WO2017169347A1 - 型内発泡成形体、発泡複合成形体、発泡複合成形体の製造方法、および金型 - Google Patents
型内発泡成形体、発泡複合成形体、発泡複合成形体の製造方法、および金型 Download PDFInfo
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- WO2017169347A1 WO2017169347A1 PCT/JP2017/006737 JP2017006737W WO2017169347A1 WO 2017169347 A1 WO2017169347 A1 WO 2017169347A1 JP 2017006737 W JP2017006737 W JP 2017006737W WO 2017169347 A1 WO2017169347 A1 WO 2017169347A1
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- mold
- foam
- molded body
- polyurethane
- mold foam
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C39/10—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. casting around inserts or for coating articles
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C27/00—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas
- A47C27/14—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas with foamed material inlays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/24—Feeding the material into the mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/26—Moulds or cores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/26—Moulds or cores
- B29C39/28—Moulds or cores with means to avoid flashes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/08—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles using several expanding or moulding steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/1285—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements the preformed part being foamed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60N—SEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
- B60N2/00—Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles
- B60N2/90—Details or parts not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/58—Upholstery or cushions, e.g. vehicle upholstery or interior padding
Definitions
- the present invention relates to an in-mold foam-molded product obtained by in-mold foam-molding foamed particles containing an olefin resin, a foam composite molded product in which an in-mold foam molded product and a urethane foam are integrated, and a foam composite molded product. And a mold for integrally molding a polyurethane foam on an in-mold foam molded product.
- the in-mold foam molding is manufactured by in-mold foam molding of polyolefin resin foam particles.
- the in-mold foam-molded body is disposed in a polyurethane foam molding die and is integrated with a polyurethane foam foam-molded from a polyurethane liquid to form a foam composite molded body.
- the foamed composite molded body is used as a vehicle seat such as an automobile by being covered with a seat cover.
- polyurethane foam is molded in the gap between the polyurethane foam molding die and the contact surface that contacts the polyurethane foam molding die, making it difficult to attach the foam composite molding to the vehicle body. Or there exists a problem that it is necessary to remove the polyurethane foam which exists between a foaming composite molded object and a vehicle body.
- Patent Documents 1 and 2 disclose a technique for preventing a polyurethane liquid or a polyurethane foam from entering a vehicle body mounting surface of a sheet core material.
- the resin molded body disclosed in Patent Document 1 has a large number of engaging elements on the surface of the substrate, and is provided with sealing protrusions that are continuous in the length direction at both ends in the width direction of the substrate surface. And it manufactures by mounting
- Patent Document 1 The resin molded body disclosed in Patent Document 1 prevents the resin from flowing out to the engaging element side by the sealing protrusion when the resin is introduced into the mold due to the above configuration.
- the composite sheet disclosed in Patent Document 2 includes a first nonwoven fabric layer, a second nonwoven fabric layer, and a film material having extensibility, and the film material is interposed between the first nonwoven fabric layer and the second nonwoven fabric layer.
- the first non-woven fabric layer, the second non-woven fabric layer, and the film material are integrated by performing needle punching in the laminated state.
- the composite sheet disclosed in Patent Document 2 is a film material because mechanical entanglement by needle punching is used to integrate the first nonwoven fabric layer, the second nonwoven fabric layer, and the film material with the above configuration. A number of holes are opened.
- the urethane foam stock solution that has passed through the film material through one nonwoven fabric layer and a hole opened in the film material is used as the other.
- the non-woven fabric layer absorbs the urethane foam stock solution from the surface of the other non-woven fabric layer and prevents it from oozing out.
- Japanese Patent Publication “JP 2009-78555 A” (published on April 16, 2009) Japanese Patent Publication “Japanese Patent Laid-Open No. 2008-44160 (published February 28, 2008)”
- Patent Documents 1 and 2 have a function of preventing the polyurethane liquid or polyurethane foam from entering the vehicle body mounting surface of the sheet core material, but are generated in the in-mold foam molded body. It has a function to prevent the polyurethane liquid and polyurethane foam from entering the gap formed between the contact surface of the in-mold foam molded product and the polyurethane foam molding die due to sink marks and warpage. Not done. For this reason, the above problem cannot be solved.
- the present invention has been made in view of the above problems, and its purpose is to prevent polyurethane foam from being molded to an unintended location and to easily and efficiently attach a foamed composite molded body to a vehicle body.
- An object of the present invention is to provide an in-mold foam-molded article that makes it possible.
- an in-mold foam molded article of the present invention is an in-mold foam molded article containing an olefin-based resin having a melting point or a softening temperature of 110 ° C. or higher.
- the polyurethane liquid and the polyurethane foam obtained from the polyurethane liquid are provided with a projecting portion for sealing that prevents the polyurethane liquid from entering between the contact surface and the mold.
- the method for producing a foamed composite molded body of the present invention includes a step of placing an in-mold foamed molded body in a mold (polyurethane foam molding mold) and a process of introducing a polyurethane liquid into the mold. And a step of foaming the polyurethane liquid and integrally molding a polyurethane foam into the in-mold foam molded body, wherein the in-mold foam molded body has an olefin having a melting point or a softening temperature of 110 ° C. or higher.
- An in-mold foam-molded body containing a resin wherein the in-mold foam-molded body is in the arrangement completed state, and at least a part of itself is in contact with the mold, and in the arrangement completion state,
- For sealing to prevent the polyurethane liquid introduced into the mold and the polyurethane foam obtained from the polyurethane liquid from entering between the contact surface and the mold It is characterized by comprising a detecting section.
- the mold of the present invention is a mold for integrally molding a polyurethane foam on an in-mold foam molded article containing an olefin resin having a melting point or a softening temperature of 110 ° C. or higher.
- the in-mold foam-molded product has a contact surface where at least a part of the in-mold foam-molded product is in contact with the mold when the in-mold foam-molded product is disposed in the mold.
- a sealing protrusion for preventing the polyurethane liquid introduced into the mold and the polyurethane foam obtained from the polyurethane liquid from entering between the contact surface and the mold.
- the mold includes a pressing protrusion that presses the sealing protrusion into the mold by pressing the in-mold foam molded body in the arrangement completed state into the mold. It is characterized by a door.
- the present invention has the effect of preventing the polyurethane foam from being molded to an unintended location and allowing the foamed composite molded body to be easily and efficiently attached to the vehicle body.
- FIG. 3 is a cross-sectional view of the in-mold foam molded body of FIG.
- FIG. 4 is a magnified view of a portion indicated by B in FIG. 3, showing the shape of the sealing protrusion of the in-mold foam molded body according to Embodiment 1 of the present invention.
- A) is sectional drawing which shows the shaping
- (b) is sectional drawing which shows the molding method of the foaming composite molded object which concerns on Embodiment 1 of this invention.
- FIG. 1 shows the shape of the protrusion part for a seal
- FIG. 1 The in-mold foam-molded body as a modified example of the in-mold foam-molded body according to Embodiment 1 is described, and shows the in-mold foam-molded body after the polyurethane foam is integrally molded in the polyurethane foam molding die D. It is sectional drawing. It is sectional drawing which shows the structure of the foaming composite molded object which concerns on Embodiment 2 of this invention.
