ZA200108611B - Catalyst system. - Google Patents
Catalyst system. Download PDFInfo
- Publication number
- ZA200108611B ZA200108611B ZA200108611A ZA200108611A ZA200108611B ZA 200108611 B ZA200108611 B ZA 200108611B ZA 200108611 A ZA200108611 A ZA 200108611A ZA 200108611 A ZA200108611 A ZA 200108611A ZA 200108611 B ZA200108611 B ZA 200108611B
- Authority
- ZA
- South Africa
- Prior art keywords
- methyl
- zirconium dichloride
- dimethylsilanediyl
- azapentalene
- dimethyl
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 33
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 10
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 5
- 150000001336 alkenes Chemical class 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 25
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 230000000737 periodic effect Effects 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000002879 Lewis base Substances 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 150000007527 lewis bases Chemical class 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 125000002034 haloarylalkyl group Chemical group 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 14
- 229920000642 polymer Polymers 0.000 abstract description 7
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 247
- -1 methyl-zirconocene cation Chemical class 0.000 description 94
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 59
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 24
- 229910052726 zirconium Inorganic materials 0.000 description 23
- DNMINOWCGCDWKQ-UHFFFAOYSA-N 5-methylcyclopenta[b]pyrrole Chemical compound C1=NC2=CC(C)=CC2=C1 DNMINOWCGCDWKQ-UHFFFAOYSA-N 0.000 description 20
- WUKFGBUJEPLCSN-UHFFFAOYSA-N 5-methyl-2h-cyclopenta[b]thiophene Chemical compound C1SC2=CC(C)=CC2=C1 WUKFGBUJEPLCSN-UHFFFAOYSA-N 0.000 description 19
- ZGEGEMSWVWZKKD-UHFFFAOYSA-N 5-methyl-1-phenyl-2h-cyclopenta[b]pyrrole Chemical compound C12=CC(C)=CC2=CCN1C1=CC=CC=C1 ZGEGEMSWVWZKKD-UHFFFAOYSA-N 0.000 description 16
- FLNSMWIFPVKXPV-UHFFFAOYSA-N 2,5-dimethyl-2h-cyclopenta[b]thiophene Chemical compound CC1=CC2=CC(C)SC2=C1 FLNSMWIFPVKXPV-UHFFFAOYSA-N 0.000 description 15
- YNSOSPOWYQTGQP-UHFFFAOYSA-N 5-methyl-2h-cyclopenta[b]furan Chemical compound C1OC2=CC(C)=CC2=C1 YNSOSPOWYQTGQP-UHFFFAOYSA-N 0.000 description 15
- 150000003254 radicals Chemical class 0.000 description 11
- FJTIXNPQMYWPRB-UHFFFAOYSA-N 2,5-dimethylcyclopenta[b]pyrrole Chemical compound CC1=NC2=CC(C)=CC2=C1 FJTIXNPQMYWPRB-UHFFFAOYSA-N 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- TUVNTOZFUMXLAJ-UHFFFAOYSA-N 5-methyl-1h-cyclopenta[c]furan Chemical compound O1CC2=CC(C)=CC2=C1 TUVNTOZFUMXLAJ-UHFFFAOYSA-N 0.000 description 8
- OEGDPPCJMHJLGR-UHFFFAOYSA-N 5-methyl-2-phenyl-1h-cyclopenta[c]pyrrole Chemical compound C1C2=CC(C)=CC2=CN1C1=CC=CC=C1 OEGDPPCJMHJLGR-UHFFFAOYSA-N 0.000 description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- RMNKHKYRLLFLPT-UHFFFAOYSA-N 5-methylcyclopenta[c]pyrrole Chemical compound N1=CC2=CC(C)=CC2=C1 RMNKHKYRLLFLPT-UHFFFAOYSA-N 0.000 description 6
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- APEIPNONNWFGEU-UHFFFAOYSA-N 2,5-dimethyl-2h-cyclopenta[b]furan Chemical compound CC1=CC2=CC(C)OC2=C1 APEIPNONNWFGEU-UHFFFAOYSA-N 0.000 description 5
- VZENYRLLQMKOTD-UHFFFAOYSA-N 5-methyl-1h-cyclopenta[c]thiophene Chemical compound S1CC2=CC(C)=CC2=C1 VZENYRLLQMKOTD-UHFFFAOYSA-N 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 229910052735 hafnium Inorganic materials 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- BSUUCQOCNBWYSN-UHFFFAOYSA-N 2,5-dimethyl-1-phenyl-2h-cyclopenta[b]pyrrole Chemical compound CC1C=C2C=C(C)C=C2N1C1=CC=CC=C1 BSUUCQOCNBWYSN-UHFFFAOYSA-N 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 4
