WO2011099485A1 - 染色又は脱色キット - Google Patents
染色又は脱色キット Download PDFInfo
- Publication number
- WO2011099485A1 WO2011099485A1 PCT/JP2011/052655 JP2011052655W WO2011099485A1 WO 2011099485 A1 WO2011099485 A1 WO 2011099485A1 JP 2011052655 W JP2011052655 W JP 2011052655W WO 2011099485 A1 WO2011099485 A1 WO 2011099485A1
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- WIPO (PCT)
- Prior art keywords
- agent
- hair dyeing
- decoloring
- hair
- sealed container
- Prior art date
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
- A45D2200/051—Airtight containers
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
- A45D2200/058—Means for mixing different substances prior to application
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Definitions
- the present invention relates to a staining or decoloring kit.
- the decoloring agent or hair dye that discharges the mixed liquid in a foam form from the non-aerosol foamer is a liquid or cream-like decoloring agent or hair dye that has been known for a long time.
- the formulations used in these conventional dosage forms cannot be used as they are.
- the present invention is charged with a first agent containing an alkali agent, a second agent containing an oxidizing agent, a thickening composition containing a thickener, and a first agent, a second agent and a thickening composition.
- the present invention provides a hair dyeing or decoloring kit including an openable / closable sealed container for shaking to form a foam of a mixed solution.
- the present invention is capable of opening and closing to form a foam of a mixed solution by adding a first agent containing an alkali agent, a second agent containing an oxidizing agent, and shaking the first agent and the second agent.
- a hair dyeing or decoloring kit comprising a sealed container having anti-slip means for both the longitudinal and lateral directions on the surface is provided.
- the alkali agent, the oxidizing agent, and the thickener are contained in the same molded body or in separate molded bodies, and the alkaline agent and the oxidizing agent exist in separate phases.
- the present invention provides a hair dyeing or decoloring kit comprising one or a plurality of moldings to be formed, and an openable / closable sealed container for charging the moldings and the medium and shaking to form bubbles of the mixed solution.
- the present invention provides a hair dyeing or decoloring method comprising the following steps (a) to (d).
- (A) A step of charging all of the first agent containing an alkali agent, the second agent containing an oxidizing agent, and the thickening composition containing a thickener into an openable / closable sealed container body
- (b) A step of sealing the sealed container
- (c) a step of shaking the sealed container to form foam
- foam a step of removing the formed foam from the sealed container and applying it to the hair
- the present invention provides a hair dyeing or decoloring method comprising the following steps (a) to (d).
- steps (a) to (d) A step of charging both the first agent containing an alkaline agent and the second agent containing an oxidizing agent into an openable / closable sealed container body having anti-slip means for both the longitudinal and lateral directions on the surface
- steps (b) The step of sealing the closed container
- steps (c) The step of shaking the closed container to form bubbles of the mixed solution
- the present invention provides a hair dyeing or decoloring method comprising the following steps (a) to (e).
- the present invention provides a hair dyeing or decoloring method comprising the following steps (a) to (d).
- the present invention 1) The structure of the container is simple 2) Foam can be easily formed 3) The degree of freedom of formulation is high 4) The advantage of the foam hair dye of Patent Document 2 is easy even for unskilled people It can be applied evenly to hair and results in no color unevenness in the finish. 5) Excellent storage stability of the agent. 6) Good dyeing and other basic performance as a hair dye.
- the present invention relates to a hair coloring or decoloring kit that satisfies all the requirements of being able to be performed simultaneously.
- the present inventors have found that all of these requirements are satisfied by a hair dyeing or decoloring kit using a specific container and a hair dyeing or decoloring method including a specific process.
- Examples of the hair dyeing or decoloring kit of the present invention include two-part, three-part, and composite molded body types.
- ⁇ As a two-part formula, -From the 1st agent containing an alkali agent and a thickener, and the 2nd agent containing an oxidizing agent-From the 1st agent containing an alkaline agent, and the 2nd agent containing an oxidizing agent and a thickener Narumono
- ⁇ A phase containing an alkali agent and a thickener and a phase containing an oxidizing agent in the same molded body ⁇ A phase containing an alkaline agent in the same molded body, an oxidizing agent and a thickener Having a phase to contain ⁇ A phase containing an alkali agent and a thickener in the same molded body and a phase containing an oxidizing agent and a thickener ⁇
- An alkali agent is contained in the same molded body Having a phase, a phase containing an oxidizer, and a phase containing a thickener ⁇ A phase containing an alkali agent and a phase containing an oxidizer in the same molded body, and a separate thickener Used in combination with molded products containing
- the first agent and the second agent are in any form known in the art, such as liquid, gel, jelly, powder, granule, cream, and molded body (eg, tablet). There may be.
- the composite molded body has a layered or island-like structure in which a phase containing an alkali agent, a phase containing an oxidizing agent, and a phase containing a thickener are joined by an inert intermediate layer.
- the thickener may be included in the phase containing the alkaline agent or the phase containing the oxidizing agent, but the alkaline agent and oxidizing agent should be in separate phases.
- Preferable specific examples of such a molded body include those described in JP-T-2003-518028 and JP-T-2003-525873.
- Such a composite molded body does not contain a medium, in order to form a mixed solution, it is used together with the medium.
- the medium water and, if necessary, an organic solvent are used.
- organic solvents include lower alkanols such as ethanol and 2-propanol; aromatic alcohols such as benzyl alcohol and benzyloxyethanol; lower polyols such as propylene glycol, dipropylene glycol, 1,3-butanediol, diethylene glycol, and glycerin; Cellosolves such as cellosolve, butyl cellosolve, benzyl cellosolve; and carbitols such as ethyl carbitol and butyl carbitol.
- the molded body may take any geometrical structure, but the mass per piece is from the viewpoint of ease of operation of pouring into a closed container, shaking and dissolving, and the role of itself as a stirrer. It is preferably 1 to 20 g, more preferably 1.5 to 10 g, and further preferably 2 to 8 g.
- oxidation assistants such as persulfate, auxiliary ingredients such as animal and plant extracts, fragrances, alkaline agents, oxidizing agents, thickeners (media), used before hair dyeing
- auxiliary ingredients such as animal and plant extracts, fragrances, alkaline agents, oxidizing agents, thickeners (media)
- media oxidizing agents
- thickeners media
- Additional agents such as pretreatment agents and post-treatment agents used after hair dyeing may be included, and when these auxiliary agents and treatment agents are further included, in this specification, two-part, three-part types are used. Or it shall be a composite molding type.
- the term “mixed liquid” refers to a mixed liquid of all the components put into the sealed container unless otherwise specified.
- -A two-part type consisting of a first agent containing an alkali agent and a thickener and a second agent containing an oxidizing agent-a first agent containing an alkaline agent, and a second agent containing an oxidizing agent
- a three-part type consisting of a thickening composition containing a thickener, either a phase containing an alkali agent and a thickener and a phase containing an oxidizing agent in the same molded body
- the hair may be hair that has grown on the head (hair) or hair that has grown on other parts, but it is preferably hair. Moreover, as long as it is hair, it may be a doll or any animal, but human hair is preferred.
- the thickener is a mixed liquid of the first agent and the second agent, a mixed liquid of the first agent, the second agent and the thickening composition, or a mixed liquid of the molded body and the medium. It is an ingredient to do.
- a two-agent type or a three-agent type it can be contained in either the first agent or the second agent, and is contained in the thickening composition separately from the first agent or the second agent.
- one or more selected from synthetic polymers, semi-synthetic polymers, and natural polymers can be used.
- Synthetic polymers include, for example, carbomers (for example, Sumitomo Seika Akpek HV-501), acrylates copolymers (for example, Rohm and Haas Aculine 33 polymer, BASF Rubiflex Soft), (PEG-150 / stearyl alcohol) / SMDI) copolymer (for example, Rohm and Haas Aculine 46, Aculin 46B), dimethyldiallylammonium chloride / acrylamide copolymer (for example, Nalco Marcoat 100, Marcoat 550), vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer ( For example, the copolymer 845, the copolymer 937, the copolymer 958), etc.
- Examples of semi-synthetic polymers include o- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydroxyethylcellulose chloride (for example, UCARE Polymer JR-125, JR-30M, JR-400, Dow Chemical Japan Co., Ltd.).
- hydroxypropylcellulose For example, Nippon Soda Co., Ltd. Nisso HPC-H, HPC-M), hydroxypropyl methylcellulose (for example, Shin-Etsu Chemical Co., Ltd. Metroze 60SH series, Metroze 65SH series, Metroze 90SH series), hydroxypropyl xanthan gum (eg, Dainippon Sumitomo Pharma Labor gum) EX), pullulan fatty acid ester and the like.
- Examples of the natural polymer include pullulan (for example, Hayashibara Shoji Pullulan PF-20, pullulan PI-20), xanthan gum (for example, Dainippon Sumitomo Pharma Co., Ltd., Echogum), Kanten (for example, Ina Food Industry Co., Ltd. Ina Agar CS). , Gellan gum (eg, Dainippon Sumitomo Pharma Kelcogel), collagen (eg, Koken Maribrene Mask SH), alginic acid (eg, Dainippon Sumitomo Pharma Arginic Acid HFD), gum arabic (eg, Ina Food Industry) Inagera Arabic gum CS), guar gum (for example, Ina Food Industry Co., Ltd. Inager Guar gum CS), locust bean gum (Ina Food Industry Co., Ltd. Inagel locust bean gum CS) and the like.
- pullulan for example, Hayashibara Shoji Pullulan PF-20, pullulan PI-20
- the composition containing the thickener may be any of the first agent, the second agent, and the thickening composition.
- the liquid, the gel, the jelly, the powder It may take any form such as a granule, a cream, and a molded body.
- liquid, gel, jelly, and cream are preferable, and liquid, gel, and jelly are more preferable.
- the viscosity of the liquid mixture is reduced at the start of shaking by gradually disintegrating / dissolving as it is shaken from the “solid” state in other liquid compositions. From the viewpoint of facilitating the formation of bubbles without increasing the viscosity and stabilizing the foam formed by increasing the viscosity of the liquid mixture at the end of shaking, gel and jelly are preferred.
- the composition containing a thickener prevents formation of “dama” at the time of mixing, facilitates foam formation without increasing the viscosity of the liquid mixture at the start of shaking, and viscosity of the liquid mixture at the end of shaking.
- a composition containing water or a water-soluble organic solvent is preferable.
