 及び他のペムフィグス属の種、パーキンシエラ・サッカリシダ (Perkinsiella saccharicida)、フォロドン・フムリ (Phorodon humuli)、キジラミ科 (Psyllidae)、例えばシラ・マリ (Psylla mali)、シラ・ピリ (Psylla piri) 及び他のシラ属の種、ロパロミズス・アスカロニクス (Rhopalomyzus ascalonicus)、ロパロシフム・マイジス (Rhopalosiphum maidis)、ロパロシフム・パジ (Rhopalosiphum padi)、ロパロシフム・インサーツム (Rhopalosiphum insertum)、サパフィス・マラ (Sappaphis mala)、サパフィス・マリ (Sappaphis mali)、シザフィス・グラミヌム (Schizaphis graminum)、シゾノイラ・ラヌキノサ (Schizoneura lanuginosa)、シトビオン・アベネ (Sitobion avenae)、トリアロイロデス・バポラリオルム (Trialeurodes vaporariorum)、トキソテラ・オーランチイアンド (Toxoptera aurantiiand) 及びビテウス・ビチフォリイ (Viteus vitifolii);
鱗翅目昆虫(鱗翅目(Lepidoptera))、例えばアグロチス・イプシロン (Agrotis ypsilon)、アグロチス・セゲツム (Agrotis segetum) 及び他のアグロチス属の種、アラバマ・アルギラセア (Alabama argillacea)、アンチカルシア・ゲマタリス (Anticarsia gemmatalis)、アルギレスシア・コンジュゲラ (Argyresthia conjugella)、オートグラファ・ガンマ (Autographa gamma)、ブパルス・ピニアリウス (Bupalus piniarius)、カコエシア・ムリナナ (Cacoecia murinana)、カプア・レチクラナ (Capua reticulana)、ケイマトビア・ブルマタ (Cheimatobia brumata)、キロ・スプレサリス (Chilo suppresalis) 及び他のキロ属の種、コリストノイラ・フミフェラナ (Choristoneura fumiferana)、コリストノイラ・オクシデンタリス (Choristoneura occidentalis)、シルフィス・ウニプンクタ (Cirphis unipuncta)、クナフロクロシス・メジナリス (Cnaphlocrocis medinalis)、シジア・ポモネラ (Cydia pomonella)、デンドロリムス・ピニ (Dendrolimus pini)、ジアファニア・ニチダリス (Diaphania nitidalis)、ジアトラエア・グランジオセラ (Diatraea grandiosella)、エアリアス・インスラナ (Earias insulana)、エラスモパルプス・リグノセルス (Elasmopalpus lignosellus)、ユーポエシリア・アンビグエラ (Eupoecilia ambiguella)、ユーキソア (Euxoa) 属の種、エベトリア・ボウリアナ (Evetria bouliana)、フェルチア・スブテラネア (Feltia subterranea)、ガレリア・メロネラ (Galleria mellonella)、グラフォリタ・フネブラナ (Grapholitha funebrana)、グラフォリタ・モレスタ (Grapholitha molesta)、ヘリオシス・アルミゲラ (Heliothis armigera)、ヘリオシス・ビレセンス (Heliothis virescens)、ヘリオシス・ゼア (Heliothis zea)、ヘルラ・ウンダリス (Hellula undalis)、ヒベルニア・デフォリアリア (Hibernia defoliaria)、ヒファントリア・クネア (Hyphantria cunea)、ハイポノモイタ・マリネルス (Hyponomeuta malinellus)、ケイフェリア・リコペルシセラ (Keiferia lycopersicella)、ランブジナ・フィセラリア (Lambdina fiscellaria)、ラフィグマ・エキシグア (Laphygma exigua)、レロデア・ユーファラ (Lerodea eufala)、ロイコプテラ・コーヒーラ (Leucoptera coffeella)、ロイコプテラ・シテラ (Leucoptera scitella)、リトコレチス・ブランカルデラ (Lithocolletis blancardella)、ロベシア・ボトラナ (Lobesia botrana)、ロキソステゲ・スチクチカリス (Loxostege sticticalis)、リマントリア・ジスパー (Lymantria dispar)、リマントリア・モナカ (Lymantria monacha)、リオネチア・クレルケラ (Lyonetia clerkella)、マラコソマ・ノイストリア (Malacosoma neustria)、マメストラ・ブラシケ (Mamestra brassicae)、モンフィデ (Momphidae) 属の種、オルギア・シュードツガタ (Orgyia pseudotsugata)、オストリニア・ヌビラリス (Ostrinia nubilalis)、パノリス・フラメア (Panolis flammea)、ペクチノフォラ・ゴシピエラ (Pectinophora gossypiella)、ペリドロマ・サウシア (Peridroma saucia)、ファレラ・ブセファラ (Phalera bucephala)、フトリマエア・オペルクレラ (Phthorimaea operculella)、フィロクニスチス・シトレラ (Phyllocnistis citrella)、ピエリス・ブラシケ (Pieris brassicae)、プラシペナ・スカブラ (Plathypena scabra)、プルテラ・キシロステラ (Plutella xylostella)、シュードプルシア・インクルデンス (Pseudoplusia includens)、リアシオニア・フルストラナ (Rhyacionia frustrana)、スクロビパルプラ・アブソルタ (Scrobipalpula absoluta)、セサミア・ノナグリオイデス (Sesamia nonagrioides) 及び他のセサミア属の種、シトロガ・セレアレラ (Sitotroga cerealella)、スパルガノシス・ピレリアナ (Sparganothis pilleriana)、スポドプテラ・フルギペルダ (Spodoptera frugiperda)、スポドプテラ・リトラリス (Spodoptera littoralis)、スポドプテラ・リツラ (Spodoptera litura)、タウマトポエア・ピチオカンパ (Thaumatopoea pityocampa)、トルトリクス・ビリダナ (Tortrix viridana)、トリコプルシア・ニ (Trichoplusia ni) 及びゼイラフェラ・カナデンシス (Zeiraphera Canadensis);
直翅目昆虫(直翅目(Orthoptera))、例えばバッタ科 (Acrididae)、アケタ・ドメスチカ (Acheta domestica)、ブラタ・オリエンタリス (Blatta orientalis)、ブラテラ・ゲルマニカ (Blattella germanica)、フォルフィクラ・オーリクラリア (Forficula auricularia)、グリロタルパ・グリロタリパ (Gryllotalpa gryllotalpa)、ロクスタ・ミグラトリア (Locusta migratoria)、メラノプルス・ビビタツス (Melanoplus bivittatus)、メラノプルス・フェムル−ルブルム (Melanoplus femur-rubrum)、メラノプルス・メキシカヌス (Melanoplus mexicanus)、メラノプルス・サングイニペス (Melanoplus sanguinipes)、メラノプルス・スプレツス (Melanoplus spretus)、ノマダクリス・セプテムファシアタ (Nomadacris septemfasciata)、ペリプラネタ・アメリカナ (Periplaneta americana)、シストセルカ・アメリカナ (Schistocerca americana)、シストセルカ・ペレグリナ (Schistocerca peregrina)、スタウロノツス・マロカヌス (Stauronotus maroccanus) 及びタキシネス・アシナモルス (Tachycines asynamorus);
シロアリ類(等翅目(Isoptera))、例えばカロテルメス・フラビコリス (Calotermes flavicollis)、コプトテルメス (Coptotermes) 属の種、ダルブルス・マイジス (Dalbulus maidis)、ロイコテルメス・フラビペス (Leucotermes flavipes)、マクロテルメス・ギルブス (Macrotermes gilvus)、レチクリテルメス・ルシフグス (Reticulitermes lucifugus) 及びテルメス・ナタレンシス (Termes natalensis);