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 241000723368 Conium Species 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000012968 metallocene catalyst Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- FKTXDTWDCPTPHK-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical group FC(F)(F)[C](F)C(F)(F)F FKTXDTWDCPTPHK-UHFFFAOYSA-N 0.000 description 2
- ABIPLJQFLRXYES-UHFFFAOYSA-N 1,2,3,3a-tetrahydropentalene Chemical class C1=CC=C2CCCC21 ABIPLJQFLRXYES-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000010499 C–H functionalization reaction Methods 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 208000014797 chronic intestinal pseudoobstruction Diseases 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- BIEBZGCKLFWMCR-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1h-indene Chemical class C1C=CC=C2CCCC21 BIEBZGCKLFWMCR-UHFFFAOYSA-N 0.000 description 1
- IIFFFBSAXDNJHX-UHFFFAOYSA-N 2-methyl-n,n-bis(2-methylpropyl)propan-1-amine Chemical compound CC(C)CN(CC(C)C)CC(C)C IIFFFBSAXDNJHX-UHFFFAOYSA-N 0.000 description 1
- VAFGZWDYTDHMCR-UHFFFAOYSA-N 2H-cyclopenta[b]furan-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CCOC2=C1)C VAFGZWDYTDHMCR-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- VCFVRHAQERGNFA-UHFFFAOYSA-L C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C2=CC=CC=C2C=C1 VCFVRHAQERGNFA-UHFFFAOYSA-L 0.000 description 1
- OJVWBQRZCJLURF-UHFFFAOYSA-L C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 Chemical compound C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 OJVWBQRZCJLURF-UHFFFAOYSA-L 0.000 description 1
- WVDMUPUELBMOLS-UHFFFAOYSA-N CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C3=CC=CC=C3)=CC1=C2C1=CC=CC=C1.Cl.Cl.Cl.Cl Chemical compound CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C3=CC=CC=C3)=CC1=C2C1=CC=CC=C1.Cl.Cl.Cl.Cl WVDMUPUELBMOLS-UHFFFAOYSA-N 0.000 description 1
- XLQWMFYISNEWDQ-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl XLQWMFYISNEWDQ-UHFFFAOYSA-N 0.000 description 1
- QBPATROIDJMBJY-UHFFFAOYSA-L CC1=Cc2c(cccc2-c2ccc3ccccc3c2)C1[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1ccc2ccccc2c1)=[Si](C)C Chemical compound CC1=Cc2c(cccc2-c2ccc3ccccc3c2)C1[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2-c1ccc2ccccc2c1)=[Si](C)C QBPATROIDJMBJY-UHFFFAOYSA-L 0.000 description 1
- HTDDXKQCZCVYJW-UHFFFAOYSA-N CCC1=CC2=C(CC)C=CC=C2C1[Zr](C1C2=CC=CC(CC)=C2C=C1CC)=[Si](C)C.CCC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3CC)=[Si](C)C)=CC1=C2C1=CC=CC=C1.Cl.Cl.Cl.Cl Chemical compound CCC1=CC2=C(CC)C=CC=C2C1[Zr](C1C2=CC=CC(CC)=C2C=C1CC)=[Si](C)C.CCC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3CC)=[Si](C)C)=CC1=C2C1=CC=CC=C1.Cl.Cl.Cl.Cl HTDDXKQCZCVYJW-UHFFFAOYSA-N 0.000 description 1
- COGMWBULKSMXCE-UHFFFAOYSA-L C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C.[Cl-].[Cl-].[Zr+2] COGMWBULKSMXCE-UHFFFAOYSA-L 0.000 description 1
- UYPSSALGYXHKIS-UHFFFAOYSA-L C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] Chemical compound C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] UYPSSALGYXHKIS-UHFFFAOYSA-L 0.000 description 1
- VNFPYROUPDRSIC-UHFFFAOYSA-L C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C(CCCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] Chemical compound C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C(CCCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] VNFPYROUPDRSIC-UHFFFAOYSA-L 0.000 description 1