- the water-soluble organic solvent include lower alkanols such as ethanol and 2-propanol; lower polyols such as propylene glycol, 1,3-butanediol, diethylene glycol and glycerin.
- the content of water or the water-soluble organic solvent in the composition containing the thickener is preferably 10 to 99.5% by mass, more preferably 20 to 95% by mass, and further preferably 30 to 90% by mass.
- the composition containing the thickener when the composition containing the thickener is gel-like or jelly-like, when mixing the agent, 1) At the stage where each agent is simply put into the closed container body, the mixture distinguishes between the region (gel, jelly) derived from the composition containing the thickener component and the remaining region (liquid). It is in a mixed state. 2) When an external force is applied to the mixture by shaking the sealed container, the region derived from the composition containing the thickener component (gel-like, jelly-like) gradually becomes smaller by disintegrating and dissolving, and finally A suitable mixed state is obtained.
- the gel form means a state in which colloidal particles of the composition components interact with each other to form a three-dimensional network structure, and the space is filled with a liquid.
- gel and jelly are not concepts that can be strictly distinguished.
- the composition containing the thickener When the composition containing the thickener is in the form of powder or granules, it is an aggregate of fine solids.
- the viscosity When the composition containing the thickener is liquid, gel or cream, the viscosity is more than 200 ⁇ mPa ⁇ s and less than 100,000 mPa ⁇ s, moreover 500 ⁇ 80,000 mPa ⁇ s, and more preferably 1,000 ⁇ 50,000 mPa -S is preferable.
- the jelly strength is preferably 5 to 1000 g, more preferably 10 to 500 g, and even more preferably 50 to 350 g.
- the viscosity is a viscosity measured by rotating for 1 minute at 25 ° C. using a TVB-10M viscometer (Toki Sangyo Co., Ltd.).
- the rotor and rotation speed shall be measured by the following combinations.
- Rotor is M2
- rotation speed is 60 rpm
- Rotor is M3
- rotation speed is 30rpm
- Rotor is M3
- rotation speed is 12 rpm ⁇
- 10,000mPa ⁇ s is over 100,000mPa ⁇ s: Rotor is M4, rotation speed is 6rpm
- the jelly strength is measured in accordance with JIS K6503: 2001.
- a texture analyzer (TA-1000 texture analyzer, Kett Science Co., Ltd.)
- 120 g of sample is placed flat in a jelly cup with an inner diameter of 60 mm and a height of 60 mm so that air does not enter, the sample temperature is 20 ° C, and the penetration distance of the probe It shall be measured as 4 mm and probe penetration speed of 1 mm / s.
- the remaining composition excluding the composition containing the thickener is easy to handle and easily forms foam, and has a viscosity (25 ° C.) of 1 to 200 mPa ⁇ s, more preferably 2 to 120 mPa ⁇ s. S, more preferably 5 to 80 mPa ⁇ s.
- the viscosity (25 ° C.) of the mixed solution may be higher than that of the remaining composition excluding the composition containing the thickener.
- the viscosity (25 ° C.) of the liquid mixture is increased from the viewpoint of stabilizing the foam formed by the low viscosity, which facilitates the formation of foam and the high viscosity after the foam is formed. It is preferably 1.2 times or more, preferably 2 times or more, more preferably 10 times or more of the remaining composition excluding the composition containing a sticky agent.
- the viscosity (25 ° C.) of the mixed solution is preferably 50 to 20,000 mPas from the viewpoint that the formed foam easily penetrates to the root of the hair when applied to the hair and easily spreads from the root to the tip of the hair.
- S preferably 500 to 10,000 mPa ⁇ s, more preferably 1,000 to 5,000 mPa ⁇ s.
- the viscosity of the liquid mixture here refers to the viscosity of the solution obtained by mixing under the following conditions, not the viscosity of the foam of the liquid mixture formed by shaking the sealed container.
- the viscosity of the mixed solution was measured by measuring a total of 50 g of all agents in a specified ratio, and put into a 100 mL beaker (55 mm barrel diameter, 70 mm height). ) Is stirred at 600 rpm for 1 minute, and then allowed to stand, and the viscosity is 10 minutes after the addition. If it is within this viscosity range after 10 minutes, there is little risk of dripping even if the viscosity decreases on a scale of several tens of minutes, which is the normal standing time of the hair dye. If there is, it is easy to spread from the root of the hair to the tip of the hair.
- various components can be added to the hair dye or depigmenting agent. Even if a component that inhibits the thickening action of the thickener is contained in the hair dye, it is appropriate after 10 minutes from the start of mixing. Since it is only necessary to obtain a high viscosity, a wide range can be selected from the thickeners described above.
- alkaline agent An alkaline agent is contained in the first agent of the hair dyeing or decoloring kit of the present invention or in one phase of the composite molded article.
- the alkaline agent include ammonia and salts thereof (for example, ammonium carbonate and ammonium hydrogen carbonate); ethanolamine and salts thereof (for example, monoethanolamine and diethanolamine); isopropanolamine, 2-amino-2-methylpropanol Alkanolamines other than ethanolamine such as 2-aminobutanol and salts thereof; alkanediamines such as 1,3-propanediamine and salts thereof; guanidine carbonate, sodium carbonate, potassium carbonate, guanidine bicarbonate, sodium bicarbonate, bicarbonate Examples thereof include carbonates such as potassium, among which ammonia, monoethanolamine, and ammonium hydrogen carbonate are preferable.
- alkaline agents may be used in combination of two or more, combining ammonia or a salt thereof and ethanolamine or a salt thereof from the viewpoint of sufficient decolorization and hair dyeing effect, and reduction of irritating odor during hair damage and treatment. It is preferable to use it.
- the content of these alkaline agents is preferably from 0.01 to 15% by mass, more preferably from 0.1 to 10% by mass, more preferably from 0.2 to 10% by mass, from the viewpoint of sufficient decolorization / hair dyeing effect and reduction of hair damage and scalp irritation. More preferably, it is ⁇ 5% by mass.
- the pH of the mixed solution is preferably 7 to 12, more preferably 8 to 11, from the viewpoint that sufficient hair dyeing or decoloring property can be obtained and the above thickener can be selected in a wide range. More preferably, it is 8.5 to 10.5.
- An oxidizing agent is contained in the second agent of the hair dyeing or decoloring kit of the present invention or in one phase of the composite molded article.
- the oxidizing agent include hydrogen peroxide and hydrogen peroxide generating agents such as urea peroxide, melamine peroxide, sodium perborate, potassium perborate, sodium percarbonate, and potassium percarbonate.
- hydrogen peroxide hydrogen peroxide
- hydrogen peroxide generating agents such as urea peroxide, melamine peroxide, sodium perborate, potassium perborate, sodium percarbonate, and potassium percarbonate.
- Two or more kinds of oxidizing agents may be used in combination, and the content thereof is 0.1% in the mixed solution in terms of hydrogen peroxide in terms of sufficient decolorization / hair dyeing effect and reduction of hair damage and scalp irritation. It is preferably ⁇ 10% by mass, and more preferably 1 to 5% by mass.
- any one or more of the first agent, the second agent, and the thickening composition of the hair dyeing or decoloring kit of the present invention, or one or more phases of the composite molded article may contain a surfactant.
- the total concentration of all the surfactants in the mixed solution is 0.01 to 20% by mass, more preferably 0.1 to 15% by mass, from the viewpoint of good foaming and easy foaming after applying foam to hair. Furthermore, 1 to 10% by mass is preferable.
- Anionic surfactants include sulfate surfactants such as alkyl sulfates and polyoxyalkylene alkyl ether sulfates; fatty acid salts, N-acyl amino acid salts (N-acyl sarcosine salts, N-acyl glutamate salts, N-acyl salts) Glycine salts, etc.), alkyl succinates or alkenyl succinate salts, polyoxyalkylene alkyl ether carboxylates, fatty acid amide ether acetates and other carboxylic acid surfactants; alkyl phosphates, alkyl ether phosphates, etc.
- sulfate surfactants such as alkyl sulfates and polyoxyalkylene alkyl ether sulfates; fatty acid salts, N-acyl amino acid salts (N-acyl sarcosine salts, N-acyl glutamate salts, N-acyl salts) Glycine salt
- Acid ester surfactants Polyoxyalkylene alkyl ether sulfosuccinates, isethionate fatty acid ester salts, acyl taurine salts, sulfonic acid surfactants such as alkylbenzene sulfonic acids, ⁇ -olefin sulfonic acids, alkane sulfonic acids, and the like.
- alkyl sulfates and polyoxyalkylene alkyl sulfates are preferred, those having an alkyl group of 10 to 24 carbon atoms, more preferably those having a carbon number of 12 to 18, and this alkyl group being Those that are linear are preferred.
- polyoxyalkylene alkyl sulfates are preferable, and polyoxyethylene alkyl sulfates are particularly preferable, and those having an average addition mole number of oxyethylene groups of 1 to 10, and more preferably 2 to 5 are more preferable.
- N-acyl amino acid salts and ether carboxylates are also preferred.
- N-acyl glutamates having 10 to 18 carbon atoms in the acyl group, average addition moles of oxyethylene groups having 10 to 18 carbon atoms in the alkyl group Of 3 to 15 are preferred.
- Two or more anionic surfactants can be used in combination, and the content in the mixed solution is preferably 0.01 to 15% by mass, more preferably 0.1 to 10% by mass, and further preferably 1 to 5% by mass.
- amphoteric surfactants nonionic surfactants, cationic surfactants, and semipolar surfactants can be used.
- Amphoteric surfactants include carbobetaines, amidebetaines, sulfobetaines, hydroxysulfobetaines, amidesulfobetaines, phosphobetaines, imidazo having 8 to 24 carbon atoms, alkyl groups, alkenyl groups or acyl groups. Examples thereof include linium-based surfactants, and among them, carbobetaine-based surfactants and sulfobetaine-based surfactants are preferable.
- Preferred amphoteric surfactants include lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, lauryl hydroxysulfobetaine and the like. Two or more amphoteric surfactants can be used in combination, and the content in the mixed solution is preferably 0.01 to 15% by mass, more preferably 0.1 to 10% by mass, and further preferably 1 to 5% by mass.
- nonionic surfactant examples include alkyl polyglucoside, polyoxyalkylene alkyl ether, alkyl glyceryl ether and the like.
- alkyl polyglucoside those in which the alkyl group has 8 to 18 carbon atoms, more preferably 8 to 14 carbon atoms, and further 9 to 11 carbon atoms are preferable, and those in which the alkyl group is linear are preferable.