アザミウマ類(総翅目(Thysanoptera))、例えばフランクリニエラ・フスカ (Frankliniella fusca)、フランクリニエラ・オクシデンタリス (Frankliniella occidentalis)、フランクリニエラ・トリチキ (Frankliniella tritici) 及び他のフランクリニエラ属の種、シルトトリプス・シトリ (Scirtothrips citri)、トリプス・オリゼ (Thrips oryzae)、トリプス・パルミ (Thrips palmi) 及びトリプス・タバキ (Thrips tabaci);
クモ綱動物、例えばクモ形類動物(ダニ目(Acarina))、例えばヒメダニ科 (Argasidae)、マダニ科 (Ixodidae) 及びヒゼンダニ科 (Sarcoptidae) のもの、例えばアンブリオマ・アメリカヌム (Amblyomma americanum)、アンブリオマ・バリエガツム (Amblyomma variegatum)、アルガス・ペルシクス (Argas persicus)、ブーフィルス・アヌラツス (Boophilus annulatus)、ブーフィルス・デコロラツス (Boophilus decoloratus)、ブーフィルス・ミクロプルス (Boophilus microplus)、デルマセントル・シルバルム (Dermacentor silvarum)、ヒアロマ・トルンカツム (Hyalomma truncatum)、イクソデス・リシヌス (Ixodes ricinus)、イクソデス・ルビクンドゥス (Ixodes rubicundus)、オルニトドルス・モウバタ (Ornithodorus moubata)、オトビウス・メグニニ (Otobius megnini)、デルマニスス・ガリネ (Dermanyssus gallinae)、プソロプテス・オビス (Psoroptes ovis)、リピセファルス・アペンジクラツス (Rhipicephalus appendiculatus)、リピセファルス・エベルトシ (Rhipicephalus evertsi)、サルコプテス・スカビエイ (Sarcoptes scabiei)、並びにフシダニ科 (Eriophyidae) の種、例えばアクルス・シュレクテンダリ (Aculus schlechtendali)、フィロコプトラタ・オレイボラ (Phyllocoptrata oleivora) 及びエリオフィエス・シェルドニ (Eriophyes sheldoni);タルソネミデ科 (Tarsonemidae) の種、例えばフィトネムス・パリドゥス (Phytonemus pallidus) 及びポリファゴタルソネムス・ラツス (Polyphagotarsonemus latus);ヒメハダニ科 (Tenuipalpidae) の種、例えばブレビパルプス・フォエニシス (Brevipalpus phoenicis);ハダニ科(Tetranychidae)の種、例えばテトラニクス・シナバリヌス (Tetranychus cinnabarinus)、テトラニクス・カンザワイ (Tetranychus kanzawai)、テトラニクス・パシリクス (Tetranychus pacificus)、テトラニクス・テラリウス (Tetranychus telarius) 及びテトラニクス・ウルチケ (Tetranychus urticae)、パノニクス・ウルミ(Panonychus ulmi)、パノニクス・シトリ (Panonychus citri) 及びオリゴニクス・プラテンシス (oligonychus pratensis);
線虫、特に植物寄生線虫、例えば根コブ線虫、メロイドギネ・ハプラ (Meloidogyne hapla)、メロイドギネ・インコグニタ (Meloidogyne incognita)、メロイドギネ・ジャバニカ (Meloidogyne javanica) 及び他のメロイドギネ属の種;
嚢腫形成線虫、ジャガイモシストセンチュウ (Globodera rostochiensis) 及び他のグロボデラ属 (Globodera) の種;ヘテロデラ・アベネ (Heterodera avenae)、ヘテロデラ・グリシネス (Heterodera glycines)、ヘテロデラ・シャクチイ (Heterodera schachtii)、ヘテロデラ・トリフォリイ (Heterodera trifolii) 及び他のヘテロデラ属の種;種子コブ線虫、アングイナ属 (Anguina) の種;茎及び葉の線虫、アフェレンコイデス属 (Aphelenchoides) の種;刺咬線虫、ベロノライムス・ロンギカウダツス (Belonolaimus longicaudatus) 及び他のベロノライムス属の種;松の線虫、ブルサフェレンクス・キシロフィルス (Bursaphelenchus xylophilus) 