- UGHVVZPWSGOULV-UHFFFAOYSA-L C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] Chemical compound C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] UGHVVZPWSGOULV-UHFFFAOYSA-L 0.000 description 1
- APVINWWOYNALMI-UHFFFAOYSA-L C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].C(C)(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] Chemical compound C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].C(C)(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C1)[Zr+2] APVINWWOYNALMI-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- CUKHCTWZWOSFEK-UHFFFAOYSA-L [Cl-].[Cl-].C(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].C(CC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] CUKHCTWZWOSFEK-UHFFFAOYSA-L 0.000 description 1
- QGJLJKHOOAJSMP-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].C(CCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] QGJLJKHOOAJSMP-UHFFFAOYSA-L 0.000 description 1
- OZDQSNTZXVWRSA-UHFFFAOYSA-L [Cl-].[Cl-].C(CCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].C(CCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] OZDQSNTZXVWRSA-UHFFFAOYSA-L 0.000 description 1
- SVVDRYUEAWXWQM-UHFFFAOYSA-L [Cl-].[Cl-].C(CCCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].C(CCCCC)C1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] SVVDRYUEAWXWQM-UHFFFAOYSA-L 0.000 description 1
- PMZZKZTWSBQJHU-UHFFFAOYSA-J [Cl-].[Cl-].CC1(C=C(C=C1)C)[Zr+2]C1(C=C(C=C1)C)C.[Cl-].[Cl-].C(CCC)C1(C=CC=C1)[Zr+2]C1(C=CC=C1)CCCC Chemical compound [Cl-].[Cl-].CC1(C=C(C=C1)C)[Zr+2]C1(C=C(C=C1)C)C.[Cl-].[Cl-].C(CCC)C1(C=CC=C1)[Zr+2]C1(C=CC=C1)CCCC PMZZKZTWSBQJHU-UHFFFAOYSA-J 0.000 description 1
- HBANPAZOMWHHIL-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].CC1=CC=C(C=C1)C=1C(C2=CC=CC=C2C=1)[Zr+2] HBANPAZOMWHHIL-UHFFFAOYSA-L 0.000 description 1
- YVQPUXMWIMJFBY-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2c(cc(C)cc2C)C1[Zr++](C1C(C)=Cc2c1cc(C)cc2C)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2c(cc(C)cc2C)C1[Zr++](C1C(C)=Cc2c1cc(C)cc2C)=[Si](C)C YVQPUXMWIMJFBY-UHFFFAOYSA-L 0.000 description 1
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 1
- PDBOLQCPEKXSBW-UHFFFAOYSA-M [Ti]Cl Chemical compound [Ti]Cl PDBOLQCPEKXSBW-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000005741 alkyl alkenyl group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006388 chemical passivation reaction Methods 0.000 description 1
- YEDVUDDWJVRKIS-UHFFFAOYSA-N cyclopenta[b]pyrrole Chemical compound C1=C[C]2[N]C=CC2=C1 YEDVUDDWJVRKIS-UHFFFAOYSA-N 0.000 description 1
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical class N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- MKMUUVUYHMGIFI-UHFFFAOYSA-N dimethyl-[(2-phenyl-1H-cyclopenta[c]pyrrol-5-yl)methylidene]silane Chemical compound C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C MKMUUVUYHMGIFI-UHFFFAOYSA-N 0.000 description 1
- DGUIDBYKNGVRCS-UHFFFAOYSA-N dimethyl-[(5-methyl-2H-cyclopenta[b]furan-2-yl)methylidene]silane Chemical compound C[Si](=CC1OC2=CC(=CC2=C1)C)C DGUIDBYKNGVRCS-UHFFFAOYSA-N 0.000 description 1
- UOKWFSNVSIMQSB-UHFFFAOYSA-N dimethyl-[(5-methyl-2H-cyclopenta[b]thiophen-2-yl)methylidene]silane Chemical compound C[Si](=CC1C=C2C=C(C=C2S1)C)C UOKWFSNVSIMQSB-UHFFFAOYSA-N 0.000 description 1
- GDZRSSPGIXTSJF-UHFFFAOYSA-N dimethyl-[(5-methylcyclopenta[b]pyrrol-2-yl)methylidene]silane Chemical compound C[Si](=CC1=NC2=CC(=CC2=C1)C)C GDZRSSPGIXTSJF-UHFFFAOYSA-N 0.000 description 1