- the average condensation degree of glucoside is preferably 1 to 5, and more preferably 1 to 2.
- polyoxyalkylene alkyl ether those in which the alkyl group has 10 to 22 carbon atoms, more preferably 12 to 18 carbon atoms, are preferred, and those in which the alkyl group is linear are preferred.
- Polyoxyethylene alkyl ethers are more preferable, and those having an average addition mole number of oxyethylene groups of 1 to 40, more preferably 4 to 30, are particularly preferable.
- the alkyl glyceryl ether those in which the alkyl group has 8 to 18 carbon atoms, more preferably 8 to 12 carbon atoms, are preferred, and those in which the alkyl group is branched are preferred.
- Two or more nonionic surfactants can be used in combination, and the content in the mixed solution is preferably 0.01 to 15% by mass, more preferably 0.1 to 10% by mass, and further preferably 1 to 5% by mass.
- cationic surfactant for example, one represented by the following general formula (1) can be used.
- R 1 , R 2 , R 3 and R 4 independently represent a hydrocarbon group which may have a substituent, and at least one of R 1 and R 2 has 8 to 36 carbon atoms. And the remainder has 1 to 7 carbon atoms or R 3 and R 4 together with the adjacent nitrogen atom may be substituted with an alkyl group having 1 to 4 carbon atoms, A 5- to 7-membered ring that may contain a nitrogen atom, an oxygen atom, or a sulfur atom as a hetero atom other than the atom may be formed.
- a ⁇ represents an anion.
- hydrocarbon group examples include a linear or branched alkyl group, a linear or branched alkenyl group, an aryl group, an aralkyl group, and the like.
- substituent examples include a hydroxy group, an alkoxy group, and an aryloxy group.
- the ring formed by R 3 and R 4 together with the adjacent nitrogen atom include a morpholine ring, an imidazoline ring, a piperazine ring, a piperidine ring, and a pyrrolidine ring.
- anion examples include chloride ion, bromide ion, iodide ion, methyl sulfate ion, ethyl sulfate ion, acetate ion, phosphate ion, sulfate ion, lactate ion, and saccharin ion.
- cationic surfactant examples include cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, isostearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, cocoyl trimethyl ammonium chloride, cetyl trimethyl bromide.
- Examples of the cationic surfactant include monoalkyltrimethylammonium salt and dialkyldimethylammonium salt, that is, R 1 , or R 1 and R 2 are linear or branched carbon atoms having 8 to 30, more preferably 10 to 24, Further, those having 12 to 18 alkyl groups and the remainder being methyl groups are preferred, and among them, monoalkyltrimethylammonium salts are preferred.
- Two or more kinds of cationic surfactants can be used in combination, and the content in the mixed solution is preferably 0.1 to 5% by mass, more preferably 0.2 to 3% by mass, and further preferably 0.3 to 1% by mass.
- the mass ratio of the surfactant to the cationic surfactant is preferably 1 to 100, more preferably 2 to 50, and further preferably 4 to 20.
- Examples of the semipolar surfactant include alkylamine oxide.
- the product of the present invention is a decoloring kit
- no dye is contained.
- the product of the present invention is a hair dyeing kit, it is oxidized in the first agent or in the phase containing the alkaline agent of the composite molded product. Contains dye intermediates or direct dyes.
- oxidation dye intermediate As the oxidation dye intermediate, known precursors and couplers usually used in hair dyes can be used.
- the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N, N-bis (2-hydroxyethyl) -paraphenylenediamine, 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- (4 -Aminophenyl) amino) -2-propanol, PEG-3,3,2'-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-aminophenol , 2- (2-(2-
- couplers examples include metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5-methylphenetole, and 2,4-diamino.
- Two or more precursors and couplers may be used in combination, and the content of each of the precursor and the coupler is preferably 0.01 to 5% by mass, more preferably 0.1 to 4% by mass in the mixed solution.
- Direct dye examples include acid dyes, nitro dyes, disperse dyes, and basic dyes.
- acid dyes include Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No.
- Acid Orange 3, etc., and nitro dyes include 2-nitro -p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4-amino-3-nitrophenol, 4- Hydroxypropylamino-3-nitrophenol, HC Blue No.2, HC Orange No.1, HC Red No.1, HC Yellow No.2, HC Yellow No.4, HC Yellow No.5, HC Red No.3 N, N-bis- (2-hydroxyethyl) -2-nitro-p-phenylenediamine, etc., and disperse dyes include Disperse Violet 1, Disperse Blue 1, Disperse Black 9, etc.
- Basic dyes such as Basic Blue 99 and Basic Kuburaun 16, Basic Brown 17, Basic Red 76, Basic Red 51, Basic Yellow 57, Basic Yellow 87, Basic Orange 31, and the like.
- Two or more direct dyes may be used in combination, or may be used in combination with an oxidation dye intermediate.
- the content thereof is preferably 0.001 to 5% by mass, more preferably 0.01 to 3% by mass in the mixed solution.
- the hair dyeing or decoloring kit of the present invention from the viewpoint of making the foam of the mixed solution have a firm foam quality and evenly dyeing from the root of the hair to the tip of the hair, 0.01 to 3% by mass of an oil agent is contained in the mixed solution It is preferable to formulate such that 0.03 to 2.5% by mass, and further 0.05 to 2% by mass is preferable.
- oils include hydrocarbons such as squalene, squalane, liquid paraffin, liquid isoparaffin, cycloparaffin; glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; beeswax, whale wax, lanolin, carnauba wax, etc.
- Esters such as isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isononyl isononanoate, tridecyl isononanoate
- Higher fatty acids such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, isostearyl acid, isopalmitic acid; Call, cetyl alcohol, stearyl alcohol, behenyl alcohol, 2-octyldodecanol, higher alcohols such as cetostearyl alcohol; Other isostearyl glyceryl ether, polyoxypropylene butyl ether. Of these, higher alcohol
- organic solvents include lower alkanols such as ethanol and 2-propanol; aromatic alcohols such as benzyl alcohol and benzyloxyethanol; lower polyols such as propylene glycol, dipropylene glycol, 1,3-butanediol, diethylene glycol, and glycerin; Cellosolves such as cellosolve, butyl cellosolve, benzyl cellosolve; and carbitols such as ethyl carbitol and butyl carbitol.
- Optional ingredients In addition to the above components, other components usually used as cosmetic raw materials can be added to the first agent, the second agent, the thickening composition, and the composite molded body used in the present invention.
- Such optional ingredients include animal and vegetable oils and fats, silicones, ethers, protein derivatives, hydrolyzed proteins, amino acids, preservatives, chelating agents, stabilizers, antioxidants, plant extracts, herbal extracts, vitamins, fragrances And ultraviolet absorbers.
- the sealed container may have any shape as long as the contents can be bubbled by shaking.
- the hermetic container is composed of, for example, a container body and a hermetic lid. In this case, even if the container body and the hermetic lid are separated, the main body and the lid are not separated by a non-separable type (for example, a hinge or the like). It may be a square root).
- the container body is preferably a hollow rotating column whose one of the bottom surfaces is open from the viewpoint of ease of manufacture, and a fall prevention leg may be installed on the remaining bottom surface.
- the rotating column body include a cylindrical body, a conical column body, and a double conical column body.
- the container body has a size that is easy to hold and shake with one hand, and in the case of a rotating column, in view of the foamed hair dye volume, at least one side of the side has a radius from the central axis. It is preferably 3 to 6 cm, more preferably 3.5 to 5.5 cm, further preferably 4 to 5 cm. In addition, since the foamed hair dye is preferably scooped with a hand, the inner periphery of the open mouth is 25 in terms of the size that allows easy insertion into the container and easy opening and closing of the lid. It is preferably ⁇ 35 cm, more preferably 26-34 cm, and even more preferably 27-33 cm.
- the height of the container body is preferably 10 to 22 cm, more preferably 11 to 20 cm, and further preferably 12 to 18 cm.
- the capacity of the sealed container is equal to the volume of the foamed hair dye.
- the total volume of the sealed container is preferably 100 to 2000 mL, more preferably 300 to 1500 mL, and even more preferably 500 to 1000 mL in total for the container body and the sealing lid.
- the ratio of the volume of the sealed container, which is the total amount of the container body and the sealed lid part, to the volume of the mixed liquid is easy to spread from the root of the hair to the tip of the hair, From the viewpoint of producing bubbles that do not easily drip and are easy to form by shaking, 3 to 10 is preferable, 4 to 9, and 5 to 8 are more preferable.
- the sealing lid may be an outer lid fitted from the outside of the container body or an inner lid fitted inside. Further, the shape of the sealing lid may be convex outward, concave or flat, but it is preferably convex outward from the viewpoint of easiness of foaming. More preferably.
- One mode of the sealed container in the case where the sealed lid is a dome shape is shown in FIG.
- the container body is a multiplet structure composed of two or more, preferably two members, and is used as a container body with a multiple structure in the process of distribution / storage, etc.
- One or more of them may be used as a sealing lid.
- the volume of the entire container can be reduced in the process of distribution / storage, and the capacity of the sealed container described later can be increased during use.
- FIGS. 2 (a) is a longitudinal sectional view of a double-structure airtight container, (b) is a perspective view thereof, and FIG. 3 shows a state in use.
- the sealed container may have means that can be expanded and contracted in the depth direction.
- the expansion and contraction is preferable because the volume of the entire container can be reduced in the process of distribution and storage, while the capacity of the sealed container can be increased during use.
- the amount of foam in the sealed container is reduced during use, it is preferable because the foam in the container body can be easily taken out by contracting the expansion / contraction means.
- the foam in an airtight container can be discharged from the discharge outlet mentioned later by contracting an expansion-contraction means, it is preferable.
- the means that can be expanded and contracted in the depth direction may be provided in either or both of the container main body and the sealing lid, but from the viewpoint of ease of handling, it is preferable that the container main body has a means that can be expanded and contracted. Any means capable of expanding and contracting in the depth direction may be used, but a bellows structure is preferable because it can be easily expanded and contracted and the sealing property of the container can be secured.
- FIG. 4 shows an embodiment of a sealed container having a bellows structure as an extendable means. In FIG. 4, (a) shows a state during contraction and (b) shows a state during extension.
- the internal volume in the case of the airtight container which has a "stretchable means" shall say the volume when fully extended.
- the airtight container may have a discharge port at any position.
- the container body has means capable of expanding and contracting in the depth direction, it is preferable that the foam in the container body can be discharged from the discharge port by contracting the body.