- (A) shows the presence or absence of intrusion of the polyurethane foam in the molding of the foamed composite molded body using the in-mold foam molded body of Example 1, and the in-mold foam molded body of Example 1 is seen from the contact surface side.
- (B) shows the presence or absence of intrusion of polyurethane foam in the molding of a foamed composite molded article using the in-mold foam molded article of Comparative Example 2, and shows the in-mold foam molded article of Comparative Example 2 It is the figure which looked at from the contact surface side.
- Embodiment 1 The in-mold foam molded body 20 and the foamed composite molded body 10 in the present embodiment will be described with reference to FIGS.
- FIG. 1 is a cross-sectional view showing the structure of a foamed composite molded body 10 in the present embodiment.
- the foamed composite molded body 10 is a molded body in which an in-mold foam molded body 20 and a polyurethane foam 30 are integrally molded.
- the in-mold foam molded body 20 is an in-mold foam molded body made of foamed particles containing an olefin resin, for example, an in-mold foam molded body made of polyolefin resin foamed particles.
- the base resin constituting the expanded particles containing the olefin resin in the present embodiment is not particularly limited as long as the base resin contains at least the olefin resin, but from the viewpoint of strength, impact resistance, and heat resistance, A polyolefin resin or a composite resin of a polyolefin resin and a polystyrene resin is preferable, and a polyolefin resin is most preferable. Furthermore, in the case of polyolefin resin, recycling becomes easy.
- the polyolefin resin is not particularly limited, and examples thereof include polypropylene resin and polyethylene resin.
- the polypropylene resin include a propylene homopolymer, an ethylene / propylene copolymer, an ethylene / propylene / 1-butene copolymer, and the like.
- polyethylene resins include ethylene homopolymers, high density polyethylene resins, medium density polyethylene resins, low density polyethylene resins, linear low density polyethylene resins, and more specifically, ethylene / Examples thereof include 1-butene copolymer and ethylene-4-methyl-1-pentene copolymer.
- the copolymer may be a random copolymer or a block copolymer.
- the production method of the expanded particles is not particularly limited, and examples thereof include conventionally known production methods.
- the production methods disclosed in International Publication No. WO2009 / 075208 and Japanese Patent Application Publication No. 2006-117842 are listed.
- the production methods disclosed in Japanese Patent Laid-Open Publication No. 2008-239794 and International Patent Publication No. WO2016 / 152243 may be mentioned, but the present invention is not limited thereto. Absent.
- the foamed particles thus obtained, additives such as a flame retardant, an antistatic agent and a colorant can be appropriately contained or coated by a conventionally known method.
- the particle diameter of the expanded particles is not particularly limited, and may be, for example, 1 mm to 10 mm, but is preferably 1 mm to 5 mm from the viewpoint of filling into a mold apparatus for in-mold foam molding. 3 mm is more preferable.
- the expansion ratio of the expanded particles is not particularly limited, and may be, for example, 3 to 90 times. However, from the viewpoint of mechanical strength or moldability, 5 to 60 times is preferable, and 5 to 45 times is preferable. More preferred.
- Such expanded particles are commercially available, for example, as Eperan-PP, Eperan-XL manufactured by Kaneka Corporation, and are easily available.
- the expanded particles containing the olefin resin used in the present invention have heat resistance against the molding temperature of the polyurethane foam when the in-mold expanded molded body and the polyurethane foam are integrally molded (that is, the melting point of the expanded particles or It is preferable that the softening temperature is high.
- the melting point or softening temperature of the expanded particles containing the olefin resin used in the present invention is preferably 110 ° C. or higher and 160 ° C.
- the softening temperature in this invention means a Vicat softening point.
- the Vicat softening point is one of the indices representing the heat resistance of the resin.
- JIS K7196 Softening temperature test method by thermomechanical analysis of thermoplastic film and sheet”. It is measured according to the method.
- the in-mold foam molded body 20 will be described as an in-mold foam molded body made of polyolefin resin foam particles.
- the in-mold foam molded body 20 may be an in-mold foam molded body made of foamed particles containing an olefin resin, and need not necessarily be an in-mold foam molded body made of polyolefin resin foam particles. There is no.
- the in-mold foam-molded body 20 in one embodiment of the present invention is obtained by insert-molding an insert material I (mainly metal wire) into the above-mentioned in-mold foam-molded body, and is used as a sheet core material of a vehicle seat. May be used.
- the in-mold foam molded body 20 is molded by heat-foaming and fusing polyolefin resin foam particles using a mold apparatus for in-mold foam molding.
- the mold apparatus for in-mold foam molding includes a concave unit having a concave mold and a concave housing that holds the concave mold, and a convex unit having a convex mold and a convex housing that holds the convex mold. .
- a space is formed by the concave mold and the convex mold, and the polyolefin resin foamed particles are filled in the space.
- the polyolefin resin expanded particles may be polyolefin resin expanded particles whose internal pressure is increased by press-fitting an inorganic gas into the interior in advance, or an atmospheric pressure polyolefin resin expanded particle to which no internal pressure is applied. It may be.
- a saturated water vapor pressure of about 0.04 to 0.40 MPa (G) is supplied into the chambers provided in the concave housing and the convex housing, respectively.
- the foamed resin particles are heated and foamed and fused.
- the in-mold foam-molded body 20 obtained by in-mold foam-molding the polyolefin resin foam particles is molded.
- FIG. 2 is a view of the in-mold foam molded body 20 according to the present embodiment as viewed from the contact surface 21a side.
- FIG. 3 is a cross-sectional view of the in-mold foam molded body 20 of FIG.
- FIG. 4 shows the shape of the sealing protrusion 22 of the in-mold foam molded body 20 in the present embodiment, and is an enlarged view of a portion indicated by B in FIG.
- the in-mold foam molded body 20 in the present embodiment includes a base portion 21 that is a conventional in-mold foam molded body, and a projecting portion 22 for sealing.
- the base 21 and the projecting portion 22 for sealing are simultaneously molded by heating and foaming and fusing foamed particles of polyolefin resin in a mold apparatus for in-mold foam molding.
- the base 21 is the center of the seat core material of the vehicle seat, and constitutes a conventional in-mold foam molded body.
- the base 21 includes a contact surface 21a that contacts the polyurethane foam molding die D when placed in a polyurethane foam molding die (mold) D, which will be described later, and a polyurethane foam forming surface 21b on which the polyurethane foam is formed. Is provided on the surface (see FIG. 5B).
- the projecting portion 22 for sealing is a projection provided so as to project from the contact surface 21 a of the base portion 21.
- the sealing protrusion 22 in the present embodiment is provided on a part of the outer peripheral portion of the contact surface 21 a.
- the seal protrusion 22 is formed so that the area of the cross section perpendicular to the protrusion direction becomes smaller as it approaches the tip. Accordingly, the seal protrusion 22 is formed so as to be easily deformed in accordance with the pressing force applied at the time of contact with another object, as it approaches the tip of the seal protrusion 22. As a result, when the sealing protrusion 22 interferes with another object, the sealing protrusion 22 is easily crushed.
- the sealing projection 22 has a trapezoidal cross section.
- the protruding portion for sealing is formed by extrusion molding.
- the sealing protrusions continuous in one direction could be formed.