- IPZJQDSFZGZEOY-UHFFFAOYSA-N dimethylmethylene Chemical compound C[C]C IPZJQDSFZGZEOY-UHFFFAOYSA-N 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JZBZLRKFJWQZHU-UHFFFAOYSA-N n,n,2,4,6-pentamethylaniline Chemical compound CN(C)C1=C(C)C=C(C)C=C1C JZBZLRKFJWQZHU-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- NEMUVWSQFWIZKP-UHFFFAOYSA-N n-methyl-n-trichlorosilylmethanamine Chemical compound CN(C)[Si](Cl)(Cl)Cl NEMUVWSQFWIZKP-UHFFFAOYSA-N 0.000 description 1
- 125000005151 nonafluorobutanesulfonyl group Chemical group FC(C(C(S(=O)(=O)*)(F)F)(F)F)(C(F)(F)F)F 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- GUVXZFRDPCKWEM-UHFFFAOYSA-N pentalene Chemical compound C1=CC2=CC=CC2=C1 GUVXZFRDPCKWEM-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 125000005147 toluenesulfonyl group Chemical group C=1(C(=CC=CC1)S(=O)(=O)*)C 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- GIIXTFIYICRGMZ-UHFFFAOYSA-N tris(2,3-dimethylphenyl)phosphane Chemical compound CC1=CC=CC(P(C=2C(=C(C)C=CC=2)C)C=2C(=C(C)C=CC=2)C)=C1C GIIXTFIYICRGMZ-UHFFFAOYSA-N 0.000 description 1
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19917985A DE19917985A1 (de) | 1999-04-21 | 1999-04-21 | Katalysatorsystem |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200108611B true ZA200108611B (en) | 2002-10-21 |
Family
ID=7905294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200108611A ZA200108611B (en) | 1999-04-21 | 2001-10-19 | Catalyst system. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6949614B1 (ja) |
| EP (1) | EP1175262B1 (ja) |
| JP (1) | JP2002542342A (ja) |
| KR (1) | KR20020010609A (ja) |
| CN (1) | CN1137148C (ja) |
| AT (1) | ATE259675T1 (ja) |
| AU (1) | AU4547800A (ja) |
| BR (1) | BR0009871B1 (ja) |
| DE (2) | DE19917985A1 (ja) |
| ES (1) | ES2215651T3 (ja) |
| WO (1) | WO2000062928A1 (ja) |
| ZA (1) | ZA200108611B (ja) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG74749A1 (en) * | 1998-09-09 | 2000-08-22 | Sumitomo Chemical Co | Modified aluminium oxy compound polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocaron polymer |
| SG83828A1 (en) | 1999-12-27 | 2001-10-16 | Sumitomo Chemical Co | Catalyst for addition polymerization, and process for producing addition polymer with the same |
| EP1446429B1 (en) | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
| JP4571798B2 (ja) | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| WO2003042258A1 (en) | 2001-11-12 | 2003-05-22 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene and 1-butene polymers |
| EP1527108A2 (en) | 2002-07-15 | 2005-05-04 | Basell Polyolefine GmbH | Preparation of supported catalyst systems |
| JP2005538198A (ja) | 2002-09-06 | 2005-12-15 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| WO2004033510A2 (en) | 2002-10-10 | 2004-04-22 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| JP2006504834A (ja) | 2002-11-04 | 2006-02-09 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 改良された活性を有する触媒組成物の製造方法 |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| US7534848B2 (en) | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| US7390862B2 (en) * | 2003-05-12 | 2008-06-24 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene |
| CN100390207C (zh) * | 2004-04-26 | 2008-05-28 | 中国科学院化学研究所 | 一种聚烯烃复合材料的制备方法 |
| CN100471881C (zh) * | 2004-04-26 | 2009-03-25 | 中国科学院化学研究所 | 一种负载型茂金属催化剂的制备方法 |
| CA2584395A1 (en) | 2004-10-18 | 2006-04-27 | Basell Poliolefine Italia S.R.L. | Butene-1 (co)polymers having low isotacticity |
| KR101216434B1 (ko) | 2004-10-21 | 2012-12-28 | 바젤 폴리올레핀 게엠베하 | 1-부텐 중합체 및 그 제조 방법 |
| JP2008536813A (ja) | 2005-03-18 | 2008-09-11 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
| PL1858907T3 (pl) | 2005-03-18 | 2009-04-30 | Basell Polyolefine Gmbh | Metalocenowe związki |
