WO2011069281A1 - 一种全氟离子交换树脂及其制备方法和应用 - Google Patents

一种全氟离子交换树脂及其制备方法和应用 Download PDF

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Publication number
WO2011069281A1
WO2011069281A1 PCT/CN2009/001432 CN2009001432W WO2011069281A1 WO 2011069281 A1 WO2011069281 A1 WO 2011069281A1 CN 2009001432 W CN2009001432 W CN 2009001432W WO 2011069281 A1 WO2011069281 A1 WO 2011069281A1
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WO
WIPO (PCT)
Prior art keywords
ion exchange
exchange resin
reaction
monomer
sulfonyl
Prior art date
Application number
PCT/CN2009/001432
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English (en)
French (fr)
Chinese (zh)
Inventor
张永明
秦胜
高自宏
张恒
魏茂祥
李勇
王军
Original Assignee
山东东岳神舟新材料有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 山东东岳神舟新材料有限公司 filed Critical 山东东岳神舟新材料有限公司
Priority to EP09851961.4A priority Critical patent/EP2511311B1/de
Priority to JP2012542328A priority patent/JP5577411B2/ja
Priority to US13/514,954 priority patent/US9023554B2/en
Priority to PCT/CN2009/001432 priority patent/WO2011069281A1/zh
Priority to CA2783850A priority patent/CA2783850C/en
Publication of WO2011069281A1 publication Critical patent/WO2011069281A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466—Monomers containing sulfur
    • C08F216/1475—Monomers containing sulfur and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • 3282875 is the first publication published by DuPont on the synthesis of sulfonyl fluoride monomer and the preparation of sulfonic acid resin.
  • the emulsion polymerization reaction in aqueous system is adopted.
  • US 3,560,568 is a patent published by DuPont for the preparation of short-side sulfonyl fluoride monomer, sulfonic acid resin and its properties.
  • the conditions of the ternary copolymerization reaction include: the reaction temperature may be 15-100 ° C, preferably 20-80 ° C, the reaction pressure is 2-10 MPa, preferably 2-6 MPa, the reaction time It can be from 1 to 10 hours, preferably from 2 to 8 hours.
  • the invention is a ternary copolymerization of tetrafluoroethylene (TFE) with two short-side sulfonyl fluoroether ether monomers having different structures to obtain a high molecular weight functional perfluoro ion exchange resin, and the terpolymer has high Chemical stability, high ion exchange capacity and good high temperature mechanical stability.
  • the perfluorinated ion exchange resin provided by the present invention still follows the rule that the smaller the ion exchange capacity and the greater the mechanical strength, the ion exchange capacity can reach 0.56 - 2.63 mmol / g (dry resin). Among them, the mechanical strength of the resin having an ion exchange capacity of 1.28-1.95 mmol/g exceeds 30 MPa.
  • the fluorine core magnetic integral value shows that the molecular weight of the tetrafluoroethylene monomer in the polymer structure is 81%.
  • the mole percentage of the sulfonyl fluoride side olefin ether monomer (I) is 10%
  • the mole percentage of the sulfonyl fluoride side olefin ether monomer (II) is 9.0%
  • the total ion exchange capacity is 1.33 mmol/g ( Dry resin).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
PCT/CN2009/001432 2009-12-11 2009-12-11 一种全氟离子交换树脂及其制备方法和应用 WO2011069281A1 (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP09851961.4A EP2511311B1 (de) 2009-12-11 2009-12-11 Perfluoriertes ionenaustauschharz, herstellungsverfahren und verwendung
JP2012542328A JP5577411B2 (ja) 2009-12-11 2009-12-11 パーフルオロイオン交換樹脂、その調製法および使用
US13/514,954 US9023554B2 (en) 2009-12-11 2009-12-11 Perfluorinated ion exchange resin, preparation method and use thereof
PCT/CN2009/001432 WO2011069281A1 (zh) 2009-12-11 2009-12-11 一种全氟离子交换树脂及其制备方法和应用
CA2783850A CA2783850C (en) 2009-12-11 2009-12-11 Perfluorinated ion exchange resin, preparation method and use thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2009/001432 WO2011069281A1 (zh) 2009-12-11 2009-12-11 一种全氟离子交换树脂及其制备方法和应用