- the in-mold foam-molded body 20 in the present embodiment is molded using the in-mold foam-molding mold apparatus, the sealing protrusion 22 having an arbitrary size is formed at an arbitrary place. be able to.
- the foamed composite molded body 10 is a molded body in which an in-mold foam molded body 20 and a polyurethane foam 30 are integrally molded.
- the foamed composite molded body 10 has the surface where the in-mold foam molded body 20 is exposed (that is, the contact surface 21a of the base 21 of the in-mold foam molded body 20) attached to the vehicle body, and the polyurethane foam 30 is molded. By covering the surface with a seat cover, it is used as a vehicle seat for an automobile or the like.
- the molding method of the foamed composite molded body 10 will be described in detail.
- FIG. (A) of FIG. 5 is sectional drawing which shows the shaping
- (b) is sectional drawing which shows the shaping
- the member number 20 ′ is given to the in-mold foam molded body.
- the conventional in-mold foam molded body 20 ′ is configured only by the base 21 ′.
- the method of forming the foam composite molded body by integrally molding the in-mold foam molded body and the polyurethane foam 30 is as follows. It arrange
- the sealing protrusion 22 is formed on the contact surface 21 a of the base 21 of the in-mold foam molded body 20.
- the sealing protrusion 22 is provided at a position where it abuts on the polyurethane foam molding die D.
- the polyurethane liquid P and the polyurethane foam 30 can be prevented from entering the gap between the contact surface 21a of the base 21 of the in-mold foam molded body 20 and the polyurethane foam molding die D. ing.
- the seal protrusion 22 is formed so as to be easily deformed in accordance with the pressing force applied at the time of contact with another object, as it approaches the tip of the seal protrusion 22.
- the sealing protrusion 22 comes into contact with the polyurethane foam molding die D, the tip of the sealing protrusion 22 is crushed.
- the sealing projection 22 and the polyurethane foam molding die D can be more closely attached.
- the foamed composite molded body 10 is formed such that the closer the seal protrusion 22 is to the tip of the seal protrusion 22, the easier it is to deform in accordance with the pressing force applied when contacting the other object. Is attached to the vehicle body, the seal projection 22 is crushed by contacting the vehicle body. As a result, the possibility of hindering the mounting of the foamed composite molded body 10 to the vehicle body can be reduced.
- the sealing protrusion 22 is formed of a foam, and the closer to the tip of the sealing protrusion 22, the easier it is to deform according to the pressing force applied when contacting with another object. Since it is formed, it has high flexibility. Therefore, the adhesion of the sealing protrusion 22 to the polyurethane foam molding die D can be increased.
- the process of closing the polyurethane foam molding die D is performed.
- in-mold foaming is performed. It is preferable that the sealing protrusion 22 is pressed against the polyurethane foam molding die D by pressing the polyurethane foam molding die D into the molded body 20. Thereby, the protrusion part 22 for a seal
- the in-mold foam molded body 20 of the present invention has a configuration in which the sealing protrusion 22 abuts on the polyurethane foam molding die D when the in-mold foam molded body is disposed on the polyurethane foam molding die D.
- the degree of penetration of the polyurethane liquid P and the polyurethane foam 30 into the gap between the contact surface 21a of the base portion 21 of the in-mold foam molded body 20 and the polyurethane foam molding die D due to its viscosity and surface tension. Changes. Therefore, the length and width of the seal projection 22 can be adjusted as appropriate according to the degree of penetration.
- the polyurethane liquid P and the polyurethane foam 30 are not in contact with the polyurethane foam molding die D. It is possible to prevent entry into the gap between the contact surface 21a of the base portion 21 and the polyurethane foam molding die D.
- the size of the seal protrusion 22 will be described. As described above, the size of the sealing protrusion 22 is between the contact surface 21a of the base 21 of the in-mold foam molded body 20 and the polyurethane foam molding die D of the polyurethane liquid P and the polyurethane foam 30. It is adjusted appropriately according to the degree of penetration into the gap. Specifically, from the viewpoint of preventing the polyurethane liquid P and the polyurethane foam 30 from entering, it is preferable to make the sealing protrusion 22 large, and when the sealing protrusion 22 is brought into contact with the polyurethane foam molding die D From the viewpoint of ease of deformation, it is preferable to form the sealing protrusion 22 small.
- the protrusion height of the seal protrusion 22 (the vertical length of the seal protrusion 22 in FIG. 3) is preferably 1.0 mm to 15.0 mm, more preferably 2.0 mm to 12. It is 0 mm or less, More preferably, it is 3.0 mm or more and 8.0 mm or less.
- the protrusion height of the seal protrusion 22 is smaller than the lower limit value, the predetermined shape of the seal protrusion 22 cannot be obtained.
- the protrusion height of the seal protrusion 22 is larger than the upper limit value, the seal protrusion 22 is not easily deformed, so that the seal protrusion 22 is brought into contact with the polyurethane foam molding die D.
- the width of the sealing protrusion 22 (the left and right lengths of the sealing protrusion 22 in FIG. 3) is preferably 1.0 mm or more and 15.0 mm or less, more preferably 2.0 mm or more and 10.0 mm or less. More preferably, it is 3.0 mm or more and 5.0 mm or less.
- the sealing protrusion 22 is provided at a location where a gap between the polyurethane foam molding die D and the contact surface 21a is assumed to be large. As a result, it is possible to efficiently suppress the polyurethane liquid P and the polyurethane foam 30 from entering the gap between the contact surface 21a of the base 21 of the in-mold foam molded body 20 and the polyurethane foam molding die D. ing.
- the in-mold foam molded article when the polyurethane liquid P is heated to foam the polyurethane liquid P, the in-mold foam molded article deforms (shrinks). Therefore, the gap between the contact surface of the base of the in-mold foam molded body and the polyurethane foam molding die D is increased, and the polyurethane liquid P and the polyurethane foam 30 are in contact with the contact surface of the base of the in-mold foam molded body. There was a problem that it entered due to a gap between the polyurethane foam molding die D.
- the in-mold foam molded body 20 in the present embodiment is molded from foamed particles of a polyolefin resin having a melting point or softening temperature of 110 ° C. or higher.
- a polyolefin resin having a melting point or softening temperature of 110 ° C. or higher.
- an insert material I such as a metal wire may be insert molded.
- strength of an in-mold foaming molding can be improved.
- the insert material I exposed from the in-mold foam molded body it becomes easy to attach the in-mold foam molded body to other parts and the vehicle body.
- the shrinkage rate between the in-mold foam-molded body and the metal wire is different.
- sink marks and warps occur more remarkably.
- the gap between the contact surface of the base of the in-mold foam molded body and the polyurethane foam molding die D becomes large, and the polyurethane liquid P and the polyurethane foam 30 are contact surfaces of the base of the in-mold foam molded body. And the polyurethane foam molding die D.
- the in-mold foam molded article of the present invention is provided with the sealing protrusion, the polyurethane liquid is formed in the gap between the contact surface of the in-mold foam molded article and the polyurethane foam molding die D. Intrusion of P and polyurethane foam 30 can be prevented.
- the in-mold foam molded body 20 in the present embodiment is made of a polyolefin-based resin and has a surface (the surface of the base portion 21).
- the surface has a contact surface 21a with which at least a part of the surface abuts against the polyurethane foam molding die D when the in-mold foam molded body 20 is disposed in the polyurethane foam molding die D.