| AU2006226366A1 (en) | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerizatio of olefins |
| JP2008534705A (ja) | 2005-03-23 | 2008-08-28 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィン類の重合法 |
| WO2006117285A1 (en) | 2005-05-03 | 2006-11-09 | Basell Polyolefine Gmbh | Process for the polymerization of alpha olefins |
| US7985799B2 (en) | 2005-05-11 | 2011-07-26 | Basell Poliolefine Italia S.R.L. | Polymerization process for preparing polyolefin blends |
| US8051611B2 (en) * | 2005-06-24 | 2011-11-08 | Dryvit Systems, Inc. | Exterior insulation and finish system and method and tool for installing same |
| EP1902062B1 (en) * | 2005-06-30 | 2012-06-13 | Basell Polyolefine GmbH | Metallocene compounds |
| US7897707B2 (en) * | 2006-07-17 | 2011-03-01 | Albemarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
| US20100136078A1 (en) * | 2007-05-23 | 2010-06-03 | Pierre Herben | Insecticidal composition and article obtained thereof |
| CN101677571B (zh) * | 2007-05-23 | 2013-04-24 | 巴塞尔聚烯烃股份有限公司 | 杀虫组合物及由其获得的制品 |
| ATE485318T1 (de) * | 2007-06-25 | 2010-11-15 | Basell Polyolefine Gmbh | 1-butenethylencopolymere |
| KR100905544B1 (ko) * | 2007-08-13 | 2009-07-01 | 금호석유화학 주식회사 | 이형원자가 배위된 단분자 알루미늄과 코발트가 함유된촉매와 이를 이용한 폴리부타디엔의 제조방법 |
| JP2011515517A (ja) * | 2008-03-20 | 2011-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンコポリマー |
| EP2254917A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
| KR20100137472A (ko) * | 2008-03-20 | 2010-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 1-부텐 기재 중합체의 조성물 |
| US20100324238A1 (en) * | 2008-03-20 | 2010-12-23 | Basell Poliolefine Italia S.R.L | 1-butene terpolymers |
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| EP0748821B1 (de) | 1995-06-12 | 1998-11-04 | TARGOR GmbH | Übergangsmetallverbindung |
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-
1999
- 1999-04-21 DE DE19917985A patent/DE19917985A1/de not_active Withdrawn
-
2000
- 2000-04-12 KR KR1020017013418A patent/KR20020010609A/ko active IP Right Grant
- 2000-04-12 BR BRPI0009871-0A patent/BR0009871B1/pt not_active IP Right Cessation
- 2000-04-12 ES ES00926878T patent/ES2215651T3/es not_active Expired - Lifetime
- 2000-04-12 AU AU45478/00A patent/AU4547800A/en not_active Abandoned
- 2000-04-12 DE DE50005332T patent/DE50005332D1/de not_active Expired - Fee Related
- 2000-04-12 CN CNB008064636A patent/CN1137148C/zh not_active Expired - Fee Related
- 2000-04-12 AT AT00926878T patent/ATE259675T1/de not_active IP Right Cessation
- 2000-04-12 WO PCT/EP2000/003263 patent/WO2000062928A1/de active IP Right Grant
- 2000-04-12 JP JP2000612058A patent/JP2002542342A/ja active Pending
- 2000-04-12 US US09/980,926 patent/US6949614B1/en not_active Expired - Fee Related
- 2000-04-12 EP EP00926878A patent/EP1175262B1/de not_active Expired - Lifetime
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2001
- 2001-10-19 ZA ZA200108611A patent/ZA200108611B/en unknown
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| Publication number | Publication date |
|---|---|
| ES2215651T3 (es) | 2004-10-16 |
| EP1175262A1 (de) | 2002-01-30 |
| ATE259675T1 (de) | 2004-03-15 |
| US6949614B1 (en) | 2005-09-27 |
| KR20020010609A (ko) | 2002-02-04 |
| CN1137148C (zh) | 2004-02-04 |
| AU4547800A (en) | 2000-11-02 |
| CN1347343A (zh) | 2002-05-01 |
| EP1175262B1 (de) | 2004-02-18 |
| BR0009871A (pt) | 2002-01-08 |
| WO2000062928A1 (de) | 2000-10-26 |
| DE19917985A1 (de) | 2000-10-26 |
| DE50005332D1 (de) | 2004-03-25 |
| BR0009871B1 (pt) | 2010-10-05 |
| JP2002542342A (ja) | 2002-12-10 |
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