Publications (1)

Publication Number Publication Date
WO2011069281A1 true WO2011069281A1 (zh) 2011-06-16

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2009/001432 WO2011069281A1 (zh) 2009-12-11 2009-12-11 一种全氟离子交换树脂及其制备方法和应用

Country Status (5)

Country Link
US (1) US9023554B2 (de)
EP (1) EP2511311B1 (de)
JP (1) JP5577411B2 (de)
CA (1) CA2783850C (de)
WO (1) WO2011069281A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
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CN111097553A (zh) * 2019-11-26 2020-05-05 南京源泉环保科技股份有限公司 一种处理氰化镀镉废水的固体材料及其制作方法与应用

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EP2511311B1 (de) 2009-12-11 2013-11-27 Shandong Huaxia Shenzhou New Material Co., Ltd. Perfluoriertes ionenaustauschharz, herstellungsverfahren und verwendung
CA2784539C (en) * 2009-12-15 2015-06-30 Shandong Huaxia Shenzhou New Material Co., Ltd High exchange capacity perfluorinated ion exchange resin, preparation method and use thereof
EP3018157B1 (de) * 2013-07-03 2017-11-15 Asahi Glass Company, Limited Verfahren zur herstellung eines fluorhaltigen polymers
US9932480B2 (en) * 2014-07-03 2018-04-03 Toyota Motor Engineering & Manufacturing North America, Inc. PEG-assisted deposition of crack-free titania nanocrystalline coatings over Al flakes
KR102212936B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
KR102212933B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
KR102212938B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
KR102212934B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
KR102212937B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
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KR102212935B1 (ko) * 2019-07-12 2021-02-05 (주)상아프론테크 과불소계 술폰화 이오노머 제조용 조성물, 이를 이용한 과불소계 술폰화 이오노머, 이를 포함하는 pemfc용 복합 전해질막 및 이를 포함하는 pemfc용 막-전극 접합체
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CN115490798A (zh) * 2022-09-28 2022-12-20 国家电投集团氢能科技发展有限公司 抗氧化离子交换树脂及其制备方法和全氟离子交换膜

Citations (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2393967A (en) 1942-12-24 1946-02-05 Du Pont Process for polymerizing tetrafluoroethylene
US3041317A (en) 1960-05-02 1962-06-26 Du Pont Fluorocarbon sulfonyl fluorides
GB1034197A (en) 1963-09-13 1966-06-29 Du Pont Sulphonic acid derivatives of fluorocarbon vinyl ethers, and polymers thereof
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3560568A (en) 1968-11-26 1971-02-02 Du Pont Preparation of sulfonic acid containing fluorocarbon vinyl ethers
EP0031724A2 (de) 1979-12-27 1981-07-08 E.I. Du Pont De Nemours And Company Verstärkte Membranen, Verfahren und Vorrichtung zu ihrer Herstellung und ihre Verwendung als Ionenaustauschermembranen in der Chloralkali-Elektrolyse oder als Katalysatoren
US4789717A (en) 1986-04-29 1988-12-06 Ausimont S.P.A. Process for the polymerization in aqueous dispersion of fluorinated monomers
US4864006A (en) 1986-06-26 1989-09-05 Ausimont S.P.A. Process for the polymerization in aqueous dispersion of fluorinated monomers
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5082472A (en) 1990-11-05 1992-01-21 Mallouk Robert S Composite membrane for facilitated transport processes
US5246792A (en) 1991-09-13 1993-09-21 Tanaka Kikinzoku Kogyo K.K. Structure of ion exchange membrane
US5608022A (en) 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
CN1147567A (zh) * 1995-07-10 1997-04-16 旭硝子株式会社 电解用的阳离子交换膜和生产高纯度氢氧化钾的方法
US5654109A (en) 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US5981097A (en) 1996-12-23 1999-11-09 E.I. Du Pont De Nemours And Company Multiple layer membranes for fuel cells employing direct feed fuels
EP1091435A1 (de) 1998-05-13 2001-04-11 Daikin Industries, Ltd. Material für festen polyelektrolyten, geeignet für die verwendung in brennstoffzellen
EP1172382A2 (de) 2000-06-23 2002-01-16 Ausimont S.p.A. Polymerisationsverfahren von sulphonischen Monomeren
US20020014405A1 (en) 2000-06-23 2002-02-07 Ausimont S.P.A. Fluorinated Ionomers
US6639011B2 (en) 2001-12-21 2003-10-28 Ausimont S.P.A. Polymerization process of sulphonic monomers
US6680346B1 (en) 1999-04-15 2004-01-20 Mirane Corporation Phosphorus atom-containing fluorinated cation exchange membrane and proton conduction type fuel cell using the same
WO2004007576A1 (ja) * 2002-06-14 2004-01-22 Daikin Industries, Ltd. 含フッ素共重合体製造方法、含フッ素共重合体及び成形体
JP2006083342A (ja) * 2004-09-17 2006-03-30 Asahi Glass Co Ltd スルホン酸型官能基を有するパーフルオロカーボン重合体の製造方法、およびイオン交換膜の製造方法
WO2008046816A1 (en) * 2006-10-17 2008-04-24 Solvay Solexis S.P.A. Process for stabilizing fluoropolymer having ion exchange groups
CN101220120A (zh) * 2007-01-12 2008-07-16 山东东岳神舟新材料有限公司 带有磺酰氟及醚端基侧基的氟树脂及其合成方法与应用
US20090227749A1 (en) * 2008-03-05 2009-09-10 Asahi Glass Company, Limited Process for producing perfluorocarbon polymer

