WO2012121224A1 - 樹脂組成物ならびにこれを用いたプリプレグおよび積層板 - Google Patents
樹脂組成物ならびにこれを用いたプリプレグおよび積層板 Download PDFInfo
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- WO2012121224A1 WO2012121224A1 PCT/JP2012/055600 JP2012055600W WO2012121224A1 WO 2012121224 A1 WO2012121224 A1 WO 2012121224A1 JP 2012055600 W JP2012055600 W JP 2012055600W WO 2012121224 A1 WO2012121224 A1 WO 2012121224A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/092—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/05—Insulated conductive substrates, e.g. insulated metal substrate
- H05K1/056—Insulated conductive substrates, e.g. insulated metal substrate the metal substrate being covered by an organic insulating layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/102—Oxide or hydroxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/302—Conductive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
Definitions
- the present invention relates to a resin composition, and more particularly to a resin composition that can be suitably used in a printed wiring board having high thermal conductivity. Furthermore, the present invention relates to a prepreg produced using the resin composition, and a laminate and a metal foil-clad laminate using the prepreg.
- thermosetting resins such as epoxy resins used for printed wiring board insulation layers themselves have low thermal conductivity. Therefore, in order to improve thermal conductivity as a printed wiring board, a method of highly filling an inorganic filler excellent in thermal conductivity into a thermosetting resin is known (for example, see Patent Document 1).
- thermosetting resin composition is highly filled with an inorganic filler, there are problems such as poor processability, brittleness, and high cost of the resin composition.
- the volume ratio of the thermosetting resin is reduced and cracks and voids are likely to occur between the resin and the inorganic filler, the moisture resistance (water absorption rate and moisture absorption heat resistance) and solder heat resistance are reduced.
- the adhesiveness of resin and an inorganic filler becomes inadequate, and there exists a subject that copper foil peel strength falls.
- boron nitride is known as an inorganic filler having excellent thermal conductivity (see, for example, Patent Document 2).
- Patent Document 2 boron nitride (“ UHP-2 (Showa Denko) is used.
- This hexagonal boron nitride is known to be excellent in electrical insulation and chemical stability in addition to thermal conductivity, and is non-toxic and relatively inexpensive.
- hexagonal boron nitride grows in the a-axis direction (hexagonal network surface direction) and does not grow in the c-axis direction (stacking direction) as the particle size increases.
- Patent Document 2 reports that by using a silane coupling agent having a specific functional group, it is possible to improve moisture resistance characteristics (moisture absorption heat resistance) required for printed wiring board applications, but versatility is poor, The effect was limited.
- patent document 3 it can improve the thermal conductivity of a board
- the resin used in the examples of the document is only an epoxy resin having a general structure, and a substrate obtained by curing the resin is required to have a high glass transition temperature and high demand for printed wiring board applications. It cannot be said that it has sufficient characteristics in terms of copper foil peel strength, moisture absorption heat resistance, solder heat resistance, water absorption rate, and flame retardancy.
- one or both of the epoxy resin and the curing agent contain a naphthalene structure
- the inorganic filler contains hexagonal boron nitride
- the inorganic filler contains 50 to 85% by volume of the entire resin composition.
- a sheet or a substrate is prepared by curing a resin composition characterized in that the sheet is formed.
- the use of the cured product described in this document is a heat dissipation sheet, which is required for printed wiring board applications, such as high glass transition temperature, high copper foil peel strength, moisture absorption heat resistance, solder heat resistance, water absorption rate, difficulty. It cannot be said that it has sufficient characteristics in terms of flammability.
- the present invention has been made in view of the above-described background art, and its purpose is to provide a high glass transition temperature, copper foil peel strength, moisture absorption heat resistance, solder heat resistance, low water absorption, difficulty required for printed wiring board applications.
- a resin composition for printed wiring boards having flammability, a low coefficient of thermal expansion and high heat dissipation characteristics a prepreg using the resin composition, and a laminate and a metal foil-clad laminate using the prepreg is there.
- the present inventors have found that the epoxy resin (A), the curing agent (B), the first filler (C), the second filler (D), and the wetting and dispersing agent (E). And the first filler (C) is a borate particle coated with hexagonal boron nitride to solve the above problem. As a result, the present invention has been completed.
- the curing agent (B) is represented by the following general formula (II): (In the formula, R represents a hydrogen atom or a methyl group, and n represents an integer of 1 to 50.) The resin composition of 1 or 2 represented by these. 4).
- the epoxy resin (A) is represented by the following general formula (I): (In the formula, a plurality of R's are present independently and each represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a phenyl group. N is an average value and 1 ⁇ n ⁇ 20.)
- the second filler (D) is at least selected from the group consisting of alumina, magnesium oxide, magnesium carbonate, magnesium hydroxide, aluminum nitride, aluminum hydroxide, boehmite, titanium oxide, zinc oxide, silica, and talc. 5.
- the resin composition according to the present invention has good curability, and the laminate or metal foil-clad laminate obtained by curing the obtained prepreg has a high glass transition temperature, peel strength, solder heat resistance, moisture absorption heat resistance, Since it has excellent water absorption, flame retardancy, etc., and high thermal conductivity, it is suitable for printed wiring board materials that support high density, and industrial practicality is extremely high.
- the resin composition according to the present invention comprises an epoxy resin (A), a curing agent (B), a first filler (C), a second filler (D), and a wetting and dispersing agent (E
- the first filler (C) is borate particles coated with hexagonal boron nitride.
- the resin composition may further include other components such as a silane coupling agent and a maleimide compound.
- the resin composition by this invention is used suitably for preparation of the prepreg for printed wiring boards. Hereinafter, each component constituting the resin composition will be described.
- Epoxy resin (A) used in the present invention is not particularly limited as long as it is a compound having two or more epoxy groups in one molecule.
- the epoxy resin (A) used in the present invention is not particularly limited as long as it is a compound having two or more epoxy groups in one molecule.
- bisphenol A type epoxy resin bisphenol F type epoxy resin, phenol novolac type epoxy resin, cresol novolac type epoxy resin, bisphenol A novolak type epoxy resin, brominated bisphenol A type epoxy resin, brominated phenol novolak type epoxy.
- examples thereof include resins, biphenyl type epoxy resins, phenol aralkyl type epoxy resins, biphenyl aralkyl type epoxy resins, and naphthol aralkyl type epoxy resins. These epoxy resins can be used alone or in combination of two or more.
- the biphenyl aralkyl type epoxy resin and the naphthol aralkyl type epoxy resin represented by the general formula (I) are flame retardant, water absorption, adhesion, thermal expansion coefficient, dielectric constant, insulating property, heat resistance, moisture resistance. Etc. are preferable because of a good balance.
- R's are present independently and each represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a phenyl group.
- N is an average value and 1 ⁇ n ⁇ 20.
- the content of the epoxy resin (A) is not particularly limited, but from the viewpoint of flame retardancy, water absorption, adhesion, thermal expansion coefficient, dielectric constant, insulation, heat resistance, moisture resistance, etc., the epoxy resin (A ) And the curing agent (B) in a total amount of 100 parts by mass, preferably 10 to 90 parts by mass, more preferably 30 to 70 parts by mass.