- the position of the discharge port may be any of the sealed containers, but is preferably located on the sealed lid from the viewpoint of ease of taking out the bubbles.
- FIG. 5 shows an embodiment in which the sealed lid has a discharge port in a sealed container having a bellows structure.
- the material of the container body and the sealing lid is not particularly limited as long as it can be sealed without leaking the liquid mixture and has a strength that can withstand the formation of bubbles by shaking. Plastic, paper and the like are suitable.
- the airtight container is a container in which the liquid mixture of the respective agents is made into a uniform foam state by putting each agent into the sealed container and then shaking and holding it with a gloved hand. Moreover, as described above, it is preferable to have a corresponding capacity. Therefore, even when a user with a small hand shakes with a gloved hand, it is preferable that the surface has anti-slip means for both the vertical and horizontal directions so that the sealed container does not slip. .
- the anti-slip means may be concave, convex or irregular on the surface of the container, but preferably has a convex shape that can easily catch the belly of the finger when held.
- the bump of the convex is easily caught by the fingers when held, and is not painful, it is preferably 0.1 to 5 mm, more preferably 0.2 to 3 mm, and even more preferably 0.25 to 2.5 mm from the surface of the container. .
- the longitudinal section in the bulge direction is a droplet shape or a square shape.
- the anti-slip means may be on the entire side surface of the container surface or on a part thereof.
- the container body and sealing lid it should be at least in the container body from the viewpoint of being able to shake well, but from both the container body and the sealing lid from the viewpoint of opening and closing the lid with a gloved hand. Is more preferable.
- anti-slip means are shown below, but are not limited thereto. Moreover, they are not concepts that can be strictly distinguished from each other. A plurality of examples may be combined.
- -Concave shape A slipper's thumb is applied to an elliptical recess that is concave on the surface of the container. Since the thumb plays an important role in fixing the container, when the thumb is securely fixed, it becomes a non-slip means in both the vertical and horizontal directions.
- the size and depth are not particularly limited as long as the thumb is caught, but at least the size and the depth at which the belly of the thumb is caught are preferable.
- Point-like / elliptical / rectangular shape A single point-like / elliptical / rectangular protrusion is preferable because it prevents slipping in the vertical and horizontal directions by hooking the belly of the thumb. It is more preferable that the center spacing of the plurality of point-like projections is within 2 cm along the side of the container, since the hook of the thumb is stronger. It is preferable that the center interval of the dotted / ellipsoidal / rectangular protrusions is 8 to 15 cm along the side of the container, because it can be hooked between the belly of the thumb and other fingers.
- the diameter of the dot-like projection is preferably 1 mm to 1 cm, and more preferably 2 to 5 mm.
- the length of the oval / rectangular protrusion is preferably 2 mm to 3 cm, more preferably 5 mm to 1 cm.
- the maximum length direction may or may not be inclined with respect to the container vertical direction.
- -Straight line (1) A straight line having an inclination of ⁇ 20 to ⁇ 70 degrees with respect to the vertical direction of the container and having a total length of 1 to 12 cm can be prevented from slipping in both the vertical and horizontal directions. It is also preferable that a plurality of straight lines having the same inclination with respect to the longitudinal direction of the container are arranged at equal intervals or at non-equal intervals over one-sixteenth or more of the side surface of the container.
- a wavy line with a total length of 1 to 12 cm having an inclination of 0 to ⁇ 90 degrees with respect to the vertical direction of the container is preferable because it prevents slipping in both the vertical and horizontal directions. It is also preferable that a plurality of wavy lines having the same inclination with respect to the longitudinal direction of the container are arranged at equal intervals or non-equal intervals over one-sixteenth or more of the side surface of the container. It is also preferable that they are created equally.
- the period and wave height of the wavy line are preferably 5 mm to 6 cm, respectively. It is also preferable that they are arranged at positions where the belly of the thumb and the belly of other fingers hit each other.
- the width of the straight line is preferably 0.1 mm to 5 mm, more preferably 0.5 mm to 3 mm.
- -Handle A cup-like ring may be placed. Since the handle can be pinched, the container can be stably fixed, and it becomes a non-slip means in both the vertical and horizontal directions.
- ⁇ Strap or band Place a strap or band on a part of the container so that fingers or hands can be inserted.
- ⁇ Linear (2) (example of combination): One or more first straight lines with an inclination of ⁇ 0 to 90 degrees with respect to the vertical direction of the container and a total length of 1 to 12 cm, and ⁇ 20 to It is also preferable that one or more second straight lines having an inclination of 90 degrees are arranged over one-sixteenth or more of the side surface of the container, and are arranged uniformly over the entire side surface. That is also preferred.
- each of the first straight line and / or the second straight line is three or more.
- the interval between the first straight lines or the interval between the second straight lines may be equal intervals or non-equal intervals. It is also preferable that they are arranged at positions where the belly of the thumb and the belly of other fingers hit each other.
- the width of each straight line is preferably 0.1 mm to 5 mm, and more preferably 0.5 mm to 3 mm. FIG. 6 shows specific examples of these slip prevention means.
- the hair dyeing or decoloring kit of the present invention is mixed with the first agent, the second agent and the thickening composition by shaking, or the alkali agent, oxidizing agent, thickener and the like in the molded body and the medium.
- the foam of the mixed solution is formed while mixing. Therefore, from the viewpoint of promoting mixing, it is preferable to further include a stirrer as a component of the kit.
- the stirrer moves vigorously through the foam during shaking and shakes. After completion, it is preferable to sink immediately to the bottom of the container body.
- the specific gravity of the stirring bar is, 5.0 ⁇ 8.0g / cm 3, more 6.0 ⁇ 7.9g / cm 3, more preferably in the range of 7.0 ⁇ 7.8g / cm 3.
- the material having such a specific gravity include metals, and preferably iron and stainless steel.
- the material forming the stirrer may be dissolved in the hair dye.
- the stirrer is more preferably a metal coated with plastic. In this case, it is preferable that the average specific gravity of the whole stirring bar is in the numerical range.
- the shape of the stirrer is preferably a round shape or a football shape from the viewpoint of promoting mixing and obtaining a uniform and sufficient amount of bubbles.
- the number of stirrers used in the hair dyeing or decoloring kit is preferably 1 to 10, more preferably 2 to 5, and more preferably 3 to 4 from the viewpoint of promoting mixing and obtaining a uniform and sufficient amount of foam.
- the wearing time may be any time before that, but when the agent is added in step (a) Since hands may become dirty, it is preferable to wear gloves before performing step (a). Moreover, it is preferable to comb the hair in advance at any stage before the foam is applied to the hair. Thereby, since it becomes difficult to entangle hair during the process of foaming again at a process (e), there is no possibility that a liquid mixture may scatter. Moreover, it is not necessary to perform the blocking operation generally used by application of a hair dye composition, and it is preferable not to perform a blocking operation. Thereby, the operation of applying the foam of the mixed solution to the hair and the operation of foaming again become easy.
- No hair styling is applied to the hair to which the hair dye composition is applied, from the standpoint that hair can be dyed evenly, liquid dripping is prevented, and sufficient hair coloring effects are obtained. It is preferable. Moreover, it is preferable that it is dry hair from a viewpoint that a liquid mixture does not become thin and can be dyed evenly, liquid dripping is prevented, and sufficient hair dyeing effect is obtained. When washing hair immediately before the hair dyeing treatment, it is preferable to dry the hair before the hair dyeing treatment.
- each agent may be mixed by stirring in advance. However, at the time of shaking in step (c), which will be described later, the bubbles are mixed at the same time. Just do it. After step (a) is completed, it may take several minutes to 10 minutes to perform the subsequent steps.
- step (d) the reaction of the oxidation dye proceeds and the thickening of the system by the thickener progresses. From step (a) to step (d), it is preferable to proceed to the step of applying the foam of step (d) to the hair immediately after completion.
- the sealed container has the above-described anti-slip means.
- Step (b) This is a step in which after all of the agent is charged into the sealed container body, the sealed container body is sealed with a sealing lid. What is necessary is just to prevent the contents from overflowing when shaking in the step (c) described later, and if there is a sealing mechanism specific to the container, sealing may be performed according to that mechanism.
- Each agent added in step (a) may be mixed in advance, but from the viewpoint of simplifying the operation, it is preferable to mix them simultaneously by shaking.
- a tool may be used, but it is preferable to shake by hand from the viewpoint of simplifying the operation. Although it may be shaken with one hand, it is preferable to shake with both hands from the viewpoint of securely fixing the sealed container. Examples of the positions of both hands when fixing the container include the following cases.
- ⁇ One hand is the sealing lid
- the other hand is the bottom on the opposite side of the sealing lid '' or ⁇
- One hand is the It is preferable that the side face and the other hand be a sealing lid.
- the speed of shaking is preferably 1 to 6 reciprocations per second, more preferably 2 to 5 reciprocations, and even more preferably 3 to 4 reciprocations from the viewpoint of forming fine bubbles having a sufficient bubble volume.
- the width of shaking is preferably 5 to 50 cm, more preferably 10 to 40 cm, and even more preferably 20 to 30 cm.
- the number of shakes is preferably 5 to 60 reciprocations, more preferably 10 to 50 reciprocations, and even more preferably 20 to 40 reciprocations from the viewpoint of efficiently forming fine bubbles having a sufficient volume.
- the foam formed from the inside of the sealed container it may be transferred to another container using some means. In this case, after moving to another container, the foam is applied to the hair by some means.
- the foam may be scooped out from the inside of the closed container using a tool such as a comb or a brush, and then the foam may be applied to the hair using the tool.
- the foam may be scooped out from the inside of the closed container using a hand, and then the foam scooped in the hand may be applied to the hair as it is. It is preferable to use a hand because it is easy to apply and spread on the hair, and the amount of application at one time is too large and does not scatter, and the number of times of scooping is too small to increase.
- the time of foaming again may be after the foam has completely disappeared, in the middle of disappearance of the foam, or before the applied foam changes. Or it may be in the middle of application, even after it completes application to the whole range which wants to apply foam. That is, the process (d) may be completed after the process (d) is completed, or the process (e) may be performed between the processes (d).
- the viscosity of the mixed solution may decrease and the viscosity of the mixed solution may increase. After the foam disappears, dripping may occur if the viscosity is lowered, and if the viscosity is increased, it is difficult to foam again and it may be difficult to spread the agent.
