WO2012118162A1 - 重合液、この重合液から得られた導電性ポリマーフィルム及び固体電解コンデンサ - Google Patents
重合液、この重合液から得られた導電性ポリマーフィルム及び固体電解コンデンサ Download PDFInfo
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- WO2012118162A1 WO2012118162A1 PCT/JP2012/055285 JP2012055285W WO2012118162A1 WO 2012118162 A1 WO2012118162 A1 WO 2012118162A1 JP 2012055285 W JP2012055285 W JP 2012055285W WO 2012118162 A1 WO2012118162 A1 WO 2012118162A1
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- Prior art keywords
- polymerization
- polymerization solution
- monomer
- conductive polymer
- water
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0036—Formation of the solid electrolyte layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/50—Physical properties
- C08G2261/51—Charge transport
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
Definitions
- the present invention relates to a polymerization liquid for electrolytic polymerization that gives a conductive polymer having a low environmental load and excellent economical efficiency and high heat resistance.
- the present invention also relates to a conductive polymer film and a solid electrolytic capacitor obtained from this polymerization solution.
- Conductive polymers obtained by polymerization of monomers having a ⁇ -conjugated double bond such as thiophene, aniline, and pyrrole are excellent in conductivity and suitable for various electrochemical applications, including solid electrolytic capacitors, It has been applied to a wide range of fields such as polymer batteries, antistatic films, display elements, sensors, and electrode materials.
- the conductive polymer is preferably used.
- the polymerization liquid for electrolytic polymerization used to obtain these conductive polymers usually contains a monomer having a ⁇ -conjugated double bond, a supporting electrolyte, and a solvent for dissolving them. It is.
- Patent Document 1 Japanese Patent Laid-Open No. 61-239617 discloses a method for obtaining a conductive polymer layer by electrolytic polymerization of aniline substituted with an alkyl group or an alkoxyl group. Water is used as the solvent.
- Patent Document 2 Japanese Patent Application Laid-Open No. 1-313521) discloses 3,4-ethylenedioxythiophene (hereinafter 3,4-ethylenedioxythiophene is represented as “EDOT”, and poly (3,4-ethylenedioxythiophene).
- Patent Document 3 Japanese Patent Laid-Open No. 3-18009 discloses a solid electrolytic capacitor including a conductive polymer layer formed by electrolytic polymerization of unsubstituted pyrrole.
- acetonitrile or water is a polymerization solution. It is used as a solvent.
- Patent Document 4 Japanese Patent Application Laid-Open No. 2010-374666 discloses a dopant released from a conventionally proposed supporting electrolyte such as perchlorate ion, p-toluenesulfonate ion, and borodisalicylate ion in paragraph 0026.
- Patent Document 5 Japanese Patent Laid-Open No. 2000-269087 discloses the use of an aqueous medium polymerization solution obtained by emulsifying a thiophene derivative with an alkylnaphthalene sulfonic acid surfactant for the production of a solid electrolytic capacitor. Yes.
- Non-Patent Document 1 lecture collection “Synthesis of Highly Functional Conducting Polymers (PPy, PEDOT, etc.) and Application Development to Electronic / Energy Devices and Future Prospects”, pp30-33) describes the electropolymerization of pyrrole.
- sodium triisopropylnaphthalene sulfonate is used as the supporting electrolyte.
- an organic solvent as a solvent for the polymerization solution generally increases the environmental burden and is economically disadvantageous as compared with the use of a water solvent. Furthermore, many organic solvents are harmful to the human body. In the case of electrolytic polymerization using a flammable solvent, it is necessary to take measures to prevent a fire due to electric sparks. Therefore, it is preferable to use water as the solvent for the polymerization solution, and it is also preferable to use an inexpensive one that dissolves the supporting electrolyte in the aqueous solvent.
- borodisalicylic acid and / or its salt is relatively inexpensive and economically advantageous, while borodisalicylic acid and / or its salt is dissolved in water. It is known that when the mixture is stirred, precipitation occurs rapidly, or precipitation occurs gradually without stirring. Therefore, when borodisalicylic acid and / or a salt thereof is selected as a supporting electrolyte in the electropolymerization of a monomer having a ⁇ -conjugated double bond, an organic solvent has been selected.
- Patent Document 6 Japanese Patent Application Laid-Open No.
- 2-588178 discloses a solid electrolytic capacitor by electrolytic polymerization using a polymerization liquid containing an organic solvent, a monomer such as pyrrole, and an alkyl-substituted ammonium borodisalicylate as a supporting electrolyte.
- alkyl substituted ammonium borodisalicylate is selected as a supporting electrolyte that dissolves in an organic solvent.
- This document also shows that a polymer film having a problem in terms of thermal stability can be obtained from a polymerization liquid using ammonium borodisalicylate having low solubility in an organic solvent as a supporting electrolyte and using a solvent obtained by adding water to the organic solvent. It is described.
- JP 61-239617 A Japanese Unexamined Patent Publication No. 1-313521 JP-A-3-18009 JP 2010-37466 A JP 2000-269087 A Japanese Patent Laid-Open No. 2-58818
- FIG. 1 shows an FT-IR spectrum of a precipitate formed when ammonium borodisalicylate is dissolved in water, compared with FT-IR spectra of salicylic acid and boric acid. From this figure, it can be seen that the precipitate contains salicylic acid and boric acid.
- the obtained conductive polymer film and solid electrolytic capacitor were obtained from a polymerization solution containing an anionic surfactant having a sulfonic acid group or a sulfonic acid group as described in Patent Document 5 and Non-Patent Document 1.
- Patent Document 6 describes that the addition of water to the polymerization solution lowers the heat resistance of the polymer film, but considering this, the results of the above-described experiment are surprising.
- an object of the present invention is to provide a polymer solution containing water as a main solvent and having a ⁇ -conjugated double bond, and borodisalicylic acid and / or a salt thereof as a supporting electrolyte.
- An object of the present invention is to provide a polymerization solution that suppresses the formation of precipitates due to hydrolysis and gives a conductive polymer having high heat resistance.
- the inventors have found that the above-described object can be achieved by allowing a suitable amount of nitrobenzene and / or a nitrobenzene derivative to coexist in the polymerization solution as a stabilizer.
- the present invention first involves a solvent comprising 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent, at least one monomer having a ⁇ -conjugated double bond, borodisalicylic acid and borodisalicylic acid.
- a polymerization liquid for electrolytic polymerization of the above-mentioned monomer comprising at least one supporting electrolyte selected from the group consisting of salts and at least one stabilizer selected from the group consisting of nitrobenzene and nitrobenzene derivatives.
- the present invention relates to a polymerization liquid characterized in that the content of the stabilizer is more than 1/8 mol with respect to 1 mol of the supporting electrolyte.
- water-rich solvent A solvent composed of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent is hereinafter referred to as “water-rich solvent”.
- water-rich solvent the total amount of water and the organic solvent is 100% by mass.
- the water content in the water-rich solvent may be 80% by mass or more, preferably 90% by mass or more, more preferably 95% by mass or more, and particularly 100% by mass. preferable.
- FIG. 2 shows an aqueous solution in which ammonium borodisalicylate is dissolved at a concentration of 0.267 mM, an aqueous solution in which p-nitrophenol is dissolved at a concentration of 0.083 mM, and ammonium borodisalicylate and p-nitrophenol, respectively.
- 2 shows UV spectra for aqueous solutions dissolved at concentrations of 0.267 mM and 0.083 mM. In the UV spectrum of the aqueous solution of ammonium borodisalicylate, the maximum absorption is observed at 298 nm, and in the UV spectrum of the aqueous solution of p-nitrophenol, at 317 nm.
- a group consisting of a water-rich solvent, at least one monomer having a ⁇ -conjugated double bond, at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylate, and nitrobenzene and a nitrobenzene derivative Even when the electrolytic polymerization is repeated using a polymerization solution containing at least one stabilizer selected from the above, no precipitation occurs in the polymerization solution, and the obtained conductive polymer contains borodisalicylic acid and / or Just as the conductive polymer obtained from the polymerization solution containing no stabilizer immediately after the salt was dissolved (before the precipitation occurred), it showed excellent heat resistance.
- the formation of the complex suppresses hydrolysis of the borodisalicylate ion, and the borodisalicylate ion is contained in the conductive polymer film as a dopant in the process of electrolytic polymerization. It was thought that the electroconductive polymer film which has was obtained.
- the at least one stabilizer selected from the group consisting of nitrobenzene and nitrobenzene derivatives may be a single compound or a mixture of two or more, but the saturated dissolution amount in the polymerization solution is 1 mol of the supporting electrolyte.
- the compound which is 1/8 mol or less with respect to the other compounds is used as a mixture with other compounds. If the amount of the stabilizer is 1/8 mol or less with respect to 1 mol of the supporting electrolyte, the effect of suppressing precipitation formation may not be sufficient.
- the content of the stabilizer is preferably 1 ⁇ 4 or more, more preferably 1 ⁇ 2 mol or more, and particularly preferably 1 mol or more with respect to 1 mol of the supporting electrolyte.
