WO2014029842A1 - Composition de maquillage comprenant un pigment bleu - Google Patents

Composition de maquillage comprenant un pigment bleu Download PDF

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Publication number
WO2014029842A1
WO2014029842A1 PCT/EP2013/067459 EP2013067459W WO2014029842A1 WO 2014029842 A1 WO2014029842 A1 WO 2014029842A1 EP 2013067459 W EP2013067459 W EP 2013067459W WO 2014029842 A1 WO2014029842 A1 WO 2014029842A1
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WO
WIPO (PCT)
Prior art keywords
anthocyan
acid
dye powder
chosen
ranging
Prior art date
Application number
PCT/EP2013/067459
Other languages
English (en)
Inventor
Patrick Choisy
Martin Michel
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to JP2015527921A priority Critical patent/JP6453215B2/ja
Priority to CN201380043507.9A priority patent/CN104540898B/zh
Priority to ES13756364.9T priority patent/ES2648195T3/es
Priority to BR112015003700-3A priority patent/BR112015003700B1/pt
Priority to US14/422,868 priority patent/US11554090B2/en
Priority to EP13756364.9A priority patent/EP2888326B1/fr
Publication of WO2014029842A1 publication Critical patent/WO2014029842A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9794—Liliopsida [monocotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B63/00—Lakes
    • C09B63/005—Metal lakes of dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes

Definitions

  • Makeup composition comprising a blue pigment
  • the present invention relates to a process for making up human keratin materials using a blue dye powder comprising an anthocyan.
  • the aim of the present invention is thus to provide a blue colour powder which shows good photostability without any fading of the colour hue.
  • Such a dye powder is obtained by stabilizing anthocyans in the presence of certain metal ions and tannic acid.
  • the present invention relates to a process for making up keratin materials, comprising the application to the keratin materials of a dye powder having a blue colour comprising at least one anthocyan, metal ions chosen from the group of ions derived from Al(lll), Ca(ll), Cu(ll), Fe(ll), Fe(lll), Mg(ll), Mn(ll) and Zn(ll) and mixtures thereof, tannic acid or a gallotannin derivative thereof, or mixtures thereof.
  • the invention also relates to a cosmetic composition
  • a cosmetic composition comprising, in a physiologically acceptable medium, (i) a dye powder having a blue colour comprising at least one anthocyan, metal ions chosen from the group of ions derived from Al(lll), Ca(ll), Cu(ll), Fe(ll), Fe(lll), Mg(ll), Mn(ll) and Zn(ll) and mixtures thereof, tannic acid or a gallotannin derivative thereof, or mixtures thereof, and (ii) a cosmetic additive chosen from fragrances, preserving agents, film-forming polymers, fillers, UV-screening agents, thickeners, silicone oils, plant oils, liquid paraffins, waxes, moisturizers, vitamins, proteins, ceramides, antioxidants, free-radical scavengers, organic solvents, mineral pigments (titanium dioxide or iron oxides) and nacres.
  • Blue is the hue of that portion of the visible spectrum lying between green and indigo.
  • CIE Commission Internationale de I'Eclairage
  • CIELAB CIE Technical Report, Colorimetry 2 nd Edition, CIE 15.2 - 1986, corrected reprint 1996.
  • the CIELAB colour space is produced by plotting the quantities L * , a * , b * in rectangular coordinates.
  • the L * coordinate of an object is the lightness intensity as measured on a scale from 0 (black) to 100 (absolute white).
  • the a * and b * coordinates have no specific numerical limits.
  • the parameter a * runs from pure green (negative a * ) to pure red (positive a * ), while b * runs from pure blue (negative b * ) to pure yellow (positive b * ).
  • the hue angle h ab is calculated from a * and b * values as:
  • Blue within the scope of the present invention refers to a CIELAB hue angle h ab between 210° and 325°, for example between 225° and 315°.
  • the dye powder used according to the invention comprises at least one anthocyan.
  • Anthocyans are, as is known, anthocyanidol glycosides (Jin-Ming Kong et al., Phytochemistry, 64, 923-933 (2003)).
  • anthocyans More than 500 different anthocyans exist in nature. Their main differences relate to the number of hydroxyl groups and of methoxy groups, the nature and number of sugar units present, the aliphatic or aromatic carboxylate groups attached to the sugars in the molecule and the position of these bonds (A Castafieda-Ovando et al., Food Chemistry, 1 13, 859-871 (2009)).
  • Anthocyanidols are compounds of formula (I) below:
  • the sugars bonded to the anthocyanidols are especially glucose, rhamnose, galactose, xylose, arabinose and glucuronic acid.
  • the main glycoside derivatives in nature are 3-monosides, 3-biosides, 3,5-diglucosides and 3,7-diglucosides.
  • the anthocyans may also be acetylated, and the sugars may be acylated with methyl or malonic, p-coumaric acid, ferulic acid, sinapylic acid or caffeic acid substituents (F.J. Francis, Colorants, p. 56, Eagan Press (1999)).
  • the most common anthocyan is cyanidin-3-O-glucoside.
  • the anthocyans used according to the present invention may be chosen from those of formula (I) in which R-i , R 2 and R 4 independently denote H, OH, OMe, a sugar unit or an acylated sugar unit (acyl group derived from malonic acid, p- coumaric acid, ferulic acid or caffeic acid) and R 3 , Rs, R6 and R 7 independently denote H, OH or OMe.
  • the anthocyans may be of natural or synthetic origin.
  • a certain number of plants are naturally rich in anthocyans. Examples that may be mentioned include black carrot, elderberry, hibiscus, blackcurrant, purple corn and black potato.
  • the four main anthocyans present in blackcurrant are cyanidin-3-O- rutinoside, cyanidin-3-O-rutinoside, delphinidin-3-O-glucoside and delphinidin-3-O- rutinoside.
  • Black grape and red cabbage are the two most important sources of anthocyans in nature.
  • the anthocyanidin units of the anthocyans present in black grape are cyanidin, peonidin, malvidin, petunidin and delphinidin; and the organic acids present are acetic acid, coumaric acid and caffeic acid.
  • the only sugar present is glucose (F.J. Francis, Colorants, p. 56, Eagan Press (1999)).
  • a grape anthocyan, malvidin-3,5,-diglucoside, corresponds to formula (II) below, in which Glu is glucose and Me is the methyl radical.
  • the anthocyans used according to the present invention may be cyanidin-3-O- rutinoside, delphinidin-3-O-rutinoside, cyanidin-3-O-glucoside or malvidin-3,5,-0- diglucoside.
  • anthocyans present in red cabbage are described in formula (III). These anthocyans comprise the basic structure cyanidin-3-diglucoside, but comprise different groups Ri and R 2 .
  • the groups Ri and R 2 of these seven anthocyans are sinapyl, ferulyl or p-coumaryl, as indicated in Table 1 .