- step (c) again after moving to step (d) means that the ratio between the amount of the contents and the volume of the sealed container changes, making it difficult to form appropriate foam
- step (c) is not performed after moving to the step (d) because the hand holding the container is more easily slippery. Therefore, from the viewpoint of eliminating the inconvenience due to the change in viscosity, it is more preferable to perform the step (e) while performing the step (d) and perform only the step (e) after the application of foam is completed.
- the re-foaming may be performed once continuously or may be repeated intermittently a plurality of times. It may be re-foamed every time the action of removing the foam from the closed container and applying to the hair is performed, but it may be re-foamed preferably every 2 to 10 times, more preferably every 3 to 5 times.
- the standing time is preferably 3 to 60 minutes, more preferably 5 to 45 minutes from the start of application of foam. After completion of standing, wash away the mixture. Then, after shampooing and rinsing as appropriate, the hair is washed and dried.
- a hair dye having the following formulation was prepared.
- the component whose concentration is not specified in the component name is the active amount.
- Formulation Example 1 ⁇ First agent (liquid) (mass%) Paraaminophenol 0.1 Toluene-2,5-diamine 0.046 5-Aminoorthocresol 0.23 Strong ammonia water (28%) 6.0 Ammonium bicarbonate 10.5 Alkyl (C10-16) glucoside 6.16 Laureth sulfate Na 2.7 Tricedes-9 0.5 Laureth-23 2.0 Myristyl alcohol 0.2 Propylene glycol 4.0 Ethanol 10.0 Polyquaternium 22 * 1 0.4 Polyquaternium 7 * 2 0.5 Ascorbic acid 0.4 Sulfite Na 0.5 EDTA-4Na 0.1 Fragrance 0.95 Purified water balance
- Second agent (liquid) (mass%) Hydrogen peroxide solution (35%) 16.3 Laureth sulfate Na 0.62 Cetearyl alcohol 0.48 Myristyl alcohol 0.28 Oxyquinoline sulfate 0.04 Etidronic acid 0.08 Amount of sodium hydroxide second agent adjusted to pH 3.5 Purified water balance
- Second agent 40 g: 60 g: 12 g PH of the mixture: 9.1
- the first agent, second agent, and third agent of this formulation are put in a cylindrical sealable plastic container with an inner diameter of 9 cm and a height of 14 cm at a time, 30 reciprocations at a rate of 3 times per second, 30 cm
- the foam was formed by shaking at a width of. All the liquids that were added turned into solid foam, and the liquid did not separate from the foam even after standing for about 10 minutes.
- a projection with a diameter of 3 mm and a height of 2 mm is arranged on the one-third portion of the side of the plastic container, and another projection of the same size is arranged at a position symmetrical to the projection. If the thumb belly and the index finger belly are hooked on the protrusion, the projection can be more suitably shaken.
- Formulation Example 2 A hair dye having the following formulation was prepared. ⁇ First agent (liquid) (mass%) Paraaminophenol 0.1 Toluene-2,5-diamine 0.046 5-Aminoorthocresol 0.23 Strong ammonia water (28%) 6.0 Ammonium bicarbonate 8.0 Monoethanolamine 2.4 Alkyl (C10-16) glucoside 2.0 Cocoyl glutamate Na 6.0 Laureth-6 acetate Na 2.0 Tricedes-9 0.5 Laureth-23 2.0 Myristyl alcohol 0.2 Propylene glycol 4.25 Ethanol 9.5 Polyquaternium 22 * 4 1.125 EDTA-4Na 0.1 Fragrance 0.95 Purified water balance
- Second agent liquid (mass%) Hydrogen peroxide solution (35%) 16.3 Stearyl trimonium chloride 0.84 Setes-40 0.55 Cetearyl alcohol 0.88 Myristyl alcohol 0.25 Oxyquinoline sulfate 0.04 Etidronic acid 0.08 Amount of sodium hydroxide second agent adjusted to pH 3.5 Purified water balance
- Second agent: Third agent 40 g: 60 g: 3 g PH of the mixture: 9.2 Viscosity of the liquid mixture of the first agent and the second agent: 15mPa ⁇ s Viscosity of liquid mixture of first agent, second agent and third agent: 350 mPa ⁇ s
- the container used and the foam formation method are the same as in Formulation Example 1.
- the foam When the foam is pressed against the hair, it is easy to handle and has good foaming that can easily penetrate to the base of the hair.
- Formulation Example 3 The same hair dye as in Formulation Example 2 was prepared, except that 17.1 g was used instead of the third agent in Formulation Example 2. ⁇ Third agent (gel) (mass%) Hydroxyethyl cellulose * 6 6.4 Purified water balance
- Formulation Example 4 The same hair dye as in Formulation Example 2 was prepared except that 19.3 g was used instead of the third agent in Formulation Example 2 as follows. ⁇ Third agent (gel) (mass%) Hydroxyethyl cellulose * 7 17.1 Purified water balance
- Viscosity of the liquid mixture of the first agent and the second agent 15mPa ⁇ s
- a hair dye having the following formulation is prepared.
- First agent prowder
- Toluene sulfate-2,5-diamine 2.5 Metaaminophenol sulfate 1.25 Paraaminophenol sulfate 1.25 Resorcinol 1.25 Sodium carbonate 50.0 HEDTA-3Na 2.5 ⁇ -cyclodextrin 6.25 Ammonium sulfate 12.5 Lauryl sulfate Na 1.25 Stearic acid Mg 1.25 Sodium sulfate balance
- Second agent 20 g: 125 g: 5 g
- Favorable foam can be formed by the container used in Formulation Example 1, and good hair dyeing results can be obtained.
