JP6057041B1 - ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール - Google Patents
ポリオール組成物、接着性コーティング剤、その硬化物、接着性シート、及び太陽電池モジュール Download PDFInfo
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- JP6057041B1 JP6057041B1 JP2016550294A JP2016550294A JP6057041B1 JP 6057041 B1 JP6057041 B1 JP 6057041B1 JP 2016550294 A JP2016550294 A JP 2016550294A JP 2016550294 A JP2016550294 A JP 2016550294A JP 6057041 B1 JP6057041 B1 JP 6057041B1
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- Prior art keywords
- meth
- coating agent
- hydroxyl group
- adhesive coating
- sheet
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 73
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical class C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
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- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- AQHHHDLHHXJYJD-UHFFFAOYSA-N propranolol Chemical compound C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
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- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
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- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
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- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
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- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
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- C09J7/22—Plastics; Metallised plastics
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
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- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
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Abstract
Description
(II-1-a)炭素原子数2〜9の多価脂肪族アルコール、
(II-2-a)飽和脂肪族ジカルボン酸、芳香族ジカルボン酸、又はこれらの酸無水物、及び
(II-3)植物油脂肪酸
を反応させて得られるポリエステルポリオール(A);
(II-2-b)不飽和ジカルボン酸又はその無水物、
を反応させて得られるポリエステルポリオール(B);
(II-2-b)不飽和ジカルボン酸又はその無水物、及び
(II-3)植物油脂肪酸
を反応させて得られるポリエステルポリオール(C);
(II-1-b)ひまし油、
(II-2-a)飽和脂肪族ジカルボン酸、芳香族ジカルボン酸、又はこれらの酸無水物及び
を反応させて得られるポリエステルポリオール(D)
が挙げられる。
0g/eq.の範囲にあるもの、とりわけ200〜800g/eq.の範囲にあるものが、接着性コーティング剤における封止材との接着性が良好なものとなる点から好ましい。
カラム ;東ソー株式会社製 TSK−GUARDCOLUMN SuperHZ−L
+東ソー株式会社製 TSK−GEL SuperHZM−M×4
検出器 ;RI(示差屈折計)
データ処理;東ソー株式会社製 マルチステーションGPC−8020modelII
測定条件 ;カラム温度 40℃
溶媒 テトラヒドロフラン
流速 0.35ml/分
標準 ;単分散ポリスチレン
試料 ;樹脂固形分換算で0.2質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(100μl)
エチレン‐テトラフルオロエチレン共重合体シートなどのフッ素樹脂シート;ポリアクリルニトリル、ポリメチルメタクリレート等のアクリル系樹脂シート;フィルム剛性、コストの観点からポリエステル系樹脂シートであることが好ましく、特にポリエチレンテレフタレートシートであることが好ましい。
カラム ;東ソー株式会社製 TSK−GUARDCOLUMN SuperHZ−L
+東ソー株式会社製 TSK−GEL SuperHZM−M×4
検出器 ;RI(示差屈折計)
データ処理;東ソー株式会社製 マルチステーションGPC−8020modelII
測定条件 ;カラム温度 40℃
溶媒 テトラヒドロフラン
流速 0.35ml/分
標準 ;単分散ポリスチレン
試料 ;樹脂固形分換算で0.2質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(100μl)
