WO2016147830A1 - ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール - Google Patents
ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール Download PDFInfo
- Publication number
- WO2016147830A1 WO2016147830A1 PCT/JP2016/055595 JP2016055595W WO2016147830A1 WO 2016147830 A1 WO2016147830 A1 WO 2016147830A1 JP 2016055595 W JP2016055595 W JP 2016055595W WO 2016147830 A1 WO2016147830 A1 WO 2016147830A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- meth
- coating agent
- adhesive coating
- hydroxyl group
- polyol composition
- Prior art date
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 106
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 102
- 239000011248 coating agent Substances 0.000 title claims abstract description 82
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 229920005862 polyol Polymers 0.000 title claims abstract description 55
- 150000003077 polyols Chemical class 0.000 title claims abstract description 55
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000000576 coating method Methods 0.000 title abstract description 18
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 45
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 45
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 35
- 239000003566 sealing material Substances 0.000 claims abstract description 22
- 239000012790 adhesive layer Substances 0.000 claims abstract description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 72
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 70
- 239000005056 polyisocyanate Substances 0.000 claims description 37
- 229920001228 polyisocyanate Polymers 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 32
- 229920000515 polycarbonate Polymers 0.000 claims description 21
- 239000004417 polycarbonate Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000010410 layer Substances 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 53
- -1 polyethylene terephthalate Polymers 0.000 description 39
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 33
- 239000002585 base Substances 0.000 description 32
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- 229920005989 resin Polymers 0.000 description 23
- 239000011347 resin Substances 0.000 description 23
- 239000010408 film Substances 0.000 description 20
- 239000007787 solid Substances 0.000 description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 16
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 15
- 229920001225 polyester resin Polymers 0.000 description 15
- 239000004645 polyester resin Substances 0.000 description 15
- 239000004593 Epoxy Substances 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 13
- 150000004665 fatty acids Chemical class 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000005038 ethylene vinyl acetate Substances 0.000 description 11
- 239000003960 organic solvent Substances 0.000 description 11
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 description 10
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- 150000002009 diols Chemical class 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 5
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical class C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 239000001530 fumaric acid Substances 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- 238000010248 power generation Methods 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 3
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 3
- 229940043375 1,5-pentanediol Drugs 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920000417 polynaphthalene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- MECNWXGGNCJFQJ-UHFFFAOYSA-N 3-piperidin-1-ylpropane-1,2-diol Chemical compound OCC(O)CN1CCCCC1 MECNWXGGNCJFQJ-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- RPPBZEBXAAZZJH-UHFFFAOYSA-N cadmium telluride Chemical compound [Te]=[Cd] RPPBZEBXAAZZJH-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- LCPNYLRZLNERIG-ZETCQYMHSA-N (2S)-6-amino-2-[2-(oxomethylidene)hydrazinyl]hexanoyl isocyanate Chemical compound NCCCC[C@H](NN=C=O)C(=O)N=C=O LCPNYLRZLNERIG-ZETCQYMHSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- WBODDOZXDKQEFS-UHFFFAOYSA-N 1,2,3,4-tetramethyl-5-phenylbenzene Chemical group CC1=C(C)C(C)=CC(C=2C=CC=CC=2)=C1C WBODDOZXDKQEFS-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- ZIZJPRKHEXCVLL-UHFFFAOYSA-N 1,3-bis(6-isocyanatohexyl)-1,3-diazetidine-2,4-dione Chemical compound O=C=NCCCCCCN1C(=O)N(CCCCCCN=C=O)C1=O ZIZJPRKHEXCVLL-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- FWWWRCRHNMOYQY-UHFFFAOYSA-N 1,5-diisocyanato-2,4-dimethylbenzene Chemical compound CC1=CC(C)=C(N=C=O)C=C1N=C=O FWWWRCRHNMOYQY-UHFFFAOYSA-N 0.000 description 1
- LIPRQQHINVWJCH-UHFFFAOYSA-N 1-ethoxypropan-2-yl acetate Chemical compound CCOCC(C)OC(C)=O LIPRQQHINVWJCH-UHFFFAOYSA-N 0.000 description 1
- RQBUVIFBALZGPC-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanatophenyl)benzene Chemical compound C1=CC(N=C=O)=CC=C1C1=CC=C(N=C=O)C=C1 RQBUVIFBALZGPC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- OJRJDENLRJHEJO-UHFFFAOYSA-N 2,4-diethylpentane-1,5-diol Chemical compound CCC(CO)CC(CC)CO OJRJDENLRJHEJO-UHFFFAOYSA-N 0.000 description 1
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- SEFYJVFBMNOLBK-UHFFFAOYSA-N 2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane Chemical compound C1OC1COCCOCCOCC1CO1 SEFYJVFBMNOLBK-UHFFFAOYSA-N 0.000 description 1
- SHKUUQIDMUMQQK-UHFFFAOYSA-N 2-[4-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COCCCCOCC1CO1 SHKUUQIDMUMQQK-UHFFFAOYSA-N 0.000 description 1
- HIGURUTWFKYJCH-UHFFFAOYSA-N 2-[[1-(oxiran-2-ylmethoxymethyl)cyclohexyl]methoxymethyl]oxirane Chemical compound C1OC1COCC1(COCC2OC2)CCCCC1 HIGURUTWFKYJCH-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- BYPFICORERPGJY-UHFFFAOYSA-N 3,4-diisocyanatobicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(N=C=O)C(N=C=O)=CC1C2 BYPFICORERPGJY-UHFFFAOYSA-N 0.000 description 1
- SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical compound CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 description 1
- BLCFRFQELNMPIZ-UHFFFAOYSA-N 3-methylpent-1-ene-1,5-diol Chemical compound OCCC(C)C=CO BLCFRFQELNMPIZ-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
- FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 1
- OKKDHVXHNDLRQV-UHFFFAOYSA-N 6-[3-(6-isocyanatohexyl)-2,4-dioxo-1,3-diazetidin-1-yl]hexyl n-(6-isocyanatohexyl)carbamate Chemical compound O=C=NCCCCCCNC(=O)OCCCCCCN1C(=O)N(CCCCCCN=C=O)C1=O OKKDHVXHNDLRQV-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical compound N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 description 1
- GWGWXYUPRTXVSY-UHFFFAOYSA-N N=C=O.N=C=O.CC1=CC=C(C)C=C1 Chemical compound N=C=O.N=C=O.CC1=CC=C(C)C=C1 GWGWXYUPRTXVSY-UHFFFAOYSA-N 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- AQHHHDLHHXJYJD-UHFFFAOYSA-N propranolol Chemical compound C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/049—Protective back sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/322—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention is excellent in an adhesive coating agent excellent in adhesiveness between a solar cell sealing material and a substrate sheet, a polyol composition for the coating agent, a cured product of the adhesive coating agent, adhesive strength and heat-and-moisture resistance.
- the present invention relates to an adhesive sheet and a solar cell module using the sheet.
- the solar cell used for photovoltaic power generation is the heart of a photovoltaic power generation system that directly converts sunlight energy into electrical energy, and is composed of semiconductors such as silicon, and its structure is a photovoltaic cell. Are connected in series and in parallel, and various packaging is applied to form a unit to protect the cells.
- a unit incorporated in such a package is called a solar cell module.
- a light-receiving surface that is exposed to sunlight is covered with a surface protection member such as a glass plate, and a gap between the solar cell and the surface protection member is made of a thermoplastic resin. It has the structure which sealed and also arrange
- the material for sealing the solar cell and the surface protection member is highly transparent and moisture resistant.
- An excellent ethylene-vinyl acetate copolymer resin is often used, and the back protective sheet (back sheet) is a base sheet made of a polyester sheet such as polyethylene terephthalate resin, and an adhesive is applied to both sides thereof.
- the back protective sheet is a base sheet made of a polyester sheet such as polyethylene terephthalate resin, and an adhesive is applied to both sides thereof.
- a laminated sheet of fluorine resin sheets with excellent weather resistance such as polyvinyl fluoride, polyvinylidene fluoride, polytetrafluoroethylene, polychlorotrifluoroethylene, and metal foil such as aluminum foil. Those having water vapor barrier performance are widely used.
- the laminated sheet provided with the fluororesin sheet as described above is a back sheet having excellent weather resistance, but is expensive.
- the back sheet has a sufficient practical adhesive strength, the phenomenon that the adhesive strength with time at the interface between the fluororesin sheet and the base sheet decreases due to long-term use in a humid heat environment is inevitable. However, it has not been able to sufficiently cope with higher long-term reliability and durability required in recent years.
- productivity and manufacturing cost have to be increased.