- a readily water-soluble stabilizer is preferable, and at least one compound selected from the group consisting of o-nitrophenol, m-nitrophenol, and p-nitrophenol is particularly preferable. Since the stabilizer is used to form a complex with borodisalicylate ion and suppress precipitation formation due to hydrolysis of borodisalicylate ion, at least borodisalicylic acid and / or a salt thereof. Almost simultaneously with the water-rich solvent, preferably added to the water-rich solvent before the borodisalicylic acid and / or its salt.
- Patent Document 4 The use of nitrobenzene or a derivative thereof in a polymerization solution for electrolytic polymerization is described in Patent Document 4, Patent Document 5, and Non-Patent Document 1.
- Patent Document 4 and Non-Patent Document 1 p-nitrophenol is added to a polymerization solution for producing polypyrrole.
- Non-Patent Document 1 the polymerization structure of polypyrrole may change due to the action of p-nitrophenol.
- Patent Document 5 describes that the use of nitrobenzene or a derivative thereof provides a highly ordered thiophene derivative polymer having a developed conjugated length.
- the effect of nitrobenzene or a derivative thereof in the present invention is an effect of suppressing precipitation formation by hydrolysis of borodisalicylate ion by forming a complex with borodisalicylate ion, and nitrobenzene or a derivative thereof in these documents The effect is different.
- a monomer having a saturated dissolution amount or less is contained in the polymerization solution, and the whole amount of the monomer may be dissolved in the polymerization solution, but an amount of monomer exceeding the saturation dissolution amount is contained in the polymerization solution.
- the monomer which is dissolved and cannot be dissolved may be dispersed as oil droplets in the polymerization liquid.
- this document contains at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylate used in the present invention and at least one stable electrolyte selected from the group consisting of nitrobenzene and nitrobenzene derivatives.
- the polymerization liquid of the present invention can further contain a water-soluble nonionic surfactant. Since the monomer is concentrated in the micelles of the nonionic surfactant, electrolytic polymerization proceeds rapidly, and a polymer exhibiting high conductivity is obtained. Further, since the nonionic surfactant itself is not ionized, doping with a dopant is not inhibited, and formation of a complex between the stabilizer and a borodisalicylate ion is not inhibited. For this reason, the conductive polymer film obtained from the polymerization liquid containing no nonionic surfactant and the conductive polymer film obtained from the polymerization liquid containing nonionic surfactant exhibit the same heat resistance.
- nonionic surfactant known nonionic surfactants can be used without any particular limitation, but a combination of an alkyne diol having a high dispersion effect and another nonionic surfactant, preferably polyoxyethylene alkylphenyl ether. Is preferably used in the polymerization solution because the monomer content in the polymerization solution can be greatly increased.
- the present invention also relates to a conductive polymer film obtained by introducing a substrate having a conductive portion into the polymerization liquid of the present invention and performing electrolytic polymerization.
- the polymerization liquid of the present invention further comprises an anode in which an oxide film as a dielectric is provided on the surface of a valve metal foil such as aluminum, tantalum, or niobium, and a conductive material that is in contact with the oxide film and acts as a true cathode. It can be suitably used for producing a solid electrolytic capacitor including a polymer layer.
- a solid electrolytic capacitor is produced before the precipitation is formed using a polymerization solution containing only borodisalicylic acid and / or borodisalicylate and not containing the stabilizer, and further a solid electrolytic capacitor is produced after the precipitation is produced.
- the ESR of the solid electrolytic capacitor obtained from the polymer solution after the precipitation is higher than the ESR of the solid electrolytic capacitor obtained from the polymer solution before the precipitation, but this increase is suppressed by the combined use of the stabilizer. Therefore, it becomes possible to manufacture a solid electrolytic capacitor with high reproducibility by repeatedly using the same polymerization solution.
- the present invention is also a solid electrolytic capacitor comprising an anode made of a valve metal foil having an oxide film on the surface, and a conductive polymer layer provided on the anode, wherein the conductive polymer layer is the above-mentioned
- the present invention relates to a solid electrolytic capacitor according to a first embodiment, which is formed by introducing an anode into the polymerization solution of the present invention and performing electrolytic polymerization.
- a conductive layer (apparent cathode) is provided on the conductive polymer, and the solid electrolytic capacitor of the first form is configured.
- the present invention also includes an anode made of a valve metal foil having an oxide film on the surface, a cathode made of the valve metal foil, and a separator holding a conductive polymer layer disposed between the anode and the cathode.
- a solid electrolytic capacitor comprising: a capacitor element in which the conductive polymer layer includes the anode, the cathode, and a separator disposed therebetween; and introduced into the polymerization solution of the present invention.
- the present invention relates to a solid electrolytic capacitor according to a second embodiment, which is formed by impregnating a liquid and performing electrolytic polymerization. The conductive polymer layer is held on the separator by electrolytic polymerization. By this method, a wound type or stacked type solid electrolytic capacitor can be obtained.
- a monomer conventionally used for producing a conductive polymer can be used as long as it is stable in a water-rich solvent.
- EDOT EDOT
- a PEDOT film having excellent heat resistance, visible light transparency (transparency), high conductivity and high electrochemical capacity is obtained, and particularly low tan ⁇ .
- the polymerization solution of the present invention containing at least one kind of stabilizing agent is capable of forming a precipitate by hydrolysis of borodisalicylic acid ions in a water-rich solvent by forming a complex of the stabilizing agent and borodisalicylic acid ions. Therefore, it can be repeatedly used for electrolytic polymerization, has a small environmental load, and is excellent in economic efficiency. Moreover, by using the polymerization liquid of the present invention, a conductive polymer film and a solid electrolytic capacitor having excellent heat resistance can be obtained.
- 2 is an FT-IR spectrum of a precipitate formed by hydrolysis of ammonium borodisalicylate.
- 2 is a UV spectrum of ammonium borodisalicylate, p-nitrophenol, and mixtures thereof.
- the polymerization solution for electrolytic polymerization of the present invention was selected from the group consisting of a water-rich solvent, at least one monomer having a ⁇ -conjugated double bond, borodisalicylic acid and borodisalicylate. It contains at least one supporting electrolyte and at least one stabilizer selected from nitrobenzene and nitrobenzene derivatives as essential components.
- water that has a low environmental load and is economically superior is used as a main solvent.
- the polymerization liquid of the present invention may contain an organic solvent such as methanol, ethanol, isopropanol, butanol, ethylene glycol, acetonitrile, acetone, tetrahydrofuran, and methyl acetate. More than% is water. Water is preferably 90% by mass or more of the whole solvent, more preferably 95% by mass or more of the whole solvent, and particularly preferably the solvent consists of water alone. When the content of the organic solvent in the water-rich solvent increases, a conductive polymer film in which polymer particles are densely packed becomes difficult to be formed on the electrode by electrolytic polymerization, and the content of the organic solvent is reduced to 20% by mass of the whole solvent. When exceeding, the heat resistance of the obtained conductive polymer film and solid electrolytic capacitor will fall remarkably.
- an organic solvent such as methanol, ethanol, isopropanol, butanol, ethylene glycol, acetonitrile, acetone, tetrahydrofuran, and
- a monomer having a ⁇ -conjugated double bond is used as the monomer.
- a monomer having a ⁇ -conjugated double bond conventionally used for the production of a conductive polymer can be used as long as it is stable in a water-rich solvent. Examples of typical monomers are shown below. These monomers may be used alone or as a mixture of two or more.
- thiophene and thiophene derivatives for example, 3-alkylthiophene such as 3-methylthiophene and 3-ethylthiophene, 3,4-dialkylthiophene such as 3,4-dimethylthiophene and 3,4-diethylthiophene, 3-methoxy 3-alkoxythiophene such as thiophene, 3-ethoxythiophene, 3,4-dialkoxythiophene such as 3,4-dimethoxythiophene, 3,4-diethoxythiophene, 3,4-methylenedioxythiophene, EDOT, 3, 3,4-alkylenedioxythiophene such as 4- (1,2-propylenedioxy) thiophene, 3,4-methyleneoxythiathiophene, 3,4-ethyleneoxythiathiophene, 3,4- (1,2- 3,4-Al, such as propyleneoxythia) thiophene 3,4-alkylene dithiathioph
- N-alkylpyrrole such as N-methylpyrrole and N-ethylpyrrole
- 3-alkylpyrrole such as 3-methylpyrrole and 3-ethylpyrrole
- 3-methoxypyrrole 3-ethoxypyrrole
- 3-alkoxypyrrole N-phenylpyrrole, N-naphthylpyrrole, 3,4-dimethylpyrrole, 3,4-diethylpyrrole, 3,4-dialkylpyrrole, 3,4-dimethoxypyrrole, 3,4- 3,4-dialkoxypyrrole such as diethoxypyrrole
- aniline and aniline derivatives such as 2,5-dialkylaniline such as 2,5-dimethylaniline and 2-methyl-5-ethylaniline, 2,5-dimethoxyaniline, 2-methoxy-5-ethoxyaniline and the like
- 2,3,5-trialkoxyaniline such as 2,5-dialkoxyaniline, 2,3,5-trimethoxyaniline, 2,3,5-triethoxyaniline, 2,3,5,6-tetramethoxyaniline
- 2,3,5,6-tetraalkoxyaniline such as 2,3,5,6-tetraethoxyaniline
- Furan and furan derivatives for example, 3-alkylfurans such as 3-methylfuran and 3-ethylfuran, 3,4-dialkylfurans such as 3,4-dimethylfuran and 3,4-diethylfuran, 3-methoxy 3-Alkoxyfuran such as furan and 3-ethoxyfuran, 3,4-dialkoxyfuran such as 3,4-dimethoxyfuran and 3,4-diethoxyfuran can be used.