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、キシレンの50質量部と、酢酸n−ブチルの16質量部を仕込んで、攪拌を開始し、窒素雰囲気中で115℃にまで昇温した。同温度に達した処で、メチルメタクリレート44.0質量部、イソブチルメタクリレート40.0質量部、2−ヒドロキシエチルメタクリレート15.0質量部、メタクリル酸1.0質量部の混合物と、パーブチルO(日油株式会社製、t−ブチルペルオキシ−2−エチルヘキサノエート)の0.8質量部を15質量部のキシレンに希釈したものを、同時に、5時間かけて滴下した。その後も、同温度で、反応を続け、滴下終了1時間後にキシレンの42質量部と、酢酸ノルマルブチルの10質量部、パーヘキサC(日油株式会社製、1,1−ジ(t−ブチルパーオキシ)シクロヘキサン)の0.1質量部を投入した。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、トルエンの46質量部を仕込んで、攪拌を開始し、窒素雰囲気中で105℃にまで昇温した。同温度に達した処で、メチルメタクリレート20.0質量部、イソブチルアクリレート5.0質量部、シクロヘキシルメタクリレート69.5質量部、2−ヒドロキシエチルメタクリレート5.0質量部、メタクリル酸0.5質量部の混合物と、パーブチルO(日油株式会社製、t−ブチルペルオキシ−2−エチルヘキサノエート)の0.5質量部と、パーブチルZ(日油株式会社製、t-ブチルパーオキシベンゾエート)の0.5質量部を20質量部のトルエンに希釈したものを、同時に、4時間かけて滴下した。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、メチルメタクリレート18.0質量部、n−ブチルメタクリレート78.0質量部、2−ヒドロキシエチルメタクリレート2.0質量部、グリシジルメタクリレート2.0質量部、トルエン100質量部を仕込み、攪拌しながら100℃まで昇温し、アゾビスイソブチロニトリル0.15質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部を加えて2時間反応させた。
温度計、攪拌機、還流冷却器および窒素ガス導入管を備えた四つ口フラスコに、メチルメタクリレート18.0質量部、n−ブチルメタクリレート80.0質量部、2−ヒドロキシエチルメタクリレート2.0質量部、トルエン100質量部を仕込み、攪拌しながら100℃まで昇温し、アゾビスイソブチロニトリル0.15質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部加えて2時間重合し、更にアゾビスイソブチロニトリル0.07質量部を加えて2時間反応させた。その後、室温にまで冷却して、不揮発分50質量%のアクリル樹脂(4)の有機溶剤溶液を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン17質量部、ジプロピレングリコール42質量部、フマル酸35質量部、ヤシ油脂肪酸6質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が12,000、ガードナー粘度U−V、固形分の水酸基価が220mgKOH/g、二重結合当量300g/eq.のポリエステルポリオール(A1)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、エチレングリコール8質量部、ペンタエリスリトール12質量部、無水フタル酸40質量部、ひまし油40質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が16,000、ガードナー粘度U−V、固形分の水酸基価が120mgKOH/g、二重結合当量700g/eq.のポリエステルポリオール(2)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン40質量部、ネオペンチルグリコール16質量部、無水フタル酸25質量部、フマル酸19質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、
重量平均分子量(Mw)が4,700、ガードナー粘度U−V、固形分の水酸基価が270mgKOH/g、二重結合当量550g/eq.のポリエステルポリオール(3)を得た。
攪拌棒、温度センサー、精留管を有するフラスコに、トリメチロールプロパン15質量部、1,3−ブタンジオール32質量部、無水フタル酸9質量部、アジピン酸45質量部、及び有機チタン化合物0.2質量部を仕込み、乾燥窒素をフラスコ内に流入させ攪拌しながら210℃に加熱しエステル化反応を行った。酸価が5.0mgKOH/g以下となったところで反応を停止し、100℃まで冷却後、酢酸エチルで固形分80質量%に希釈して、重量平均分子量(Mw)が12,000、ガードナー粘度U−V、固形分の水酸基価が170mgKOH/gのポリエステルポリオール(4)を得た。
下記の表3〜表7に示す配合に従い、主剤成分を調整した。その後、主剤に硬化剤を配合し(比較例5〜8では更に触媒を配合)、酢酸エチルで固形分濃度30質量%に調整し接着性コーティング剤を得た。(表3〜表7の配合量は、固形分換算値。)。
N−3300:1,6−ヘキサメチレンジイソシアネートのイソシアヌレート体(住化バイエルウレタン社製「スミジュールN−3300」イソシアネート基(NCO)含有量21.8質量%、粘度2500mPa・s/25℃))
N−3200:1,6−ヘキサメチレンジイソシアネートのビュレット体(住化バイエルウレタン社製「デスモジュールN−3200」イソシアネート基(NCO)含有量23.0質量%、粘度2100mPa・s/25℃)
N−3400:1,6−ヘキサメチレンジイソシアネートのウレトジオン体(住化バイエルウレタン社製「デスモジュールN−3400」イソシアネート基(NCO)含有量21.8質量%、粘度175mPa・s/25℃))
TSE−100:1,6−ヘキサメチレンジイソシアネートのイソシアヌレート体(旭化成(株)製「デュラネートTSE−100」、イソシアネート基(NCO)含有量12.1質量%、粘度1650mPa・s/25℃)
T5651:ポリカーボネートジオール(旭化成ケミカルズ社製「デュラノール」、1,5−ペンタンジオールと1,6−ヘキサンジオールから得られるポリカーボネート樹脂、数平均分子量1,000、水酸基価100〜120mgKOH/g)
UM−90:ポリカーボネートジオール(宇部興産(株)製「エタナコール」、数平均分子量:約900、1,6−ヘキサンジオールと炭酸エステルとを反応させて得られるポリカーボネートジオール、及び、1,4−シクロヘキサンジメタノールと炭酸エステルとを反応させて得られるポリカーボネートジオールの質量比が1:3の混合物)
EX−321:トリメチロールプロパンのジグリシジルエーテルとトリグリシジルエーテルの混合物(ナガセケムテックス(株)製「デナコール EX−321」エポキシ当量140g/eq.)
860−80SE:ビスフェノールA型エポキシ樹脂(DIC(株)製「エピクロン860−80SE」エポキシ当量250g/eq.酢酸エチルカット品、固形分80質量%)
JER828:ビスフェノールA型エポキシ樹脂(三菱化学株式会社製「JER828」エポキシ当量190g/eq.)