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3884885A (en) 1973-08-01 1975-05-20 Du Pont Melt processing of fluorinated polymers
US4316192A (en) 1979-11-01 1982-02-16 The Bendix Corporation Beam forming network for butler matrix fed circular array
US4417969A (en) 1980-06-11 1983-11-29 The Dow Chemical Co. Sulfonic acid electrolytic cell membranes
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4453991A (en) * 1981-05-01 1984-06-12 E. I. Du Pont De Nemours And Company Process for making articles coated with a liquid composition of perfluorinated ion exchange resin
IT1184149B (it) 1985-03-11 1987-10-22 Montefluos Spa Processo per la preparazione di fluorossi-alo-composti
US4661411A (en) 1986-02-25 1987-04-28 The Dow Chemical Company Method for depositing a fluorocarbonsulfonic acid polymer on a support from a solution
IT1229510B (it) 1989-01-27 1991-09-03 Ausimont Srl A M Procedimento per la preparazione di alfa bromoalcilfluoruri.
CA2096304C (en) 1993-05-14 1998-08-11 Antti-Jussi Tiitola Replaceable hockey stick components
US5718947A (en) 1995-03-14 1998-02-17 The Dow Chemicalcompany Processes for forming thin, durable coatings of cation-containing polymers on selected substrates
WO2002103083A1 (en) * 2001-06-15 2002-12-27 Asahi Glass Company, Limited Fluorine-containing cation-exchange membrane and electroytic soda process
US6861489B2 (en) 2001-12-06 2005-03-01 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US7094851B2 (en) 2001-12-06 2006-08-22 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
JP5103024B2 (ja) * 2003-09-10 2012-12-19 旭化成イーマテリアルズ株式会社 安定化フルオロポリマー
US7265162B2 (en) 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
CN102127180B (zh) * 2006-02-03 2012-10-17 大金工业株式会社 含有-so3h基的含氟聚合物
CA2673069C (en) * 2006-12-22 2016-06-21 Vincenzo Arcella Process for operating a fuel cell in dry conditions
GB0714361D0 (en) 2007-07-24 2007-09-05 3M Innovative Properties Co Cation conductive membranes comprising polysulfonic acid polymers and metal salts having an F-containing anion
CN101698654B (zh) 2009-10-26 2010-11-10 山东东岳神舟新材料有限公司 本体催化法制备功能性含氟单体
CN101696178B (zh) 2009-10-26 2010-10-06 山东东岳神舟新材料有限公司 一类氟烯烃的制备方法
CN101712639B (zh) 2009-11-13 2013-09-25 山东华夏神舟新材料有限公司 立管式催化反应制备功能性含氟单体
EP2511311B1 (de) 2009-12-11 2013-11-27 Shandong Huaxia Shenzhou New Material Co., Ltd. Perfluoriertes ionenaustauschharz, herstellungsverfahren und verwendung
CN101709101B (zh) 2009-12-15 2011-09-07 山东东岳神舟新材料有限公司 高交换容量全氟离子交换树脂及其制备方法和用途