- the monomer it is preferable to use a monomer selected from thiophene having substituents at the 3-position and 4-position.
- the substituents at the 3-position and 4-position of the thiophene ring may form a ring together with the carbons at the 3-position and 4-position.
- EDOT electrospray dioxide
- the polymerization solution of the present invention contains a compound selected from the group consisting of borodisalicylic acid and borodisalicylate as a supporting electrolyte. These compounds may be used alone or as a mixture of two or more. Borodisalicylic acid and / or borodisalicylate is used at a concentration not higher than the saturated dissolution amount in the polymerization solution and in an amount capable of obtaining a sufficient current for electrolytic polymerization, preferably 10 mM or more, particularly preferably 30 mM or more. Used in concentration.
- borodisalicylate examples include ammonium salt, alkylammonium salt such as ethylammonium salt and butylammonium salt, dialkylammonium salt such as diethylammonium salt and dibutylammonium salt, triethylammonium salt and tributylammonium salt.
- Tetraalkylammonium salts such as trialkylammonium salts, tetraethylammonium salts, tetrabutylammonium salts, alkali metal salts such as lithium salts, sodium salts, potassium salts, alkaline earth metals such as magnesium salts, calcium salts Salt.
- the polymerization liquid of the present invention further includes nitrobenzene and / or a nitrobenzene derivative having a function of forming a complex with borodisalicylate ions and suppressing precipitation due to hydrolysis of borodisalicylate ions in a water-rich solvent.
- nitrobenzene and / or a nitrobenzene derivative having a function of forming a complex with borodisalicylate ions and suppressing precipitation due to hydrolysis of borodisalicylate ions in a water-rich solvent.
- the stabilizer is used at a concentration equal to or less than the saturated dissolution amount in the polymerization solution, and in an amount exceeding 1/8 mol with respect to 1 mol of the supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylate. used.
- the stabilizer may be a single compound or two or more compounds, but the compound whose saturation dissolution amount in the polymerization solution is 1/8 mol or less with respect to 1 mol of the supporting electrolyte. Is used in admixture with other compounds. If the amount of the stabilizer is 1/8 mol or less with respect to 1 mol of the supporting electrolyte, the effect of suppressing precipitation formation may not be sufficient.
- the content of the stabilizer is preferably 1 ⁇ 4 or more, more preferably 1 ⁇ 2 mol or more, and particularly preferably 1 mol or more with respect to 1 mol of the supporting electrolyte.
- nitrobenzene derivatives include nitrophenol, nitrobenzyl alcohol, nitrobenzoic acid, dinitrobenzoic acid, dinitrobenzene, nitroanisole, and nitroacetophenone.
- the stabilizer is preferably a readily water-soluble compound, and o-nitrophenol, m-nitrophenol, p-nitrophenol, and mixtures thereof are particularly preferable.
- the polymerization solution is prepared by the following method depending on the monomer content.
- a water-rich solvent, monomer, borodisalicylic acid and / or salt thereof, and nitrobenzene and / or derivative thereof are introduced into a container for producing a polymerization solution
- the polymerization solution is prepared by dissolving each component in a water-rich solvent using a mechanical stirring means.
- the amount of the monomer exceeds the saturated dissolution amount, that is, a water-rich solvent, a monomer, borodisalicylic acid and / or a salt thereof, and nitrobenzene and / or a derivative thereof are introduced into a container for producing a polymerization solution.
- the polymerization solution can be prepared by dispersing the phase-separated monomer as oil droplets in the polymerization solution by subjecting the solution to ultrasonic irradiation.
- Ultrasonic irradiation is applied to a solution obtained by adding a monomer exceeding the saturated dissolution amount in a water-rich solvent to disperse the monomer as oil droplets, and then borodisalicylic acid and / or a salt thereof and nitrobenzene and / or
- the polymerization liquid of the present invention can also be obtained by adding the derivative.
- an ultrasonic oscillator conventionally known for ultrasonic cleaners, cell grinders and the like can be used without particular limitation.
- the phase-separated monomer must be oil droplets having a diameter of several ⁇ m or less.
- the output of the ultrasonic wave is preferably 4 W / cm 2 or more.
- the ultrasonic irradiation time is not strictly limited but is preferably in the range of 2 to 10 minutes.
- the longer the irradiation time the more the aggregation of monomer oil droplets is inhibited, and the time until demulsification tends to be longer.
- the ultrasonic irradiation time is 10 minutes or more, the aggregation effect of oil droplets tends to be saturated. Is recognized. It is also possible to perform multiple irradiations using ultrasonic waves having different frequencies and / or outputs.
- the monomer content exceeding the saturated dissolution amount may be an amount that can obtain a dispersion in which demulsification is suppressed by ultrasonic irradiation.
- ultrasonic irradiation conditions It also changes depending on.
- the polymerization solution of the present invention includes a water-rich solvent, at least one monomer having a ⁇ -conjugated double bond, at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylate, and nitrobenzene and nitrobenzene.
- at least one stabilizer selected from the group consisting of derivatives other additives may be included as long as they do not adversely affect the present invention. Suitable additives include water-soluble nonionic surfactants. Since the monomer is concentrated in the micelles of the nonionic surfactant, electrolytic polymerization proceeds rapidly, and a polymer exhibiting high conductivity is obtained.
- the nonionic surfactant itself does not ionize, does not inhibit doping of the polymer with the borodisalicylate anion, and does not inhibit the formation of the complex between the stabilizer and the borodisalicylate ion. Therefore, the heat resistance of the conductive polymer obtained by electrolytic polymerization does not decrease.
- nonionic surfactant a known water-soluble nonionic surfactant can be used without any particular limitation.
- examples include polyalkylene glycol, polyvinyl alcohol, polyoxyalkylene alkyl ether, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene styryl phenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene-added alkylphenol formaldehyde condensate, polyoxyalkylene Addition styrylphenol formaldehyde condensate, polyoxyalkylene addition benzylphenol formaldehyde condensate, alkyne diol, polyoxyalkylene addition alkyne diol, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene castor oil, polyoxyalkylene hydrogenated castor oil , Polyglycerin alkyl agent Le, such as polyglyce
- alkyne diol having high dispersion effect such as 2,4,7,9-tetramethyl-5-decyne-4,7-diol and other nonionic surfactants, preferably polyoxyethylene (9) nonyl
- alkyne diol having high dispersion effect such as 2,4,7,9-tetramethyl-5-decyne-4,7-diol and other nonionic surfactants, preferably polyoxyethylene (9) nonyl
- a combination with a polyoxyethylene alkylphenyl ether such as a phenyl ether branched type in the polymerization liquid is preferable because the monomer content in the polymerization liquid can be greatly increased.
- a water-rich solvent, a monomer, borodisalicylic acid and / or a salt thereof, nitrobenzene and / or a derivative thereof, and a nonionic surfactant are introduced into a container for producing a polymerization solution.
- a polymerization solution is prepared by dissolving each component in a water-rich solvent by hand or using a mechanical stirring means or irradiating ultrasonic waves.
- a water-rich solvent, a monomer, nitrobenzene and / or a derivative thereof, and a nonionic surfactant are introduced into a container for producing a polymerization solution, and after preparing a solution in which each component is dissolved in a water-rich solvent, electrolysis is performed. Immediately before the polymerization, borodisalicylic acid and / or a salt thereof may be added and dissolved in this solution.
- nitrobenzene and / or a derivative thereof are added to a water-rich solvent at least almost simultaneously with borodisalicylic acid and / or a salt thereof, and preferably water-rich before borodisalicylic acid and / or a salt thereof. Add to solvent. If each component in the polymerization solution is stable, there is no limitation on the temperature during preparation.
- the polymerization solution of the present invention water is used as the main solvent.
- inexpensive borodisalicylic acid and / or a salt thereof is used as a supporting electrolyte, and precipitation formation by hydrolysis of borodisalicylic acid ions is suppressed by inexpensive nitrobenzene and / or a derivative thereof, and this polymerization solution is used repeatedly. Electropolymerization can be performed. Therefore, the polymerization liquid of the present invention is an economically advantageous polymerization liquid with a small environmental load.