- the polyurethane liquid P introduced into the polyurethane foam molding die D and the polyurethane foam 30 obtained from the polyurethane liquid P are disposed between the contact surface 21a and the polyurethane foam molding die D.
- a seal protrusion 22 is provided to prevent entry into the gap.
- the space between the contact surface 21a of the in-mold foam molded body 20 and the polyurethane foam molding die D due to sink marks or warp generated in the in-mold foam molded body 20 is as follows.
- the polyurethane liquid P and the polyurethane foam 30 are prevented from entering from the gap. Thereby, it can prevent that the polyurethane foam 30 is shape
- FIG. Therefore, it is possible to prevent the polyurethane foam from being molded at an unintended location and to easily and efficiently attach the foamed composite molded body 10 to the vehicle body.
- the seal protrusion 22 in the first embodiment has a trapezoidal cross section, but the shape of the seal protrusion of the present invention is not limited thereto.
- 6 (a) and 6 (b) show the shape of the sealing protrusion as a modification of the in-mold foam molded body 20, and are sectional views cut along a plane perpendicular to the contact surface 21a. .
- the sealing protrusion 22A as a modification is shaped so that the area of the cross section perpendicular to the protruding direction becomes smaller toward the protruding direction. It is the same as the part 22 except that the cross section has a rounded shape. Since the projecting portion 22A for sealing is formed so that the area of the cross section perpendicular to the projecting direction becomes smaller toward the projecting direction, the closer to the tip of the projecting portion 22A for sealing, the closer to the other object. It is formed so as to be easily deformed in accordance with the applied pressing force. As a result, when the sealing protrusion 22A interferes with another object, the sealing protrusion 22 is easily crushed.
- the sealing protrusion 22B as a modified example has a rectangular cross section.
- the width of the seal protrusion 22B (left and right direction in FIG. 6B)
- the entire seal protrusion 22B is easily crushed.
- the sealing protrusion 22B interferes with another object, the sealing protrusion 22 is easily crushed.
- FIG. 7 is a cross-sectional view showing the in-mold foam molded body 20A after the polyurethane foam 30 is integrally molded in the polyurethane foam molding die D.
- the in-mold foam molded body 20 ⁇ / b> A is different from the in-mold foam molded body 20 in the first embodiment in that the sealing protrusion 22 is provided.
- the sealing protrusion 22 is provided so as to protrude from the polyurethane foam forming surface 21b of the base 21 at a position close to the contact surface 21a.
- the sealing protrusion 22 in the present modification is placed on the surface of the polyurethane foam molding die D facing the polyurethane foam forming surface 21b. It is provided at a position that substantially contacts.
- sticker in this modification becomes an undercut shape
- the projecting height of the sealing projection 22 in this modification (the left and right lengths of the sealing projection 22 in FIG. 7) is 15.0 mm.
- the “undercut shape” refers to a shape that cannot be removed as it is (for example, a convex shape or a concave shape) when the molded product is removed (released) from the mold during molding. It is.
- the sealing protrusion 22 abuts on the polyurethane foam molding die D. It has become. Thereby, it can prevent that the polyurethane liquid P and the polyurethane foam 30 penetrate
- the polyurethane foam 30 is possible to prevent the polyurethane foam 30 from being molded in the gap between the contact surface 21a and the polyurethane foam molding die D.
- FIG. 8 is a cross-sectional view showing the structure of the foamed composite molded body 40 in the present embodiment.
- FIG. 9 is a view of the in-mold foam molded body 50 according to the present embodiment as viewed from the contact surface 21a side.
- FIG. 10 is a cross-sectional view showing a molding method of the foamed composite molded body 40 in the present embodiment.
- the foamed composite molded body 40 is a molded body in which the in-mold foam molded body 50 and the polyurethane foam 30 are integrally molded.
- the sealing protrusion 22 is provided on a part of the outer peripheral portion of the contact surface 21 a.
- the in-mold foam molded body 50 includes a sealing protrusion 52, and the sealing protrusion 52 is an outer peripheral portion of the contact surface 21 a of the base 21. Of all.
- FIG. 11 is a cross-sectional view showing the structure of the foamed composite molded body 60 in the present embodiment.
- the foam composite molded body 60 is a molded body in which an in-mold foam molded body 70 and the polyurethane foam 30 are integrally molded.
- the in-mold foam molded body 70 according to the present embodiment is provided with an exfoliation preventing projection (sub-projection) 71 in that the in-mold foam molded body 20 and the in-mold foam molded body according to each of the first and second embodiments. It is different from 50.
- the peeling prevention protrusion 71 is a protrusion provided to protrude from the polyurethane foam forming surface 21b of the in-mold foam molded body 70.
- the protrusion 71 for preventing peeling does not come into contact with the polyurethane foam molding die D when the in-mold foam molding 70 is disposed on the polyurethane foam molding die D. They are spaced apart.
- the peeling preventing projection 71 is formed by heating, foaming, and fusing the polyolefin resin foam particles, and the base 21 and the seal projection 52 (or the seal projection 22). Molded at the same time.
- the peeling prevention projection 71 is formed in the polyurethane liquid P introduced into the polyurethane foam molding die D when the in-mold foam molded body 70 and the polyurethane foam 30 are integrally molded to mold the foam composite molded body 60.
- the peeling preventing projection 71 is immersed. In this state, by heating the polyurethane liquid P, the entire peeling prevention projection 71 is embedded in the polyurethane foam 30. As a result, the polyurethane foam 30 can be prevented from peeling from the in-mold foam molded body 70.
- one exfoliation preventing projection 71 is provided, but the in-mold foam molded body of the present invention is not limited to this.
- the peeling prevention protrusions 71 may be provided with two or three or more.
- the peeling preventing projection 71 is provided around a place where it is desired to reliably prevent the polyurethane foam 30 from peeling from the in-mold foamed molded body 70 or a place where there is a possibility of peeling. Moreover, it is preferable to provide the protrusion part 71 for peeling prevention other than the surface which opposes the contact surface 21a in the polyurethane foam formation surface 21b of the in-mold foaming molding 70. This is because the surface facing the abutment surface 21a is a seating surface in contact with the buttocks of the occupant in a vehicle seat such as an automobile, and therefore, a peeling prevention projection 71 is provided on the surface facing the abutment surface 21a.
- the peeling preventing projection 71 may be provided on a part of the polyurethane foam forming surface 21b of the in-mold foam molded body 70 (see FIG. 11), or in parallel with the contact surface 21a of the polyurethane foam forming surface 21b. Alternatively, it may be provided all around the polyurethane foam-forming surface 21b.
- the number, shape, and size of the protrusions 71 for preventing peeling are not particularly limited, but are appropriately adjusted in consideration of the size and shape of the polyurethane foam 30. Specifically, since the size of the protrusion 71 for preventing peeling can be increased as the polyurethane foam 30 is larger, there is no upper limit, and depending on the size and shape of the polyurethane foam 30, a sufficient effect can be obtained. Since there is a possibility of developing, there is no lower limit. However, in general, for example, the protrusion height of the peeling prevention protrusion 71 (the left and right lengths of the peeling prevention protrusion 71 in FIG.