- Curing agent (B) examples include phenol resin, bismaleimide triazine resin (BT resin), acid anhydride, amine, and cyanate ester resin.
- BT resin bismaleimide triazine resin
- amine acid anhydride
- cyanate ester resin a cyanate ester resin having a high glass transition temperature of the obtained cured product and being able to balance flame retardancy, water absorption, adhesion, thermal expansion coefficient, dielectric constant, insulation, heat resistance, moisture resistance and the like is preferable. .
- the phenol resin used as the curing agent (B) in the present invention is not particularly limited as long as it is a resin having two or more phenolic hydroxyl groups in one molecule.
- examples include phenol novolac resins, alkylphenol volac resins, bisphenol A novolac resins, dicyclopentadiene type phenol resins, Xylok type phenol resins, terpene modified phenol resins, polyvinyl phenols, aralkyl type phenol resins, and the like.
- a compound in which two or more hydrogen atoms bonded to an aromatic ring are substituted with a hydroxyl group is preferable. It can be used alone or in combination of two or more.
- the equivalent ratio of the hydroxyl group of the phenol resin to the epoxy group of the epoxy resin (A) (phenolic hydroxyl group / epoxy group, molar ratio) is curable, adhesive, and storage stability.
- 0.3 to 1.5 is preferable, 0.4 to 1.0 is more preferable, and 0.5 to 1.0 is still more preferable.
- the BT resin used as the curing agent (B) in the present invention is not particularly limited as long as it is a prepolymer having a maleimide compound and a cyanate ester compound as main components.
- a prepolymer having a maleimide compound and a cyanate ester compound as main components for example, 2,2-bis (4-cyanatophenyl) propane (CX, manufactured by Mitsubishi Gas Chemical Co., Inc.), bis (3-ethyl-5-methyl-4-maleimidophenyl) methane (BMI-70: K.I.
- the BT resin containing a naphthol aralkyl-type cyanate ester compound can maintain heat resistance from the characteristic that the resin skeleton has a rigid structure, and also reduces the reaction inhibition factor to increase curability, and absorbs water and heat. Can be preferably used because of its excellent characteristics.
- the cyanate ester compound which is a raw material of the BT resin can be used alone or in combination of two or more.
- Examples of the acid anhydride used as the curing agent (B) in the present invention include methylcyclohexanetetracarboxylic dianhydride, trimellitic anhydride, pyromellitic anhydride, benzophenonetetracarboxylic dianhydride, ethylene glycol bisan. And hydrotrimellitate. These can be used alone or in combination of two or more.
- the equivalent ratio of the acid anhydride group of the acid anhydride to the epoxy group of the epoxy resin (A) is curable. From the viewpoint of adhesiveness, storage stability, etc., 0.3 to 1.5 is preferable, 0.4 to 1.0 is more preferable, and 0.5 to 1.0 is still more preferable.
- Examples of the amine used as the curing agent (B) in the present invention include dicyandiamide, diaminodiphenylmethane, metaphenylenediamine, diaminodiphenylsulfone, isophoronediamine, norbornenediamine, and diaminodiethyldiphenylmethane. These can be used alone or in combination of two or more.
- the equivalent ratio (amine / epoxy group, molar ratio) of the amino group of the amine to the epoxy group of the epoxy resin (A) is such as curability, adhesiveness, and storage stability. From the viewpoint, 0.3 to 1.5 is preferable, 0.4 to 1.0 is more preferable, and 0.5 to 1.0 is still more preferable.
- the cyanate ester resin used as the curing agent (B) in the present invention is not particularly limited as long as it has two or more cyanato groups in one molecule, and known ones can be used.
- an ⁇ -naphthol aralkyl type cyanate ester resin represented by the following general formula (II) (may be a mixture of compounds having different n) has a high glass transition temperature, a water absorption rate, and a moisture absorption heat resistance. From the viewpoints of flame retardancy, low thermal expansion, high insulation, etc., it is particularly preferable.
- R represents a hydrogen atom or a methyl group
- n represents an integer of 1 to 50.
- the content of the curing agent (B) is not particularly limited, but is preferably 10 to 90 parts by mass, and 30 to 70 parts by mass with respect to 100 parts by mass in total of the epoxy resin (A) and the curing agent (B). More preferably, it is a part. It is preferably 10 parts by mass or more from the viewpoint of improving the heat resistance of the resulting laminate, and is preferably 90 parts by mass or less from the viewpoint of preventing a decrease in solvent solubility, curability, moisture resistance, and the like. *
- the first filler (C) used in the present invention is borate particles coated with hexagonal boron nitride, and preferably the borate particles are magnesium or calcium borate particles. It is.
- the borate particles coated with hexagonal boron nitride have a structure in which the core borate is coated with scale pen-like hexagonal boron nitride to form a shell.
- the ratio of the core part is preferably 10 to 80% in terms of the area occupation ratio of the cross section of the particle.
- the thickness of the shell part is preferably several to tens of ⁇ m.
- borate particles coated with hexagonal boron nitride can be used, for example, SGPS manufactured by Denki Kagaku.
- the borate particles coated with hexagonal boron nitride have good processability of the printed wiring board obtained from the resin composition, can improve thermal conductivity, and can have low thermal expansion.
- the graphite index (GI) of the first filler (C) is not particularly limited, but from the viewpoint of thermal conductivity, the graphite index (GI) of the first filler (C) by the powder X-ray diffraction method is 2.5. The following are particularly preferred.
- the content of the first filler (C) is 100 parts by mass in total of the epoxy resin (A) and the curing agent (B) from the viewpoint of thermal conductivity, thermal expansibility, workability, and appearance of the cured product.
- the amount is preferably 1 to 400 parts by mass, and more preferably 20 to 350 parts by mass.
- the second filler (D) used in the present invention is not particularly limited as long as it is generally used. Specific examples thereof include alumina, natural silica, fused silica, and amorphous silica. , Silicas such as hollow silica, aluminum hydroxide, aluminum hydroxide heat-treated products (heat treated with aluminum hydroxide and reduced in part of crystal water), boehmite, metal hydrates such as magnesium hydroxide, Molybdenum compounds such as molybdenum oxide and zinc molybdate, zinc borate, zinc stannate, aluminum oxide, clay, kaolin, magnesium oxide, aluminum nitride, silicon nitride, talc, calcined clay, calcined kaolin, calcined talc, mica, short glass Fibers (fine glass powders such as E glass and D glass), inorganic fillers such as hollow glass, and steel Emission type, butadiene type, rubber powder, such as acrylic type, core-shell rubber powder,
- alumina, aluminum hydroxide, aluminum hydroxide heat-treated product (aluminum hydroxide is heat-treated and part of the crystal water is reduced), boehmite, magnesium hydroxide and other metal water
- a hydrate, zinc borate, alumina, magnesium oxide, aluminum nitride, silicon nitride, calcined talc and the like are suitable, and among these, alumina is preferred from the viewpoint of thermal conductivity.