- the back sheet using such an easy-adhesive agent cannot protect the solar cell from moisture or external factors when the base sheet of the back sheet is peeled off. Therefore, the easy adhesive layer is required to have a high degree of adhesion and durability. Therefore, it was necessary for the easy-adhesive to ensure adhesion to the solar cell sealing material and at the same time to ensure adhesion to a substrate sheet such as a PET sheet.
- an acrylic polymer having an acryloyl group and a hydroxyl group obtained by reacting acrylic acid with a hydroxy group-containing acrylic oligomer and a polyisocyanate component are essential components.
- a technique using a two-component adhesive is known (see Patent Document 1 below).
- Patent Document 1 Although the easy-adhesive described in Patent Document 1 expresses good adhesiveness, shrinkage is increased when the acryloyl group is crosslinked, and sufficient adhesion with a base sheet such as PET cannot be secured. Furthermore, the adhesive strength was lowered over time in a humid heat environment.
- the problem to be solved by the present invention is that an adhesive coating agent that exhibits excellent adhesive strength and heat-and-moisture resistance when the solar cell sealing material and the substrate sheet are bonded, and the polyol for the coating agent
- the object is to provide a composition, a cured product of the adhesive coating agent, an adhesive sheet obtained by applying the adhesive coating agent, and a solar cell module using the sheet.
- the present inventors have used a hydroxyl group-containing (meth) acrylic resin blended with an unsaturated double bond-containing polyester polyol as a main polyol component, and a polyisocyanate.
- a two-component curable adhesive coating agent that uses a compound as a curing agent, while maintaining good adhesion to a substrate sheet such as a PET sheet, exhibits excellent adhesion to a solar cell sealing material As a result, the present invention has been completed.
- the present invention comprises a polyol composition for a polyisocyanate-curable adhesive coating agent characterized by comprising a hydroxyl group-containing (meth) acrylic resin (I) and an unsaturated double bond-containing polyester polyol (II) as essential components.
- a polyol composition for a polyisocyanate-curable adhesive coating agent characterized by comprising a hydroxyl group-containing (meth) acrylic resin (I) and an unsaturated double bond-containing polyester polyol (II) as essential components.
- the present invention further relates to an adhesive coating agent comprising the polyol composition ( ⁇ ) and the polyisocyanate compound ( ⁇ ) as essential components.
- the present invention further relates to a cured product obtained by curing the adhesive coating agent.
- the present invention further relates to an adhesive sheet in which an adhesive layer is formed by applying and curing the adhesive coating agent on a polyester base sheet.
- the solar cell (A), the surface protective substrate (B), the solar cell sealing material (D), and the back sheet (E) are essential components
- the back sheet (E ) Has an essential layer configuration of a base sheet (a) and an adhesive layer (b) formed on the base sheet (a), which is a cured product of the adhesive coating agent according to claim 13.
- the back sheet (E) is disposed so that the adhesive layer (b) is in contact with the solar cell sealing material (D).
- an adhesive coating agent that exhibits excellent adhesion strength and heat-and-moisture resistance when the solar cell sealing material and the base sheet are adhered, the polyol composition for the coating agent, and the adhesive property A cured product of the coating agent, an adhesive sheet obtained by applying the adhesive coating agent, and a solar cell module using the sheet can be provided.
- FIG. 1 is a cross-sectional view of an example of the solar cell module of the present invention.
- polyol composition for a polyisocyanate-curable adhesive coating agent of the present invention (hereinafter simply abbreviated as “polyol composition”) is used as a main component of an adhesive coating agent constituting a back sheet of a solar cell module. It is.
- the polyisocyanate compound mentioned later is used as the hardening
- the adhesive coating agent is used not only for the back sheet of the solar cell module, but also as an adhesive coating agent when using a resin sheet as an alternative material for the surface protection glass of the solar cell module. it can.
- the hydroxyl group-containing (meth) acrylic resin (I) constituting the polyol composition of the present invention essentially comprises a hydroxyl group-containing (meth) acrylate (a) and another (meth) acrylic monomer (b).
- the component include those obtained by copolymerization.
- examples of the hydroxyl group-containing (meth) acrylate (a) include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, and polyethylene glycol mono (meth) acrylate. ) Acrylate, polypropylene glycol mono (meth) acrylate, and the like.
- the other (meth) acrylic monomer (b) is an alkyl group having 1 to 3 carbon atoms such as methyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate and the like.
- (meth) acrylic monomer (b) (meth) acrylate (b-2) esterified with an alkyl group having 4 to 16 carbon atoms is used as an essential monomer component. It is preferable from the viewpoint that adhesion to a substrate sheet such as PET is drastically improved, and adhesive strength and heat-and-moisture resistance are improved.
- (meth) acrylates (b-2) cyclohexyl (meth) acrylate, isobutyl (meth) acrylate, n-butyl (meth) acrylate, t-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate are particularly preferred.
- (meth) acrylate selected from the group consisting of lauryl (meth) acrylate is preferable from the point that the effect of improving the adhesiveness with the base material sheet becomes remarkable.
- the polarity of the adhesive coating agent itself is excellent in the adhesiveness to the base sheet depending on the composition ratio of each monomer component. It can be adjusted to the optimum range.
- the (meth) acrylate (b-1) esterified with an alkyl group having 3 to 20% by mass and having 1 to 3 carbon atoms is (a) 15 to 50% by mass and alkyl having 4 to 16 carbon atoms It is preferable to use (meth) acrylate (b-2) esterified with a group in a proportion of 30 to 76% by mass.
- (meth) acrylic acid (b-3) it is preferably used in a proportion of 0.1 to 5% by mass in the monomer component
- the hydroxyl group-containing acrylic resin (I) is an aromatic vinyl compound such as styrene and methylstyrene within a range not impairing the effects of the present invention in addition to the various monomers described above, for example, within a range of 3% by mass or less. May be used in combination as a raw material monomer.
- hydroxyl group-containing acrylic resin (I) used in the present invention examples include the hydroxyl group-containing (meth) acrylate (a) and other (meth) acrylic monomers (b), benzoyl peroxide, azobisisobutyronitrile.
- hydrocarbon solvents such as toluene, xylene, cyclohexane, n-hexane, and octane; methyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate.
- Ester solvents such as n-propyl acetate, amyl acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, ethoxyethyl propionate; ether solvents such as diethylene glycol dimethyl ether; acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc. It is preferable to carry out in an organic solvent such as a ketone solvent, or in a mixed solvent of two or more thereof.
- the hydroxyl group-containing acrylic resin (I) thus obtained preferably has a hydroxyl value in the range of 1 to 200 mgKOH / g from the viewpoint of adhesive strength and heat and humidity resistance, and has a number average molecular weight (Mn) of 5 In the range of 1,000,000 to 500,000, the adhesive strength and the heat-and-moisture resistance are also favorable.
- the unsaturated double bond-containing polyester resin (II) used in the polyol composition of the present invention comprises a polyol component (II-1), a dicarboxylic acid component (II-2), and, if necessary, a monocarboxylic acid component (II). -3) can be obtained, and by using a component having an unsaturated double bond in any of these components, an unsaturated double bond can be introduced into the resin structure. it can.
- unsaturated double bond-containing polyester resin (II) high adhesiveness and adhesion durability with the solar cell sealing material are expressed.
- polyester resin (II) is classified from the combination of raw material components, for example, (II-1-a) a polyhydric aliphatic alcohol having 2 to 9 carbon atoms, (II-2-a) polyester polyol (A) obtained by reacting saturated aliphatic dicarboxylic acid, aromatic dicarboxylic acid, or an acid anhydride thereof, and (II-3) vegetable oil fatty acid;
- polyhydric aliphatic alcohol (II-1-a) having 2 to 9 carbon atoms ethylene glycol, neopentyl glycol, diethylene glycol, tetramethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 2 3,4-trimethyl-1,3-pentanediol, 3-methylpentene-1,5-diol, 1,4-cyclohexanedimethanol and the like.
- dipropylene glycol is particularly preferred from the viewpoint that appropriate flexibility can be imparted to the coated film and the adhesive layer after coating.
- saturated aliphatic dicarboxylic acids, aromatic dicarboxylic acids, or acid anhydrides (II-2-a) thereof include benzoic acid, p-tert-butylbenzoic acid, isophthalic acid, phthalic anhydride, terephthalic acid, orthophthalic acid , 2,6-naphthalenedicarboxylic acid, azelaic acid, sebacic acid, isosebacic acid, oxalic acid, trimellitic acid, (anhydrous) succinic acid, (anhydrous) maleic acid, fumaric acid, (anhydrous) itaconic acid, tetrahydro (anhydrous)
- Examples include phthalic acid, hexahydro (anhydride) phthalic acid, hexahydroisophthalic acid, hexahydroterephthalic acid, glutaric acid, adipic acid, pimelic acid, 1,4-cyclohexanedicarboxylic acid, and the
- Examples of the unsaturated dicarboxylic acid or its anhydride (II-2-b) include fumaric acid, maleic acid, and acid anhydrides thereof.