- Electrolytic polymerization A conductive polymer having high heat resistance is formed by electrolytic polymerization using the polymerization liquid of the present invention. Electropolymerization using the polymerization solution of the present invention is carried out for forming a conductive polymer film in various applications in addition to forming a conductive polymer layer in a solid electrolytic capacitor.
- electrolytic polymerization for forming a general conductive polymer film and electrolytic polymerization for forming a conductive polymer layer in a solid electrolytic capacitor will be described separately.
- a working electrode substrate of the conductive polymer film
- a material having at least a conductive portion on the surface is used.
- Platinum, nickel A conductive plate such as titanium, steel, carbon, foil, net, sintered body, foam or the like can be used.
- a transparent substrate in which a vapor-deposited layer of semiconductor ceramics such as tin-doped indium oxide (ITO), tin oxide, or fluorine-doped tin oxide is provided on the surface of transparent and insulating glass or plastic can be used as a working electrode.
- ITO tin-doped indium oxide
- tin oxide tin oxide
- fluorine-doped tin oxide fluorine-doped tin oxide
- the electrolytic polymerization is performed by any one of a constant potential method, a constant current method, and a potential sweep method using the polymerization solution of the present invention.
- a potential of 1.0 to 1.5 V is suitable for the saturated calomel electrode
- a current value of 1 to 10000 ⁇ A / cm 2 is suitable, and in the case of the potential sweep method, depending on the type of monomer, the range of 0 to 1.5 V with respect to the saturated calomel electrode is 5 to 200 mV / It is preferred to sweep at a rate of seconds.
- a conductive polymer film is preferably formed on the substrate with a thickness of 0.001 to 50 ⁇ m.
- the polymerization temperature is not strictly limited, but is generally in the range of 10 to 60 ° C.
- the polymerization time is generally in the range of 0.6 seconds to 10 hours.
- PEDOT film having extremely high transparency polymerization by a constant current method is performed at a current value of 5 to 500 ⁇ A / cm 2 , preferably 10 to 100 ⁇ A / cm 2 , for 0.6 to 120 seconds, preferably 6 to Preferably it is performed for 60 seconds.
- a highly transparent PEDOT film having a thickness of 0.001 to 0.05 ⁇ m, preferably 0.003 to 0.035 ⁇ m can be obtained.
- the conductive polymer film after electrolytic polymerization is washed with water, ethanol or the like and dried, whereby a conductive polymer film having excellent electrochemical activity and excellent heat resistance can be obtained on the substrate. Since the conductive polymer film of the present invention is excellent in adhesion to the substrate, it can be used as it is placed on the substrate. The relatively thick conductive polymer film should be peeled off from the substrate. You can also.
- the transparent electrode described above When the transparent substrate described above is used as a substrate and a transparent PEDOT film is formed on the substrate, the transparent electrode has excellent heat resistance, high conductivity, and high electrochemical capacity as it is disposed on the substrate.
- This transparent electrode can be suitably used as a component of various electronic devices such as an organic electroluminescence device and a touch panel display.
- the PEDOT film can be peeled from the substrate to form a conductive transparent film, which can be suitably used as a self-supporting and flexible transparent electrode, and has high transparency on an insulating plastic tray or plastic sheet. By applying the PEDOT film, charging can be prevented without affecting the appearance.
- anodes aluminum foils, tantalum foils, niobium foils, valve metal foils such as titanium foils, preferably aluminum foils, are etched by chemical or electrochemical techniques to expand the surface. Furthermore, a chemical conversion treatment using an aqueous solution of ammonium adipate, an aqueous solution of ammonium phosphate, or the like to form an oxide film on the surface of the valve metal foil is used.
- the conductive polymer layer may be directly formed on the oxide film using the leakage current of the oxide film of the anode, or may be formed on a conductive film provided in advance on the oxide film.
- the conductive polymer layer may be formed after the anode oxide film is brought into contact with a corrosive gas such as a halogen gas or a corrosive liquid such as an acid aqueous solution to form electrical microdefects in the oxide film.
- the anode oxide film may be immersed in an aqueous manganese nitrate solution and then thermally decomposed at 300 to 400 ° C. to form a manganese oxide layer on the surface of the oxide film, and then a conductive polymer layer may be formed.
- the chemical polymerization film is formed by preparing a solution in which both the monomer and the oxidizing agent are dissolved in a solvent such as water, methanol, ethanol, isopropanol, butanol, and acetonitrile, and applying this solution by brush painting, dropping coating, dip coating, spraying.
- a solvent such as water, methanol, ethanol, isopropanol, butanol, and acetonitrile
- the oxidizing agent examples include trivalent iron salts such as iron (III) paratoluenesulfonate, iron (III) naphthalenesulfonate, and iron (III) anthraquinonesulfonate, or peroxydisulfuric acid ammonium, peroxodisulfate sodium and the like.
- trivalent iron salts such as iron (III) paratoluenesulfonate, iron (III) naphthalenesulfonate, and iron (III) anthraquinonesulfonate, or peroxydisulfuric acid ammonium, peroxodisulfate sodium and the like.
- a sulfate or the like can be used, and a single compound may be used, or two or more compounds may be used.
- an anode in which conductivity is imparted to the oxide film is introduced into the polymerization solution of the present invention together with the counter electrode to perform electrolytic polymerization.
- a counter electrode for electrolytic polymerization a platinum plate, a nickel plate, or the like can be used.
- the electrolytic polymerization is performed by any one of a constant potential method, a constant current method, and a potential sweep method.
- a potential of 1.0 to 1.5 V is suitable for the saturated calomel electrode
- a current value of 1 to 10000 ⁇ A / cm 2 is suitable, and in the case of the potential sweep method, depending on the type of monomer, the range of 0 to 1.5 V with respect to the saturated calomel electrode is 5 to 200 mV / It is preferred to sweep at a rate of seconds.
- the polymerization temperature is not strictly limited, but is generally in the range of 10 to 60 ° C.
- the polymerization time is generally in the range of 1 minute to 10 hours.
- the conductive polymer layer formed on the anode is washed with water, ethanol, etc., dried, and then a conductive layer (apparent cathode) is formed on the conductive polymer layer with carbon paste, silver paste, etc.
- the solid electrolytic capacitor of the 1st form excellent in can be obtained.
- (C) Solid electrolytic capacitor of the second embodiment An anode made of a valve metal foil having an oxide film on the surface, a cathode made of the valve metal foil, and a conductive polymer layer disposed between the anode and the cathode were held.
- an anode made of a valve metal foil having an oxide film on the surface, a cathode made of the valve metal foil, the anode and the cathode A capacitor element including a separator disposed between the two is obtained.
- a valve metal foil such as an aluminum foil, a tantalum foil, a niobium foil, or a titanium foil, preferably an aluminum foil, is chemically or electrochemically used.
- the surface of the valve metal foil is formed by performing chemical treatment using an adipate aqueous solution, an ammonium phosphate aqueous solution, or the like by performing an etching treatment by a technique and further performing chemical conversion treatment using an aqueous solution of ammonium adipate or an aqueous solution of ammonium phosphate.
- a valve metal foil such as an aluminum foil, a tantalum foil, a niobium foil, a titanium foil, and preferably an aluminum foil, which has been subjected to etching treatment by a chemical or electrochemical technique, is used.
- the separator Manila paper, kraft paper, synthetic fiber paper, glass paper, glass paper and manila paper, mixed paper of kraft paper, or the like can be used.
- the anode and cathode are wound or laminated through a separator to obtain a capacitor element.
- a solution in which both a monomer and an oxidizing agent are dissolved in a solvent such as water, methanol, ethanol, isopropanol, butanol, acetonitrile, and the like is prepared.
- a chemically polymerized film is formed on the cathode surface.
- the oxidizing agent examples include trivalent iron salts such as iron (III) paratoluenesulfonate, iron (III) naphthalenesulfonate, and iron (III) anthraquinonesulfonate, or peroxydisulfuric acid ammonium, peroxodisulfate sodium and the like.
- trivalent iron salts such as iron (III) paratoluenesulfonate, iron (III) naphthalenesulfonate, and iron (III) anthraquinonesulfonate, or peroxydisulfuric acid ammonium, peroxodisulfate sodium and the like.
- a sulfate or the like can be used, and a single compound may be used, or two or more compounds may be used.
- This element is washed with water, ethanol or the like and dried, and then introduced into the polymerization solution of the present invention to perform electrolytic polymerization.
- the electrolytic polymerization is performed by any one of a constant potential method, a constant current method, and a potential sweep method.
- a potential of 1.0 to 1.5 V is suitable for the saturated calomel electrode
- a current value of 1 to 10000 ⁇ A / cm 2 is suitable, and in the case of the potential sweep method, depending on the type of monomer, the range of 0 to 1.5 V with respect to the saturated calomel electrode is 5 to 200 mV / It is preferred to sweep at a rate of seconds.
- the polymerization temperature is not strictly limited, but is generally in the range of 10 to 60 ° C.
- the polymerization time is generally in the range of 1 minute to 10 hours.
- the conductive polymer layer held on the separator is washed with water, ethanol or the like and dried to obtain a solid electrolytic capacitor of the second form excellent in heat resistance.