- the average particle diameter (D 50 ) of the second filler (D) is preferably 0.1 to 10 ⁇ m, and more preferably 0.2 to 7 ⁇ m.
- the second filler (D) can be used by appropriately combining those in which the particle size distribution and the average particle size are changed. More preferably, a spherical inorganic filler is suitable for reducing the specific surface area.
- the average particle diameter (D 50 ) is preferably 0.1 to 10 ⁇ m, and more preferably 0.2 to 7 ⁇ m.
- the fluidity of the resin composition can be kept good, and by using it together with the first filler (C), the volume ratio of the inorganic filler in the resin solid component is increased and the thermal conductivity is greatly increased.
- D 50 is a median diameter (median diameter), and is a diameter in which the larger side and the smaller side are equivalent when the particle size distribution of the measured powder is divided into two. Generally, it is measured by a wet laser diffraction / scattering method.
- the thermal conductivity of the resin composition can be further improved by using magnesium oxide or aluminum nitride in combination with alumina.
- the content of the second filler (D) is 100 parts by mass in total of the epoxy resin (A) and the curing agent (B) from the viewpoint of thermal conductivity, thermal expansibility, workability, and appearance of the cured product.
- the amount is preferably 1 to 700 parts by mass, and more preferably 50 to 600 parts by mass.
- wetting and dispersing agent (E) Although it does not specifically limit as a wet dispersing agent (E) used in this invention, The dispersion stabilizer currently used for coating materials can be used suitably.
- a polymer wetting and dispersing agent having an acid group is preferable, and a polymer wetting and dispersing agent having an acid value of 20 to 200 mgKOH / g is more preferable.
- Specific examples thereof include polymer wetting and dispersing agents manufactured by BYK Japan, Inc.
- the wetting and dispersing agent (E) can be used alone or in combination of two or more.
- the content of the wetting and dispersing agent (E) is not particularly limited, but from the viewpoint of the dispersibility of the inorganic filler and the glass transition temperature of the cured product, the total amount of the epoxy resin (A) and the curing agent (B) is 100 parts by mass. On the other hand, the amount is preferably 0.1 to 20 parts by mass, more preferably 0.5 to 10 parts by mass, and still more preferably 0.5 to 7 parts by mass. If content is 0.1 mass part or more, the effect of the dispersibility improvement of an inorganic filler can be improved more, and if content is 20 mass parts or less, the fall of the glass transition temperature of hardened
- the resin composition according to the present invention may further contain a silane coupling agent as long as desired properties are not impaired.
- the silanol group of the silane coupling agent has an affinity and reactivity with a material having a hydroxyl group on the surface, so it has an effect on the organic-inorganic bond, and the surface of the inorganic filler reacts with the silane coupling agent.
- the adhesion between the thermosetting resin and the inorganic filler is improved.
- the moisture absorption heat resistance and solder heat resistance of the printed wiring board may be improved.
- the content of the silane coupling agent is preferably 0.3 to 20 parts by mass, and 0.5 to 15 parts by mass with respect to 100 parts by mass in total of the epoxy resin (A) and the curing agent (B). More preferably. If content is 0.3 mass part or more, the adhesiveness of resin and an inorganic filler can be improved more, and if content is 20 mass parts or less, the fall of the glass transition temperature of hardened
- a curing accelerator can be used in combination so as to appropriately adjust the curing rate within the range where the desired properties are not impaired.
- curing accelerators for cyanate ester resins and epoxy resins.
- Specific examples thereof include lead naphthenate, lead stearate, zinc naphthenate, zinc octylate, tin oleate, dibutyltin malate, manganese octylate, cobalt naphthenate, iron acetylacetone, imidazoles, and the like. Derivatives thereof, tertiary amines and the like can be mentioned.
- the resin composition according to the present invention may further contain a maleimide compound as long as desired properties are not impaired.
- a maleimide compound as long as desired properties are not impaired.
- These are not particularly limited as long as they are compounds having two or more maleimide groups in one molecule.
- Specific examples thereof include bis (4-maleimidophenyl) methane, 2,2-bis ⁇ 4- (4-maleimidophenoxy) -phenyl ⁇ propane, bis (3,5-dimethyl-4-maleimidophenyl) methane, bis (3-ethyl-5-methyl-4-maleimidophenyl) methane, bis (3,5-diethyl-4-maleimidophenyl) methane, tris (4-maleimidophenyl) methane, prepolymers of these bismaleimide compounds, or bis A prepolymer of a maleimide compound and an amine compound, a bismaleimide triazine resin and the like can be mentioned, and one or two or
- bis (4-maleimidophenyl) methane 2,2-bis ⁇ 4- (4-maleimidophenoxy) -phenyl ⁇ propane, bis (3-ethyl-5-methyl-4-maleimidophenyl) Methane is mentioned.
- the resin composition according to the present invention includes other thermosetting resins, thermoplastic resins and oligomers thereof, various polymer compounds such as elastomers, and other flame retardant compounds as long as the desired properties are not impaired. And may further contain additives. These are not particularly limited as long as they are generally used.
- the flame retardant compound include phosphorous compounds such as phosphate esters and melamine phosphate, nitrogen-containing compounds such as melamine and benzoguanamine, oxazine ring-containing compounds, and silicon compounds.
- Additives include UV absorbers, antioxidants, photopolymerization initiators, optical brighteners, photosensitizers, dyes, pigments, thickeners, lubricants, antifoaming agents, dispersants, leveling agents, brighteners
- a polymerization inhibitor or the like can be used in appropriate combination as desired.
- the resin composition according to the present invention may further contain an organic solvent as long as desired properties are not impaired.
- the organic solvent is not particularly limited as long as it is compatible with a thermosetting resin (particularly a mixture of a cyanate ester resin and an epoxy resin).
- Specific examples include ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone, aromatic hydrocarbons such as benzene, toluene and xylene, amides such as dimethylformamide and dimethylacetamide, and the like.
- the resin composition according to the present invention can be prepared according to a conventional method, and the above-described epoxy resin (A), curing agent (B), first filler (C), second filler (D) and
- the preparation method is not particularly limited as long as it is a method by which a resin composition uniformly containing the wetting and dispersing agent (E) and the other optional components described above can be obtained.
- the epoxy resin (A), the curing agent (B), the first filler (C), the second filler (D), and the wetting and dispersing agent (E) are sequentially blended in a solvent and sufficiently stirred. Thereby, the resin composition of this embodiment can be prepared easily.
- an organic solvent can be used as necessary.
- the organic solvent can be dissolved or compatible with a mixture of epoxy resin (A), curing agent (B), first filler (C), second filler (D) and wetting and dispersing agent (E).
- A epoxy resin
- B curing agent
- C first filler
- D second filler
- E wetting and dispersing agent
- stirring and dispersing treatment is performed using a stirring tank provided with a stirrer having appropriate stirring ability.
- the above stirring, mixing, and kneading treatment can be appropriately performed using, for example, a known apparatus such as a ball mill or a bead mill for mixing, or a revolution / spinning mixing apparatus.