- Examples of the vegetable oil fatty acid (II-3) include coconut oil fatty acid, sesame oil fatty acid, olive oil fatty acid, rapeseed oil fatty acid, soybean oil fatty acid, cacao oil fatty acid, coconut oil fatty acid and the like.
- the polyester polyol (C) obtained by reacting is preferable from the viewpoint of better adhesion to the solar cell sealing material.
- Such unsaturated double bond-containing polyester resin (II) has a double bond equivalent of 100 to 100. 0 g / eq. In the range of 200 to 800 g / eq. Those in the range are preferable from the viewpoint of good adhesion to the sealing material in the adhesive coating agent.
- the unsaturated double bond-containing polyester polyol (II) having a hydroxyl value in the range of 10 to 350 mgKOH / g provides an appropriate crosslink density after curing and further improved adhesive strength.
- the weight average molecular weight (Mw) is preferably in the range of 3000 to 20000 from the viewpoint of adhesive strength and wet heat resistance.
- the number average molecular weight (Mn) of the hydroxyl group-containing acrylic resin (I) and the weight average molecular weight (Mw) of the unsaturated double bond-containing polyester polyol (II) in the present invention are as follows. It is a value measured by the chromatography chromatography (GPC).
- Measuring device HLC-8220GPC manufactured by Tosoh Corporation Column: TSK-GUARDCOLUMN SuperHZ-L manufactured by Tosoh Corporation + Tosoh Corporation TSK-GEL SuperHZM-M ⁇ 4 Detector: RI (differential refractometer)
- Data processing Multi-station GPC-8020model II manufactured by Tosoh Corporation Measurement conditions: Column temperature 40 ° C Solvent Tetrahydrofuran Flow rate 0.35 ml / min Standard; Monodisperse polystyrene Sample; Filtered 0.2% by mass tetrahydrofuran solution in terms of resin solids with a microfilter (100 ⁇ l)
- the mixing ratio of the hydroxyl group-containing (meth) acrylic resin (I) and the unsaturated double bond-containing polyester polyol (II) described in detail above is, for example, a mass ratio [(I) / (II)] of 95/5 to A ratio of 50/50 is preferable from the viewpoint of good adhesion to a sealing material when used as an adhesive coating agent, strength of a cured coating film, and moisture and heat resistance.
- the polyol composition of the present invention further comprises a polyfunctional epoxy compound (III).
- a polyfunctional epoxy compound (III) when the adhesive layer absorbs moisture, the carboxy group generated by hydrolysis of the polyester polyol (A) can be captured by the epoxy group in the polyfunctional epoxy compound (III), and the heat and moisture resistance of the adhesive layer Can be further improved.
- Such polyfunctional epoxy compound (III) is preferably a hydroxyl group-containing epoxy compound having a molecular weight of 200 to 1,000. That is, when the molecular weight is 200 or more, in addition to the heat and moisture resistance, the adhesion strength to the substrate is further improved, and when it is 1,000 or less, the compatibility with the polyester polyol (II) is high. It will be good.
- the polyfunctional epoxy compound (III) preferably has a hydroxyl value in the range of 30 to 160 mgKOH / g, more preferably in the range of 50 to 150 mgKOH / g, since a resin composition with better curability can be obtained. More preferably.
- the polyfunctional epoxy compound (III) includes, for example, acyclic aliphatic poly (1,6-hexanediol diglycidyl luter, 1,4-butanediol diglycidyl ether, trimethylolpropane triglycidyl ether, diethylene glycol diglycidyl ether).
- Glycidyl ether cyclohexanedimethanol diglycidyl ether, 3 ′, 4′-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, ⁇ -caprolactone modified 3 ′, 4′-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxy
- Cycloaliphatic skeleton-containing epoxy compounds such as hydrogenated bisphenol A type epoxy resins; bisphenols such as bisphenol A type epoxy resins and bisphenol F type epoxy resins Le epoxy resins; biphenyl type epoxy resins such as tetramethyl biphenyl type epoxy resin; dicyclopentadiene - phenol addition reaction type epoxy resins.
- trimethylolpropane triglycidyl ether and bisphenol type epoxy resin are preferable in that a resin composition excellent in base material adhesion under wet heat conditions and initial adhesive strength can be obtained.
- the polyfunctional epoxy compound (III) is based on a total of 100 parts by mass of the hydroxyl group-containing (meth) acrylic resin (I) and the unsaturated double bond-containing polyester polyol (II) constituting the polyol composition of the present invention. It is preferable to blend at a ratio of 4.0 to 30.0 parts by mass from the viewpoint of heat and moisture resistance and blocking resistance.
- the polyol composition of the present invention further comprises a hydroxyl group-containing polycarbonate (IV).
- the crosslink density of the cured product can be dramatically improved, and the adhesive strength and heat-and-moisture resistance can be further improved.
- the hydroxyl group-containing polycarbonate (IV) used here has a number average molecular weight (Mn) in the range of 500 to 3,000.
- the hydroxyl group concentration is moderately high, the crosslinking density at the time of curing is improved, and the heat and heat resistance is increased. It is preferable from the viewpoint that the effect of improvement is remarkable, and in particular, a number average molecular weight (Mn) in the range of 800 to 2,000 is more preferable.
- the method for measuring the number average molecular weight (Mn) is a value measured under the same conditions as the GPC measurement conditions in the above-described novel polyester polyol.
- the hydroxyl group-containing polycarbonate (IV) has a hydroxyl value in the range of 20 to 300 mgKOH / g, more preferably in the range of 40 to 250 mgKOH / g, from the viewpoint that it becomes a resin composition with more excellent curability. . Moreover, it is preferable that it is polycarbonate diol at the point which is excellent in the base-material adhesiveness on wet heat conditions.
- the hydroxyl group-containing polycarbonate (IV) can be produced, for example, by a method of polycondensation reaction between a polyhydric alcohol and a carbonylating agent.
- Examples of the polyhydric alcohol used in the production of the hydroxyl group-containing polycarbonate (IV) include ethylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, , 8-nonanediol, linear alkanediols such as diethylene glycol; 1,2-propylene glycol, 1,3-butylene glycol, 2-methyl-1,3-propanediol, neopentyl glycol, 3-methyl-1, 5-pentanediol, 2-n-butyl-2-ethyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, 2, 4-diethyl-1,5-pentanediol, 1,2-hexane glycol, 1,2-octyl Alicycl
- Examples of the carbonylating agent used in the production of the hydroxyl group-containing polycarbonate (IV) include phosgene, ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, dibutyl carbonate, diphenyl carbonate and the like. These may be used alone or in combination of two or more.
- diols selected from 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, and 1,4-cyclohexanedimethanol and the carbonylating agent are particularly preferred from the viewpoint of compatibility. What is obtained by reaction with is preferable.
- the mixture ratio is 100 mass in total of the hydroxyl-containing (meth) acrylic resin (I) and unsaturated double bond containing polyester polyol (II) in the polyol composition of this invention.
- a ratio of 2.0 to 30.0 parts by mass with respect to parts is preferable from the viewpoint of providing a resinous coating agent capable of maintaining high substrate adhesion even under wet heat conditions.
- the polyol composition of the present invention comprises the hydroxyl group-containing (meth) acrylic resin (I), the unsaturated double bond-containing polyester polyol (II), the polyfunctional epoxy compound (III), and the hydroxyl group-containing polycarbonate (IV).
- Other hydroxyl group-containing compound (V) may be contained.
- Such hydroxyl group-containing compounds include, for example, polyester polyols obtained by reacting polybasic acids with polyhydric alcohols, polyester polyurethane polyols obtained by reacting polybasic acids, polyhydric alcohols and polyisocyanates, dibasic acids , Linear polyester polyurethane polyols obtained by reacting diols and diisocyanates, ether glycols such as polyoxyethylene glycol and polyoxypropylene glycol, bisphenols such as bisphenol A and bisphenol F, ethylene oxide and propylene oxide in the bisphenol And the like, and the like. These may be used alone or in combination of two or more.
- the hydroxyl group-containing compound (V) is an effect in the adhesive coating agent of the present invention, in a range that does not impair the adhesion to the base sheet and wet heat conditions, specifically, in the polyol composition of the present invention, 20 It can be used in the range of not more than mass%.