  • the anthocyans used according to the present invention may be one or more of the cyanidin-3-diglucosides A to G described previously.
  • the anthocyans may be added in the form of plant matter or an extract of plant matter. It may be advantageous to avoid unnecessary purification of the plant matter.
  • the other components of the plant matter may be advantageous for the dye powder.
  • other components of the plant matter for instance flavonoids, are advantageous for their antioxidant properties.
  • the plant matter may be, for example, legumes, fruit or flowers.
  • the plant matter may be chosen from red cabbage, red onion, purple potato, grape, cranberry, strawberry, raspberry, aronia, black soybean, blackcurrant, elderberry, hibiscus, radish, gooseberry, bilberry, cherry, aubergine, black carrot and black rice.
  • the anthocyan may be present in the dye powder in a content ranging from 0.05% to 50% by weight, preferably ranging from 0.3% to 25% by weight and preferentially ranging from 5% to 15% by weight relative to the total weight of solids of the dye powder.
  • the dye powder according to the invention comprises metal ions chosen from ions derived from Al(lll), Ca(ll), Cu(ll), Fe(ll), Fe(lll), Mg(ll), Mn(ll) and Zn(ll), and mixtures thereof.
  • the metal ions are preferably chosen from ions derived from Fe(ll), Fe(lll) and Mg(ll), and mixtures thereof.
  • the ion derived from Fe(ll) is preferred.
  • calcium gluconate contains the (Ca 2+ ) ion derived from Ca(ll); magnesium chloride, MgCI 2 , or magnesium gluconate contains Mg(ll) ions (Mg 2+ ); ferrous sulfate, FeS0 4 , iron gluconate (CeHnOr ⁇ Fe contains Fe(ll) ions (Fe 2+ ); ferric sulfate, Fe 2 (S0 4 ) 3 , contains Fe(lll) ions (Fe 3+ ); and aluminium sulfate, AI 2 (S0 4 ) 3 , contains Al(lll) ions (Al 3+ ).
  • the metal ions may be present in the dye powder in a metal ion/anthocyan weight ratio ranging from 0.01/1 to 10/1 and preferably ranging from 0.05/1 to 5/1 by weight.
  • the dye composition comprises tannic acid or a gallotannin derivative thereof, or mixtures thereof.
  • Tannic acid is a mixture of polygalloyi glucoses or of polygalloyi quinic acid esters with a number of galloyl units per molecule ranging from 2 to 12, dependent on the plant source used to extract the tannic acid.
  • gallotannin derivatives of tannic acid means the polygalloyi glucose compounds and the polygalloyi quinic acid esters described previously.
  • Tannic acid or a gallotannin derivative thereof, and mixtures thereof may be present in the dye powder in a tannic acid or gallotannin derivative/anthocyan weight ratio ranging from 0.05/1 to 20/1 and preferably ranging from 0.1/1 to 10/1 .
  • the dye powder may comprise additional ingredients as described below.
  • the dye powder may comprise an amino acid, which may be chosen from taurine, proline and arginine. This amino acid acts as a bathochromic agent.
  • the amino acid may be present in the dye powder in an amino acid/anthocyan weight ratio ranging from 0.1/1 to 25/1 , preferably ranging from 0.5/1 to 20/1 and preferentially ranging from 1/1 to 16.5/1.
  • the dye powder may comprise a phospholipid, and in particular phosphatidylcholine (also known as lecithin). This phospholipid allows a good interaction between the anthocyan, the metal ions and the tannic acid.
  • phosphatidylcholine also known as lecithin
  • Phospholipids are a class of lipids which are predominant components of cell membranes and which may form lipid bilayers.
  • a phospholipid molecule is constructed with four components: fatty acids, a backbone onto which the fatty acids are attached and a phosphate ester.
  • the phospholipid backbone may be glycerol or sphingosine.
  • Glycerol-based phospholipids are known as phosphoglycerides (Biochemistry 5 Edition, J. Berg et al., W.H. Freeman & Co (2002)).
  • phospholipids examples include phosphatidic acid, phosphatidylethanolamine, phosphatidylcholine, phosphatidylserine, phosphatidylinositol, phosphatidylinositol phosphate, phosphatidylinositol bisphosphate, phosphatidylinositol triphosphate, ceramide phosphoryl choline, ceramide phosphorylethanolamine and ceramide phosphoryl glycerol.
  • Phospholipids are one of the constituents of lecithin. Lecithin is present in egg yolk and may also be extracted from seed oils.
  • the phospholipids used in the present invention may be a sunflower or soybean lecithin.
  • the main phospholipids of soybean or sunflower lecithin are phosphatidylcholine, phosphatidylinositol, phosphatidylethanolamine and phosphatidic acid.
  • the phospholipid may be phosphatidylcholine.
  • Use is made, for example, of the product sold under the trade name Ultralec by the company ADM.
  • the phospholipid may be present in the dye powder in a phospholipid/anthocyan weight ratio ranging from 0.1/1 to 50/1 and preferably ranging from 0.5/1 to 30/1 .
  • the composition may comprise a monocarboxylic or dicarboxylic acid containing from 2 to 6 carbon atoms, chosen especially from acetic acid, malic acid and tartaric acid.
  • This acid is advantageously present to adjust the pH of the dye composition preparation to between 3.5 and 8.
  • the pH of the dye preparation is between 3.5 and 7, preferably between 4 and 6 and preferentially between 4 and 5.5.
  • the dye powder may be prepared in a first step by mixing in water the anthocyan (especially in plant extract form), while adjusting the pH to between 3.5 and 8.0, the metal ions in salt form, the tannic acid or gallotannin derivatives thereof and the other additional ingredients.