- the first solid electrolytic capacitor and the second solid electrolytic capacitor in the present invention have a reduced tan ⁇ and ESR, and exhibit excellent heat resistance.
- Comparative experiment 2 Three liquids were prepared by adding 4-hydroxyacetophenone of different concentrations and 0.08M ammonium borodisalicylate to 50 mL of distilled water and dissolving them. The concentration of 4-hydroxyacetophenone was 0.010M, 0.050M or 0.100M. These solutions were left overnight. Precipitation occurred in any liquid. Therefore, it was speculated that the effect of suppressing precipitation formation in Experiments 1 and 2 was not due to the hydroxy group.
- Comparative experiment 3 A mixture of different concentrations of 9: 1 molar ratio of 4-hydroxyacetophenone and 2-hydroxybenzoic acid and 0.08M ammonium borodisalicylate were dissolved in 50 mL of distilled water. A seed solution was prepared. The concentration of the mixture was 0.010M, 0.050M or 0.100M in total for both compounds. These solutions were left overnight. Precipitation occurred in any liquid. Therefore, it was speculated that the effect of suppressing precipitation in Experiment 3 was not due to the hydroxy group and carboxy group.
- Example 1 Distilled water (50 mL) was introduced into a glass container, and 0.113 g (concentration: 0.016 M) of EDOT was added to this solution, followed by stirring at 25 ° C. for 60 minutes to obtain a solution in which the entire amount of EDOT was dissolved in water. To this solution, 0.7 g (concentration 0.1 M) of p-nitrophenol and 1.08 g of ammonium borodisalicylate (concentration 0.08 M) were added in this order, and the mixture was stirred uniformly, and EDOT, p- A polymerization solution in which nitrophenol and ammonium borodisalicylate were dissolved in water was obtained. Even when the obtained liquid was allowed to stand at room temperature for 1 day, no precipitation was observed.
- Example 2 The same procedure as in Example 1 was repeated except that 0.35 g (concentration 0.05M) of p-nitrophenol was used. Even when the obtained liquid was allowed to stand at room temperature for 1 day, no precipitation was observed.
- Example 3 The same procedure as in Example 1 was repeated except that 0.14 g (concentration 0.02M) of p-nitrophenol was used. Even when the obtained liquid was allowed to stand at room temperature for 1 day, no precipitation was observed.
- Example 4 Distilled water (50 mL) was introduced into a glass container, and 0.14 g (concentration: 0.02 M) of EDOT was added to this solution to obtain a solution in which EDOT was phase-separated from water.
- this liquid was irradiated with ultrasonic waves having a frequency of 20 kHz and an output of 2.6 W / cm 2 for 5 minutes, an emulsion in which EDOT was dispersed in water as oil droplets was obtained.
- the size of the EDOT oil droplet of this liquid was measured by a dynamic light scattering method at 25 ° C., the average diameter of the oil droplets was 214 nm in number average.
- Example 5 Distilled water (50 mL) was introduced into a glass container, and nonionic surfactant 2,4,7,9-tetramethyl-5-decyne-4,7-diol was added to this solution in an amount of 0.4% by mass. Further, 0.18 g of EDOT (concentration 0.025M), 0.35 g of p-nitrophenol (concentration 0.05M), and 1.08 g of ammonium borodisalicylate (concentration 0.08M) were added and polymerized by stirring uniformly. A liquid was obtained. The amount of the monomer corresponds to almost the maximum amount of the monomer that can be dissolved in the aqueous solution containing the surfactant.
- EDOT concentration 0.025M
- p-nitrophenol concentration 0.05M
- ammonium borodisalicylate concentration 0.08M
- Example 6 Distilled water (50 mL) was introduced into a glass container, and polyoxyethylene (9) nonylphenyl ether branched type, which is a nonionic surfactant, was added to the liquid in an amount of 1.0% by mass. 03M), 0.35 g of p-nitrophenol (concentration 0.05M) and 1.08 g of ammonium borodisalicylate (concentration 0.08M) were added and stirred uniformly to obtain a polymerization solution. The amount of the monomer corresponds to almost the maximum amount of the monomer that can be dissolved in the aqueous solution containing the surfactant.
- polyoxyethylene (9) nonylphenyl ether branched type which is a nonionic surfactant
- Example 7 Distilled water (50 mL) was introduced into a glass container, and 0.4% by mass of 2,4,7,9-tetramethyl-5-decyne-4,7-diol, a nonionic surfactant, and polyoxyethylene ( 9) A nonylphenyl ether branched type was added in an amount of 1.0% by mass, and 0.57 g (concentration 0.08M) of EDOT, 0.35 g of p-nitrophenol (concentration 0.05M), and ammonium borodisalicylate 1 0.08 g (concentration 0.08M) was added and stirred uniformly to obtain a polymerization solution. The amount of the monomer corresponds to almost the maximum amount of the monomer that can be dissolved in the aqueous solution containing the surfactant.
- Comparative Example 1 The same procedure as in Example 1 was repeated except that 0.07 g (concentration 0.01 M) of p-nitrophenol was used. When the obtained liquid was allowed to stand at room temperature for 1 day, a slight amount of precipitation was observed. In the comparative experiment of electropolymerization shown below, a solution containing no precipitate immediately after the addition of p-nitrophenol and ammonium borodisalicylate was used.
- Comparative Example 2 When 1.08 g (concentration: 0.08M) of ammonium borodisalicylate was added to a solution in which only EDOT used in Example 1 was dissolved in water and stirred, a large amount of precipitate was immediately formed. This precipitate was poorly water-soluble salicylic acid and boric acid (see FIG. 1). In the comparative experiment of electropolymerization shown below, a solution containing no precipitate immediately after adding ammonium borodisalicylate was used.
- Electrolytic Polymerization I Production and Evaluation of Solid Electrolytic Capacitor Example 8
- the etched aluminum foil was converted to a film withstand voltage of 3 V and then punched out to a projected area of 1 ⁇ 1 cm 2 to form an anode.
- This anode was immersed in an ethanol solution containing 20% by mass of EDOT and then dried at room temperature. Subsequently, it was immersed in an ethanol solution containing 20 mass% of para-toluenesulfonic acid iron (III) as an oxidizing agent, dried at room temperature for 10 minutes, and then subjected to a high temperature treatment.
- This chemical oxidative polymerization process was repeated to form a PEDOT chemical polymerized film on the anode oxide film.
- the anode having the PEDOT chemical polymerization film thus obtained was subjected to a re-chemical conversion treatment in an aqueous solution of ammonium adipate, then washed with water and dried.
- an anode provided with a PEDOT chemical polymerization film was used as a working electrode, a Pt foil having an area of 4 cm ⁇ 4 cm as a counter electrode, and a silver-silver chloride electrode as a reference electrode, and 0.5 mA.
- Constant current electrolytic polymerization was performed for 60 minutes under a current condition of / cm 2 . Even after the polymerization was completed, no precipitation was observed in the polymerization solution, and repeated polymerization was possible using the same polymerization solution.
- the polymerized membrane was washed with ethanol, washed with water, and dried. Finally, a graphite paste was applied on the PEDOT electropolymerization layer and dried, and then a silver paste was applied and dried to obtain a solid electrolytic capacitor having an anode with a film withstand voltage of 3V.
- Example 9 The procedure of Example 8 was repeated using the polymerization solution of Example 2 instead of the polymerization solution of Example 1. Even after the polymerization was completed, no precipitation was observed in the polymerization solution, and repeated polymerization was possible using the same polymerization solution.
- Example 10 The procedure of Example 8 was repeated using the polymerization solution of Example 4 instead of the polymerization solution of Example 1. Even after the polymerization was completed, no precipitation was observed in the polymerization solution, and repeated polymerization was possible using the same polymerization solution.
- Comparative Example 3 The procedure of Example 8 was repeated using the polymerization solution of Comparative Example 1 (before precipitation) instead of the polymerization solution of Example 1. Precipitation began to form in the polymerization solution during the polymerization, and repeated polymerization using the same polymerization solution was difficult.
- Comparative Example 4 The procedure of Example 8 was repeated using the polymerization solution of Comparative Example 2 (before precipitation) instead of the polymerization solution of Example 1. Precipitation began to form in the polymerization solution during the polymerization, and repeated polymerization using the same polymerization solution was impossible.
- Comparative Example 5 50 mL of water is introduced into a glass container, and 0.14 g (concentration 0.02M) of EDOT and 1.08 g (concentration 0.08M) of sodium butylnaphthalenesulfonate, which is a surfactant having a sulfonate group, are added to this solution. The mixture was stirred at 25 ° C. for 60 minutes to obtain a polymerization solution. Then, using this polymerization solution, the anode provided with the chemical polymerization film of PEDOT used in Example 8 was used as a working electrode, a Pt foil having an area of 4 cm ⁇ 4 cm was used as a counter electrode, and a silver-silver chloride electrode was used as a reference electrode.
- Constant current electropolymerization was carried out for 60 minutes under a current condition of 0.5 mA / cm 2 .