- the polyol composition described above may further contain various organic solvents.
- the organic solvent may be contained in such a form that the solvent used in the synthesis of each resin component constituting the polyol composition remains as it is in the polyol composition.
- organic solvents include ketone compounds such as acetone, methyl ethyl ketone (MEK) and methyl isobutyl ketone, cyclic ether compounds such as tetrahydrofuran (THF) and dioxolane, methyl acetate, ethyl acetate, and n-butyl acetate.
- Examples include ester compounds, aromatic compounds such as toluene and xylene. These may be used alone or in combination of two or more.
- the solid content concentration of the polyol composition and the solid content concentration of the adhesive coating agent can be appropriately adjusted.
- the amount of the organic solvent is not particularly limited.
- the polyol composition as the main agent a hydroxyl group-containing (meth) acrylic resin (I), an unsaturated double bond-containing polyester polyol (II), etc.
- the polyol component has a solid content concentration of 40 to 70% by mass in terms of adjustment of the adhesive coating agent and subsequent workability of coating.
- polyol composition ( ⁇ ) a polyol component of the adhesive coating agent of the present invention
- polyol composition ( ⁇ ) a polyol component of the adhesive coating agent of the present invention
- a polyol composition ( ⁇ ) a polyol component of the adhesive coating agent of the present invention
- a polyisocyanate compound ( ⁇ ) can be used as a curing agent for the adhesive coating agent.
- polyisocyanate compound ( ⁇ ) used here examples include aliphatic polyisocyanates and aromatic polyisocyanates.
- aliphatic polyisocyanate examples include aliphatic diisocyanates such as 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,8-octamethylene diisocyanate, and L-lysine diisocyanate, or alicyclic systems.
- aliphatic diisocyanates such as 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,8-octamethylene diisocyanate, and L-lysine diisocyanate, or alicyclic systems.
- a polyisocyanate is mentioned.
- alicyclic polyisocyanate examples include alicyclic diisocyanates such as hydrogenated 4,4'-diphenylmethane diisocyanate (hydrogenated MDI), isophorone diisocyanate, norbornene diisocyanate, and the like.
- aromatic polyisocyanate examples include 4,4′-diphenylmethane diisocyanate (MDI), 4,4′-biphenyl diisocyanate tridenic diisocyanate, 1,3-xylylene diisocyanate, 1,4-xylene diisocyanate, p- Aromatic diisocyanates such as tetramethylxylene diisocyanate, m-tetramethylxylene diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 1,5-naphthalene diisocyanate, m-phenylene diisocyanate, p-phenylene diisocyanate Etc.
- MDI 4,4′-diphenylmethane diisocyanate
- 4′-biphenyl diisocyanate tridenic diisocyanate 1,3-xylylene diisocyanate
- 1,4-xylene diisocyanate 1,4-xy
- polyisocyanate having three or more functional groups examples include, for example, triphenylmethane triisocyanate, 1,6,11-undecane triisocyanate, 4,4 ′, 4 ′′ -triphenylmethane triisocyanate, 2,4,4′-biphenyl triisocyanate, 2,4,4′-diphenylmethane triisocyanate, polymethylene phenyl isocyanate and the like.
- Further examples include isocyanurate type polyisocyanates, adduct type polyisocyanates, burette type polyisocyanates, and uretdione type polyisocyanates obtained by using the above polyisocyanate compounds.
- non-yellowing polyisocyanates such as aliphatic diisocyanates and alicyclic diisocyanates, and the nurate polyisocyanates, burette polyisocyanates, and uretdione polyisocyanates can provide a coating film with excellent appearance.
- non-yellowing polyisocyanates such as aliphatic diisocyanates and alicyclic diisocyanates
- the nurate polyisocyanates, burette polyisocyanates, and uretdione polyisocyanates can provide a coating film with excellent appearance.
- aliphatic diisocyanate nurate type polyisocyanate, aliphatic diisocyanate burette type polyisocyanate, and aliphatic diisocyanate uretdione type polyisocyanate are particularly preferable.
- the blending ratio of the polyol composition ( ⁇ ) and the polyisocyanate compound ( ⁇ ) detailed above is equivalent to the isocyanate group in the polyisocyanate compound ( ⁇ ) with respect to the hydroxyl group in the polyol composition ( ⁇ ).
- the ratio [NCO / OH] is preferably in the range of 0.25 to 3.00 from the viewpoints of adhesion to the sealing material, strength of the cured coating film, and heat and humidity resistance.
- the hydroxyl group in the polyol composition ( ⁇ ) is not only the hydroxyl group in the hydroxyl group-containing (meth) acrylic resin (I) and the unsaturated double bond-containing polyester polyol (II), but also a polyfunctional epoxy described later.
- the compound (III), the hydroxyl group in the hydroxyl group-containing polycarbonate (IV) and the other hydroxyl group-containing compound (V) are further included, the hydroxyl group in the compound is also meant.
- the adhesive coating agent of the present invention may further contain various organic solvents.
- the solvent include ketone compounds such as acetone, methyl ethyl ketone (MEK) and methyl isobutyl ketone, cyclic ether compounds such as tetrahydrofuran (THF) and dioxolane, and esters such as methyl acetate, ethyl acetate and n-butyl acetate.
- aromatic compounds such as toluene and xylene. These may be used alone or in combination of two or more.
- the fluidity of the adhesive coating agent is appropriately optimized according to the requirements of the coating apparatus.
- the organic solvent is preferably blended.
- various inorganic pigments, organic pigments, or carbon black, fillers, ultraviolet absorbers, antioxidants and / or A light stabilizer or the like can be contained.
- These various blending materials preferably form a premix previously blended with the polyol composition ( ⁇ ) or the polyisocyanate compound ( ⁇ ), but from the viewpoint of workability, the polyol composition ( ⁇ ). It is preferable to blend in.
- titanium dioxide as the inorganic pigment from the viewpoint that the surface of the solar battery cell back sheet is white, and sunlight is reflected to increase the power generation efficiency of the solar battery cell. Further, when emphasizing the design property, it is preferable to blend carbon black.
- titanium dioxide those having an average particle diameter in the range of 0.1 to 1.5 ⁇ m are preferable. Titanium dioxide having an average particle size of 1.5 ⁇ m or less is preferable because the surface smoothness of the cured coating film is good.
- Titanium dioxide with an average particle size of 0.1 to 1.5 ⁇ m takes into consideration the toughness of the cured coating itself and the adhesion that can follow the flexibility of the substrate to be coated, depending on the desired level of weather resistance
- it may be added to the main agent and / or the curing agent, but is preferably 25 to 900 parts by weight per 100 parts by weight in total in terms of non-volatile content of all curable components in view of excellent weather resistance.
- the filler can be used as an antiblocking agent, and specific examples include silica having an average particle diameter of 1 to 20 ⁇ m, resin beads, and the like.
- the amount of the filler used is in the range of 0.1 to 10.0 parts by weight per 100 parts by weight in terms of the nonvolatile content of all curable components, and can impart blocking resistance without deteriorating the adhesive performance. It is preferable from the point.
- the adhesive coating agent of the present invention is applied to the base material for the back sheet that protects the solar battery cells of the solar battery module, thereby expressing good easy-adhesion performance and excellent adhesive strength. And resistance to moist heat.
- the adhesive coating composition of the present invention is applied not only to the back sheet, but also to the base sheet of the sheet when using a transparent resin sheet that replaces the solar cell surface protecting glass plate, It is also possible to develop easy adhesion performance to the solar cell sealing material.
- the amount of the adhesive coating agent of the present invention applied to the base sheet is not particularly limited, but is, for example, in the range of 1 to 20 g / m 2 , especially 3 to 10 g / m 2. However, it is preferable at the point which can provide the outstanding weather resistance with a small quantity.
- a gravure coater, a micro gravure coater, a reverse coater, a bar coater, a roll coater, a die coater or the like can be used.
- the adhesive coating agent of the present invention expresses good adhesion performance to the base sheet, but if necessary, the base sheet such as a polyester resin film is cured for the purpose of imparting further adhesive strength.
- Surface treatment may be performed on the surface on which the coating film is formed. Examples of the surface treatment include corona treatment, plasma treatment, ozone treatment, flame treatment, and radiation treatment.