- the prepreg according to the present invention is obtained by impregnating or coating the above resin composition on a substrate.
- the method for producing a prepreg according to the present invention contains an epoxy resin (A), a curing agent (B), a first filler (C), a second filler (D) and a wetting and dispersing agent (E) as essential components. If it is the method of manufacturing a prepreg combining the resin composition to perform and a base material (F), it will not specifically limit. For example, a method of producing a prepreg by impregnating or applying the resin composition to the substrate (F) and then semi-curing it by a method of heating for 1 to 60 minutes in a dryer at 100 to 200 ° C. Be mentioned.
- the adhesion amount of the resin composition to the base material (F) is preferably in the range of 40 to 95% by mass in the ratio of the resin composition to the total amount of prepreg.
- the base material (F) used in the present invention known materials used for various printed wiring board materials can be used.
- inorganic fibers such as E glass, D glass, S glass, NE glass, and quartz
- organic fibers such as polyimide, polyamide, and polyester can be used. It is also possible to use in combination.
- poly (paraphenylenebenzobisoxazole) fiber is preferable from the viewpoint of thermal conductivity, tensile elastic modulus, and flame retardancy.
- the shape include woven fabric, non-woven fabric, roving, chopped strand mat, and surfacing mat.
- the thickness is not particularly limited, but usually about 0.01 to 0.3 mm is used.
- what surface-treated with the silane coupling agent etc., and what carried out the fiber opening process physically in the woven fabric can use it suitably from the surface of moisture absorption heat resistance.
- a film of polyimide, polyamide, polyester or the like can be used as the base material, and the thickness of the film is not particularly limited, but is preferably about 0.002 to 0.05 mm, and more preferably a surface treated by plasma treatment or the like. .
- the laminate or metal foil-clad laminate according to the present invention is formed by lamination using the prepreg described above. Specifically, it is manufactured by laminating one or more of the above-described prepregs and laminating with a configuration in which a metal foil such as copper or aluminum is arranged on one or both sides as desired.
- the metal foil to be used is not particularly limited as long as it is used for a printed wiring board material.
- As a molding condition a general laminated board for a printed wiring board and a multilayer board can be applied.
- the temperature is generally 100 to 300 ° C.
- the pressure is 2 to 100 kgf / cm 2
- the heating time is generally in the range of 0.05 to 5 hours. It is.
- ⁇ -naphthol aralkyl resin (SN485, OH group equivalent: 214 g / eq. Softening point: 86 ° C., Nippon Steel Chemical Co., Ltd.)
- a solution prepared by dissolving 20 g (0.0935 mol) and 14.16 g (0.14 mol) of triethylamine in 92 ml of methylene chloride was added dropwise over 1 hour using a dropping funnel. After completion of the addition, 4.72 g of triethylamine was further added. (0.047 mol) was added dropwise over 15 minutes.
- Example 1 40 parts by mass of the ⁇ -naphthol aralkyl type cyanate ester compound obtained in Synthesis Example 1 and 20 parts by mass of bis (3-ethyl-5-methyl-4-maleimidophenyl) methane (BMI-70, manufactured by KAI Kasei Co., Ltd.) Parts, biphenyl aralkyl type epoxy resin (NC-3000-FH, Nippon Kayaku Co., Ltd.) 40 parts by mass, silane coupling agent (Z6040, Toray Dow Corning Co., Ltd.) 10 parts by mass, acid group 5 parts by mass of a wetting and dispersing agent containing BYK-W903 (manufactured by Big Chemie Japan Co., Ltd.) is dissolved and mixed with methyl ethyl ketone, and spherical alumina (D 50 : 3.5 ⁇ m, AX3-15, Nippon Steel Materials Co., Ltd.) 400 parts by mass (produced by Micron) and
- This varnish was diluted with methyl ethyl ketone, impregnated with 47.2 g / m 2 of E glass cloth (Asahi Kasei E-Materials Co., Ltd.), dried by heating at 160 ° C. for 3 minutes, and a resin content of 82 mass. % Prepreg was obtained.
- 8 sheets of this prepreg were stacked, 12 ⁇ m electrolytic copper foils were placed one above the other, and pressed at a pressure of 30 kgf / cm 2 and a temperature of 220 ° C. for 120 minutes to obtain a copper-clad laminate having a thickness of 0.8 mm. .
- Solder heat resistance A sample obtained by cutting a copper-clad laminate into a size of 50 ⁇ 50 mm was floated in a solder bath at a temperature of 288 ° C., and the time until blistering was measured. The case where blistering did not occur for 30 minutes or more was designated as “ ⁇ ”, and the case where blistering occurred in less than 30 minutes was designated as “x”. 5) Water absorption rate: Based on JIS C6481, the water absorption rate after treatment at 121 ° C. and 2 atm for 5 hours was measured with a pressure cooker tester (PC-3 type, manufactured by Hirayama Seisakusho). 6) Glass transition temperature: Measured by DMA method according to JIS C6481. 7) Combustion test: Evaluated according to UL94 vertical combustion test method.
- Example 2 An experiment similar to that of Example 1 was performed except that 300 parts by mass of true spherical alumina (AX3-15) and 100 parts by mass of calcium borate particles (SGPS) coated with hexagonal boron nitride were used.
- AX3-15 true spherical alumina
- SGPS calcium borate particles coated with hexagonal boron nitride
- Example 3 Except for using 300 parts by mass of true spherical alumina (AX3-15), 300 parts by weight of true spherical alumina (D 50 : 3 ⁇ m, DAW-03, manufactured by Denki Kagaku Kogyo Co., Ltd.) was used. Experiments were performed.
- Example 4 An experiment similar to Example 2 was performed except that 300 parts by mass of non-spherical alumina (D 50 : 3 ⁇ m, AA-3, manufactured by Sumitomo Chemical Co., Ltd.) was used instead of 300 parts by mass of true spherical alumina (AX3-15). Carried out.
- non-spherical alumina D 50 : 3 ⁇ m, AA-3, manufactured by Sumitomo Chemical Co., Ltd.
- AX3-15 true spherical alumina
- Comparative Example 1 Instead of 50 parts by mass of calcium borate particles (SGPS) coated with hexagonal boron nitride, 50 parts by mass of scale pen-shaped boron nitride (D 50 : 9 ⁇ m, HP-1, manufactured by Mizushima Alloy Iron Co., Ltd.) is used. Except that, the same experiment as in Example 1 was performed.
- SGPS calcium borate particles
- HP-1 manufactured by Mizushima Alloy Iron Co., Ltd.
- Example 2 An experiment similar to that of Example 2 was conducted except that 100 parts by mass of scale pen-shaped boron nitride (HP-1) was used instead of 100 parts by mass of calcium borate particles (SGPS) coated with hexagonal boron nitride. did.
- HP-1 scale pen-shaped boron nitride
- SGPS calcium borate particles
- Example 4 The same experiment as in Example 2 was performed except that 100 parts by mass of scale pen-shaped boron nitride (HP-4W) was used instead of 100 parts by mass of calcium borate particles (SGPS) coated with hexagonal boron nitride. did.