及び他のブルサフェレンクス属の種;リング線虫、クリコネマ属 (Criconema) の種、クリコネメラ属 (Criconemella) の種、クリコネモイデス属 (Criconemoides) の種、メソクリコネマ属 (Mesocriconema) の種;茎及び球根の線虫、ジチレンクス・デストラクター (Ditylenchus destructor)、ジチレンクス・ジプサキ (Ditylenchus dipsaci) 及び他のジチレンクス属の種;オール線虫、ドリコドルス属 (Dolichodorus) の種;スパイラル線虫、ヘリオコチレンクス・マルチシンクツス (Heliocotylenchus multicinctus) 及び他のヘリオコチレンクス属の種;葉鞘及び類葉鞘の線虫、ヘミシクリオフォラ属 (Hemicycliophora) の種及びヘミクリコネモイデス属 (Hemicriconemoides) の種;ヒルシュマンニエラ属 (Hirshmanniella) の種;槍形線虫、ホプロアイムス属 (Hoploaimus) の種;偽根コブ線虫、ナコブス属 (Nacobbus ) の種;針形線虫、ロンギドルス・エロンガツス (Longidorus elongatus) 及び他のロンギドルス属の種;病変線虫、プラチレンクス・ネグレクツス (Pratylenchus neglectus)、プラチレンクス・ペネトランス (Pratylenchus penetrans)、プラチレンクス・クルビタツス (Pratylenchus curvitatus)、プラチレンクス・グーデイイ (Pratylenchus goodeyi) 及び他のプラチレンクス属の種;穿孔線虫、ラドフォルス・シミリス (Radopholus similis) 及び他のラドフォルス属の種;腎臓形線虫、ロチレンクス・ロブスツス (Rotylenchus robustus) 及び他のロチレンクス属の種;スクテロネマ属 (Scutellonema) の種;短く太い根の線虫、トリコドルス・プリミチブス (Trichodorus primitivus) 及び他のトリコドルス属の種、パラトリコドルス (Paratrichodorus) 属の種;スタント線虫、チレンコリンクス・クライトニ (Tylenchorhynchus claytoni)、チレンコリンクス・ドゥビウス (Tylenchorhynchus dubius) 及び他のチレンコリンクス属の種;柑橘類の線虫、チレンクルス属 (Tylenchulus) の種;ダガー形線虫、クシフィネマ属 (Xiphinema) の種;並びに他の植物寄生線虫の種。
A)プレミックスの製造
280gの水、0.75gのクエン酸、2gの Acticide MBS(1,2−ベンゾイソチアゾール−3(2H)−オン+2−メチル−2H−イソチアゾール−3−オン)、83.3gの Pluronic PE 10500(非イオン性界面活性剤、BASF からのエチレンプロピレンオキシドブロック共重合体、水中18重量%)及び100gの Soprophor FLK (Rhodia からのイオン性トリスチリルフェニルエトキシレート)の溶液を、容器中で(溶解するまで)攪拌することにより製造した。その後に、180gのフィプロニル、次いで120gのアルファ−シペルメスリンを攪拌条件下に加えた。次いで2.5gの Rhodorsil 416(ジアルキルポリシロキサン消泡剤、Rhodia から)及び0.5gの Rhodorsil 432 (ジアルキルポリシロキサン消泡剤、Rhodia から)を、生成する混合物が均質になるまで加えた。
別の容器中で、300gのトウモロコシ油及び20gの式(Ib)のアルコールアルコキシレート(AKZO からの GT2624)を、攪拌しながら透明液体が得られるまで混合した。
320gの油相を770.75gの粉砕プレミックスに加え(量は特定成分の純度に依存する)、コロイドミルにより均質になるまで粉砕した。
実施例1の手順を繰り返したが、段階B)における式(Ib)のアルコールアルコキシレートを脂肪酸ポリエチレングリコールエステルの市販の混合物(Geronol(登録商標) VO 2001、Rodhia からの非イオン性乳化剤)で、又は9−オクタデセン酸のポリエチレングリコール300エステル(Alkamuls(登録商標) A、Rodhia からの非イオン性乳化剤)で置き換えた。両方の場合に、製剤は安定でなく、分離した。
Claims (13)
- (a) 5〜50重量%の少なくとも一つの農薬;及び
(b) 0.5〜30重量%の、式Ib又はIcの少なくとも一つの非イオン性界面活性剤
R 1 −O−(EO) n −(PO) m −H (Ib)
R 1 −O−(PO) r −(EO) s −H (Ic)
〔式中、