- the base sheet for the solar battery back sheet used here is a polyester resin sheet such as a polyethylene terephthalate sheet, a polybutylene terephthalate sheet or a polynaphthalene terephthalate; a polyolefin sheet such as a polyethylene sheet, a polypropylene sheet or a polycyclopentadiene sheet; Vinyl fluoride sheet, polyvinylidene fluoride sheet, polytetrafluoroethylene sheet, tetrafluoroethylene-6 fluoropropylene copolymer (FEP) sheet, ethylene-4 fluoroethylene copolymer (ETFE) sheet ethylene-tetrafluoroethylene Fluorine resin sheets such as copolymer sheets; Acrylic resin sheets such as polyacrylonitrile and polymethyl methacrylate; Polyester resins from the viewpoint of film rigidity and cost It is preferably over bets, particularly preferably polyethylene terephthalate sheet.
- a polyester resin sheet such as a polyethylene terephthalate sheet,
- the thickness of the above-described base sheet for backsheet is not particularly limited and is preferably in the range of 10 to 400 ⁇ m, for example. It is preferable that the thickness is in the range of 80 to 300 ⁇ m because drying can be performed for a long time to provide excellent adhesion without imparting any influence on the substrate such as warping or settling, and to provide excellent weather resistance.
- Such a base sheet for a solar battery back sheet may be composed of only one layer, or may have a multilayer structure of two or more layers. Furthermore, a vapor deposition film or the like on which a metal oxide or a nonmetal inorganic oxide is vapor-deposited may be laminated.
- the metal oxide or non-metal inorganic oxide to be deposited for example, oxides such as silicon, aluminum, magnesium, calcium, potassium, tin, sodium, boron, titanium, lead, zirconium, yttrium can be used. .
- Alkali metal and alkaline earth metal fluorides can also be used, and these can be used alone or in combination, such as physical vapor deposition methods such as vacuum vapor deposition and ion plating, and chemical vapor deposition methods such as plasma CVD. The thing vapor-deposited using is mentioned.
- the solar cell backsheet of the present invention may have a barrier property in which a film layer or a coating layer such as a metal foil or a weather resistant resin layer is disposed between a plurality of base material sheets. Good.
- examples of the metal foil include thin films of aluminum, aluminum oxide, silicon oxide, tin oxide, magnesium oxide, and the like.
- aluminum foil is preferable from the viewpoint of corrosion resistance.
- the thickness is preferably 10 ⁇ m to 100 ⁇ m, more preferably 20 ⁇ m to 50 ⁇ m.
- Various conventionally known adhesives can be used for laminating the metal foil.
- the weather-resistant resin layer may be a laminate of polyester resin films such as polyvinylidene fluoride film, polyethylene terephthalate, polybutylene terephthalate, polynaphthalene terephthalate, etc., using various known adhesives, or Lumiflon from Asahi Glass Co., Ltd. Examples thereof include a coating layer formed by applying a highly weather-resistant paint such as
- the base sheet is laminated with a deposited film in which a metal oxide or a non-metallic inorganic oxide is deposited, or a film layer such as a metal foil or a weather-resistant resin layer between a plurality of base sheets.
- the coating layer may be provided, the present invention can exhibit excellent adhesive strength and heat-and-moisture resistance only by applying an adhesive coating agent to the base sheet. It is preferable to use a base sheet composed of only layers. By using such a base sheet composed of only one layer, a sheet can be produced with high productivity while ensuring sufficient performance as a back sheet.
- the surface protecting resin sheet that can be used is a polyethylene terephthalate sheet, polybutylene as in the case of the back sheet.
- Polyester resin sheet such as terephthalate sheet and polynaphthalene terephthalate
- polyolefin sheet such as polyethylene sheet, polypropylene sheet and polycyclopentadiene sheet
- polyvinyl fluoride sheet such as polyethylene sheet, polypropylene sheet and polycyclopentadiene sheet
- polyvinyl fluoride sheet such as polyethylene sheet, polypropylene sheet and polycyclopentadiene sheet
- polyvinyl fluoride sheet polyvinylidene fluoride sheet
- polytetrafluoroethylene sheet tetrafluoroethylene-6
- Fluorine resin sheet such as fluorinated propylene copolymer (FEP) sheet, ethylene-4 fluorinated ethylene copolymer (ETFE) sheet, ethylene-tetrafluoroethylene copolymer sheet
- Lil acrylic resin sheet
- a fluororesin sheet, a polyester resin sheet, an acrylic resin sheet, and polycarbonate are preferable from the viewpoint of transparency.
- a fluororesin sheet, an acrylic resin sheet, and a polycarbonate are preferable from the viewpoint of weather resistance, and a polyester resin sheet is preferable because it is an inexpensive material and is advantageous in terms of cost.
- the adhesive sheet of the present invention can be obtained by applying the above-described adhesive coating agent of the present invention on the back sheet base sheet or the surface protecting base sheet detailed above and curing it. .
- the curing reaction can be performed, for example, at 25 ° C. to 60 ° C. for 1 day to 5 days.
- FIG. 1 is a cross-sectional view of the module.
- the battery cell encapsulant (D) and the back sheet (E) are essential components, and the back sheet (E) is formed on the base sheet (a) and the base sheet (a).
- the adhesive layer (b), which is a cured product of the adhesive coating agent of the present invention, has an essential layer structure, and the adhesive layer (b) is in contact with the solar cell sealing material (D).
- the one in which the back sheet (E) is disposed can be mentioned.
- the surface protective substrate (B) is formed of a resin sheet and a cured layer of the adhesive coating agent of the present invention formed on the resin sheet.
- positioned so that a stop material (D) may be touched may be sufficient.
- examples of the battery surface protective material (B) include a glass plate, a plastic plate of polycarbonate or polyacrylate, and the like as described above.
- a glass plate is preferable.
- white glass with high transparency is preferable among the glass plates.
- ethylene vinyl acetate resin can be used for the sealing agent (D) used for the solar cell module of the present invention.
- a sealing material (D) preferably contains an organic peroxide in the sealing agent (D) because the crosslinking reaction of the adhesive coating agent is promoted.
- the solar cell (A) for example, a single crystal silicon solar cell element, a polycrystalline silicon solar cell element, a single junction type, an amorphous silicon type solar cell element constituted by a tandem structure type, gallium, etc.
- III-V compound semiconductor solar cell elements such as arsenic (GaAs) and indium phosphorus (InP), II-VI compound semiconductor solar cell elements such as cadmium tellurium (CdTe), copper / indium / selenium system (CIS system), Copper / indium / gallium / selenium-based (CIGS-based), copper / indium / gallium / selenium / sulfur-based (CIGS-based)
- I-III-VI group compound semiconductor solar cell elements, dye-sensitized solar cell elements, organic A solar cell element etc. are mentioned.
- the method for producing such a solar cell module is, for example, an ethylene vinyl acetate resin (EVA) sheet serving as a sealing material, a plurality of solar cells (A), an ethylene vinyl acetate resin on the battery surface protective material (B). (EVA) sheet, the back sheet (E) of the present invention is disposed, heated while evacuating, and the two EVA sheets are dissolved to seal the solar cell element. At this time, the plurality of solar cell elements are joined in series by the interconnector (C).
- EVA ethylene vinyl acetate resin
- the number average molecular weight (Mn) and the weight average molecular weight (Mw) were measured by gel permeation chromatography (GPC) under the following conditions.
- Measuring device HLC-8220GPC manufactured by Tosoh Corporation Column: TSK-GUARDCOLUMN SuperHZ-L manufactured by Tosoh Corporation + Tosoh Corporation TSK-GEL SuperHZM-M ⁇ 4 Detector: RI (differential refractometer)
- Data processing Multi-station GPC-8020model II manufactured by Tosoh Corporation Measurement conditions: Column temperature 40 ° C Solvent Tetrahydrofuran Flow rate 0.35 ml / min Standard; Monodisperse polystyrene Sample; Filtered 0.2% by mass tetrahydrofuran solution in terms of resin solids with a microfilter (100 ⁇ l)
- Table 1 shows property values of the obtained acrylic resin (4).
- Examples 1 to 18 and Comparative Examples 1 to 8 The main ingredient components were prepared according to the formulations shown in Tables 3 to 7 below. Thereafter, a curing agent was blended in the main agent (further a catalyst was blended in Comparative Examples 5 to 8), and the solid content concentration was adjusted to 30% by mass with ethyl acetate to obtain an adhesive coating agent. (The blending amounts in Tables 3 to 7 are solid content conversion values.)
- N-3300 isocyanurate of 1,6-hexamethylene diisocyanate (“Sumidur N-3300” isocyanate group (NCO) content 21.8% by mass, viscosity 2500 mPa ⁇ s / 25 ° C., manufactured by Sumika Bayer Urethane Co., Ltd.)
- N-3200 Burette body of 1,6-hexamethylene diisocyanate (“Desmodur N-3200” manufactured by Sumika Bayer Urethane Co., Ltd., isocyanate group (NCO) content 23.0 mass%, viscosity 2100 mPa ⁇ s / 25 ° C.)