- HP-4W scale pen-shaped boron nitride
- SGPS calcium borate particles
- Example 5 An experiment similar to that of Example 1 was performed except that 500 parts by mass of true spherical alumina (AX3-15) was used and calcium borate particles (SGPS) coated with hexagonal boron nitride were not used.
- AX3-15 true spherical alumina
- SGPS calcium borate particles coated with hexagonal boron nitride
- Example 6 The same experiment as in Example 1 was performed, except that the dispersant (BYK-W903) was not used.
Abstract
Description
1.エポキシ樹脂(A)と、
硬化剤(B)と、
第一の充填材(C)と、
第二の充填材(D)と、
湿潤分散剤(E)と
を含んでなり、該第一の充填材(C)が、六方晶窒化ホウ素で被覆されたホウ酸塩粒子である、樹脂組成物。
2.前記ホウ酸塩粒子が、マグネシウム又はカルシウムのホウ酸塩粒子である、1に記載の樹脂組成物。
3.前記硬化剤(B)が、下記一般式(II):
で表される、1又は2に記載の樹脂組成物。
4.前記エポキシ樹脂(A)が、下記一般式(I):
で表される、1~3のいずれかに記載の樹脂組成物。
5.前記第二の充填材(D)が、アルミナ、酸化マグネシウム、炭酸マグネシウム、水酸化マグネシウム、窒化アルミニウム、水酸化アルミニウム、ベーマイト、酸化チタン、酸化亜鉛、シリカ、及びタルクからなる群から選択される少なくとも一種である、1~4のいずれかに記載の樹脂組成物。
6.前記第二の充填材(D)の平均粒子径(D50)が、0.1~10μmである、1~5のいずれかに記載の樹脂組成物。
7.シランカップリング剤をさらに含んでなる、1~6のいずれかに記載の樹脂組成物。
8.前記第一の充填材(C)の含有量が、前記エポキシ樹脂(A)と前記硬化剤(B)の合計100質量部に対して、1~400質量部である、1~7のいずれかに記載の樹脂組成物。
9.前記第二の充填材(D)の含有量が、前記エポキシ樹脂(A)と前記硬化剤(B)の合計100質量部に対して、1~700質量部である、1~8のいずれかに記載の樹脂組成物。
10.前記湿潤分散剤(E)が、酸性基からなる官能基を1つ以上含むコポリマーからなる、1~9のいずれかに記載の樹脂組成物。
11.前記湿潤分散剤(E)は、酸価が20~200mgKOH/gである高分子湿潤分散剤である、1~10のいずれかに記載の樹脂組成物。
12.前記湿潤分散剤(E)の含有量が、前記成分(A)~(D)の合計100質量部に対して、0.1~20質量部である、1~11のいずれかに記載の樹脂組成物。
13.1~12のいずれかに記載の樹脂組成物を基材(F)に含浸または塗布させてなる、プリプレグ。
14.13に記載のプリプレグを積層成形してなる、積層板。
15.13に記載のプリプレグと、金属箔とを積層成形してなる、金属箔張積層板。
本発明による樹脂組成物は、エポキシ樹脂(A)と、硬化剤(B)と、第一の充填材(C)と、第二の充填材(D)と、湿潤分散剤(E)とを含んでなり、該第一の充填材(C)が、六方晶窒化ホウ素で被覆されたホウ酸塩粒子である。樹脂組成物は、シランカップリング剤およびマレイミド化合物等の他の成分をさらに含んでもよい。本発明による樹脂組成物は、プリント配線板用プリプレグの作製に好適に用いられる。以下、樹脂組成物を構成する各成分について説明する。
本発明において使用されるエポキシ樹脂(A)は、1分子中に2個以上のエポキシ基を有する化合物であれば、特に限定されるものではない。例えば、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、フェノールノボラック型エポキシ樹脂、クレゾールノボラック型エポキシ樹脂、ビスフェノールAノボラック型エポキシ樹脂、臭素化ビスフェノールA型エポキシ樹脂、臭素化フェノールノボラック型エポキシ樹脂、3官能フェノール型エポキシ樹脂、4官能フェノール型エポキシ樹脂、ナフタレン型エポキシ樹脂、ビフェニル型エポキシ樹脂、フェノールアラルキル型エポキシ樹脂、ビフェニルアラルキル型エポキシ樹脂、ナフトールアラルキル型エポキシ樹脂、脂環式エポキシ樹脂、ポリオール型エポキシ樹脂、リン含有エポキシ樹脂、グリシジルアミン、グリシジルエステル、ブタジエンなどの2重結合をエポキシ化した化合物、水酸基含有シリコン樹脂類とエピクロルヒドリンとの反応により得られる化合物等が挙げられる。好適なものとして、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、フェノールノボラック型エポキシ樹脂、クレゾールノボラック型エポキシ樹脂、ビスフェノールAノボラック型エポキシ樹脂、臭素化ビスフェノールA型エポキシ樹脂、臭素化フェノールノボラック型エポキシ樹脂、ビフェニル型エポキシ樹脂、フェノールアラルキル型エポキシ樹脂、ビフェニルアラルキル型エポキシ樹脂、ナフトールアラルキル型エポキシ樹脂が挙げられる。これらのエポキシ樹脂は、1種もしくは2種以上を適宜混合して使用することも可能である。この中でも特に、一般式(I)で表されるビフェニルアラルキル型エポキシ樹脂およびナフトールアラルキル型エポキシ樹脂が難燃性、吸水率、密着性、熱膨張率、誘電率、絶縁性、耐熱性、耐湿性等のバランスが良いため好ましい。
本発明において使用される硬化剤(B)は、フェノール樹脂、ビスマレイミドトリアジン樹脂(BT樹脂)、酸無水物、アミン、シアン酸エステル樹脂等が挙げられる。特に、得られた硬化物のガラス転移温度が高く、難燃性、吸水率、密着性、熱膨張率、誘電率、絶縁性、耐熱性、耐湿性等のバランスが取れるシアン酸エステル樹脂が好ましい。
本発明において使用される第一の充填材(C)は、六方晶窒化ホウ素で被覆されたホウ酸塩粒子であり、好ましくは該ホウ酸塩粒子がマグネシウム又はカルシウムのホウ酸塩粒子であるものである。
本発明において使用される第二の充填材(D)は、一般に使用されるものであれば、特に限定されるものではないが、その具体例としては、アルミナ、天然シリカ、溶融シリカ、アモルファスシリカ、中空シリカ等のシリカ類、水酸化アルミニウム、水酸化アルミニウム加熱処理品(水酸化アルミニウムを加熱処理し、結晶水の一部を減じたもの)、ベーマイト、水酸化マグネシウム等の金属水和物、酸化モリブデン、モリブデン酸亜鉛等のモリブデン化合物、ホウ酸亜鉛、錫酸亜鉛、酸化アルミニウム、クレー、カオリン、酸化マグネシウム、窒化アルミニウム、窒化ケイ素、タルク、焼成クレー、焼成カオリン、焼成タルク、マイカ、ガラス短繊維(EガラスやDガラスなどのガラス微粉末類)、中空ガラスなど無機系の充填材や、スチレン型、ブタジエン型、アクリル型などのゴムパウダー、コアシェル型のゴムパウダー、シリコーンレジンパウダー、シリコーンゴムパウダー、シリコーン複合パウダーなど有機系の充填材が挙げられる。特に熱伝導率を高めるために、アルミナ、水酸化アルミニウム、水酸化アルミニウム加熱処理品(水酸化アルミニウムを加熱処理し、結晶水の一部を減じたもの)、ベーマイト、水酸化マグネシウム等の金属水和物、ホウ酸亜鉛、アルミナ、酸化マグネシウム、窒化アルミニウム、窒化ケイ素、焼成タルクなどが好適で、その中でも熱伝導性の観点からアルミナであることが好ましい。