- Formulation Example 6 According to the procedure described in Example 1 of Japanese translation of PCT publication No. 2003-518028, 25 tablets of 4 g of hair dyed body are produced. Into the sealed container used in Formulation Example 1, 100 g of purified water and 25 tablets of the hair-dyed product to be produced are put at a time, foamed by shaking 30 times at a rate of 3 times per second, and a width of 30 cm. Form. All the composition to be added dissolves, and the resulting liquid becomes elastic and firm foam, and the liquid does not separate from the foam even if left for about 10 minutes. The foam to be formed is applied by scooping it from the container with a gloved hand and pressing it against a wig (No.755s Beaulux).
- Foaming is performed again by an operation such as shampooing at a rate of once every three times of scooping the foam and applying it to the hair. Allow all foam to form on the entire hair and leave for 30 minutes. Wash with water, shampoo, conditioner twice and dry. Even if a person who has never used a hair dye normally performs the above operation, a uniform and good result can be obtained by visual evaluation of the hair dyeing result by a specialized panelist.
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Abstract
Description
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤、増粘剤を含有する増粘用組成物の全てを、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤の両方を、表面に縦方向、横方向の両方向に対する滑り止め手段を有する開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤の両方を、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程
(e)前記適用した泡を毛髪上で再度泡立てる工程
(a)アルカリ剤、酸化剤及び増粘剤の三者が、同一の成型体中に又は別々の成型体中に含有されてなり、アルカリ剤と酸化剤とが別々の相中に存在する1又は複数の成型体と、媒体とを、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程
1)容器の構造が単純である
2)簡便に泡を形成できる
3)処方の自由度が高い
4)特許文献2の泡状染毛剤の利点である、慣れない人であっても簡単に毛髪にムラなく適用でき、仕上がりに色ムラが生じないという結果も得られる
5)剤の保存安定性にも優れている
6)染毛剤としての基本的な性能である染まり等も良好に得られる
という要求を全て同時に満足させる染毛又は脱色キットに関する。
本発明の染毛又は脱色キットの態様としては、二剤式、三剤式及び複合成型体式が挙げられ、
●二剤式としては、
・アルカリ剤と増粘剤を含有する第1剤と、酸化剤を含有する第2剤からなるもの
・アルカリ剤を含有する第1剤と、酸化剤と増粘剤を含有する第2剤からなるもの
●三剤式としては、
・アルカリ剤を含有する第1剤と、酸化剤を含有する第2剤と、増粘剤を含有する増粘用組成物からなるもの
・アルカリ剤と増粘剤を含有する第1剤と、酸化剤を含有する第2剤と、増粘剤を含有する増粘用組成物からなるもの
・アルカリ剤を含有する第1剤と、酸化剤と増粘剤を含有する第2剤と、増粘剤を含有する増粘用組成物からなるもの
を例示することができる。
●複合成型体式としては、
・同一の成型体中にアルカリ剤と増粘剤を含有する相と、酸化剤を含有する相を有するもの
・同一の成型体中にアルカリ剤を含有する相と、酸化剤と増粘剤を含有する相を有するもの
・同一の成型体中にアルカリ剤と増粘剤を含有する相と、酸化剤と増粘剤を含有する相を有するもの
・同一の成型体中にアルカリ剤を含有する相と、酸化剤を含有する相と、増粘剤を含有する相を有するもの
・同一の成型体中にアルカリ剤を含有する相と、酸化剤を含有する相を有し、別途増粘剤を含有する成型体と組み合わせて用いるもの
・アルカリ剤と増粘剤を含有する第1剤と、酸化剤を含有する第2剤からなる二剤式のもの
・アルカリ剤を含有する第1剤と、酸化剤を含有する第2剤と、増粘剤を含有する増粘用組成物からなる三剤式のもの
・同一の成型体中にアルカリ剤と増粘剤を含有する相と、酸化剤を含有する相を有するもの
のいずれかの態様が好ましい。
本発明において、毛髪とは頭に生えた状態の毛髪(頭髪)であっても、他の部分に生えている毛髪であってもよいが、頭髪であることが好ましい。また毛髪であれば、人形や、どのような動物のものであってもよいが、人間の頭髪が好ましい。
本発明において増粘剤とは、第1剤と第2剤との混合液、第1剤と第2剤と増粘用組成物との混合液、又は成型体と媒体の混合液を増粘する成分である。二剤式又は三剤式の場合には、第1剤、第2剤のいずれかに含有させることもでき、また第1剤、第2剤とは別個に、増粘用組成物に含有させることもできる。複合成型体式の場合には、当該成型体中のアルカリ剤を含有する相、酸化剤を含有する相のいずれに含有させることもでき、またこれらとは別の相に含有させることも、別の成型体に含有させることもできる。
合成高分子としては、例えば、カーボマー(例えば、住友精化社アクペックHV-501)、アクリレーツコポリマー(例えば、ロームアンドハース社アキュリン33ポリマー、BASF社ルビフレックスソフト)、(PEG-150/ステアリルアルコール/SMDI)コポリマー(例えば、ロームアンドハース社アキュリン46、アキュリン46B)、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体(例えば、ナルコ社マーコート100、マーコート550)、ビニルピロリドン・ジメチルアミノエチルメタクリレート共重合体(例えば、アイエスピー社コポリマー845、コポリマー937、コポリマー958)等が挙げられる。
半合成高分子としては、例えば、塩化o-[2-ヒドロキシ-3-(ラウリルジメチルアンモニオ)プロピル]ヒドロキシエチルセルロース(例えば、ダウ・ケミカル日本社UCARE Polymer JR-125、JR-30M、JR-400、ライオン社レオガードG)、塩化o-[2-ヒドロキシ-3-(トリメチルアンモニオ)プロピル]グアーガム(例えば、大日本住友製薬社ラボールガムCG-M、ラボールガムCG-6L、ラボールガムCG-M7、ラボールガムCG-M8M、ローディア社ジャグアーC-13S、ジャグアーC-14S、ジャグアーC-17、ジャグアーC-210、ジャグアーC-162、HI-CARE1000)、カチオン化デキストラン、メチルセルロース(例えば、信越化学社メトローズSM)、ヒドロキシエチルセルロース(例えば、ダウ・ケミカル日本社セロサイズQP4400H、QP52000H、ダイセル化学工業社SE-600、SE-850)、ヒドロキシプロピルセルロース(例えば、日本曹達社日曹HPC-H、HPC-M)、ヒドロキシプロピルメチルセルロース(例えば、信越化学社メトローズ60SHシリーズ、メトローズ65SHシリーズ、メトローズ90SHシリーズ)、ヒドロキシプロピルキサンタンガム(例えば、大日本住友製薬社ラボールガムEX)、プルラン脂肪酸エステル等が挙げられる。
天然高分子としては、例えば、プルラン(例えば、林原商事社プルランPF-20、プルランPI-20)、キサンタンガム(例えば、大日本住友製薬社エコーガム)、カンテン(例えば、伊那食品工業社伊那寒天CS)、ジェランガム(例えば、大日本住友製薬社ケルコゲル)、コラーゲン(例えば、高研社マリブレンマスクSH)、アルギン酸(例えば、大日本住友製薬社アルギニックッアシッドHFD)、アラビアゴム(例えば、伊那食品工業社イナゲルアラビアガムCS)、グアーガム(例えば、伊那食品工業社イナゲルグアーガムCS)、ローカストビーンガム(伊那食品工業社イナゲルローカストビーンガムCS)等が挙げられる。
1)単に密閉容器本体に各剤を投入した段階では、混合物は、増粘剤成分を含有する組成物に由来する領域(ゲル状、ゼリー状)と、残余の領域(液状)とを区別しうる混合状態となっている。
2)密閉容器を振って混合物に外力を加えると、増粘剤成分を含有する組成物に由来する領域(ゲル状、ゼリー状)は、崩壊・溶解することで次第に小さくなり、最終的には好適な混合状態となる。
・500mPa・s以下の場合 :ローターはM2、回転数は60rpm
・500mPa・sを超え4,000mPa・s以下の場合 :ローターはM3、回転数は30rpm
・4,000mPa・sを超え10,000mPa・s以下の場合 :ローターはM3、回転数は12rpm
・10,000mPa・sを超え100,000mPa・s以下の場合:ローターはM4、回転数は6rpm
本発明の染毛又は脱色キットの第1剤中、又は複合成型体の一つの相中にはアルカリ剤を含有する。アルカリ剤としては、例えば、アンモニア及びその塩(例えば、炭酸アンモニウム、炭酸水素アンモニウム等);エタノールアミン及びその塩(例えば、モノエタノールアミン、ジエタノールアミン等);イソプロパノールアミン、2-アミノ-2-メチルプロパノール、2-アミノブタノール等のエタノールアミン以外のアルカノールアミン及びその塩;1,3-プロパンジアミン等のアルカンジアミン及びその塩;炭酸グアニジン、炭酸ナトリウム、炭酸カリウム、炭酸水素グアニジン、炭酸水素ナトリウム、炭酸水素カリウム等の炭酸塩等が挙げられ、その中でもアンモニア、モノエタノールアミン、炭酸水素アンモニウムが好ましい。これらアルカリ剤は、2種以上併用してもよく、十分な脱色・染毛効果、及び毛髪損傷や施術中の刺激臭低減の点から、アンモニア又はその塩と、エタノールアミン又はその塩を組み合わせて用いるのが好ましい。
本発明の染毛又は脱色キットの第2剤中、又は複合成型体の一つの相中には酸化剤を含有する。酸化剤としては、過酸化水素、及び過酸化水素発生剤である過酸化尿素、過酸化メラミン、過ホウ酸ナトリウム、過ホウ酸カリウム、過炭酸ナトリウム、過炭酸カリウム等が挙げられる。第2剤が液体である場合は、過酸化水素が好ましく、第2剤が固体である場合や酸化剤が成型体に含まれる場合は、過酸化尿素が好ましい。
本発明の染毛又は脱色キットの第1剤、第2剤、増粘用組成物のうちいずれか1以上、又は複合成型体の1以上の相には、界面活性剤を含有させることができる。全ての界面活性剤の混合液中の合計濃度としては、泡立ちの良さ、及び毛髪に泡を適用した後に再度泡立てやすいものとする観点から、0.01~20質量%、更には0.1~15質量%、更には1~10質量%が好ましい。
本発明品が脱色キットである場合には、染料は含有せず、本発明品が染毛キットである場合には、第1剤中、又は複合成型体のアルカリ剤を含有する相中に酸化染料中間体又は直接染料を含有する。