  • the solid phase of the mixture obtained in the first step is isolated, especially by centrifugation, and then frozen, and is then dried, for example by lyophilization to recover the dye powder.
  • a support such as maltodextrin may be added to the mixture obtained in the first step and the composition may be atomized to recover a dye powder.
  • the cosmetic composition comprising the dye powder also comprises a physiologically acceptable medium, i.e. a medium that is compatible with human keratin materials and/or fibres, for instance, in a non-limiting manner, the skin, mucous membranes, the nails, the scalp and/or the hair.
  • a physiologically acceptable medium i.e. a medium that is compatible with human keratin materials and/or fibres, for instance, in a non-limiting manner, the skin, mucous membranes, the nails, the scalp and/or the hair.
  • the composition according to the invention may also contain cosmetic additives as described previously.
  • the amounts of these various additives are those conventionally used in the cosmetics field, and may range, for example, from 0.01 % to 30% of the total weight of the composition. In general, the amounts are adjusted as a function of the formulation a y c
  • a cosmetic composition according to the invention may be in the form of a makeup product for the hair (in particular for coloured coating of the hair), the eyelashes, the eyebrows, the skin, the lips or the nails.
  • Blue pigments were prepared from the following compositions: - ⁇ is
  • Pigment 9 The following solutions were first prepared in 0.1 M pH 5 sodium acetate buffer in deionized water.
  • Bilberry extract mixture of aqueous-alcoholic extract of bilberry fruit and of maltodextrin (bilberry fruit PE 25% anthocyanosides from Naturex)
  • Tannic acid 0.39 g in 20 ml of buffer
  • Phosphatidylcholine (Ultralec® U from ADM): 2.4 g in 20 ml of buffer
  • the bilberry extract placed in the buffer was mixed with iron sulfate or magnesium sulfate and optionally with malic acid; the mixture was stirred for 2 hours in the darkness, at 25°C; tannic acid was then added, and the mixture was then stirred for a further 2 hours under the same conditions; next, the mixture was heated for 3 hours at 75°C. Phosphatidylcholine and proline were then optionally added, and the mixture was stirred for 72 hours at 25°C.
  • the mixture was optionally centrifuged to recover the final solid phase.
  • This solid phase was then frozen at -22°C and then freeze-dried.
  • a blue pigment was prepared according to the following procedure:
  • the pH was checked and adjusted to between 5.5 and 6.0.
  • the total of the sodium bicarbonate additions was 100 g.
  • the total volume of the mixture was adjusted to 10 litres and stirred for 16 hours at 4°C.
  • 1 kg of maltodextrin 20 DE was dissolved in the mixture and then pasteurized at 75°C for 1 hour.
  • the mixture was cooled and stirred for 48 hours at 4°C and was then atomized to obtain a powder. A blue pigment was thus obtained.
  • Example 11 study of the photostability of the blue pigments
  • the photostability of the pigments prepared in Examples 1 to 10 was measured according to the following protocol:
  • the water-in-oil emulsion having the following composition was prepared: 5% of pigment to be tested
  • the emulsion prepared was spread onto a contrast card.
  • the emulsion containing the pigment to be tested was applied to a 50 ⁇ thick
  • the deposit obtained was then subjected to irradiation under a Lot Oriel sun simulator for i hour (power 1600 W).
  • the colour of the deposit spread on the white part of the contrast card was measured with the colorimeter, taking care to avoid the zones previously read for the measurement at to (measurement at t1 of L1 , a1 , b1 ).
  • the photostability is determined by calculating the difference ⁇ between the colour measurements before and after irradiation performed on the white background of the contrast card:
  • the photostability is proportionately better the closer to 0 value of the colour difference ⁇ thus determined.
  • the eyeshadow applied to the eyelids has a beautiful blue colour.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
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  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique comprenant une poudre à pigment bleu qui renferme une anthocyane, un ion métallique et de l'acide tannique ainsi qu'un adjuvant cosmétique. L'invention concerne également un procédé permettant de maquiller des matières kératinées par application de la composition cosmétique sur les matières kératinées.
PCT/EP2013/067459 2012-08-23 2013-08-22 Composition de maquillage comprenant un pigment bleu WO2014029842A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2015527921A JP6453215B2 (ja) 2012-08-23 2013-08-22 青色顔料を含むメークアップ組成物
CN201380043507.9A CN104540898B (zh) 2012-08-23 2013-08-22 包含蓝色颜料的化妆品组合物
ES13756364.9T ES2648195T3 (es) 2012-08-23 2013-08-22 Composición de maquillaje que comprende un pigmento azul
BR112015003700-3A BR112015003700B1 (pt) 2012-08-23 2013-08-22 Processo para maquilar matérias queratínicas e composição cosmética
US14/422,868 US11554090B2 (en) 2012-08-23 2013-08-22 Makeup composition comprising a blue pigment
EP13756364.9A EP2888326B1 (fr) 2012-08-23 2013-08-22 Composition de maquillage comprenant un pigment bleu