本発明において使用される湿潤分散剤(E)としては、特に限定されないが、塗料用に使用されている分散安定剤を好適に用いることができる。とりわけ、酸基を有する高分子湿潤分散剤が好ましく酸価が20~200mgKOH/gである高分子湿潤分散剤がより好ましい。その具体例としては、ビックケミー・ジャパン(株)製の高分子湿潤分散剤、例えば、BYK-W161、BYK-W903、BYK-W940、BYK-W996、BYK-W9010、Disper-BYK110、Disper-BYK111、Disper-BYK180等が挙げられるが、これらに特に限定されない。湿潤分散剤(E)は、1種を単独で或いは2種以上を組み合わせて使用することができる。
本発明による樹脂組成物は、所期の特性が損なわれない範囲において、シランカップリング剤をさらに含んでもよい。シランカップリング剤のシラノール基は、表面に水酸基を持つ素材と、特に親和性及び反応性を示すため、有機物-無機物の結合に効果があり、無機充填材の表面がシランカップリング剤と反応する場合には、熱硬化性樹脂と無機充填材の密着性が改善される。さらに、プリント配線板の吸湿耐熱性や半田耐熱性が改善される場合がある。
本発明によるプリプレグは、上記の樹脂組成物を基材に含浸または塗布してなるものである。本発明によるプリプレグの製造方法は、エポキシ樹脂(A)、硬化剤(B)、第一の充填材(C)、第二の充填材(D)および湿潤分散剤(E)を必須成分として含有する樹脂組成物と基材(F)とを組み合わせてプリプレグを製造する方法であれば、特に限定されない。例えば、上記樹脂組成物を基材(F)に含浸または塗布させた後、100~200℃の乾燥機中で、1~60分加熱させる方法などにより半硬化させ、プリプレグを製造する方法などが挙げられる。基材(F)に対する樹脂組成物の付着量は、プリプレグの総量に対する樹脂組成物の割合で40~95質量%の範囲が好ましい。
本発明による積層板又は金属箔張積層板は、上述のプリプレグを用いて積層成形したものである。具体的には前述のプリプレグを1枚あるいは複数枚以上を重ね、所望によりその片面もしくは両面に、銅やアルミニウムなどの金属箔を配置した構成で、積層成形することにより製造する。使用する金属箔は、プリント配線板材料に用いられるものであれば、特に限定されない。成形条件としては、通常のプリント配線板用積層板および多層板の手法が適用できる。例えば、多段プレス、多段真空プレス、連続成形、オートクレーブ成形機などを使用し、温度は100~300℃、圧力は2~100kgf/cm2、加熱時間は0.05~5時間の範囲が一般的である。また、本発明のプリプレグと、別途作成した内層用の配線板を組み合わせ、積層成形することにより、多層板とすることも可能である。
温度計、攪拌器、滴下漏斗及び還流冷却器を取りつけた反応器を予めブラインにより0~5℃に冷却しておき、そこへ塩化シアン7.47g(0.122mol)、35%塩酸9.75g(0.0935mol)、水76ml、及び塩化メチレン44mlを仕込んだ。
この反応器内の温度を-5~+5℃、pHを1以下を保ちながら、撹拌下、α-ナフトールアラルキル樹脂(SN485、OH基当量:214g/eq.軟化点:86℃、新日鐵化学(株)製)20g(0.0935mol)、及びトリエチルアミン14.16g(0.14mol)を塩化メチレン92mlに溶解した溶液を滴下漏斗により1時間かけて滴下し、滴下終了後、更にトリエチルアミン4.72g(0.047mol)を15分間かけて滴下した。
合成例1で得たα-ナフトールアラルキル型シアン酸エステル化合物40質量部と、ビス(3-エチル-5-メチル-4-マレイミドフェニル)メタン(BMI-70、ケイアイ化成(株)製)20質量部と、ビフェニルアラルキル型エポキシ樹脂(NC-3000-FH、日本化薬(株)製)40質量部と、シランカップリング剤(Z6040、東レダウコーニング(株)製)10質量部と、酸基を含む湿潤分散剤(BYK-W903、ビッグケミージャパン(株)製)5質量部とをメチルエチルケトンで溶解混合し、真球状アルミナ(D50:3.5μm、AX3-15、新日鉄マテリアルズ(株)マイクロン社製)400質量部と、六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(D50:12μm、窒化ホウ素純度80~85質量%、ホウ酸カルシウム純度15~20質量%、SGPS、電気化学工業(株)製)50質量部と、ニッカオクチックスマンガン(Mn8%)(日本化学産業(株)製)0.01質量部と、2,4,5-トリフェニルイミダゾール(東京化成工業(株)製)0.5質量部とを混合してワニスを得た。このワニスをメチルエチルケトンで希釈し、質量47.2g/m2のEガラスクロス(旭化成イーマテリアルズ(株)製)に含浸塗工し、160℃で3分間加熱乾燥して、樹脂含有量82質量%のプリプレグを得た。次に、このプリプレグを8枚重ね、12μmの電解銅箔を上下に配置し、圧力30kgf/cm2、温度220℃で120分間プレスを行い、厚さ0.8mmの銅張り積層板を得た。
1)熱伝導率:得られた積層板の密度を測定し、また、比熱をDSC(TA Instrumen Q100型)により測定し、さらに、キセノンフラッシュアナライザ(Bruker:LFA447Nanoflash)により面方向の熱拡散率を測定した。そして、面方向の熱伝導率を以下の式から算出した。
熱伝導率(W/m・K)=密度(kg/m3)×比熱(kJ/kg・K)×熱拡散率(m2/S)×1000
2)ピール強度:C6481プリント配線板用銅張積層板試験方法5.7引き剥がし強さ参照
3)吸湿耐熱性:50mm×50mmのサンプルの片面の半分以外の全銅箔をエッチング除去した試験片を、プレシッヤークッカー試験機(平山製作所製、PC-3型)で121℃、2気圧で3時間処理後、260℃の半田中に60秒浸漬した後の外観変化を目視で観察。(フクレ発生数/試験数)
4)半田耐熱性:銅張り積層板を50×50mmのサイズにカットした試料を、温度288℃の半田槽に浮かべて、ふくれが発生するまでの時間を測定した。30分以上ふくれが発生しないものを「○」、30分未満でふくれが発生したものを「×」とした。
5)吸水率:JIS C6481に準拠して、プレッシャークッカー試験機(平山製作所製、PC-3型)で121℃、2気圧で5時間処理後の吸水率を測定。
6)ガラス転移温度:JIS C6481に準拠して、DMA法にて測定。
7)燃焼試験:UL94垂直燃焼試験法に準拠して評価した。
真球状アルミナ(AX3-15)を300質量部、六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)を100質量部用いた以外は実施例1と同様の実験を実施した。
真球状アルミナ(AX3-15)300質量部の代わりに、真球状アルミナ(D50:3μm、DAW-03、電気化学工業(株)製)を300質量部使用した以外は実施例2と同様の実験を実施した。
真球状アルミナ(AX3-15)300質量部の代わりに、非球状アルミナ(D50:3μm、AA-3、住友化学工業製)を300質量部使用した以外は、実施例2と同様の実験を実施した。
六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)50質量部の代わりに、鱗ペン形状窒化ホウ素(D50:9μm、HP-1、水島合金鉄(株)製)を50質量部使用した以外は、実施例1と同様の実験を実施した。
六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)100質量部の代わりに、鱗ペン形状窒化ホウ素(HP-1)を100質量部使用した以外は、実施例2と同様の実験を実施した。
六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)50質量部の代わりに、鱗ペン形状窒化ホウ素(D50:6μm、HP-4W、水島合金鉄(株)製)を50質量部使用した以外は、実施例1と同様の実験を実施した。
六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)100質量部の代わりに、鱗ペン形状窒化ホウ素(HP-4W)を100質量部使用した以外は、実施例2と同様の実験を実施した。
真球状アルミナ(AX3-15)を500質量部用い、六方晶窒化ホウ素で被覆されたホウ酸カルシウム粒子(SGPS)を使用しなかった以外は、実施例1と同様の実験を実施した。