R1はブチル、i−ブチル、n−ペンチル、i−ペンチル、ネオペンチル、n−ヘキシル、i−ヘキシル、n−オクチル、i−オクチル、2−エチルヘキシル、ノニル、i−ノニルであり;
EOはエチレンオキシであり;
POはプロピレンオキシであり;
mは1〜10の数であり;
nは1〜10の数であり;
rは1〜10の数であり;
sは1〜10の数である〕;及び
(c) 0.5〜30重量%の少なくとも一つのイオン性トリスチリルフェニルアルコキシレート;及び
(d) 5〜50重量%の少なくとも一つの植物油;及び
(e) 合計100重量%になる量の水
を含む製剤であって、
農薬が水相中に懸濁液の形態で存在しており、そして油中の農薬濃度が、油の総重量に関して5重量%を越えない製剤。 - 油中の農薬濃度が、油の総重量に関して0.5重量%を越えない、請求項1に記載の製剤。
- 非イオン性界面活性剤(b)の式Ib又はIcにおいて、mは1〜5であり、nは1〜5であり、rは1〜5であり、sは1〜5である、請求項1〜2の何れかに記載の製剤。
- 非イオン性界面活性剤(b)の式Ibにおいて、R1が2−エチルヘキシルである、請求項3に記載の製剤。
- 成分(c)がイオン性のリン酸化又は硫酸化されたイオン性トリスチリルフェノールエトキシレートである、請求項1〜4の何れかに記載の製剤。
- エチレンオキシド/プロピレンオキシドブロック共重合体からなる群から選択されるもう一つの非イオン性界面活性剤(g)を追加して含む、請求項1〜5の何れかに記載の製剤。
- 油が農薬を含まない、請求項1〜6の何れかに記載の製剤。
- 植物油が、ココナツ油、パーム核油、パーム油、ダイズ油、ナタネ油、キャノーラ油及びメイズ油から選択される、請求項1〜7の何れかに記載の製剤。
- 製剤が、有機溶剤(f)を含まない、請求項1〜8の何れかに記載の製剤。
- 農薬が、フィプロニル及び/又はアルファシペルメスリンから選択される、請求項1〜9の何れかに記載の製剤。
- 有害昆虫及び/又は植物病原菌を駆除する方法であって、該有害昆虫及び/又は植物病原菌、それらの生息地、繁殖地、食糧供給物、有害昆虫及び/又は植物病原菌が生育しているか又は生育できる植物、種子、土壌、地区、材料又は環境を、又は該有害昆虫及び/又は植物病原菌による攻撃又は侵入から保護すべき材料、植物、種子、土壌、表面又は空間を、有効量の請求項1〜10の何れかに記載の農芸化学製剤と接触させることを含む方法。
- 望ましくない植生を抑制する方法であって、除草有効量の請求項1〜10の何れかに記載の農芸化学製剤を、植物、それらの生息地又は該植物の種子に作用させる方法。
- 請求項1〜10の何れかに記載の製剤で処理された種子。
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DE102004021434A1 (de) * | 2004-04-30 | 2005-11-24 | Basf Ag | Schnelle schaumarme Netzer für hydrophobe Oberflächen |
RU2370955C2 (ru) | 2004-09-13 | 2009-10-27 | Сертис Юроп Бв | Препарат для протравливания семян |
ES2651787T3 (es) * | 2005-04-26 | 2018-01-29 | Bayer Intellectual Property Gmbh | Suspoemulsiones de agua en aceite |
CA2617696A1 (en) * | 2005-08-11 | 2007-02-15 | Basf Aktiengesellschaft | Pesticidal mixtures comprising a phenylsemicarbazone |
TWI444140B (zh) | 2005-11-18 | 2014-07-11 | Cheminova As | 艾維菌素類之水包油調配物 |
WO2007110355A2 (en) | 2006-03-24 | 2007-10-04 | Basf Se | Liquid non aqueous agrochemical formulations comprising distyrylphenol ethoxylate |
PL2048946T3 (pl) * | 2006-08-04 | 2016-06-30 | Basf Se | Niewodne koncentraty substancji czynnych o działaniu chwastobójczym |