- N-3400 Uretodione form of 1,6-hexamethylene diisocyanate (“Desmodur N-3400” isocyanate group (NCO) content 21.8% by mass, viscosity 175 mPa ⁇ s / 25 ° C., manufactured by Sumika Bayer Urethane Co., Ltd
- 860-80SE Bisphenol A type epoxy resin (“Epiclon 860-80SE” manufactured by DIC Corporation, epoxy equivalent 250 g / eq. Ethyl acetate cut product, solid content 80% by mass)
- JER828 bisphenol A type epoxy resin (“JER828” epoxy equivalent 190 g / eq.
- JR-403 Titanium oxide (Taika "JR-403"
- M-215 EO-modified diacrylate of isocyanuric acid (“Aronix M-215” manufactured by Toa Gosei Co., Ltd.)
- Polyisocyanate compound * 1 Isocyanurate of hexamethylene diisocyanate blocked with 3,5-dimethylpyrazole (solid content 75% by weight ethyl acetate solution)
- the adhesive coating agent obtained in each Example and Comparative Example was applied to a polyethylene terephthalate film (“DS-10” manufactured by Toho Sichuan) so that the coating amount after drying was 3 to 4 g / m 2. After drying at 120 ° C. for 30 seconds to form an adhesive layer, aging was performed at 40 ° C. for 3 days to obtain an adhesive laminated film having an easy-adhesion layer.
- DS-10 polyethylene terephthalate film manufactured by Toho Sichuan
- the obtained adhesive laminated film was cut into a width of 80 mm and a length of 200 mm to obtain an evaluation adhesive laminated film.
- PCT pressure cooker test
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Photovoltaic Devices (AREA)
- Adhesive Tapes (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
(II-1-a)炭素原子数2~9の多価脂肪族アルコール、
(II-2-a)飽和脂肪族ジカルボン酸、芳香族ジカルボン酸、又はこれらの酸無水物、及び
(II-3)植物油脂肪酸
を反応させて得られるポリエステルポリオール(A);
(II-2-b)不飽和ジカルボン酸又はその無水物、
を反応させて得られるポリエステルポリオール(B);
(II-2-b)不飽和ジカルボン酸又はその無水物、及び
(II-3)植物油脂肪酸
を反応させて得られるポリエステルポリオール(C);
(II-1-b)ひまし油、
(II-2-a)飽和脂肪族ジカルボン酸、芳香族ジカルボン酸、又はこれらの酸無水物及び
を反応させて得られるポリエステルポリオール(D)
が挙げられる。
0g/eq.の範囲にあるもの、とりわけ200~800g/eq.の範囲にあるものが、接着性コーティング剤における封止材との接着性が良好なものとなる点から好ましい。
カラム ;東ソー株式会社製 TSK-GUARDCOLUMN SuperHZ-L
+東ソー株式会社製 TSK-GEL SuperHZM-M×4
検出器 ;RI(示差屈折計)
データ処理;東ソー株式会社製 マルチステーションGPC-8020modelII
測定条件 ;カラム温度 40℃
溶媒 テトラヒドロフラン
流速 0.35ml/分
標準 ;単分散ポリスチレン
試料 ;樹脂固形分換算で0.2質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(100μl)
エチレン‐テトラフルオロエチレン共重合体シートなどのフッ素樹脂シート;ポリアクリルニトリル、ポリメチルメタクリレート等のアクリル系樹脂シート;フィルム剛性、コストの観点からポリエステル系樹脂シートであることが好ましく、特にポリエチレンテレフタレートシートであることが好ましい。
カラム ;東ソー株式会社製 TSK-GUARDCOLUMN SuperHZ-L
+東ソー株式会社製 TSK-GEL SuperHZM-M×4
検出器 ;RI(示差屈折計)
データ処理;東ソー株式会社製 マルチステーションGPC-8020modelII
測定条件 ;カラム温度 40℃
溶媒 テトラヒドロフラン
流速 0.35ml/分
標準 ;単分散ポリスチレン
試料 ;樹脂固形分換算で0.2質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(100μl)
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、キシレンの50質量部と、酢酸n-ブチルの16質量部を仕込んで、攪拌を開始し、窒素雰囲気中で115℃にまで昇温した。同温度に達した処で、メチルメタクリレート44.0質量部、イソブチルメタクリレート40.0質量部、2-ヒドロキシエチルメタクリレート15.0質量部、メタクリル酸1.0質量部の混合物と、パーブチルO(日油株式会社製、t-ブチルペルオキシ-2-エチルヘキサノエート)の0.8質量部を15質量部のキシレンに希釈したものを、同時に、5時間かけて滴下した。その後も、同温度で、反応を続け、滴下終了1時間後にキシレンの42質量部と、酢酸ノルマルブチルの10質量部、パーヘキサC(日油株式会社製、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン)の0.1質量部を投入した。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、トルエンの46質量部を仕込んで、攪拌を開始し、窒素雰囲気中で105℃にまで昇温した。同温度に達した処で、メチルメタクリレート20.0質量部、イソブチルアクリレート5.0質量部、シクロヘキシルメタクリレート69.5質量部、2-ヒドロキシエチルメタクリレート5.0質量部、メタクリル酸0.5質量部の混合物と、パーブチルO(日油株式会社製、t-ブチルペルオキシ-2-エチルヘキサノエート)の0.5質量部と、パーブチルZ(日油株式会社製、t-ブチルパーオキシベンゾエート)の0.5質量部を20質量部のトルエンに希釈したものを、同時に、4時間かけて滴下した。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、メチルメタクリレート18.0質量部、n-ブチルメタクリレート78.0質量部、2-ヒドロキシエチルメタクリレート2.0質量部、グリシジルメタクリレート2.0質量部、トルエン100質量部を仕込み、攪拌しながら100℃まで昇温し、アゾビスイソブチロニトリル0.15質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部を加えて2時間反応させた。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、メチルメタクリレート18.0質量部、n-ブチルメタクリレート80.0質量部、2-ヒドロキシエチルメタクリレート2.0質量部、トルエン100質量部を仕込み、攪拌しながら100℃まで昇温し、アゾビスイソブチロニトリル0.15質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部を加えて2時間反応させた。その後、室温にまで冷却して、不揮発分50質量%のアクリル樹脂(4)の有機溶剤溶液を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン17質量部、ジプロピレングリコール42質量部、フマル酸35質量部、ヤシ油脂肪酸6質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が12,000、ガードナー粘度U-V、固形分の水酸基価が220mgKOH/g、二重結合当量300g/eq.のポリエステルポリオール(A1)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、エチレングリコール8質量部、ペンタエリスリトール12質量部、無水フタル酸40質量部、ひまし油40質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が16,000、ガードナー粘度U-V、固形分の水酸基価が120mgKOH/g、二重結合当量700g/eq.のポリエステルポリオール(2)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン40質量部、ネオペンチルグリコール16質量部、無水フタル酸25質量部、フマル酸19質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、
重量平均分子量(Mw)が4,700、ガードナー粘度U-V、固形分の水酸基価が270mgKOH/g、二重結合当量550g/eq.のポリエステルポリオール(3)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン15質量部、1,3-ブタンジオール32質量部、無水フタル酸9質量部、アジピン酸45質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が12,000、ガードナー粘度U-V、固形分の水酸基価が170mgKOH/gのポリエステルポリオール(4)を得た。
下記の表3~表7に示す配合に従い、主剤成分を調整した。その後、主剤に硬化剤を配合し(比較例5~8では更に触媒を配合)、酢酸エチルで固形分濃度30質量%に調整し接着性コーティング剤を得た。(表3~表7の配合量は、固形分換算値。)。
N-3300:1,6-ヘキサメチレンジイソシアネートのイソシアヌレート体(住化バイエルウレタン社製「スミジュールN-3300」イソシアネート基(NCO)含有量21.8質量%、粘度2500mPa・s/25℃))
N-3200:1,6-ヘキサメチレンジイソシアネートのビュレット体(住化バイエルウレタン社製「デスモジュールN-3200」イソシアネート基(NCO)含有量23.0質量%、粘度2100mPa・s/25℃)
N-3400:1,6-ヘキサメチレンジイソシアネートのウレトジオン体(住化バイエルウレタン社製「デスモジュールN-3400」イソシアネート基(NCO)含有量21.8質量%、粘度175mPa・s/25℃))
TSE-100:1,6-ヘキサメチレンジイソシアネートのイソシアヌレート体(旭化成(株)製「デュラネートTSE-100」、イソシアネート基(NCO)含有量12.1質量%、粘度1650mPa・s/25℃)
T5651:ポリカーボネートジオール(旭化成ケミカルズ社製「デュラノール」、1,5-ペンタンジオールと1,6-ヘキサンジオールから得られるポリカーボネート樹脂、数平均分子量1,000、水酸基価100~120mgKOH/g)
UM-90:ポリカーボネートジオール(宇部興産(株)製「エタナコール」、数平均分子量:約900、1,6-ヘキサンジオールと炭酸エステルとを反応させて得られるポリカーボネートジオール、及び、1,4-シクロヘキサンジメタノールと炭酸エステルとを反応させて得られるポリカーボネートジオールの質量比が1:3の混合物)
EX-321:トリメチロールプロパンのジグリシジルエーテルとトリグリシジルエーテルの混合物(ナガセケムテックス(株)製「デナコール EX-321」エポキシ当量140g/eq.)