JR−403:酸化チタン(テイカ製「JR−403」)
M−215:イソシアヌル酸EO変性ジアクリレート(東亜合成社製「アロニックスM−215」
ポリイソシアネート化合物*1:3,5−ジメチルピラゾールでブロックされたヘキサメチレンジイソシアネートのイソシアヌレート体(固形分75質量%酢酸エチル溶液)
評価用積層体を、引張試験機( (株)エー・アンド・ディー製)の上下のクリップに未接着部分を挟み、クロスヘッド速度100mm/分で180度剥離試験を行った。得られた測定値に対して、以下のように評価した。
○:30N/10mm以上〜50N/10mm未満
△:10N/10mm以上〜30N/10mm未満
×:10N/10mm未満
[耐湿熱性評価方法]
前記接着力評価用積層体をプレッシャークッカーテスト(PCT)に24、48時間かけ(試験条件:121℃で、相対湿度が100%)、前記と同じ条件で、耐湿熱試験後の剥離強度を測定した。
B:表面保護基材
C:インターコネクタ
D:封止材
E:バックシート
F:端子
a:基材シート
b:接着性コーティング剤の硬化物である接着層
Claims (17)
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)を必須成分とすることを特徴とするポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基含有(メタ)アクリレート(a)と、その他の(メタ)アクリル単量体(b)とを必須成分として共重合して得られるものである請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基含有(メタ)アクリレート(a)、前記炭素原子数が1〜3のアルキル基でエステル化された(メタ)アクリレート(b−1)、前記炭素原子数4〜16のアルキル基でエステル化された(メタ)アクリレート(b−2)を必須の単量体成分として用い、水酸基含有(メタ)アクリル樹脂(I)を構成する単量体成分中、水酸基含有(メタ)アクリレート(a)を3〜20質量%、炭素原子数が1〜3のアルキル基でエステル化された(メタ)アクリレート(b−1)を、15〜50質量%、炭素原子数4〜16のアルキル基でエステル化された(メタ)アクリレート(b−2)を30〜76質量%、となる割合で共重合してなるものである請求項2記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有(メタ)アクリル樹脂(I)が、水酸基価1〜200mgKOH/gの範囲にあるものである請求項3記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記不飽和二重結合含有ポリエステルポリオール(II)が、二重結合当量100〜1000g/eq.のものである請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記不飽和二重結合含有ポリエステルポリオール(II)が、水酸基価10〜350mgKOH/gの範囲にあるものである請求項5記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)の質量比[(I)/(II)]が95/5〜50/50となる割合である請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)に加え、更にエポキシ樹脂(III)を有する請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記エポキシ樹脂(III)の配合割合が、ポリオール組成物の必須成分である水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)の合計100質量部に対して、4.0〜30.0質量部となる割合で配合する請求項8記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、不飽和二重結合含有ポリエステルポリオール(II)、更に水酸基含有ポリカーボネート(IV)を有する請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 前記水酸基含有ポリカーボネート(IV)の配合割合が、ポリオール組成物の必須成分である水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)の合計100質量部に対して、2.0〜30.0質量部となる割合で配合する請求項10記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 水酸基含有(メタ)アクリル樹脂(I)、及び不飽和二重結合含有ポリエステルポリオール(II)に加え、更に二酸化チタンを配合してなる請求項1記載のポリイソシアネート硬化型接着性コーティング剤用ポリオール組成物。
- 請求項1〜12の何れか一つに記載のポリオール組成物(α)と、ポリイソシアネート化合物(β)を必須成分とすることを特徴とする接着性コーティング剤。
- 前記ポリオール組成物(α)と、ポリイソシアネート化合物(β)との配合割合が、該ポリオール組成物(α)中の水酸基に対する前記ポリイソシアネート化合物(β)中のイソシアネート基との当量比[NCO/OH]が0.25〜3.00となる割合である請求項13記載の接着性コーティング剤。
- 請求項13記載の接着性コーティング剤を硬化させてなる硬化物。
- ポリエステル基材シート上に、請求項13記載の接着性コーティング剤を塗布、硬化させて接着層を形成した接着性シート。
- 太陽電池セル(A)、表面保護基材(B)、太陽電池セル用封止材(D)、及びバックシート(E)を必須の構成要素とし、該バックシート(E)が、基材シート(a)と該基材シート(a)上に形成された請求項13記載の接着性コーティング剤の硬化物である接着層(b)とを必須の層構成とするものであり、かつ、前記接着層(b)が太陽電池セル用封止材(D)に接する様に、前記バックシート(E)が配設されていることを特徴とする太陽電池モジュール。
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2016
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- 2016-02-25 WO PCT/JP2016/055595 patent/WO2016147830A1/ja active Application Filing
- 2016-02-25 CN CN201680003475.3A patent/CN107109168A/zh active Pending
- 2016-02-25 EP EP16764660.3A patent/EP3181649B1/en active Active
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EP3181649A1 (en) | 2017-06-21 |
TW201641654A (zh) | 2016-12-01 |
US20170327720A1 (en) | 2017-11-16 |
EP3181649B1 (en) | 2020-04-22 |
JPWO2016147830A1 (ja) | 2017-04-27 |
CN107109168A (zh) | 2017-08-29 |
TWI634181B (zh) | 2018-09-01 |
EP3181649A4 (en) | 2018-03-28 |
WO2016147830A1 (ja) | 2016-09-22 |
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