分散剤(BYK―W903)を使用しなかった以外は、実施例1と同様の実験を実施した。
Claims (15)
- エポキシ樹脂(A)と、
硬化剤(B)と、
第一の充填材(C)と、
第二の充填材(D)と、
湿潤分散剤(E)と
を含んでなり、該第一の充填材(C)が、六方晶窒化ホウ素で被覆されたホウ酸塩粒子である、樹脂組成物。 - 前記ホウ酸塩粒子が、マグネシウム又はカルシウムのホウ酸塩粒子である、請求項1に記載の樹脂組成物。
- 前記第二の充填材(D)が、アルミナ、酸化マグネシウム、炭酸マグネシウム、水酸化マグネシウム、窒化アルミニウム、水酸化アルミニウム、ベーマイト、酸化チタン、酸化亜鉛、シリカ、及びタルクからなる群から選択される少なくとも一種である、請求項1~4のいずれか一項に記載の樹脂組成物。
- 前記第二の充填材(D)の平均粒子径(D50)が、0.1~10μmである、請求項1~5のいずれか一項に記載の樹脂組成物。
- シランカップリング剤をさらに含んでなる、請求項1~6のいずれか一項に記載の樹脂組成物。
- 前記第一の充填材(C)の含有量が、前記エポキシ樹脂(A)と前記硬化剤(B)の合計100質量部に対して、1~400質量部である、請求項1~7のいずれか一項に記載の樹脂組成物。
- 前記第二の充填材(D)の含有量が、前記エポキシ樹脂(A)と前記硬化剤(B)の合計100質量部に対して、1~700質量部である、請求項1~8のいずれか一項に記載の樹脂組成物。
- 前記湿潤分散剤(E)が、酸性基からなる官能基を1つ以上含むコポリマーからなる、請求項1~9のいずれか一項に記載の樹脂組成物。
- 前記湿潤分散剤(E)は、酸価が20~200mgKOH/gである高分子湿潤分散剤である、請求項1~10のいずれか一項に記載の樹脂組成物。
- 前記湿潤分散剤(E)の含有量が、前記成分(A)~(D)の合計100質量部に対して、0.1~20質量部である、請求項1~11のいずれか一項に記載の樹脂組成物。
- 請求項1~12のいずれか一項に記載の樹脂組成物を基材(F)に含浸または塗布させてなる、プリプレグ。
- 請求項13に記載のプリプレグを積層成形してなる、積層板。
- 請求項13に記載のプリプレグと、金属箔とを積層成形してなる、金属箔張積層板。
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Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000196137A (ja) * | 1998-12-25 | 2000-07-14 | Kyocera Corp | 半導体発光装置およびその製造方法 |
JP2000223807A (ja) | 1999-02-04 | 2000-08-11 | Denki Kagaku Kogyo Kk | 高熱伝導性絶縁基板 |
JP2001122615A (ja) * | 1999-10-27 | 2001-05-08 | Denki Kagaku Kogyo Kk | 窒化ホウ素被覆球状ホウ酸塩粒子とそれを含む混合粉末、及びそれらの製造方法 |
JP2001348488A (ja) | 2000-06-06 | 2001-12-18 | Matsushita Electric Works Ltd | 熱伝導性樹脂組成物、プリプレグ、放熱性回路基板及び放熱性発熱部品 |
JP2006193607A (ja) * | 2005-01-13 | 2006-07-27 | Mitsubishi Gas Chem Co Inc | 樹脂組成物並びにこれを用いたプリプレグ及び積層板 |
JP2006348187A (ja) * | 2005-06-16 | 2006-12-28 | Mitsubishi Gas Chem Co Inc | 樹脂組成物並びにそれを用いたプリプレグおよび銅張積層板 |
JP2007045968A (ja) * | 2005-08-11 | 2007-02-22 | Mitsubishi Gas Chem Co Inc | 熱硬化性樹脂組成物 |
JP2007045984A (ja) * | 2005-08-12 | 2007-02-22 | Mitsubishi Gas Chem Co Inc | 難燃性樹脂組成物、並びにこれを用いたプリプレグ及び積層板 |
JP2008214602A (ja) * | 2007-02-07 | 2008-09-18 | Mitsubishi Gas Chem Co Inc | プリプレグ及び積層板 |
JP2009035728A (ja) * | 2007-07-12 | 2009-02-19 | Mitsubishi Gas Chem Co Inc | プリプレグ及び積層板 |
JP2010047450A (ja) * | 2008-08-22 | 2010-03-04 | Kaneka Corp | 六方晶窒化ホウ素及びその製造方法 |
JP2010059025A (ja) * | 2008-09-05 | 2010-03-18 | Kaneka Corp | 六方晶窒化ホウ素粉末の製造方法 |
JP2010229368A (ja) | 2009-03-30 | 2010-10-14 | Shin Kobe Electric Mach Co Ltd | エポキシ樹脂組成物並びにプリプレグ、積層板及び配線板 |
JP2011012193A (ja) | 2009-07-03 | 2011-01-20 | Denki Kagaku Kogyo Kk | 樹脂組成物及びその用途 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3685629B2 (ja) | 1998-12-11 | 2005-08-24 | 電気化学工業株式会社 | ホウ酸塩粒子、その粒子を含む無機粉末の製法及び用途 |
EP1961554B1 (en) | 2007-02-07 | 2010-01-27 | Mitsubishi Gas Chemical Company, Inc. | Prepreg and laminate |
SG10201605363VA (en) * | 2011-07-14 | 2016-08-30 | Mitsubishi Gas Chemical Co | Resin composition for printed wiring boards |
-
2012
- 2012-03-05 JP JP2013503544A patent/JP5999369B2/ja active Active
- 2012-03-05 US US14/001,752 patent/US9629239B2/en active Active
- 2012-03-05 KR KR1020137023260A patent/KR101867118B1/ko active IP Right Grant
- 2012-03-05 EP EP12754288.4A patent/EP2684904B1/en active Active
- 2012-03-05 SG SG2013053525A patent/SG191950A1/en unknown
- 2012-03-05 CN CN2012800115428A patent/CN103429633A/zh active Pending
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- 2012-03-05 WO PCT/JP2012/055600 patent/WO2012121224A1/ja active Application Filing
- 2012-03-07 TW TW101107703A patent/TWI572656B/zh active
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000196137A (ja) * | 1998-12-25 | 2000-07-14 | Kyocera Corp | 半導体発光装置およびその製造方法 |