酸化染料中間体としては、通常染毛剤に使用されている公知のプレカーサー及びカプラーを用いることができる。プレカーサーとしては、例えばパラフェニレンジアミン、トルエン-2,5-ジアミン、2-クロロ-パラフェニレンジアミン、N-メトキシエチル-パラフェニレンジアミン、N,N-ビス(2-ヒドロキシエチル)-パラフェニレンジアミン、2-(2-ヒドロキシエチル)-パラフェニレンジアミン、2,6-ジメチル-パラフェニレンジアミン、4,4′-ジアミノジフェニルアミン、1,3-ビス(N-(2-ヒドロキシエチル)-N-(4-アミノフェニル)アミノ)-2-プロパノール、PEG-3,3,2′-パラフェニレンジアミン、パラアミノフェノール、パラメチルアミノフェノール、3-メチル-4-アミノフェノール、2-アミノメチル-4-アミノフェノール、2-(2-ヒドロキシエチルアミノメチル)-4-アミノフェノール、オルトアミノフェノール、2-アミノ-5-メチルフェノール、2-アミノ-6-メチルフェノール、2-アミノ-5-アセタミドフェノール、3,4-ジアミノ安息香酸、5-アミノサリチル酸、2,4,5,6-テトラアミノピリミジン、2,5,6-トリアミノ-4-ヒドロキシピリミジン、4,5-ジアミノ-1-(4′-クロロベンジル)ピラゾール、4,5-ジアミノ-1-ヒドロキシエチルピラゾールとこれらの塩等が挙げられる。
直接染料としては、酸性染料、ニトロ染料、分散染料、塩基性染料等が挙げられる。酸性染料としては、青色1号、紫色401号、黒色401号、だいだい色205号、赤色227号、赤色106号、黄色203号、アシッドオレンジ3等が挙げられ、ニトロ染料としては、2-ニトロ-p-フェニレンジアミン、2-アミノ-6-クロロ-4-ニトロフェノール、3-ニトロ-p-ヒドロキシエチルアミノフェノール、4-ニトロ-o-フェニレンジアミン、4-アミノ-3-ニトロフェノール、4-ヒドロキシプロピルアミノ-3-ニトロフェノール、HCブルーNo.2、HCオレンジNo.1、HCレッドNo.1、HCイエローNo.2、HCイエローNo.4、HCイエローNo.5、HCレッドNo.3、N, N-ビス-(2-ヒドロキシエチル)-2-ニトロ-p-フェニレンジアミン等が挙げられ、分散染料としては、ディスパーズバイオレット1、ディスパーズブルー1、ディスパーズブラック9等が挙げられ、塩基性染料としては、ベーシックブルー99、ベーシックブラウン16、ベーシックブラウン17、ベーシックレッド76、ベーシックレッド51、ベーシックイエロー57、ベーシックイエロー87、ベーシックオレンジ31等が挙げられる。
本発明の染毛又は脱色キットにおいて、混合液の泡をしっかりした泡質のものとし、しかも髪の根元から毛先まで均一に染める観点から、混合液中に、油剤を0.01~3質量%含有するように処方することが好ましく、更には0.03~2.5質量%、更には0.05~2質量%含有させることが好ましい。
本発明における混合液は、媒体として、水及び必要により有機溶剤が使用される。有機溶剤としては、エタノール、2-プロパノール等の低級アルカノール;ベンジルアルコール、ベンジルオキシエタノール等の芳香族アルコール;プロピレングリコール、ジプロピレングリコール、1,3-ブタンジオール、ジエチレングリコール、グリセリン等の低級ポリオール;エチルセロソルブ、ブチルセロソルブ、ベンジルセロソルブ等のセロソルブ;エチルカルビトール、ブチルカルビトール等のカルビトールが挙げられる。かかる媒体は、二剤式又は三剤式の場合は、通常いずれかの剤が媒体を含有するため、各剤を混合することにより、各成分を所期の濃度で含有する混合液が形成される。一方、複合成型体式のように、製品中に媒体を含まない場合には、別途適切な量の媒体と共に混合することにより、各成分を所期の濃度で含有する混合液が形成される。
本発明で用いる第1剤、第2剤、増粘用組成物、複合成型体には、上記成分のほかに通常化粧品原料として用いられる他の成分を加えることができる。このような任意成分としては、動植物油脂、シリコーン、エーテル、蛋白誘導体、加水分解蛋白、アミノ酸、防腐剤、キレート剤、安定化剤、酸化防止剤、植物性抽出物、生薬抽出物、ビタミン、香料、紫外線吸収剤が挙げられる。
密閉容器の形状は、振とうすることで、内容物を泡立てることができる物ならどの様なものでもよい。密閉容器は、例えば容器本体と密閉蓋で構成され、この場合、容器本体と密閉蓋とは分離型であっても、非分離型(例えば、蝶番等により、本体と蓋とが分離することなく開平可能なもの)であってもよい。
なお、「伸縮可能な手段」を有する密閉容器の場合の内容量は、目一杯伸ばしたときの体積をいうものとする。
密閉容器は、各剤を投入し密閉した後に手袋をした手で持って振とうすることで各剤の混合液を均一な泡の状態とするものである。しかも前述のとおり、相応の容量を有することが好ましい。よって手の大きさが小さいユーザーが手袋をした手でにぎりながら振とうした場合でも、密閉容器が滑らないようにするため、表面に縦方向、横方向の両方向に対する滑り止め手段を有することが好ましい。滑り止め手段は、容器表面に凹であっても、凸であっても、凹凸を有するものであってもよいが、持ったときに指の腹が引っかかりやすい凸形状を有するのが好ましい。凸である場合の隆起は、持ったときに指の腹が引っかかりやすく、しかも痛くないという観点から、容器表面から0.1~5mm、更には0.2~3mm、更には0.25~2.5mmであるのが好ましい。隆起の形状は、隆起方向縦断面が液滴状又は方形であることが好ましい。
滑り止め手段は、容器表面の側面全体についていても、一部分についていてもよい。また容器本体、密閉蓋のうち、良好に振とうできる観点から少なくとも容器本体に有していればよいが、蓋の開閉も手袋をした手で行う観点から容器本体、密閉蓋の両方に有することがより好ましい。また、持つときに容器を確実に保持する観点から、少なくとも親指の腹が当たる位置に有することが好ましく、親指の腹とその他の指の腹が当たるそれぞれの位置に有することがより好ましい。
・凹状:容器表面に凹となる楕円形の窪みにきき手の親指をあてて滑り止めとする。親指は容器を固定する際に重要な役割を担うため、親指が確実に固定されると縦方向、横方向の両方向に対する滑り止め手段となる。親指が引っかかる窪みであれば大きさや深さは問わないが、少なくとも親指の腹が引っかかる大きさと深さであることが好ましい。
・点状/楕円状/長方形状:一つの点状/楕円状/長方形状突起は、親指の腹を引っかけて縦方向にも横方向にも滑り止めとなるので好ましい。複数の点状突起の中心間隔が容器側面に添って2cm以内であれば、親指の腹の引っかかりがより強くなるのでより好ましい。点状/楕円状/長方形状突起の中心間隔が容器側面に添って8~15cmであれば、親指の腹とそれ以外の指の腹で引っかけることができるので好ましい。点状突起の直径は1mm~1cmが好ましく、更には2~5mmであることが好ましい。楕円状/長方形状突起は、その最大部分の長さが2mm~3cmが好ましく、更には5mm~1cmであることが好ましい。最大長の方向は、容器鉛直方向に対して、傾きがあってもなくてもよい。
・直線状(1):容器鉛直方向に対し±20~±70度の傾きを持つ、全長1~12cmの直線も縦方向にも横方向にも滑り止めとなるので好ましい。複数の、容器縦方向に対して同じ傾きをもつ直線が、等間隔又は非等間隔に、容器側面の十六分の一周以上に亘って配置されていることも好ましい。親指の腹とその他の指の腹が当たるそれぞれの位置に配置されることも好ましい。直線の幅は0.1mm~5mmが好ましく、更には0.5mm~3mmがより好ましい。
・曲線状:容器鉛直方向に対し0~±90度の傾きを持つ、全長1~12cmの波線も縦方向にも横方向にも滑り止めとなるので好ましい。複数の、容器縦方向に対して同じ傾きをもつ波線が、等間隔又は非等間隔に、容器側面の十六分の一周以上に亘って配置されていることも好ましく、側面全周に亘って均等に作成されていることも同様に好ましい。波線の周期及び波高は、それぞれ5mm~6cmが好ましい。親指の腹とその他の指の腹が当たるそれぞれの位置に配置されることも好ましい。直線の幅は0.1mm~5mmが好ましく、更には0.5mm~3mmがより好ましい。
・取手状:コップの取手状の輪を配置してもよい。取手をにぎることができるようになるので、安定して容器を固定でき、縦方向、横方向の両方向に対する滑り止め手段となる。
・ストラップ状ないし帯状:容器の一部にストラップないし帯を配置して、手指又は手を入れられるようにする。ストラップないし帯により手指又は手がしっかりと固定されるように配置すると、縦方向、横方向の両方向への滑り止め手段となる。ストラップないし帯と容器との間に手がしっかりと固定されるように配置すると、縦方向、横方向の両方向への滑り止め手段となる。
・直線状(2)(組み合わせの例):容器鉛直方向に対し±0~90度の傾きを持つ、全長1~12cmの第一の直線1本又は2本以上と、それに対して±20~90度の傾きを持つ第二の直線1本又は2本以上が、容器側面の十六分の一周以上に亘って配置されていることも好ましく、側面全周に亘って均等に配置されていることも同様に好ましい。親指の腹とその他の指の腹が当たるそれぞれの位置に配置されることも好ましい。第一の直線及び/又は第二の直線は、それぞれ3本以上であることがより好ましい。第一の直線同士の間隔又は第二の直線同士の間隔は、等間隔であっても非等間隔であってもよい。親指の腹とその他の指の腹が当たるそれぞれの位置に配置されることも好ましい。直線の幅はそれぞれが0.1mm~5mmが好ましく、更には0.5mm~3mmがより好ましい。
図6に、これら滑り止め手段の具体例を示す。
本発明の染毛又は脱色キットは、振とうすることにより第1剤、第2剤及び増粘用組成物を混合しながら、又は成型体中のアルカリ剤、酸化剤、増粘剤等と媒体を混合しながら、混合液の泡を形成するものである。従って、混合を促進させる観点から、キットの構成要素として更に攪拌子を含むことも好ましい。
本発明の染毛又は脱色キットを使用して毛髪(特に頭髪)を染色又は脱色するには、次の工程(a)~(d)又は工程(a)~(e)を行うのが好ましい。
(a)アルカリ剤を含有する第1剤と酸化剤を含有する第2剤(存在する場合には、更に増粘用組成物)とを、又はアルカリ剤、酸化剤及び増粘剤を前述した形態で含有する成型体と媒体とを、開閉可能な密閉容器本体に投入する工程
(b)密閉容器を密閉する工程
(c)密閉容器を振とうして泡を形成する工程
(d)形成した泡を取り出して毛髪に適用する工程
(e)適用した泡を毛髪上で再度泡立てる工程
・片手を密閉蓋、もう一方の手を密閉蓋と反対側の底面
・片手を容器本体の側面、もう一方の手を密閉蓋
・両手とも容器本体の側面
振とうする際に容器が手から脱落したり、振とう中に万一蓋が開いて内容物が飛び散ることを防止する観点から、「片手を密閉蓋、もう一方の手を密閉蓋と反対側の底面」あるいは「片手を容器本体の側面、もう一方の手を密閉蓋」とすることが好ましい。
工程(c)が完了したら、密閉蓋を開けて、工程(d)に進む。
密閉容器の内部から形成した泡を取り出す際には、何らかの手段を用いて別の容器に移してもよい。この場合には別の容器に移した後、何らかの手段で毛髪に泡を適用することになる。あるいはくしやブラシといった道具を用いて密閉容器の内部から泡をすくい取って、その後、当該道具を用いて毛髪に泡を適用してもよい。あるいは手を用いて密閉容器の内部から泡をすくい取って、その後、手にすくい取った泡をそのまま毛髪に適用してもよい。毛髪に適用して広げる操作が行いやすく、1回の適用量が多すぎて飛び散ることもなく、少なすぎてすくい取る回数が多くなることもない点から、手を用いることが好ましい。
放置完了後は、混合液を洗い流す。その後、適宜シャンプーやリンスをした後水洗して、髪を乾燥させる。
処方例1
●第1剤(液状) (質量%)
パラアミノフェノール 0.1
トルエン-2,5-ジアミン 0.046
5-アミノオルトクレゾール 0.23
強アンモニア水(28%) 6.0
炭酸水素アンモニウム 10.5
アルキル(C10-16)グルコシド 6.16
ラウレス硫酸Na 2.7
トリセデス-9 0.5
ラウレス-23 2.0
ミリスチルアルコール 0.2
プロピレングリコール 4.0
エタノール 10.0
ポリクオタニウム22*1 0.4
ポリクオタニウム7*2 0.5
アスコルビン酸 0.4
亜硫酸Na 0.5
EDTA-4Na 0.1
香料 0.95
精製水 バランス
過酸化水素水(35%) 16.3
ラウレス硫酸Na 0.62
セテアリルアルコール 0.48
ミリスチルアルコール 0.28
硫酸オキシキノリン 0.04
エチドロン酸 0.08
水酸化Na 第2剤をpH3.5に調整する量
精製水 バランス
ヒドロキシプロピルキサンタンガム*3 2.0
エタノール 10.0
精製水 バランス
*2:マーコート550(Nalco社)
*3:ラボールガムEX(大日本住友製薬社)
各剤の使用量 第1剤:第2剤:第3剤=40g:60g:12g