- the peeling prevention protrusion 71 is preferably 1.0 mm or more and 15.0 mm or less, More preferably, it is 3.0 mm or more and 10.0 mm or less.
- the protrusion height of the peeling preventing protrusion 71 is preferably 15.0 mm or less so that it can be easily detached from the mold apparatus.
- the width of the peeling preventing projection 71 is preferably 1.0 mm or more and 15.0 mm or less, more preferably 3.0 mm or more and 10. 0 mm or less.
- This embodiment is different from the other embodiments in that the polyurethane foam molding die is provided with a pushing projection.
- FIG. 12 illustrates a process of closing the polyurethane foam molding die D1 in the present embodiment, and (a) is a cross-sectional view showing a state before the polyurethane foam molding die D1 is closed. ) Is a cross-sectional view showing a state after the polyurethane foam molding die D1 is closed.
- the polyurethane foam molding die D1 in the present embodiment includes a first die 81 and a second die 82.
- the first mold 81 is a mold in which the in-mold foam molded body 20 is installed.
- the second mold 82 is a mold for closing (mold closing) the polyurethane foam molding mold D1 by covering the first mold 81.
- the second mold 82 includes a pushing protrusion 82a.
- the second mold 82 covers the first die 81, so that the polyurethane foam molding die D1 is Closed.
- the pushing protrusion 82 a of the second mold pushes the in-mold foam molded body 20 toward the first mold 81.
- the sealing protrusion 22 of the in-mold foam molded body 20 is pressed against the first mold 81, so that the sealing protrusion 22 and the polyurethane foam molding die D1 can be more closely adhered to each other. .
- An in-mold foam-molded article is an in-mold foam-molded article containing an olefin resin having a melting point or a softening temperature of 110 ° C. or more, and the in-mold foam-molded article is disposed in a mold.
- the foam includes a sealing protrusion that prevents the foam from entering the gap between the contact surface and the mold.
- the polyurethane liquid and the gap between the contact surface of the in-mold foam molded body and the mold caused by sink marks or warps generated in the in-mold foam molded body and Prevents polyurethane foam from entering.
- a polyurethane foam is shape
- the sealing protrusion is provided on at least a part of the outer periphery of the contact surface.
- the projecting portion for sealing is provided at a position in contact with the mold when the arrangement is completed.
- the seal protrusion comes into contact with an object (other object) different from the seal protrusion as the seal protrusion approaches the tip of the seal protrusion. It is preferably formed so as to be easily deformed in accordance with the pressing force sometimes applied.
- the tip of the seal projection comes into contact with the mold, the tip of the seal projection starts from the pressure from the mold, and the entire seal projection can be easily crushed.
- molding can be stuck more.
- the sealing protrusion is crushed by contacting the vehicle body, so that the possibility of hindering the foamed composite molded body from being attached to the vehicle body can be reduced. .
- the in-mold foam-molded body according to one aspect of the present invention further includes a sub-projection portion provided apart from the mold in the arrangement completion state.
- the insert material may be insert molded.
- the strength of the in-mold foamed molded product can be improved. Furthermore, by using the insert material exposed from the in-mold foam molded body, it becomes easy to attach the in-mold foam molded body to other parts and the vehicle body.
- a foamed composite molded article according to one aspect of the present invention is a foamed composite molded article in which any of the above-mentioned in-mold foam-molded articles and polyurethane foam are integrated, The contact surface is exposed.
- the polyurethane foam is prevented from being molded on the contact surface by the sealing protrusion of the in-mold foam molded product.
- the melting point or softening temperature is preferably 115 ° C. or higher.
- the method for producing a foamed composite molded body includes a step of placing an in-mold foamed molded body in an arrangement-completed state, a step of introducing a polyurethane liquid into the mold, and the polyurethane Forming a polyurethane foam integrally with the in-mold foam molded body by foaming a liquid, and the in-mold foam molded body includes an olefin resin having a melting point or a softening temperature of 110 ° C. or higher.
- An in-mold foam-molded body wherein the in-mold foam-molded body is in the arrangement completion state, and at least a part of itself is in contact with the mold, and in the arrangement completion state, in the mold
- a sealing protrusion that prevents the introduced polyurethane liquid and the polyurethane foam obtained from the polyurethane liquid from entering between the contact surface and the mold; It is characterized in.
- the in-mold foam molded product is provided with a sealing protrusion for preventing the polyurethane foam from being molded on the contact surface.
- the polyurethane liquid is removed from the gap between the contact surface of the in-mold foam molded body and the mold due to sink marks or warpage generated in the in-mold foam molded body.
- polyurethane foam can be prevented from entering. Therefore, it is possible to prevent the polyurethane foam from being formed in the gap between the contact surface and the mold.
- the in-mold foam molded article is a mold-in-mold foam molded article including an olefin resin having a melting point or a softening temperature of 115 ° C. or higher. It is preferable.
- the method includes a step of closing the mold, and in the step of closing the mold, by pressing the mold into the in-mold foam molded body, It is preferable that the sealing protrusion is pressed against the mold.
- the seal protrusion and the mold can be more closely adhered to each other by pressing the seal protrusion to the mold.
- a mold according to an aspect of the present invention is a mold for integrally molding a polyurethane foam on an in-mold foam molded article containing an olefin resin, having a melting point or a softening temperature of 110 ° C. or higher.
- the foamed molded product includes a contact surface where at least a part of the foamed molded product comes into contact with the mold when the in-mold foamed molded product is placed in the mold, and the mold in the placement completed state.
- a polyurethane liquid introduced into the polyurethane foam, and a polyurethane foam obtained from the polyurethane liquid is provided with a sealing protrusion that prevents the intrusion between the contact surface and the mold,
- the mold is characterized in that it includes a pressing protrusion that presses the sealing protrusion into the mold by pressing the in-mold foam molded body in the arrangement completed state into the mold.
- the pushing protrusion pushes the in-mold foam molded body toward the mold.
- the seal projection can be pressed against the mold.
- the sealing projection and the mold can be more reliably brought into close contact with each other.
- the following Examples 1 to 7 were produced. Further, as Comparative Examples, the following Comparative Examples 1 to 4 were produced.
- the in-mold foam-molded bodies of Examples 1 to 7 and Comparative Examples 1 to 4 were produced in a rectangular shape with a length of 1300 mm ⁇ width of 600 mm ⁇ thickness of 150 mm.
- the metal wires used in Examples 5 to 6 and Comparative Example 4 were made of iron and had a rectangular shape with a diameter of 4.5 mm, a length of 1200 mm ⁇ a width of 500 mm.
- Example 1 The in-mold expanded molded body of Example 1 uses olefin resin expanded particles (manufactured by Kaneka Corporation, XL35, ethylene- ⁇ -olefin block copolymer, bulk density 20 g / L, melting point 117 ° C., no internal pressure applied). Made.
- a protruding portion for sealing (a cut surface in the protruding direction is trapezoidal, a protruding height of 4.0 mm, a tip width of 3.0 mm, a part of the outer peripheral portion of the contact surface, The width of the root portion was 5.0 mm).
- the protrusion for preventing peeling was not molded.
- Example 2 The in-mold foam molded body of Example 2 uses olefin resin expanded particles (manufactured by Kaneka Corporation, XL35, ethylene- ⁇ -olefin block copolymer, bulk density 20 g / L, melting point 117 ° C., no internal pressure applied). Made.