- the polymerized membrane was washed with ethanol, washed with water, and dried.
- a graphite paste was applied on the PEDOT electropolymerization layer and dried, and then a silver paste was applied and dried to obtain a solid electrolytic capacitor having an anode with a film withstand voltage of 3V.
- Comparative Example 6 Using the anode provided with the chemical polymerization film of PEDOT used in Example 8, a slurry in which PEDOT and polystyrene sulfonic acid separately prepared were dispersed on the chemical polymerization film of this anode was applied and dried. Finally, on the layer obtained from the slurry in which PEDOT and polystyrene sulfonic acid are dispersed, a graphite paste is applied and dried, and then a silver paste is applied and dried, thereby providing an anode having a coating pressure resistance of 3V. A solid electrolytic capacitor was obtained.
- Real-capacity appearance rate means a capacity appearance rate calculated based on the capacity of the oxide film after the formation of the PEDOT chemical polymerization film and the electrolytic polymerization layer.
- AmBS represents ammonium borodisalicylate
- p-Nph represents p-nitrophenol.
- the capacitors of Examples 8 to 10 and Comparative Examples 3 and 4 are comparative examples having a PEDOT layer doped with anions of an anionic surfactant having a sulfonate group or a sulfonate group. Compared to capacitors 5 and 6, the Real-capacity appearance rate was high. In addition, the capacitors of Examples 8 to 10 and Comparative Example 4 exhibited excellent capacitor characteristics in which both tan ⁇ and ESR were lower than those of Comparative Examples 5 and 6. Table 1 also shows that the capacitors of Examples 8 to 10 have lower ESR than the capacitors of Comparative Examples 3 and 4.
- the ESR of the capacitors of Comparative Examples 5 and 6 reached 16 times and 22 times the initial value after experiencing a high temperature of 150 ° C. for 600 hours, respectively, whereas the capacitors of Examples 8 to 10 and Comparative Example 4 The ESR was only 6.4 to 6.5 times the initial value even after experiencing a high temperature of 150 ° C. for 600 hours.
- the Real-capacity appearance rate of the capacitors of Examples 8 to 10 and Comparative Examples 4 and 6 was maintained at about 90% of the initial value even after experiencing a high temperature of 150 ° C. for 600 hours.
- the Real-capacity appearance rate of the capacitor of Comparative Example 5 decreased to 70% of the initial value after experiencing a high temperature of 150 ° C. for 600 hours.
- a solid electrolytic capacitor having a PEDOT layer obtained from a polymerization solution obtained by adding ammonium borodisalicylate as a supporting electrolyte to water is a PEDOT doped with an anionic surfactant having a sulfonic acid group or a sulfonic acid group. It has been found that it has better heat resistance than a conventional solid electrolytic capacitor having a layer. Although this excellent effect has not been known so far, the polymerization solution (Comparative Example 2) used in the production of the capacitor of Comparative Example 4 was repeatedly polymerized using the same polymerization solution due to the above-mentioned precipitation problem. It was impossible.
- the polymerization solutions (Examples 1, 2 and 4) used in the production of the solid electrolytic capacitors of Examples 8 to 10 do not have such a precipitation problem and should be used repeatedly for polymerization. I was able to.
- the heat resistance of the solid electrolytic capacitors of Examples 8 to 10 was the same as that of the capacitor of Comparative Example 4, and showed significantly improved heat resistance as compared with the capacitors of Comparative Examples 5 and 6.
- the capacitor of Example 8 shows substantially the same initial characteristics and thermal durability as the capacitor of Example 10, and even when the EDOT in the polymerization solution is less than or equal to the saturation dissolution amount, the capacitor exceeds the saturation dissolution amount. Even in such a case, it was found that a capacitor having equivalent initial characteristics and excellent heat resistance can be obtained.
- Electropolymerization II Production and Evaluation of Solid Electrolytic Capacitor Example 11
- the etched aluminum foil was converted to a film withstand voltage of 3 V and then punched out to a projected area of 1 ⁇ 1 cm 2 to form an anode.
- This anode was immersed in an ethanol solution containing 20% by mass of EDOT and then dried at room temperature. Subsequently, it was immersed in an ethanol solution containing 20 mass% of para-toluenesulfonic acid iron (III) as an oxidizing agent, dried at room temperature for 10 minutes, and then subjected to a high temperature treatment.
- This chemical oxidative polymerization process was repeated to form a PEDOT chemical polymerized film on the anode oxide film.
- the anode having the PEDOT chemical polymerization film thus obtained was subjected to a re-chemical conversion treatment in an aqueous solution of ammonium adipate, then washed with water and dried.
- Distilled water 50 mL was introduced into a glass container, and 0.104 g (concentration: 0.0147 M) of EDOT was added to this solution, followed by stirring at 25 ° C. for 60 minutes to obtain a solution in which the entire amount of EDOT was dissolved in water.
- 0.35 g of p-nitrophenol (concentration 0.05M) and 1.08 g of ammonium borodisalicylate (concentration 0.08M) were added in this order, and stirred uniformly to obtain a polymerization solution. It was.
- an anode provided with a PEDOT chemical polymerization film was used as a working electrode, a Pt foil having an area of 4 cm ⁇ 4 cm as a counter electrode, a silver-silver chloride electrode as a reference electrode, and a current of 1 mA / cm 2 Constant current electropolymerization was performed for 30 minutes under the conditions. Even after the polymerization was completed, no precipitation was observed in the polymerization solution, and repeated polymerization was possible using the same polymerization solution.
- the polymerized membrane was washed with ethanol, washed with water, and dried. Finally, a graphite paste was applied on the PEDOT electropolymerization layer and dried, and then a silver paste was applied and dried to obtain a solid electrolytic capacitor having an anode with a film withstand voltage of 3V.
- Example 12 The procedure of Example 11 was repeated using the polymerization solution of Example 5 instead of the polymerization solution used in Example 11.
- Example 13 The procedure of Example 11 was repeated using the polymerization solution of Example 6 instead of the polymerization solution used in Example 11.
- Example 14 The procedure of Example 11 was repeated using the polymerization solution of Example 7 instead of the polymerization solution used in Example 11.
- Comparative Example 7 50 mL of water was introduced into a glass container, 2.7% by weight of sodium butylnaphthalenesulfonate as an anionic surfactant was added to this liquid, and 0.21 g of EDOT (concentration 0.03M) was added. The mixture was stirred uniformly to obtain a polymerization solution. The amount of the monomer corresponds to almost the maximum amount of the monomer that can be dissolved in the aqueous solution containing the surfactant mixture.
- the anode provided with the chemical polymerization film of PEDOT used in Example 11 was used as a working electrode, a Pt foil having an area of 4 cm ⁇ 4 cm as a counter electrode, and a silver-silver chloride electrode as a reference electrode.
- Constant current electropolymerization was carried out for 30 minutes under a current condition of 1.0 mA / cm 2 .
- the polymerized membrane was washed with ethanol, washed with water, and dried.
- a graphite paste was applied on the PEDOT electropolymerization layer and dried, and then a silver paste was applied and dried to obtain a solid electrolytic capacitor having an anode with a film withstand voltage of 3V.
- ESR decreases as the monomer concentration in the polymerization solution increases due to the combined use of the nonionic surfactant, and in Example 14 the monomer concentration significantly increases. -Increased capacity appearance rate. This is because the monomer is concentrated in the micelles of the nonionic surfactant, so that the electropolymerization progresses rapidly and a polymer showing high conductivity is obtained, and the nonionic surfactant is doped with the dopant. This is considered to reflect no adverse effects.
- the solid electrolytic capacitor obtained from the polymerization solution containing the nonionic surfactant of Examples 12 to 14 was almost the same as the solid electrolytic capacitor obtained from the polymerization solution of Example 11 containing no nonionic surfactant. It showed the same heat resistance. Therefore, it was determined that the nonionic surfactant did not inhibit the complex formation between p-nitrophenol and borodisalicylate ion and did not inhibit the polymer doping by borodisalicylate anion.
- the solid electrolytic capacitor of Comparative Example 7 obtained from the polymerization solution using an anionic surfactant as the supporting electrolyte was significantly inferior in heat resistance as compared with the solid electrolytic capacitors of Examples 11 to 14. It was.
- the conductive polymer obtained from the polymerization solution of the present invention is applied to a wide range of fields such as solid electrolytic capacitors, polymer batteries, antistatic films, display elements, sensors, and electrode materials.