混合液のpH:9.1
普段、染毛剤をあまり使ったことがない人に、形成した泡を、手袋をした手を用いて容器からすくい取ってウイッグ(No.755s ビューラックス社)に押し当てるようにして適用してもらい、すくい取って髪に適用する操作3回に1回の割合で、シャンプーをするような操作で再度泡立てを行う。形成した泡全てを髪全体に適用した後、30分間放置する。水洗、シャンプー、コンディショナー操作を2回行い、乾燥させた。染毛結果を専門パネラーによる目視評価を行うと、均一かつ良好な結果となる。
また、上記プラスチック容器の側面の、上から3分の1の部分に直径3mm、高さ2mmの突起を1つ、その突起と対称の位置に同じ大きさの突起をもう1つ配置し、当該突起に親指の腹と人差し指の腹を引っかけると、より好適に振とうすることができる。
以下に示す処方の染毛剤を調製した。
●第1剤(液状) (質量%)
パラアミノフェノール 0.1
トルエン-2,5-ジアミン 0.046
5-アミノオルトクレゾール 0.23
強アンモニア水(28%) 6.0
炭酸水素アンモニウム 8.0
モノエタノールアミン 2.4
アルキル(C10-16)グルコシド 2.0
ココイルグルタミン酸Na 6.0
ラウレス-6酢酸Na 2.0
トリセデス-9 0.5
ラウレス-23 2.0
ミリスチルアルコール 0.2
プロピレングリコール 4.25
エタノール 9.5
ポリクオタニウム22*4 1.125
EDTA-4Na 0.1
香料 0.95
精製水 バランス
過酸化水素水(35%) 16.3
ステアリルトリモニウムクロライド 0.84
セテス-40 0.55
セテアリルアルコール 0.88
ミリスチルアルコール 0.25
硫酸オキシキノリン 0.04
エチドロン酸 0.08
水酸化Na 第2剤をpH3.5に調整する量
精製水 バランス
メチルセルロース*5 100
*5:メトローズSM-4000(信越化学工業社)
各剤の使用量 第1剤:第2剤:第3剤=40g:60g:3g
混合液のpH:9.2
第1剤と第2剤との混合液の粘度 :15mPa・s
第1剤、第2剤、第3剤の混合液の粘度:350mPa・s
処方例2の第3剤を以下のものに変えて、17.1g使用した以外は、処方例2と同じ染毛剤を調製した。
●第3剤(ゲル状) (質量%)
ヒドロキシエチルセルロース*6 6.4
精製水 バランス
第1剤と第2剤との混合液の粘度 :15mPa・s
第1剤、第2剤、第3剤の混合液の粘度:1280mPa・s
混合液のpH:9.1
処方例2の第3剤を以下のものに変えて、19.3g使用した以外は、処方例2と同じ染毛剤を調製した。
●第3剤(ゲル状) (質量%)
ヒドロキシエチルセルロース*7 17.1
精製水 バランス
第1剤と第2剤との混合液の粘度 :15mPa・s
第1剤、第2剤、第3剤の混合液の粘度:8600mPa・s
混合液のpH:9.1
以下に示す処方の染毛剤を調製する。
●第1剤(粉末) (質量%)
硫酸トルエン-2,5-ジアミン 2.5
硫酸メタアミノフェノール 1.25
硫酸パラアミノフェノール 1.25
レゾルシン 1.25
炭酸Na 50.0
HEDTA-3Na 2.5
β-シクロデキストリン 6.25
硫酸アンモニウム 12.5
ラウリル硫酸Na 1.25
ステアリン酸Mg 1.25
硫酸Na バランス
過酸化水素水(35%) 8.2
ラウレス硫酸Na 2.7
硫酸オキシキノリン 0.04
エチドロン酸 0.08
水酸化Na液(48%) 0.056
精製水 バランス
ヒドロキシエチルセルロース*7 5.0
セルロースガム*8 80.0
硫酸Na バランス
*8:セロゲンP(第一工業製薬社)
各剤の使用量 第1剤:第2剤:第3剤=20g:125g:5g
特表2003-518028号公報の実施例1記載の手順に従って、4gの染毛成型体を25錠製造する。処方例1で用いた密閉容器に、精製水100gと製造する25錠の染毛成形体を一度に投入して、1秒間に3回の速度で30往復、30cmの幅で振とうして泡を形成する。投入する全ての組成物は溶解し、生じた液体は弾力性のあるしっかりとした泡になり、10分程度放置しても泡から液体が分離することはない。
形成する泡を、手袋をする手を用いて容器からすくい取り、ウイッグ(No.755s ビューラックス社)に押し当てるようにして適用する。泡をすくい取って髪に適用する操作の3回に1回の割合で、シャンプーをするような操作で再度泡立てを行う。形成する泡全てを髪全体に適用後、30分間放置する。水洗、シャンプー、コンディショナー操作を2回行い、乾燥させる。普段、染毛剤をあまり使ったことがない人が上記操作を行う場合でも、染毛結果を専門パネラーによる目視評価を行うと、均一かつ良好な結果となる。
Claims (44)
- アルカリ剤を含有する第1剤、酸化剤を含有する第2剤、増粘剤を含有する増粘用組成物、並びに第1剤、第2剤及び増粘用組成物を投入し振とうして混合液の泡を形成するための開閉可能な密閉容器を含む染毛又は脱色キット。
- 密閉容器の表面に縦方向、横方向の両方向に対する滑り止め手段を有する請求項1記載の染毛又は脱色キット。
- 増粘用組成物が、液状、ゲル状ないしゼリー状である請求項1又は2記載の染毛又は脱色キット。
- アルカリ剤を含有する第1剤、酸化剤を含有する第2剤、並びに第1剤及び第2剤を投入し振とうして混合液の泡を形成するための、開閉可能で表面に縦方向、横方向の両方向に対する滑り止め手段を有する密閉容器を含む染毛又は脱色キット。
- 第1剤、第2剤のいずれか少なくとも一方が、増粘剤を含み、かつ液状、ゲル状ないしゼリー状の組成物である請求項4記載の染毛又は脱色キット。
- 第1剤、第2剤、増粘用組成物のうちいずれか1以上に界面活性剤を含有する請求項1~5のいずれかに記載の染毛又は脱色キット。
- アルカリ剤、酸化剤及び増粘剤の三者が、同一の成型体中に又は別々の成型体中に含有されてなり、アルカリ剤と酸化剤とが別々の相中に存在する1又は複数の成型体と、かかる成型体及び媒体を投入し振とうして混合液の泡を形成するための開閉可能な密閉容器を含む染毛又は脱色キット。
- 成型体の1個当たりの質量が1~20gである請求項7記載の染毛又は脱色キット。
- いずれか1以上の成型体に界面活性剤を含有する請求項7又は8記載の染毛又は脱色キット。
- 界面活性剤の合計濃度が混合液中の0.01~20質量%である請求項6又は9記載の染毛又は脱色キット。
- 混合液の粘度が、50~20,000mPa・sである請求項1~10のいずれかに記載の染毛又は脱色キット。
- 混合液のpHが、7~12である請求項1~11のいずれかに記載の染毛又は脱色キット。
- 密閉容器の容器本体の概略形状が、回転柱体である請求項1~12のいずれかに記載の染毛又は脱色キット。
- 容器本体の開放口の内周が25~35cmである請求項1~13のいずれかに記載の染毛又は脱色キット。
- 密閉容器の容量が100~2000mLである請求項1~14のいずれかに記載の染毛又は脱色キット。
- 密閉容器が深さ方向に伸縮可能な手段を有する請求項1~15のいずれかに記載の染毛又は脱色キット。
- 伸縮可能な手段が蛇腹構造である請求項16記載の染毛又は脱色キット。
- 密閉容器のいずれかの位置に吐出口を有する請求項16又は17記載の染毛又は脱色キット。
- 吐出口が、密閉容器の蓋に位置する請求項18記載の染毛又は脱色キット。
- 更に攪拌子を含む請求項1~19のいずれかに記載の染毛又は脱色キット。
- 次の工程(a)~(d)を含む染毛又は脱色方法。
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤、増粘剤を含有する増粘用組成物の全てを、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程 - 密閉容器の表面に縦方向、横方向の両方向に対する滑り止め手段を有する請求項21記載の染毛又は脱色方法。
- 工程(a)における増粘用組成物が、液状、ゲル状ないしゼリー状である請求項21又は22記載の染毛又は脱色キット。
- 次の工程(a)~(d)を含む染毛又は脱色方法。
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤の両方を、表面に縦方向、横方向の両方向に対する滑り止め手段を有する開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程 - 工程(d)の後、更に工程(e)を行う請求項21~24のいずれかに記載の染毛又は脱色方法。
(e)前記適用した泡を毛髪上で再度泡立てる工程 - 次の工程(a)~(e)を含む染毛又は脱色方法。
(a)アルカリ剤を含有する第1剤、酸化剤を含有する第2剤の両方を、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程
(e)前記適用した泡を毛髪上で再度泡立てる工程 - 工程(a)における第1剤、第2剤のいずれか少なくとも一方が、増粘剤を含み、かつ液状、ゲル状ないしゼリー状である請求項24~26のいずれかに記載の染毛又は脱色方法。
- 第1剤、第2剤、増粘用組成物のうちいずれか1以上に界面活性剤を含有する請求項21~27のいずれかに記載の染毛又は脱色方法。
- 次の工程(a)~(d)を含む染毛又は脱色方法。
(a)アルカリ剤、酸化剤及び増粘剤の三者が、同一の成型体中に又は別々の成型体中に含有されてなり、アルカリ剤と酸化剤とが別々の相中に存在する1又は複数の成型体と、媒体とを、開閉可能な密閉容器本体に投入する工程
(b)前記密閉容器を密閉する工程
(c)前記密閉容器を振とうして混合液の泡を形成する工程
(d)前記形成した泡を密閉容器から取り出して毛髪に適用する工程 - 成型体の1個当たりの質量が1~20gである請求項29記載の染毛又は脱色方法。
- いずれか1以上の成型体に界面活性剤を含有する請求項29又は30記載の染毛又は脱色方法。
- 界面活性剤の合計濃度が混合液中の0.01~20質量%である請求項28又は31記載の染毛又は脱色方法。
- 混合液の粘度が、50~20,000mPa・sである請求項21~32のいずれかに記載の染毛又は脱色方法。
- 混合液のpHが、7~12である請求項21~33のいずれかに記載の染毛又は脱色方法。
- 密閉容器の容器本体の概略形状が、回転柱体である請求項21~34のいずれかに記載の染毛又は脱色方法。
- 容器本体の開放口の内周が25~35cmである請求項21~35のいずれかに記載の染毛又は脱色方法。
- 密閉容器の容量が100~2000mLである請求項21~36のいずれかに記載の染毛又は脱色方法。
- 密閉容器が深さ方向に伸縮可能な手段を有する請求項21~37のいずれかに記載の染毛又は脱色方法。
- 伸縮可能な手段が蛇腹構造である請求項38記載の染毛又は脱色方法。
- 密閉容器のいずれかの位置に吐出口を有する請求項38又は39記載の染毛又は脱色方法。
- 吐出口が、密閉容器の蓋に位置する請求項40記載の染毛又は脱色方法。
- 工程(d)における泡の取り出しが、密閉容器の伸縮手段を収縮させることにより吐出口から吐出させるものである請求項40又は41記載の染毛又は脱色方法。
- 工程(d)における泡の取り出しが手によるものである請求項21~39のいずれかに記載の染毛又は脱色方法。
- 工程(a)において、更に攪拌子を密閉容器本体に投入する請求項21~43のいずれかに記載の染毛又は脱色方法。
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Also Published As
Publication number | Publication date |
---|---|
EP2535036A1 (en) | 2012-12-19 |
EP2535036B1 (en) | 2017-11-29 |
JP2011184428A (ja) | 2011-09-22 |
CN102753134A (zh) | 2012-10-24 |
US20120305416A1 (en) | 2012-12-06 |
EP2535036A4 (en) | 2015-08-05 |
TW201136610A (en) | 2011-11-01 |
TWI471141B (zh) | 2015-02-01 |
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