- seal protrusions having the same cross-sectional shape and size as the seal protrusions of the in-mold foam-molded body of Example 1 are formed on all the outer peripheral portions of the contact surfaces. Molded. Further, in the in-mold foam molded body of Example 2, the protrusion for preventing peeling was not molded.
- Example 3 The in-mold foam molded body of Example 3 uses olefin resin expanded particles (manufactured by Kaneka Corporation, XL35, ethylene- ⁇ -olefin block copolymer, bulk density 20 g / L, melting point 117 ° C., no internal pressure applied). Made.
- seal protrusions having the same cross-sectional shape and size as the seal protrusions of the in-mold foam-molded body of Example 1 are formed on all the outer peripheral portions of the contact surfaces. Molded.
- the protrusion for preventing peeling is rectangular, protrusion height 10.0 mm, width 10.0 mm, length (perpendicular to the paper surface in FIG. 11). The length in the direction (50.0 mm) was formed at the position shown in FIG.
- Example 4 The in-mold expanded molded body of Example 4 was obtained by expanding olefin resin expanded particles (manufactured by Kaneka Corporation, L-EPP36, ethylene-propylene random copolymer, bulk density 20 g / L, melting point 146 ° C., in a pressure vessel. The inner pressure was impregnated to about 0.1 MPa (G)).
- seal protrusions having the same cross-sectional shape and size as the seal protrusions of the in-mold foam-molded body of Example 1 are formed on all the outer peripheral portions of the contact surfaces. Molded.
- a peeling prevention protrusion having the same cross-sectional shape and size as the peeling prevention protrusion of the in-mold foam molding of Example 3 was formed.
- Example 5 The in-mold expanded molded body of Example 5 was obtained by expanding olefin resin expanded particles (manufactured by Kaneka Corporation, L-EPP36, ethylene-propylene random copolymer, bulk density 20 g / L, melting point 146 ° C., in a pressure vessel. It was made by integral molding with a metal wire using impregnated pressurized air to make the internal pressure about 0.1 MPa (G).
- seal protrusions having the same cross-sectional shape and size as the seal protrusions of the in-mold foam molded body of Example 1 are formed on all the outer peripheral portions of the contact surfaces. Molded. Moreover, in the in-mold foam-molded body of Example 5, the protrusion for preventing peeling was not molded.
- Example 6 The in-mold foam molded body of Example 6 was made of expanded olefin resin particles (manufactured by Kaneka Corporation, L-EPP36, ethylene-propylene random copolymer, bulk density 20 g / L, melting point 146 ° C., heated in a pressure resistant container. It was made by integral molding with a metal wire using impregnated pressurized air to make the internal pressure about 0.1 MPa (G).
- expanded olefin resin particles manufactured by Kaneka Corporation, L-EPP36, ethylene-propylene random copolymer, bulk density 20 g / L, melting point 146 ° C.
- Example 7 The in-mold expanded molded body of Example 7 uses olefin resin expanded particles (manufactured by Kaneka Corporation, XL35, ethylene- ⁇ -olefin block copolymer, bulk density 20 g / L, melting point 117 ° C., no internal pressure applied). Made.
- a projecting portion for sealing (a cut surface in the projecting direction was a rectangular shape, a projecting height of 30.0 mm, and a width of 30.0 mm) was formed on a part of the outer peripheral portion of the contact surface. .
- the protrusion for preventing peeling was not molded.
- Comparative Example 1 The in-mold foam molded body of Comparative Example 1 uses olefin resin expanded particles (manufactured by Kaneka Corporation, XL35, ethylene- ⁇ -olefin block copolymer, bulk density 20 g / L, melting point 117 ° C., no internal pressure applied). Made. In the in-mold foam-molded body of Comparative Example 1, the seal projection and the peeling prevention projection were not molded.
- Comparative Example 2 The in-mold foam molded body of Comparative Example 2 was prepared using polystyrene foam particles (manufactured by Kaneka Corporation, MKM, bulk density 17 g / L, softening temperature 100 ° C.). In the in-mold foam molded body of Comparative Example 2, the seal protrusion and the peeling prevention protrusion were not molded.
- Comparative Example 3 The in-mold foam molded body of Comparative Example 3 was prepared using polystyrene foam particles (manufactured by Kaneka Corporation, MKM, bulk density 17 g / L, softening temperature 100 ° C.). In the in-mold foam molded article of Comparative Example 3, a seal projection having the same cross-sectional shape and size as the seal projection of the in-mold foam molded article of Example 1 is formed on a part of the outer peripheral portion of the contact surface. Was molded. Moreover, in the in-mold foam-molded body of Comparative Example 3, the protrusion for preventing peeling was not molded.
- Comparative Example 4 The in-mold foam molded body of Comparative Example 4 is an expanded olefin resin particle (manufactured by Kaneka Corporation, L-EPP36, ethylene-propylene random copolymer, bulk density 20 g / L, melting point 146 ° C., added in a pressure-resistant container. It was made by integral molding with a metal wire using impregnated pressurized air to make the internal pressure about 0.1 MPa (G). In the in-mold foam molded body of Comparative Example 4, the sealing protrusion and the peeling prevention protrusion were not molded.
- Table 1 shows the results of these evaluations.
- the melting point of the olefin foam molded article particles is high. It was possible to prevent deformation (shrinkage) of the in-mold foam molded product during production of the composite molded product. Thereby, it was possible to suppress the polyurethane foam from being formed on the contact surface side.
- the in-mold foam molded bodies of Examples 1 to 7 were formed with the projecting portions for sealing, it was possible to further suppress the polyurethane foam from being molded on the contact surface side.
- the projecting portion for sealing has a rectangular cut surface in the projecting direction, and the projecting height is 30.0 mm and the width is 30.0 mm, the mold for polyurethane foam molding It did not collapse when it contacted. As a result, the gap between the contact surface of the in-mold foam molded body and the polyurethane foam molding die was increased, and a small amount of polyurethane foam entered the gap.
- FIG. 13 shows the presence or absence of intrusion of polyurethane foam in the molding of the foamed composite molded body using the in-mold foam molded body of Example 1, and abuts the in-mold foam molded body of Example 1 It is the figure seen from the surface side, (b) shows the presence or absence of the penetration
- the polyurethane foam is in contact with the contact surface of the in-mold foam molded body. It was possible to suppress entry into the gap between the polyurethane foam molding die.
- the polyurethane foam is applied to the in-mold foam molded body. It entered the gap between the contact surface and the polyurethane foam mold.
- the sealing protrusions provided in the in-mold foam molded bodies of Examples 1 to 6 have a trapezoidal cut surface in the protruding direction, and are formed so that the cross-sectional area becomes smaller toward the tip. The closer to the tip, the easier it is to deform according to the pressing force applied at the time of contact with another object. That is, the sealing protrusion has flexibility.
- the projecting portion for sealing comes into contact with the polyurethane foam molding die, the projecting portion for sealing is easily crushed, thereby increasing the adhesion between the projecting portion for sealing and the mold for molding polyurethane foam.
- the polyurethane foam could be prevented from entering the gap between the contact surface and the polyurethane foam molding die.