ES2340549T3 (es) | 2006-10-13 | 2010-06-04 | Rhodia Operations | Composicion disolvente que comprende al menos dos disolventes, y formulacion fitosanitaria que comprende dicha composicion disolvente asi como un compuesto activo. |
US20100210461A1 (en) * | 2007-07-20 | 2010-08-19 | Basf Se | Compositions comprising alcohol alkoxylates, and use of the alcohol alkoxylates as adjuvant for the agrochemical sector |
TW200915984A (en) | 2007-08-08 | 2009-04-16 | Basf Se | Aqueous microemulsions containing organic insecticide compounds |
US20110105333A1 (en) * | 2007-08-16 | 2011-05-05 | Rafel Israels | Seed Treatment Compositions and Methods |
AU2009242072A1 (en) | 2008-05-02 | 2009-11-05 | Basf Se | Improved microemulsion having wide application range |
EP2309847A2 (de) * | 2008-07-24 | 2011-04-20 | Basf Se | Öl-in-wasser emulsion umfassend lösungsmittel, wasser, tensid und pestizid |
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- 2007-11-09 KR KR1020097012781A patent/KR101526016B1/ko active IP Right Grant
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Also Published As
Publication number | Publication date |
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US20100016155A1 (en) | 2010-01-21 |
AU2007324614A1 (en) | 2008-05-29 |
AR063905A1 (es) | 2009-02-25 |
EP2107869A2 (en) | 2009-10-14 |
KR101526016B1 (ko) | 2015-06-04 |
MX2009004923A (es) | 2009-05-19 |
CA2668968A1 (en) | 2008-05-29 |
UA98128C2 (ru) | 2012-04-25 |
CA2668968C (en) | 2014-01-21 |
PH12009500961A1 (en) | 2008-05-29 |
WO2008061899A2 (en) | 2008-05-29 |
US8178117B2 (en) | 2012-05-15 |
EA200900653A1 (ru) | 2009-12-30 |
EA019134B1 (ru) | 2014-01-30 |
MX297198B (es) | 2012-03-16 |
CR10783A (es) | 2009-07-23 |
WO2008061899A3 (en) | 2009-03-05 |
KR20090105917A (ko) | 2009-10-07 |
PE20081218A1 (es) | 2008-11-06 |
JP2010510279A (ja) | 2010-04-02 |
BRPI0719027A2 (pt) | 2014-02-25 |
CN101541167A (zh) | 2009-09-23 |
CL2007003342A1 (es) | 2008-07-04 |
AU2007324614B2 (en) | 2012-12-20 |
ECSP099429A (es) | 2009-07-31 |
TW200829161A (en) | 2008-07-16 |
ZA200904264B (en) | 2010-08-25 |
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