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1257954 2012-08-23
FR1257954A FR2994693B1 (fr) 2012-08-23 2012-08-23 Composition de maquillage comprenant un pigment bleu
US201261724570P 2012-11-09 2012-11-09
US61/724,570 2012-11-09

Publications (1)

Publication Number Publication Date
WO2014029842A1 true WO2014029842A1 (fr) 2014-02-27

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PCT/EP2013/067459 WO2014029842A1 (fr) 2012-08-23 2013-08-22 Composition de maquillage comprenant un pigment bleu

Country Status (8)

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US (1) US11554090B2 (fr)
EP (1) EP2888326B1 (fr)
JP (1) JP6453215B2 (fr)
CN (1) CN104540898B (fr)
BR (1) BR112015003700B1 (fr)
ES (1) ES2648195T3 (fr)
FR (1) FR2994693B1 (fr)
WO (1) WO2014029842A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018050504A1 (fr) 2016-09-16 2018-03-22 L'oreal Poudre bleue et son utilisation en cosmétique

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3091852A1 (fr) * 2013-12-18 2016-11-16 Basf Se Phycocyanine stabilisée pour la couleur bleue
CN105113219B (zh) * 2015-09-29 2017-02-01 辽东学院 基于黑米花色素苷的棉织物抗紫外整理剂
WO2017162599A1 (fr) * 2016-03-21 2017-09-28 L'oreal Composition cosmétique comprenant un colorant soluble dans l'eau
CN106137828B (zh) * 2016-07-05 2020-08-28 上海相宜本草化妆品股份有限公司 黑米提取物及其制备方法和在化妆品中的应用
CN108864744A (zh) * 2018-09-12 2018-11-23 乐象永续科技（杭州）有限公司 色淀的制备工艺、色淀及其应用
CN111529434B (zh) * 2020-05-11 2021-09-03 山东农业大学 一种含egcg的唇部预防保健产品及其应用
FR3124384B1 (fr) * 2021-06-29 2024-01-19 Oreal Composition cosmétique parfumée comprenant au moins un composé (poly)hydroxy(C1-C16)alkylcarboxylate de métal, un colorant anthocyani(di)ne et une matière parfumante, et procédé de traitement de matière kératinique et/ou de vêtement mettant en œuvre la composition

Citations (1)

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EP1798262A1 (fr) * 2005-12-15 2007-06-20 Lcw - Les Colorants Wackherr Laques de colorants bleues comprenant des colorants naturels

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BR112015003700A2 (pt) 2017-07-04
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FR2994693A1 (fr) 2014-02-28
US20150216776A1 (en) 2015-08-06
JP6453215B2 (ja) 2019-01-16
EP2888326A1 (fr) 2015-07-01
CN104540898B (zh) 2017-08-15
JP2015526457A (ja) 2015-09-10
US11554090B2 (en) 2023-01-17
FR2994693B1 (fr) 2014-08-22
CN104540898A (zh) 2015-04-22

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