JP2000223807A (ja) | 1999-02-04 | 2000-08-11 | Denki Kagaku Kogyo Kk | 高熱伝導性絶縁基板 |
JP2001122615A (ja) * | 1999-10-27 | 2001-05-08 | Denki Kagaku Kogyo Kk | 窒化ホウ素被覆球状ホウ酸塩粒子とそれを含む混合粉末、及びそれらの製造方法 |
JP2001348488A (ja) | 2000-06-06 | 2001-12-18 | Matsushita Electric Works Ltd | 熱伝導性樹脂組成物、プリプレグ、放熱性回路基板及び放熱性発熱部品 |
JP2006193607A (ja) * | 2005-01-13 | 2006-07-27 | Mitsubishi Gas Chem Co Inc | 樹脂組成物並びにこれを用いたプリプレグ及び積層板 |
JP2006348187A (ja) * | 2005-06-16 | 2006-12-28 | Mitsubishi Gas Chem Co Inc | 樹脂組成物並びにそれを用いたプリプレグおよび銅張積層板 |
JP2007045968A (ja) * | 2005-08-11 | 2007-02-22 | Mitsubishi Gas Chem Co Inc | 熱硬化性樹脂組成物 |
JP2007045984A (ja) * | 2005-08-12 | 2007-02-22 | Mitsubishi Gas Chem Co Inc | 難燃性樹脂組成物、並びにこれを用いたプリプレグ及び積層板 |
JP2008214602A (ja) * | 2007-02-07 | 2008-09-18 | Mitsubishi Gas Chem Co Inc | プリプレグ及び積層板 |
JP2009035728A (ja) * | 2007-07-12 | 2009-02-19 | Mitsubishi Gas Chem Co Inc | プリプレグ及び積層板 |
JP2010047450A (ja) * | 2008-08-22 | 2010-03-04 | Kaneka Corp | 六方晶窒化ホウ素及びその製造方法 |
JP2010059025A (ja) * | 2008-09-05 | 2010-03-18 | Kaneka Corp | 六方晶窒化ホウ素粉末の製造方法 |
JP2010229368A (ja) | 2009-03-30 | 2010-10-14 | Shin Kobe Electric Mach Co Ltd | エポキシ樹脂組成物並びにプリプレグ、積層板及び配線板 |
JP2011012193A (ja) | 2009-07-03 | 2011-01-20 | Denki Kagaku Kogyo Kk | 樹脂組成物及びその用途 |
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JP2015534596A (ja) * | 2012-09-19 | 2015-12-03 | モーメンティブ・パフォーマンス・マテリアルズ・インク | 熱伝導性プラスチックを製造するための熱伝導性プラスチック組成物、押出装置および方法 |
WO2014084226A1 (ja) * | 2012-11-28 | 2014-06-05 | 三菱瓦斯化学株式会社 | 樹脂組成物、プリプレグ、積層板、金属箔張積層板、及びプリント配線板 |
US10178767B2 (en) | 2012-11-28 | 2019-01-08 | Mitsubishi Gas Chemical Company, Inc. | Resin composition, prepreg, laminate, metallic foil clad laminate, and printed circuit board |
JPWO2014084226A1 (ja) * | 2012-11-28 | 2017-01-05 | 三菱瓦斯化学株式会社 | 樹脂組成物、プリプレグ、積層板、金属箔張積層板、及びプリント配線板 |
JP2015013949A (ja) * | 2013-07-05 | 2015-01-22 | 株式会社トクヤマ | 樹脂組成物及びその製造方法、高熱伝導性樹脂成型体 |
US10791626B2 (en) | 2013-09-09 | 2020-09-29 | Mitsubishi Gas Chemcial Company, Inc. | Prepreg, metal foil-clad laminate, and printed wiring board |
EP3045283A4 (en) * | 2013-09-09 | 2017-05-10 | Mitsubishi Gas Chemical Company, Inc. | Prepreg, metal foil-clad laminate, and printed circuit board |
EP3045283A1 (en) * | 2013-09-09 | 2016-07-20 | Mitsubishi Gas Chemical Company, Inc. | Prepreg, metal foil-clad laminate, and printed circuit board |
US10373727B2 (en) | 2013-10-09 | 2019-08-06 | Hitachi Chemical Company, Ltd | Prepreg mica tape and coil using same |
US20150105497A1 (en) * | 2013-10-11 | 2015-04-16 | Nan Ya Plastics Corporation | Inorganic filler coated with molybdenum compound and usage thereof |
JP2015093975A (ja) * | 2013-11-14 | 2015-05-18 | 住友ベークライト株式会社 | 金属張積層板、プリント配線基板、および半導体装置 |
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US9859189B2 (en) | 2014-02-03 | 2018-01-02 | Sumitomo Bakelite Co., Ltd. | Thermally conductive sheet and semiconductor device |
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Also Published As
Publication number | Publication date |
---|---|
EP2684904A4 (en) | 2014-08-27 |
KR101867118B1 (ko) | 2018-06-12 |
EP2684904A1 (en) | 2014-01-15 |
US9629239B2 (en) | 2017-04-18 |
EP2684904B1 (en) | 2017-01-11 |
SG191950A1 (en) | 2013-08-30 |
KR20140047581A (ko) | 2014-04-22 |
TWI572656B (zh) | 2017-03-01 |
JP5999369B2 (ja) | 2016-09-28 |
TW201302885A (zh) | 2013-01-16 |
JPWO2012121224A1 (ja) | 2014-07-17 |
CN103429633A (zh) | 2013-12-04 |
SG10201600443SA (en) | 2016-02-26 |
US20130337269A1 (en) | 2013-12-19 |
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