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Abstract
Description
本発明の電解重合用の重合液は、水リッチ溶媒と、π-共役二重結合を有する少なくとも一種のモノマーと、ボロジサリチル酸及びボロジサリチル酸塩から成る群から選択された少なくとも一種の支持電解質と、ニトロベンゼン及びニトロベンゼン誘導体から選択された少なくとも一種の安定化剤と、を必須成分として含む。本発明の重合液では、環境負荷が小さく、経済的にも優れる水を主溶媒として使用する。本発明の重合液には、水に加えて、メタノール、エタノール、イソプロパノール、ブタノール、エチレングリコール、アセトニトリル、アセトン、テトラヒドロフラン、酢酸メチルなどの有機溶媒が含まれていてもよいが、溶媒全体の80質量%以上は水である。水は溶媒全体の90質量%以上であるのが好ましく、溶媒全体の95質量%以上であるのがより好ましく、溶媒が水のみから成るのが特に好ましい。水リッチ溶媒における有機溶媒の含有量が増加すると、ポリマー粒子が緻密に充填された導電性ポリマーフィルムが電解重合により電極上に形成されにくくなり、有機溶媒の含有量が溶媒全体の20質量%を超えると、得られた導電性ポリマーフィルム及び固体電解コンデンサの耐熱性が顕著に低下する。
本発明の重合液を用いた電解重合により、耐熱性の高い導電性ポリマーが形成される。本発明の重合液を用いた電解重合は、固体電解コンデンサにおける導電性ポリマー層の形成の他、さまざまな用途における導電性ポリマーフィルムの形成のために実施される。以下、一般的な導電性ポリマーフィルムの形成のための電解重合と、固体電解コンデンサにおける導電性ポリマー層を形成するための電解重合とを分けて説明する。
本発明の重合液中に導入する作用極(導電性ポリマーフィルムの基体)としては、少なくとも表面に導電性部分を有する材料が使用され、白金、ニッケル、チタン、鋼、カーボン等の導電体の板、箔、網、焼結体、発泡体等を用いることができる。また、透明で絶縁性のガラス又はプラスチックの表面にスズドープ酸化インジウム(ITO)、酸化スズ、フッ素ドープ酸化スズなどの半導体セラミックスの蒸着層を設けた透明基体を作用極とすることもできる。モノマーとしてEDOTを使用すると、この透明基体の使用により、透明なPEDOTフィルムを備えた透明電極を得ることができる。対極としては、白金、ニッケルなどの板を用いることができる。
表面に酸化皮膜を有する弁金属箔からなる陽極と、この陽極上に設けられた導電性ポリマー層とを含む、本発明の第1の形態の固体電解コンデンサの製造では、陽極として、アルミニウム箔、タンタル箔、ニオブ箔、チタン箔のような弁金属箔、好適にはアルミニウム箔、に化学的或いは電気化学的な手法によりエッチング処理を施して拡面し、さらに、アジピン酸アンモニウム水溶液、リン酸アンモニウム水溶液等を用いて化成処理し、弁金属箔の表面に酸化皮膜を形成したものが使用される。
表面に酸化皮膜を有する弁金属箔からなる陽極と、弁金属箔からなる陰極と、陽極と陰極との間に配置された導電性ポリマー層を保持したセパレータとを含む第2の形態の固体電解コンデンサの製造では、電解重合に先立って、表面に酸化皮膜を有する弁金属箔からなる陽極と、弁金属箔からなる陰極と、上記陽極と上記陰極との間に配置されたセパレータとを含むコンデンサ素子を得る。
実験1
50mLの蒸留水に、異なる濃度のp-ニトロフェノールと、0.08Mのボロジサリチル酸アンモニウムとを添加して溶解させた3種の液を調製した。p-ニトロフェノールの濃度は、0.010M、0.050M或いは0.100Mとした。これらの液を一夜放置した。いずれの液にも沈殿は認められなかった。
50mLの蒸留水に、異なる濃度のm-ニトロフェノールと、0.08Mのボロジサリチル酸アンモニウムとを添加して溶解させた3種の液を調製した。m-ニトロフェノールの濃度は、0.010M、0.050M或いは0.100Mとした。これらの液を一夜放置した。いずれの液にも沈殿は認められなかった。
50mLの蒸留水に、p-ニトロフェノールとp-ニトロ安息香酸とをモル比で9:1に混合した異なる濃度の混合物と、0.08Mのボロジサリチル酸アンモニウムとを添加して溶解させた3種の液を調製した。上記混合物の濃度は、両化合物の合計で、0.010M、0.050M或いは0.100Mとした。これらの液を一夜放置した。いずれの液にも沈殿は認められなかった。
50mLの蒸留水に0.08Mのボロジサリチル酸アンモニウムを添加して溶解させたところ、直ぐに多量の沈殿が生成した。この沈殿は、水難溶性のサリチル酸とホウ酸であった(図1参照)。
50mLの蒸留水に、異なる濃度の4-ヒドロキシアセトフェノンと、0.08Mのボロジサリチル酸アンモニウムとを添加して溶解させた3種の液を調製した。4-ヒドロキシアセトフェノンの濃度は、0.010M、0.050M或いは0.100Mとした。これらの液を一夜放置した。いずれの液にも沈殿が発生していた。したがって、実験1,2における沈殿生成の抑制効果がヒドロキシ基に起因するものではないことが推測された。
50mLの蒸留水に、4-ヒドロキシアセトフェノンと2-ヒドロキシ安息香酸とをモル比で9:1に混合した異なる濃度の混合物と、0.08Mのボロジサリチル酸アンモニウムとを添加して溶解させた3種の液を調製した。上記混合物の濃度は、両化合物の合計で、0.010M、0.050M或いは0.100Mとした。これらの液を一夜放置した。いずれの液にも沈殿が発生していた。したがって、実験3における沈殿生成の抑制効果がヒドロキシ基及びカルボキシ基に起因するものではないことが推測された。
実施例1
ガラス容器に蒸留水50mLを導入し、この液にEDOTを0.113g(濃度0.016M)添加し、25℃で60分間攪拌し、EDOTの全量が水に溶解した液を得た。この液に、p-ニトロフェノール0.7g(濃度0.1M)、及び、ボロジサリチル酸アンモニウム1.08g(濃度0.08M)を、この順番で添加し、均一に攪拌し、EDOT、p-ニトロフェノール、及びボロジサリチル酸アンモニウムが水に溶解した重合液を得た。得られた液を常温で1日間放置しても、沈殿の生成は認められなかった。
p-ニトロフェノールを0.35g(濃度0.05M)用いた以外は、実施例1と同じ手順を繰り返した。得られた液を常温で1日間放置しても、沈殿の生成は認められなかった。
p-ニトロフェノールを0.14g(濃度0.02M)用いた以外は、実施例1と同じ手順を繰り返した。得られた液を常温で1日間放置しても、沈殿の生成は認められなかった。
ガラス容器に蒸留水50mLを導入し、この液にEDOTを0.14g(濃度0.02M)添加し、EDOTが水と相分離している液を得た。この液に、周波数20kHz、出力2.6W/cm2の超音波を5分間照射したところ、水にEDOTが油滴として分散した乳濁液が得られた。この液のEDOT油滴のサイズを25℃で動的光散乱法により測定したところ、油滴の平均直径は数平均で214nmであった。次いで、この液に、p-ニトロフェノール0.7g(濃度0.1M)、及び、ボロジサリチル酸アンモニウム1.08g(濃度0.08M)を、この順番で添加し、均一に攪拌して重合液を得た。得られた液を常温で1日間放置しても、沈殿の生成は認められなかった。
ガラス容器に蒸留水50mLを導入し、この液にノニオン界面活性剤である2,4,7,9-テトラメチル-5-デシン-4,7-ジオールを0.4質量%の量で添加し、さらにEDOT0.18g(濃度0.025M)、p-ニトロフェノール0.35g(濃度0.05M)、及びボロジサリチル酸アンモニウム1.08g(濃度0.08M)を添加し、均一に攪拌して重合液を得た。上記モノマー量は、上記界面活性剤を含む水溶液に溶解させることができるモノマー量のほぼ最大量に相当する。
ガラス容器に蒸留水50mLを導入し、この液にノニオン界面活性剤であるポリオキシエチレン(9)ノニルフェニルエーテル分岐型を1.0質量%の量で添加し、さらにEDOT0.21g(濃度0.03M)、p-ニトロフェノール0.35g(濃度0.05M)、及びボロジサリチル酸アンモニウム1.08g(濃度0.08M)を添加し、均一に攪拌して重合液を得た。上記モノマー量は、上記界面活性剤を含む水溶液に溶解させることができるモノマー量のほぼ最大量に相当する。
ガラス容器に蒸留水50mLを導入し、この液にノニオン界面活性剤である2,4,7,9-テトラメチル-5-デシン-4,7-ジオールを0.4質量%とポリオキシエチレン(9)ノニルフェニルエーテル分岐型を1.0質量%の量で添加し、さらにEDOT0.57g(濃度0.08M)、p-ニトロフェノール0.35g(濃度0.05M)、及びボロジサリチル酸アンモニウム1.08g(濃度0.08M)を添加し、均一に攪拌して重合液を得た。上記モノマー量は、上記界面活性剤を含む水溶液に溶解させることができるモノマー量のほぼ最大量に相当する。
p-ニトロフェノールを0.07g(濃度0.01M)用いた以外は、実施例1と同じ手順を繰り返した。得られた液を常温で1日間放置したところ、微量の沈殿が認められた。以下に示す電解重合の比較実験では、p-ニトロフェノールとボロジサリチル酸アンモニウムを添加した直後の沈殿を含まない液を用いた。