Patent Citations (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2393967A (en) 1942-12-24 1946-02-05 Du Pont Process for polymerizing tetrafluoroethylene
US3041317A (en) 1960-05-02 1962-06-26 Du Pont Fluorocarbon sulfonyl fluorides
GB1034197A (en) 1963-09-13 1966-06-29 Du Pont Sulphonic acid derivatives of fluorocarbon vinyl ethers, and polymers thereof
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3560568A (en) 1968-11-26 1971-02-02 Du Pont Preparation of sulfonic acid containing fluorocarbon vinyl ethers
EP0031724A2 (de) 1979-12-27 1981-07-08 E.I. Du Pont De Nemours And Company Verstärkte Membranen, Verfahren und Vorrichtung zu ihrer Herstellung und ihre Verwendung als Ionenaustauschermembranen in der Chloralkali-Elektrolyse oder als Katalysatoren
US4789717A (en) 1986-04-29 1988-12-06 Ausimont S.P.A. Process for the polymerization in aqueous dispersion of fluorinated monomers
US4864006A (en) 1986-06-26 1989-09-05 Ausimont S.P.A. Process for the polymerization in aqueous dispersion of fluorinated monomers
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5082472A (en) 1990-11-05 1992-01-21 Mallouk Robert S Composite membrane for facilitated transport processes
US5246792A (en) 1991-09-13 1993-09-21 Tanaka Kikinzoku Kogyo K.K. Structure of ion exchange membrane
US5608022A (en) 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
US5654109A (en) 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
CN1147567A (zh) * 1995-07-10 1997-04-16 旭硝子株式会社 电解用的阳离子交换膜和生产高纯度氢氧化钾的方法
US5981097A (en) 1996-12-23 1999-11-09 E.I. Du Pont De Nemours And Company Multiple layer membranes for fuel cells employing direct feed fuels
EP1091435A1 (de) 1998-05-13 2001-04-11 Daikin Industries, Ltd. Material für festen polyelektrolyten, geeignet für die verwendung in brennstoffzellen
US6680346B1 (en) 1999-04-15 2004-01-20 Mirane Corporation Phosphorus atom-containing fluorinated cation exchange membrane and proton conduction type fuel cell using the same
EP1172382A2 (de) 2000-06-23 2002-01-16 Ausimont S.p.A. Polymerisationsverfahren von sulphonischen Monomeren
US20020014405A1 (en) 2000-06-23 2002-02-07 Ausimont S.P.A. Fluorinated Ionomers
US6639011B2 (en) 2001-12-21 2003-10-28 Ausimont S.P.A. Polymerization process of sulphonic monomers
US6767977B2 (en) 2001-12-21 2004-07-27 Ausimont S.P.A. Fluorinated ionomers
WO2004007576A1 (ja) * 2002-06-14 2004-01-22 Daikin Industries, Ltd. 含フッ素共重合体製造方法、含フッ素共重合体及び成形体
JP2006083342A (ja) * 2004-09-17 2006-03-30 Asahi Glass Co Ltd スルホン酸型官能基を有するパーフルオロカーボン重合体の製造方法、およびイオン交換膜の製造方法
WO2008046816A1 (en) * 2006-10-17 2008-04-24 Solvay Solexis S.P.A. Process for stabilizing fluoropolymer having ion exchange groups
CN101220120A (zh) * 2007-01-12 2008-07-16 山东东岳神舟新材料有限公司 带有磺酰氟及醚端基侧基的氟树脂及其合成方法与应用
US20090227749A1 (en) * 2008-03-05 2009-09-10 Asahi Glass Company, Limited Process for producing perfluorocarbon polymer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2511311A4

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111097553A (zh) * 2019-11-26 2020-05-05 南京源泉环保科技股份有限公司 一种处理氰化镀镉废水的固体材料及其制作方法与应用
CN111097553B (zh) * 2019-11-26 2022-07-26 南京源泉环保科技股份有限公司 一种处理氰化镀镉废水的固体材料及其制作方法与应用

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EP2511311A1 (de) 2012-10-17
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