- the sealing protrusions are formed on the entire outer peripheral portion of the contact surface, that is, the in-mold foam molding is performed on the polyurethane foam molding die.
- the space filled with the polyurethane liquid and the space formed by the abutment surface, the polyurethane foam molding die, and the sealing protrusion are completely partitioned (the space is divided). Therefore, it was possible to completely prevent the polyurethane foam from being formed on the contact surface side.
- the polyurethane foam was easily peeled from the in-mold foam molded body, whereas the in-mold foam molded bodies of Examples 3 and 4 were Since the protrusion for preventing peeling was molded, the polyurethane foam was not easily peeled from the in-mold foam molded article.
- the foamed composite molded body molded using the in-mold foam molded body of Examples 5 and 6 or Comparative Example 4 is produced by integrally molding the in-mold foam molded body with the metal wire.
- the in-mold foamed molded product was slightly deformed as compared with the case where it was not integrally molded with the metal wire.
- polyurethane is formed in the gap between the contact surface of the in-mold foam molding and the polyurethane foam molding die. It was possible to suppress the intrusion of the foam.
- the height of the projecting portion for sealing is formed as large as 8.0 mm.
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Abstract
Description
本実施形態における型内発泡成形体20および発泡複合成形体10について、図1~図6を参照しながら説明する。図1は、本実施形態における発泡複合成形体10の構造を示す断面図である。
型内発泡成形体20は、オレフィン系樹脂を含む発泡粒子からなる型内発泡成形体であり、例えば、ポリオレフィン系樹脂発泡粒子からなる型内発泡成形体である。
次に、型内発泡成形体20の形状について、図2~図4を参照しながら説明する。図2は、本実施形態における型内発泡成形体20を当接面21a側から見た図である。図3は、図2の型内発泡成形体20のA-A矢視断面図である。図4は、本実施形態における型内発泡成形体20のシール用突出部22の形状を示すものであり、図3のBで示す部分の拡大図である。
発泡複合成形体10は、図1に示すように、型内発泡成形体20とポリウレタンフォーム30とが一体成形された成形体である。発泡複合成形体10は、型内発泡成形体20が露出している面(すなわち、型内発泡成形体20の基部21の当接面21a)を車体に取り付けられると共に、ポリウレタンフォーム30が成形された面をシートカバーで覆われることにより、自動車などの車両用シートとして用いられる。以下に発泡複合成形体10の成形方法について詳細に説明する。
発泡複合成形体10の成形方法(製造方法)について、図5を参照しながら説明する。図5の(a)は、従来の発泡複合成形体の成形方法を示す断面図であり、(b)は、本実施形態における発泡複合成形体10の成形方法を示す断面図である。なお、図5の(a)に示す従来の発泡複合成形体の成形方法を示す断面図では、型内発泡成形体に20´の部材番号を付している。また、従来の型内発泡成形体20´は、基部21´のみによって構成されているものとする。
実施形態1におけるシール用突出部22は、図4に示すように、断面が台形状となっていたが、本発明のシール用突出部の形状はこれに限られない。
実施形態1における型内発泡成形体20の変形例としての型内発泡成形体20Aについて、図7に基づいて説明する。
本発明の他の実施形態について説明すれば、以下のとおりである。なお、説明の便宜上、前記実施形態にて説明した部材と同じ機能を有する部材については、同じ符号を付記し、その説明を省略する。
本発明の他の実施形態について説明すれば、以下のとおりである。なお、説明の便宜上、前記実施形態にて説明した部材と同じ機能を有する部材については、同じ符号を付記し、その説明を省略する。
本発明の他の実施形態について説明すれば、以下のとおりである。なお、説明の便宜上、前記実施形態にて説明した部材と同じ機能を有する部材については、同じ符号を付記し、その説明を省略する。
本発明の一態様に係る型内発泡成形体は、融点または軟化温度が110℃以上である、オレフィン系樹脂を含む型内発泡成形体であって、前記型内発泡成形体が金型に配置された配置完了状態において、自身の少なくとも一部が当該金型と当接する当接面と、前記配置完了状態において、前記金型内に導入されたポリウレタン液と、前記ポリウレタン液から得られたポリウレタンフォームとが、前記当接面と前記金型との間の隙間へと侵入することを防ぐシール用突出部とを備えていることを特徴としている。
実施例1の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、XL35、エチレン-α―オレフィンブロック共重合体、かさ密度20g/L、融点117℃、内圧付与なし)を用いて作製した。実施例1の型内発泡成形体では、当接面の外周部の一部にシール用突出部(突出方向の切断面が台形形状、突出高さ4.0mm、先端部の幅3.0mm、根元部の幅5.0mm)を成形した。また、実施例1の型内発泡成形体では、剥離防止用突出部を成形しなかった。
実施例2の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、XL35、エチレン-α―オレフィンブロック共重合体、かさ密度20g/L、融点117℃、内圧付与なし)を用いて作製した。実施例2の型内発泡成形体では、当接面の外周部のすべてに、実施例1の型内発泡成形体のシール用突出部と同様の断面形状・大きさを有するシール用突出部を成形した。また、実施例2の型内発泡成形体では、剥離防止用突出部を成形しなかった。
実施例3の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、XL35、エチレン-α―オレフィンブロック共重合体、かさ密度20g/L、融点117℃、内圧付与なし)を用いて作製した。実施例3の型内発泡成形体では、当接面の外周部のすべてに、実施例1の型内発泡成形体のシール用突出部と同様の断面形状・大きさを有するシール用突出部を成形した。また、実施例3の型内発泡成形体では、剥離防止用突出部(突出方向の切断面が矩形形状、突出高さ10.0mm、幅10.0mm、長さ(図11における紙面に垂直な方向の長さ)50.0mm)を図11に示す位置に成形した。
実施例4の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、L-EPP36、エチレン-プロピレンランダム共重合体、かさ密度20g/L、融点146℃、耐圧容器内にて加圧空気を含浸させて内圧を約0.1MPa(G)にした)を用いて作製した。実施例4の型内発泡成形体では、当接面の外周部のすべてに、実施例1の型内発泡成形体のシール用突出部と同様の断面形状・大きさを有するシール用突出部を成形した。また、実施例4の型内発泡成形体では、実施例3の型内発泡成形体の剥離防止用突出部と同様の断面形状・大きさを有する剥離防止用突出部を成形した。