860-80SE:ビスフェノールA型エポキシ樹脂(DIC(株)製「エピクロン860-80SE」エポキシ当量250g/eq.酢酸エチルカット品、固形分80質量%)
JER828:ビスフェノールA型エポキシ樹脂(三菱化学株式会社製「JER828」エポキシ当量190g/eq.)
JR-403:酸化チタン(テイカ製「JR-403」)
M-215:イソシアヌル酸EO変性ジアクリレート(東亜合成社製「アロニックスM-215」
ポリイソシアネート化合物*1:3,5-ジメチルピラゾールでブロックされたヘキサメチレンジイソシアネートのイソシアヌレート体(固形分75質量%酢酸エチル溶液)
評価用積層体を、引張試験機( (株)エー・アンド・ディー製)の上下のクリップに未接着部分を挟み、クロスヘッド速度100mm/分で180度剥離試験を行った。得られた測定値に対して、以下のように評価した。
○:30N/10mm以上~50N/10mm未満
△:10N/10mm以上~30N/10mm未満
×:10N/10mm未満
[耐湿熱性評価方法]
前記接着力評価用積層体をプレッシャークッカーテスト(PCT)に24、48時間かけ(試験条件:121℃で、相対湿度が100%)、前記と同じ条件で、耐湿熱試験後の剥離強度を測定した。
B:表面保護基材
C:インターコネクタ
D:封止材
E:バックシート
F:端子
a:基材シート
b:接着性コーティング剤の硬化物である接着層
Claims (17)
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)を必須成分とすることを特徴とするポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基含有(メタ)アクリレート(a)と、その他の(メタ)アクリル単量体(b)とを必須成分として共重合して得られるものである請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基含有(メタ)アクリレート(a)、前記炭素原子数が1~3のアルキル基でエステル化された(メタ)アクリレート(b-1)、前記炭素原子数4~16のアルキル基でエステル化された(メタ)アクリレート(b-2)を必須の単量体成分として用い、水酸基含有(メタ)アクリル樹脂(I)を構成する単量体成分中、水酸基含有(メタ)アクリレート(a)を3~20質量%、炭素原子数が1~3のアルキル基でエステル化された(メタ)アクリレート(b-1)を、15~50質量%、炭素原子数4~16のアルキル基でエステル化された(メタ)アクリレート(b-2)を30~76質量%、となる割合で共重合してなるものである請求項2記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基価1~200mgKOH/gの範囲にあるものである請求項3記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記不飽和二重結合含有ポリエステルポリオール(II)が、二重結合当量100~1000g/eq.のものである請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記不飽和二重結合含有ポリエステルポリオール(II)が、水酸基価10~350mgKOH/gの範囲にあるものである請求項5記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)、質量比[(I)/(II)]が95/5~50/50となる割合である請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)に加え、更にエポキシ樹脂(III)を有する請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記エポキシ樹脂(III)の配合割合が、ポリオール組成物の必須成分である水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)の合計100質量部に対して、4.0~30.0質量部となる割合で配合する請求項8記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、不飽和二重結合含有ポリエステルポリオール(II)、更に水酸基含有ポリカーボネート(IV)を有する請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有ポリカーボネート(IV)の配合割合が、ポリオール組成物の必須成分である水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)の合計100質量部に対して、2.0~30.0質量部となる割合で配合する請求項10記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)に加え、更に二酸化チタンを配合してなる請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 請求項1~12の何れか一つに記載のポリオール組成物(α)と、ポリイソシアネート化合物(β)を必須成分とすることを特徴とする接着性コーティング剤。
- 前記ポリオール組成物(α)と、ポリイソシアネート化合物(β)との配合割合が、該ポリオール組成物(α)中の水酸基に対する前記ポリイソシアネート化合物(β)中のイソシアネート基との当量比[NCO/OH]が0.25~3.00となる割合である請求項12記載の接着性コーティング剤。
- 請求項13記載の接着性コーティング剤を硬化させてなる硬化物。
- ポリエステル基材シート上に、請求項13記載の接着性コーティング剤を塗布、硬化させて接着層を形成した接着性シート。
- 太陽電池セル(A)、表面保護基材(B)、太陽電池セル用封止材(D)、及びバックシート(E)を必須の構成要素とし、該バックシート(E)が、基材シート(a)と該基材シート(a)上に形成された請求項13記載の接着性コーティング剤の硬化物である接着層(b)とを必須の層構成とするものであり、かつ、前記接着層(b)が太陽電池セル用封止材(D)に接する様に、前記バックシート(E)が配設されていることを特徴とする太陽電池モジュール。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201680003475.3A CN107109168A (zh) | 2015-03-13 | 2016-02-25 | 多元醇组合物、粘接性涂布剂、其固化物、粘接性片、及太阳能电池组件 |
EP16764660.3A EP3181649B1 (en) | 2015-03-13 | 2016-02-25 | Polyol composition, adhesive coating material, cured object obtained therefrom, adhesive sheet, and solar cell module |
JP2016550294A JP6057041B1 (ja) | 2015-03-13 | 2016-02-25 | ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール |
US15/522,450 US20170327720A1 (en) | 2015-03-13 | 2016-02-25 | Polyol composition, adhesive coating material, cured object obtained therefrom, adhesive sheet, and solar cell module |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015-050771 | 2015-03-13 | ||
JP2015050771 | 2015-03-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016147830A1 true WO2016147830A1 (ja) | 2016-09-22 |
Family
ID=56919001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2016/055595 WO2016147830A1 (ja) | 2015-03-13 | 2016-02-25 | ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール |
Country Status (6)
Country | Link |
---|---|
US (1) | US20170327720A1 (ja) |
EP (1) | EP3181649B1 (ja) |
JP (1) | JP6057041B1 (ja) |
CN (1) | CN107109168A (ja) |
TW (1) | TWI634181B (ja) |
WO (1) | WO2016147830A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017179081A (ja) * | 2016-03-29 | 2017-10-05 | 三菱ケミカル株式会社 | 硬化性組成物、硬化物及び積層体 |
WO2019093219A1 (ja) * | 2017-11-07 | 2019-05-16 | Dic株式会社 | 熱硬化型ウレタン樹脂組成物、フィルム及び物品 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2545433B (en) * | 2015-12-15 | 2017-12-20 | Grafmarine | Power generation and cell storage apparatus |
CN107746688B (zh) * | 2017-11-03 | 2019-11-05 | 通威太阳能(安徽)有限公司 | 一种聚酯型聚氨酯太阳能背板胶及其制备方法 |
CN109337634B (zh) * | 2018-09-26 | 2021-04-27 | 上海维凯光电新材料有限公司 | 用于铝塑复合标签的高耐水解抗粘背胶黏剂及其制备 |
CN111548763B (zh) * | 2020-06-24 | 2022-04-26 | 广州布鲁奥申新材料科技有限公司 | 一种高强度高耐候性双组份聚氨酯结构胶及其制备方法 |
MX2023000794A (es) * | 2020-07-30 | 2023-02-27 | Dow Global Technologies Llc | Metodo para empaquetar dispositivos de bateria. |
CN112794991B (zh) * | 2021-02-01 | 2023-01-06 | 南宁珀源能源材料有限公司 | 一种丙烯酸改性聚硫醇固化剂及其制备方法 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04255782A (ja) * | 1991-02-07 | 1992-09-10 | Toyo Ink Mfg Co Ltd | 硬化性粘着剤組成物 |
WO2007066827A1 (ja) * | 2005-12-09 | 2007-06-14 | Kansai Paint Co., Ltd. | 水性プライマー塗料組成物 |
WO2007108314A1 (ja) * | 2006-03-17 | 2007-09-27 | Kimoto Co., Ltd. | ポリエステル系フィルム用バインダー組成物及びこれを用いた光学フィルム |
JP2009179710A (ja) * | 2008-01-30 | 2009-08-13 | Yokohama Rubber Co Ltd:The | エンジニアリングプラスチック用プライマー組成物 |
WO2011034070A1 (ja) * | 2009-09-17 | 2011-03-24 | 東洋インキ製造株式会社 | 太陽電池用裏面保護シート、その製造方法、及び太陽電池モジュール |
JP2011071387A (ja) * | 2009-09-28 | 2011-04-07 | Dainippon Printing Co Ltd | 太陽電池モジュール用裏面保護シート、及び太陽電池モジュール |