実施例1で使用したEDOTのみを水に溶解させた液に、ボロジサリチル酸アンモニウムを1.08g(濃度0.08M)添加し、攪拌したところ、直ぐに多量の沈殿が生成した。この沈殿は、水難溶性のサリチル酸とホウ酸であった(図1参照)。以下に示す電解重合の比較実験では、ボロジサリチル酸アンモニウムを添加した直後の沈殿を含まない液を用いた。
実施例8
エッチングを施したアルミニウム箔を皮膜耐圧3Vに化成した後、投影面積1×1cm2に打ち抜き、陽極とした。この陽極を、20質量%のEDOTを含むエタノール溶液に浸漬した後、室温で乾燥した。次いで、酸化剤であるパラトルエンスルホン酸鉄(III)を20質量%の濃度で含むエタノール溶液に浸漬し、室温での10分間の乾燥の後、高温処理した。この化学酸化重合工程を繰り返し、陽極の酸化皮膜上にPEDOTの化学重合膜を形成した。得られたPEDOTの化学重合膜を有する陽極について、アジピン酸アンモニウム水溶液中で再化成処理を行った後、水洗し、乾燥した。
実施例1の重合液の代わりに実施例2の重合液を使用し、実施例8の手順を繰り返した。重合終了後も重合液中に沈殿が認められず、同じ重合液を使用して繰り返しの重合が可能であった。
実施例1の重合液の代わりに実施例4の重合液を使用し、実施例8の手順を繰り返した。重合終了後も重合液中に沈殿が認められず、同じ重合液を使用して繰り返しの重合が可能であった。
実施例1の重合液の代わりに比較例1(沈殿生成前)の重合液を使用し、実施例8の手順を繰り返した。重合の途中で重合液中に沈殿が生成し始め、同じ重合液を使用した繰り返しの重合が困難であった。
実施例1の重合液の代わりに比較例2(沈殿生成前)の重合液を使用し、実施例8の手順を繰り返した。重合の途中で重合液中に沈殿が生成し始め、同じ重合液を使用した繰り返しの重合は不可能であった。
ガラス容器に水50mLを導入し、この液にEDOT0.14g(濃度0.02M)と、スルホン酸塩基を有する界面活性剤であるブチルナフタレンスルホン酸ナトリウム1.08g(濃度0.08M)とを添加し、25℃で60分間攪拌して重合液を得た。次いで、この重合液を用いて、実施例8で用いたPEDOTの化学重合膜を備えた陽極を作用極とし、面積4cm×4cmのPt箔を対極とし、銀-塩化銀電極を参照電極として、0.5mA/cm2の電流条件下で60分間定電流電解重合を行った。重合後の膜をエタノールで洗浄し、水洗した後、乾燥した。最後に、PEDOTの電解重合層の上に、グラファイトペーストを塗布し、乾燥し、次いで銀ペーストを塗布し、乾燥して、皮膜耐圧3Vの陽極を備えた固体電解コンデンサを得た。
実施例8で用いたPEDOTの化学重合膜を備えた陽極を使用し、この陽極の化学重合膜上に別途調製したPEDOTとポリスチレンスルホン酸とが分散したスラリーを塗布し、乾燥した。最後に、PEDOTとポリスチレンスルホン酸とが分散したスラリーから得られた層の上に、グラファイトペーストを塗布し、乾燥し、次いで銀ペーストを塗布し、乾燥することにより、皮膜耐圧3Vの陽極を備えた固体電解コンデンサを得た。
実施例11
エッチングを施したアルミニウム箔を皮膜耐圧3Vに化成した後、投影面積1×1cm2に打ち抜き、陽極とした。この陽極を、20質量%のEDOTを含むエタノール溶液に浸漬した後、室温で乾燥した。次いで、酸化剤であるパラトルエンスルホン酸鉄(III)を20質量%の濃度で含むエタノール溶液に浸漬し、室温での10分間の乾燥の後、高温処理した。この化学酸化重合工程を繰り返し、陽極の酸化皮膜上にPEDOTの化学重合膜を形成した。得られたPEDOTの化学重合膜を有する陽極について、アジピン酸アンモニウム水溶液中で再化成処理を行った後、水洗し、乾燥した。
実施例11で用いた重合液の代わりに実施例5の重合液を使用し、実施例11の手順を繰り返した。
実施例11で用いた重合液の代わりに実施例6の重合液を使用し、実施例11の手順を繰り返した。
実施例11で用いた重合液の代わりに実施例7の重合液を使用し、実施例11の手順を繰り返した。
ガラス容器に水50mLを導入し、この液にアニオン系界面活性剤であるブチルナフタレンスルホン酸ナトリウムを2.7質量%の量で添加し、さらにEDOT0.21g(濃度0.03M)を添加し、均一に攪拌して重合液を得た。上記モノマー量は、上記界面活性剤混合物を含む水溶液に溶解させることができるモノマー量のほぼ最大量に相当する。次いで、この重合液を用いて、実施例11で用いたPEDOTの化学重合膜を備えた陽極を作用極とし、面積4cm×4cmのPt箔を対極とし、銀-塩化銀電極を参照電極として、1.0mA/cm2の電流条件下で30分間定電流電解重合を行った。重合後の膜をエタノールで洗浄し、水洗した後、乾燥した。最後に、PEDOTの電解重合層の上に、グラファイトペーストを塗布し、乾燥し、次いで銀ペーストを塗布し、乾燥して、皮膜耐圧3Vの陽極を備えた固体電解コンデンサを得た。
Claims (11)
- 100~80質量%の水と0~20質量%の有機溶媒とから成る溶媒と、
π-共役二重結合を有する少なくとも一種のモノマーと、
ボロジサリチル酸及びボロジサリチル酸塩から成る群から選択された少なくとも一種の支持電解質と、
ニトロベンゼン及びニトロベンゼン誘導体から成る群から選択された少なくとも一種の安定化剤と
を含む、前記モノマーの電解重合のための重合液であって、
前記安定化剤の含有量が、前記支持電解質1モルに対して1/8モルより多い
ことを特徴とする重合液。 - 前記安定化剤が、o-ニトロフェノール、m-ニトロフェノール、及びp-ニトロフェノールから成る群から選択された少なくとも一種の化合物である、請求項1に記載の重合液。
- 前記溶媒が水のみから成る、請求項1又は2に記載の重合液。
- 前記安定化剤がp-ニトロフェノールであり、p-ニトロフェノールの含有量が前記支持電解質1モルに対して1/4モル以上である、請求項1~3のいずれか1項に記載の重合液。
- 前記モノマーが3,4-エチレンジオキシチオフェンである、請求項1~4のいずれか1項に記載の重合液。
- 少なくとも一種のノニオン界面活性剤をさらに含む、請求項1~5のいずれか1項に記載の重合液。
- 前記ノニオン界面活性剤が、アルキンジオールとポリオキシエチレンアルキルフェニルエーテルとの混合物である、請求項6に記載の重合液。
- 前記重合液中に前記モノマーが油滴として分散している、請求項1~7のいずれか1項に記載の重合液。
- 少なくとも表面に導電性部分を有する基体を請求項1~8のいずれか1項に記載の重合液に導入して電解重合を行うことにより得られた導電性ポリマーフィルム。
- 表面に酸化皮膜を有する弁金属箔からなる陽極と、該陽極上に設けられた導電性ポリマー層と、を含む固体電解コンデンサであって、
前記導電性ポリマー層が、前記陽極を請求項1~8のいずれか1項に記載の重合液に導入して電解重合を行うことにより形成されたものであることを特徴とする固体電解コンデンサ。 - 表面に酸化皮膜を有する弁金属箔からなる陽極と、弁金属箔からなる陰極と、前記陽極と前記陰極との間に配置された導電性ポリマー層を保持したセパレータと、を含む固体電解コンデンサであって、
前記導電性ポリマー層が、前記陽極と前記陰極とこれらの間に配置されたセパレータとを含むコンデンサ素子を請求項1~8のいずれか1項に記載の重合液に導入し、該コンデンサ素子に前記重合液を含浸させ、電解重合を行うことにより形成されたものであることを特徴とする固体電解コンデンサ。
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EP12753013.7A EP2682965A4 (en) | 2011-03-01 | 2012-03-01 | POLYMERIZATION SOLUTION, POLYMERIC CONDUCTIVE FILM OBTAINED FROM THE POLYMERIZATION SOLUTION, AND SOLID ELECTROLYTIC CAPACITOR |
CN201280011313.6A CN103430262B (zh) | 2011-03-01 | 2012-03-01 | 聚合液、由该聚合液得到的导电性聚合物膜及固体电解电容器 |
US14/002,281 US9558891B2 (en) | 2011-03-01 | 2012-03-01 | Polymerization solution, conductive polymer film obtained from the polymerization solution, and solid electrolytic capacitor |
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CN103430262A (zh) | 2013-12-04 |
KR101848335B1 (ko) | 2018-04-12 |
KR20140057194A (ko) | 2014-05-12 |
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