実施例5の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、L-EPP36、エチレン-プロピレンランダム共重合体、かさ密度20g/L、融点146℃、耐圧容器内にて加圧空気を含浸させて内圧を約0.1MPa(G)にした)を用いて、金属ワイヤと一体成形して作製した。実施例5の型内発泡成形体では、当接面の外周部のすべてに、実施例1の型内発泡成形体のシール用突出部と同様の断面形状・大きさを有するシール用突出部を成形した。また、実施例5の型内発泡成形体では、剥離防止用突出部を成形しなかった。
実施例6の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、L-EPP36、エチレン-プロピレンランダム共重合体、かさ密度20g/L、融点146℃、耐圧容器内にて加圧空気を含浸させて内圧を約0.1MPa(G)にした)を用いて、金属ワイヤと一体成形して作製した。実施例6の型内発泡成形体では、当接面の外周部のすべてに、シール用突出部(突出方向の切断面が台形形状、突出高さ8.0mm、先端部の幅3.0mm、根元部の幅5.0mm)を成形した。また、実施例6の型内発泡成形体では、剥離防止用突出部を成形しなかった。
実施例7の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、XL35、エチレン-α―オレフィンブロック共重合体、かさ密度20g/L、融点117℃、内圧付与なし)を用いて作製した。実施例7の型内発泡成形体では、当接面の外周部の一部にシール用突出部(突出方向の切断面が長方形形状、突出高さ30.0mm、幅30.0mm)を成形した。また、実施例7の型内発泡成形体では、剥離防止用突出部を成形しなかった。
比較例1の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、XL35、エチレン-α―オレフィンブロック共重合体、かさ密度20g/L、融点117℃、内圧付与なし)を用いて作製した。比較例1の型内発泡成形体では、シール用突出部および剥離防止用突出部を成形しなかった。
比較例2の型内発泡成形体は、ポリスチレン発泡粒子(株式会社カネカ製、MKM、かさ密度17g/L、軟化温度100℃)を用いて作製した。比較例2の型内発泡成形体では、シール用突出部および剥離防止用突出部を成形しなかった。
比較例3の型内発泡成形体は、ポリスチレン発泡粒子(株式会社カネカ製、MKM、かさ密度17g/L、軟化温度100℃)を用いて作製した。比較例3の型内発泡成形体では、当接面の外周部の一部に、実施例1の型内発泡成形体のシール用突出部と同様の断面形状・大きさを有するシール用突出部を成形した。また、比較例3の型内発泡成形体では、剥離防止用突出部を成形しなかった。
比較例4の型内発泡成形体は、オレフィン系樹脂発泡粒子(株式会社カネカ製、L-EPP36、エチレン-プロピレンランダム共重合体、かさ密度20g/L、融点146℃、耐圧容器内にて加圧空気を含浸させて内圧を約0.1MPa(G)にした)を用いて、金属ワイヤと一体成形して作製した。比較例4の型内発泡成形体では、シール用突出部および剥離防止用突出部を成形しなかった。
実施例1~7および比較例1~4の型内発泡成形体を用いて発泡複合成形体の製造を行い、以下の3つの評価を行った。
製造した発泡複合成形体を型内発泡成形体用の検査治具に設置し、型内発泡成形体の当接面の浮きを確認し、以下のように評価した。
○:浮きがない
×:浮きがある
(2)侵入の評価基準
製造した発泡複合成形体の型内発泡成形体の当接面を確認し、以下のように評価した。○:当接面とポリウレタンフォーム成形用金型との間の隙間へのポリウレタンフォームの侵入なし
△:シール用突出部による、当接面とポリウレタンフォーム成形用金型との間の隙間へのポリウレタンフォームの侵入の抑制効果あり
□:当接面とポリウレタンフォーム成形用金型との間の隙間へのポリウレタンフォームの侵入があるが、下記×と比較して侵入量が小さい
×:当接面とポリウレタンフォーム成形用金型との間の隙間へのポリウレタンフォームの侵入あり
(3)剥離の評価基準
剥離防止用突出部付近のポリウレタンフォームを手で型内発泡成形体から引き離した際の剥離容易性を以下のように評価した。
○:容易に剥離しない
×:容易に剥離する。
20、50、70 型内発泡成形体
21 基部
21a 当接面
21b ポリウレタンフォーム形成面
22、22A、22B、52 シール用突出部
30 ポリウレタンフォーム
71 剥離防止用突出部(副突出部)
D、D1 ポリウレタンフォーム成形用金型(金型)
82a 押し込み用突起
I インサート材
P ポリウレタン液
Claims (12)
- 融点または軟化温度が110℃以上である、オレフィン系樹脂を含む型内発泡成形体であって、
前記型内発泡成形体が金型に配置された配置完了状態において、自身の少なくとも一部が当該金型と当接する当接面と、
前記配置完了状態において、前記金型内に導入されたポリウレタン液と、前記ポリウレタン液から得られたポリウレタンフォームとが、前記当接面と前記金型との間へと侵入することを防ぐシール用突出部とを備えていることを特徴とする型内発泡成形体。 - 前記シール用突出部は、前記当接面の外周の少なくとも一部に設けられていることを特徴とする請求項1に記載の型内発泡成形体。
- 前記シール用突出部は、前記配置完了状態において、前記金型と当接する位置に設けられていることを特徴とする請求項1または2に記載の型内発泡成形体。
- 前記シール用突出部は、前記シール用突出部の先端に近づくほど、前記シール用突出部とは別の物体との当接時に加えられる押圧力に応じて変形しやすいように形成されていることを特徴とする請求項1~3のいずれか1項に記載の型内発泡成形体。
- 前記配置完了状態において前記金型から離間されて設けられた副突出部をさらに備えていることを特徴とする請求項1~4のいずれか1項に記載の型内発泡成形体。
- インサート材がインサート成形されていることを特徴とする請求項1~5のいずれか1項に記載の型内発泡成形体。
- 請求項1~6のいずれか1項に記載の型内発泡成形体と、前記ポリウレタンフォームとが一体化された発泡複合成形体であって、
前記型内発泡成形体の前記当接面が露出されていることを特徴とする発泡複合成形体。 - 融点または軟化温度は、115℃以上であることを特徴とする請求項7に記載の発泡複合成形体。
- 型内発泡成形体を金型に配置された配置完了状態とする工程と、
前記金型にポリウレタン液を導入する工程と、
前記ポリウレタン液を発泡させて、前記型内発泡成形体にポリウレタンフォームを一体的に成形する工程とを含み、
前記型内発泡成形体は、融点または軟化温度が110℃以上である、オレフィン系樹脂を含む型内発泡成形体であって、
前記型内発泡成形体が前記配置完了状態において、自身の少なくとも一部が当該金型と当接する当接面と、
前記配置完了状態において、前記金型内に導入された前記ポリウレタン液と、前記ポリウレタン液から得られた前記ポリウレタンフォームとが、前記当接面と前記金型との間へと侵入することを防ぐシール用突出部とを備えていることを特徴とする発泡複合成形体の製造方法。 - 前記型内発泡成形体は、融点または軟化温度が115℃以上である、オレフィン系樹脂を含む型内発泡成形体であることを特徴とする請求項9に記載の発泡複合成形体の製造方法。
- 前記金型を閉じる工程を含み、
前記金型を閉じる工程において、前記型内発泡成形体に対して前記金型を押し込むことにより、前記シール用突出部を前記金型に圧接させることを特徴とする請求項9または10に記載の発泡複合成形体の製造方法。 - 融点または軟化温度が110℃以上である、オレフィン系樹脂を含む型内発泡成形体にポリウレタンフォームを一体的に成形する金型であって、
前記型内発泡成形体は、
前記型内発泡成形体が前記金型に配置された配置完了状態において、自身の少なくとも一部が当該金型と当接する当接面と、
前記配置完了状態において、前記金型内に導入されたポリウレタン液と、前記ポリウレタン液から得られたポリウレタンフォームとが、前記当接面と前記金型との間へと侵入することを防ぐシール用突出部とを備えており、
前記金型は、
前記配置完了状態にある前記型内発泡成形体を前記金型に押し込むことにより、前記シール用突出部を前記金型に圧接させる押し込み用突起を備えていることを特徴とする金型。
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