JP2013143458A (ja) * | 2012-01-10 | 2013-07-22 | Toyo Ink Sc Holdings Co Ltd | 太陽電池保護シート用易接着剤、及び太陽電池用保護シート、ならびに太陽電池モジュール |
JP2013209554A (ja) * | 2012-03-30 | 2013-10-10 | Nippon Bee Chemical Co Ltd | 塗料組成物及び複層塗膜形成方法 |
JP2013227520A (ja) * | 2012-03-30 | 2013-11-07 | Dai Ichi Kogyo Seiyaku Co Ltd | プライマー組成物および積層体 |
JP2014160810A (ja) * | 2013-01-22 | 2014-09-04 | Toyo Ink Sc Holdings Co Ltd | 太陽電池用裏面保護シート、その製造方法および太陽電池モジュール |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4518724A (en) * | 1982-10-04 | 1985-05-21 | Nippon Paint Co., Ltd. | Aqueous coating composition |
JPH05271614A (ja) * | 1992-01-29 | 1993-10-19 | Kansai Paint Co Ltd | 水性着色塗料組成物及びそれを用いる塗装方法 |
WO2013118575A1 (ja) * | 2012-02-10 | 2013-08-15 | 関西ペイント株式会社 | 塗料組成物 |
JP6194190B2 (ja) * | 2013-05-16 | 2017-09-06 | ヘンケルジャパン株式会社 | 太陽電池保護シート用接着剤 |
WO2016010132A1 (ja) * | 2014-07-18 | 2016-01-21 | Dic株式会社 | 太陽電池バックシート用接着剤、太陽電池バックシート接着剤用ポリオール組成物、太陽電池バックシート、及び太陽電池モジュール |
-
2016
- 2016-02-25 JP JP2016550294A patent/JP6057041B1/ja active Active
- 2016-02-25 US US15/522,450 patent/US20170327720A1/en not_active Abandoned
- 2016-02-25 EP EP16764660.3A patent/EP3181649B1/en active Active
- 2016-02-25 CN CN201680003475.3A patent/CN107109168A/zh active Pending
- 2016-02-25 WO PCT/JP2016/055595 patent/WO2016147830A1/ja active Application Filing
- 2016-03-11 TW TW105107474A patent/TWI634181B/zh not_active IP Right Cessation
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04255782A (ja) * | 1991-02-07 | 1992-09-10 | Toyo Ink Mfg Co Ltd | 硬化性粘着剤組成物 |
WO2007066827A1 (ja) * | 2005-12-09 | 2007-06-14 | Kansai Paint Co., Ltd. | 水性プライマー塗料組成物 |
WO2007108314A1 (ja) * | 2006-03-17 | 2007-09-27 | Kimoto Co., Ltd. | ポリエステル系フィルム用バインダー組成物及びこれを用いた光学フィルム |
JP2009179710A (ja) * | 2008-01-30 | 2009-08-13 | Yokohama Rubber Co Ltd:The | エンジニアリングプラスチック用プライマー組成物 |
WO2011034070A1 (ja) * | 2009-09-17 | 2011-03-24 | 東洋インキ製造株式会社 | 太陽電池用裏面保護シート、その製造方法、及び太陽電池モジュール |
JP2011071387A (ja) * | 2009-09-28 | 2011-04-07 | Dainippon Printing Co Ltd | 太陽電池モジュール用裏面保護シート、及び太陽電池モジュール |
JP2013143458A (ja) * | 2012-01-10 | 2013-07-22 | Toyo Ink Sc Holdings Co Ltd | 太陽電池保護シート用易接着剤、及び太陽電池用保護シート、ならびに太陽電池モジュール |
JP2013209554A (ja) * | 2012-03-30 | 2013-10-10 | Nippon Bee Chemical Co Ltd | 塗料組成物及び複層塗膜形成方法 |
JP2013227520A (ja) * | 2012-03-30 | 2013-11-07 | Dai Ichi Kogyo Seiyaku Co Ltd | プライマー組成物および積層体 |
JP2014160810A (ja) * | 2013-01-22 | 2014-09-04 | Toyo Ink Sc Holdings Co Ltd | 太陽電池用裏面保護シート、その製造方法および太陽電池モジュール |
Non-Patent Citations (1)
Title |
---|
See also references of EP3181649A4 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017179081A (ja) * | 2016-03-29 | 2017-10-05 | 三菱ケミカル株式会社 | 硬化性組成物、硬化物及び積層体 |
WO2019093219A1 (ja) * | 2017-11-07 | 2019-05-16 | Dic株式会社 | 熱硬化型ウレタン樹脂組成物、フィルム及び物品 |
KR20200070412A (ko) * | 2017-11-07 | 2020-06-17 | 디아이씨 가부시끼가이샤 | 열경화형 우레탄 수지 조성물, 필름 및 물품 |
KR102381732B1 (ko) | 2017-11-07 | 2022-04-04 | 디아이씨 가부시끼가이샤 | 열경화형 우레탄 수지 조성물, 필름 및 물품 |
Also Published As
Publication number | Publication date |
---|---|
CN107109168A (zh) | 2017-08-29 |
TWI634181B (zh) | 2018-09-01 |
JPWO2016147830A1 (ja) | 2017-04-27 |
EP3181649A4 (en) | 2018-03-28 |
US20170327720A1 (en) | 2017-11-16 |
JP6057041B1 (ja) | 2017-01-11 |
EP3181649A1 (en) | 2017-06-21 |
TW201641654A (zh) | 2016-12-01 |
EP3181649B1 (en) | 2020-04-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6057041B1 (ja) | ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール | |
US20180155589A1 (en) | Polyester polyol, polyol preparation for laminating adhesive agent, resin composition, curable resin composition, adhesive agent for laminating use, and back sheet for solar cell | |
JP5655314B2 (ja) | 太陽電池モジュール | |
JP6439237B2 (ja) | 新規ポリエステルポリウレタンポリオール、2液型ラミネート接着剤用ポリオール剤、樹脂組成物、硬化性樹脂組成物、2液型ラミネート用接着剤、及び太陽電池用バックシート | |
TWI499066B (zh) | 太陽電池裏面封止材用薄膜、太陽電池裏面封止材及太陽電池模組 | |
JP5540840B2 (ja) | 太陽電池裏面封止シート | |
WO2012090856A1 (ja) | 太陽電池バックシート用接着剤 | |
US20170179309A1 (en) | Adhesive for solar-cell back sheet, polyol composition for solar-cell back sheet adhesive, solar-cell back sheet, and solar cell module | |
JP2017114937A (ja) | ポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール | |
WO2012073859A1 (ja) | 屋外用ウレタン接着剤 | |
JP2017110103A (ja) | 接着剤組成物、ポリオール混合物、2液型ラミネート用接着剤、積層フィルム及び太陽電池のバックシート | |
JP2017110126A (ja) | ポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール | |
KR102351304B1 (ko) | 적층 시트를 위한 접착제 | |
JP2013251427A (ja) | 太陽電池モジュール裏面封止シート用フィルム | |
JP6589553B2 (ja) | 太陽電池保護シート用一液型易接着剤、易接着性シート、及び太陽電池モジュール | |
JP2012174744A (ja) | 太陽電池裏面保護シートならびに太陽電池モジュール | |
JP6123347B2 (ja) | 2液型ラミネート接着剤用ポリオール剤、樹脂組成物、硬化性樹脂組成物、2液型ラミネート用接着剤、及び太陽電池用バックシート | |
JP2015195317A (ja) | 太陽電池用裏面保護シート、その製造方法および太陽電池モジュール | |
JP5546706B1 (ja) | 太陽電池バックシート用接着剤 | |
JP2015156462A (ja) | 太陽電池用裏面保護シート、その製造方法および太陽電池モジュール | |
JP2019114793A (ja) | プライマーおよび太陽電池裏面保護シート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ENP | Entry into the national phase |
Ref document number: 2016550294 Country of ref document: JP Kind code of ref document: A |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 16764660 Country of ref document: EP Kind code of ref document: A1 |
|
REEP | Request for entry into the european phase |
Ref document number: 2016764660 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2016764660 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15522450 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |